101. Photocatalytic degradation of acetone, acetaldehyde and toluene in gas-phase: Comparison between nano and micro-sized TiO2
- Author
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Valentina Crocellà, Alberto Naldoni, S. Gatto, V. Capucci, Carlo Pirola, Giuseppina Cerrato, A. Di Michele, and Claudia L. Bianchi
- Subjects
Acetaldehyde ,Photochemistry ,Catalysis ,Acetone ,Photocatalytic TiO2 ,chemistry.chemical_compound ,Photodegradation ,Toluene-Acetone-Acetaldehyde ,Reactivity (chemistry) ,Fourier transform infrared spectroscopy ,Nano-sized powder ,General Environmental Science ,VOC ,Process Chemistry and Technology ,VOCs Photodegradation ,Micro-sized powder ,Toluene ,chemistry ,Photocatalysis ,Degradation (geology) - Abstract
Volatile organic compounds (VOCs) are prevalent components of indoor air pollution. The photocatalytic degradation could be an interesting method to degrade them. This paper reports the photoactivity study of two classical nano-sized and two micro-sized commercial TiO 2 powdered samples. Photocatalytic tests have been performed following the degradation of acetone, acetaldehyde and toluene in the gas phase under UV light. An accurate study of the intermediate oxidation products was performed. XPS and FTIR analyses allowed to highlight the relationship between TiO 2 surface properties and reactivity toward VOCs explaining the different behavior of the photocatalyst in case of hydrophilic and hydrophobic pollutants.
- Published
- 2014