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A series of cobalt ferrite nanoparticles were prepared using hydrothermal process by varying the reaction temperature. The structural, magnetic and dielectric properties have been studied with the help of X-ray diffractometer (XRD), vibrating sample magnetometer (VSM) and impedance analyzer respectively. XRD spectra of all samples confirmed the formation of cobalt ferrite (CoFe2O4) nanoparticles (NPs). The lattice constant ‘a’ for temperature series samples is averaged around 8.4023 Å. Crystallite size of temperature series is calculated by Debye–Scherer formula that lies in the range of 15.04–20.49 nm. Its values increase because the chance of coalescence increases by increasing temperature. The maximum packing factor is obtained for the sample with highest reaction temperature. From VSM data, we get the M–H hysteresis curves for complete temperature series which confirms the magnetic nature. The maximum saturation magnetization 150.67 emu/g is obtained for the sample prepared at highest temperature. Different magnetic parameter such as saturation magnetization, coercivity, retentivity, squareness ratio, anisotropy constant and magneton number has been calculated from VSM data. AC response of all prepared ferrites was studied with impedance analyzer of frequency range 20 Hz to 20 MHz. Ferrites are the insulating materials, so, eddy current does not induce in transformer cores made of ferrite materials. In the medical field cobalt ferrite is used for drug delivery, as a biosensor and in MRI.

This paper focusses on the synthesis of cobalt vanadate (CoVO4) nanoparticles (NPs) by precipitation method. This was further augmented by assistance from microwave. Nanotechnology has been a wonderful tool with the promising application in different fields of life. The CoVO4 NPs synthesized by microwave assisted precipitation method was characterized by advanced techniques such as X-ray powder diffraction (XRD), Energy dispersive X-ray analysis (EDX), Scanning electron microscopy (SEM), Ultraviolet visible spectroscopy (UV–vis) techniques. Rhodamine B (RhB) dye was used to evaluate the photo catalytic activity (PCA) of NPs by degradation of dye. The conditions were optimized for maximum degradation of dye. The NPs were in the nano flowers form and the size was ≤100 nm. The results regarding degradation of RhB was through PCA were promising; 83% dye was degraded at pH 10, reaction time 160 min and catalyst dose 1 g. It may conclude that the synthesized NPs could further be employed for possible treatment of industrial effluents particularly textile industry.

In the present investigation, ZnO, CuO and Fe2O3 were prepared via green route and utilized for the sequestration of DGY (Direct Golden Yellow) dye. Affecting variables i.e., temperature, contact time, adsorbent dose and pH were optimized for maximum sequestration of dye from aqueous medium. The pH 2, adsorbent dose 0.1 g/50 mL dye solution, temperature 30 °C and 50 mg/L dye initial concentration were best levels for efficient dye adsorption and equilibrium was attained in 30 min reaction time. The dye sequestration on to ZnO, CuO and Fe2O3 was an exothermic process. Freundlich and Temkin adsorption isotherms explained well the dye adsorption onto nanoadsorbents and dye adsorption followed pseudo first order kinetic model. Effect of electrolytes and heavy metal ions was also investigated and both affected the adsorption process significantly. In the presences of surfactant/detergent, the removal of dye was reduced and 0.5 N NaOH efficiently desorbed the dye from nanoadsorbents. Findings depicted that the nanoadsorbents are effectual for the sequestration of DGY dye, which can be employed for the remediation of textile effluents.

This study focuses on evaluation of degradation aptitude of white rot fungus (Coriolus versicolor) against Indosol Turquoise FBL dye. The outcome of numerous parameters including pH, temperature, carbon sources, nitrogen sources, C/N ratio and effect of dye concentration were studied. Maximum decolorization (99.896%) of Indosol Turquoise FBL was obtained by C. versicolor under optimized conditions. After three days, the maximum dye degradation (98%) was observed at pH 4 and 30 °C. Six carbon sources fructose, glucose, maltose, sucrose, rice bran and wheat bran were used and 96.66% degradation was observed by maltose at its optimum growth concentration (0.1 g/100 mL). Various nitrogen sources were employed for decolorization but ammonium nitrate decolorized dye up to 98.05%. The activity of three different enzymes laccase, Lignin peroxidase (LiP) and Manganese peroxidase (MnP) were calculated. The dead biomass of White rot fungus (WRF) was used for biosorption experiments. Maximum q (36 mg/g) was obtained at pH 2, at 30 °C using 0.05 g biosorbent. An increase in the q value was observed with increase in dye concentration. Freundlich adsorption isotherm and pseudo second order kinetics were followed by the data. It can be concluded that C. versicolor could be an efficient source for degradation of dyes from industrial effluents.

Water gets polluted by industrial effluents, mainly composed of heavy metals and organic materials. Water soluble heavy metals can be taken up by living organisms. Chromium mainly occurs in the form of chromate and cationic hydroxo complexes in water. Apart from conventional methods of heavy metal removal, there are some novel approaches such as using dendrimers for removal of heavy metal. Dendrimers are extremely branched nano sized polymers with a three-dimensional symmetry around a core that imparts poly functionality. PAMAM (poly amido amine) dendrimers having ethylene diamine as core and methyl acrylate as repeating unit was divergently synthesized. Characterization of PAMAM dendrimers was evaluated by UV–Vis spectroscopy, zeta sizer, scanning electron microscopy (SEM) and Fourier-transform infrared (FT-IR) spectroscopy. Zero generation dendrimers have amine terminal groups, showed intense amide group peak at 1596.76 cm−1. The λ max value was 278 nm. SEM exhibited spherical shape for full generation while needle like structure for −0.5 generation. Evaluation of chromium removal from wastewater has been done by atomic absorption spectroscopy (AAS). The data revealed that optimal removal of Cr occurs at dendrimer concentration of 5 mL, Cr concentration of 300 ppm, contact time of 2 min and pH 7. The synthesized dendrimers have effectively removed Cr from tannery wastewater.

Wastewater treatment coagulation is one of the most important physicochemical operations used in industry. The adsorption capability of marigold leaf powder, tea waste and ferrous sulfate was investigated for domestic and tannery effluents. These adsorbents significantly affected the pH, electrical conductivity (EC) and turbidity of wastewater. Maximum decrease in all the attributes was observed for 10 g of adsorbents application. All the adsorbents significantly affected the physiochemical attributes of both wastewaters. Similarly, maximum adsorption potential was observed in case of tea waste powder. Maximum decrease in all physiochemical attributes such as pH (15%), EC (21%), turbidity (54%), total dissolved solids (TDS; 36%), total suspended solids (TSS; 43%), total hardness (TH; 52%), chloride contents (59%) and phosphate contents (60%) was observed with the application of 10 g of tea waste. Regarding the heavy metals, maximum decrease for cadmium (Cd; 47%), lead (Pb; 81%), arsenic (As; 44%), copper (Cu; 75%), iron (Fe; 49%), chromium (Cr; 68%) and zinc (Zn; 64%) was observed in same treatment. The decreasing order in terms of their adsorption potential for coagulants was tea waste > marigold leaf powder > ferrous sulfate. However, for the wastewater, the maximum effect of adsorbents was observed in case of domestic wastewater as compared to the tannery water. Based on these data, it is suggested that tea waste has maximum adsorption potential for the remediation of wastewater.

Pure and palladium (Pd) doped Diamond-like carbon (DLC) thin films have been deposited on glass substrates by using KrF Excimer laser having 248 nm wavelength. The doping concentration of Pd in DLC is 0%, 0.5%, 1.0%, 1.5% and 2.0%. Internal structure, surface morphology, mechanical and electrical characteristics have been carried out by Raman spectroscopy, scanning electron microscopy (SEM), Vickers hardening and four point probes, respectively. Using Raman spectra an improved graphitic behavior of DLC has been observed with increase of Pd contents. Some nano rods were observed at the surface of pure and Pd doped DLC thin films. With increase of Pd concentration in DLC, initially there is an accumulation of particles is observed and when the doping concentration is high i.e. at 2%, cracks formation takes place. The electrical resistivity is decreased by adding Pd into DLC thin films. Further, doping of Pd decreased the hardness of films. These characteristics of Pd doped DLC with increased hardness and electrical conductivity make it potential candidate for electronic devices. Also, doping enhance the graphitic behavior, therefore this material can be used for anti-bacterial and anti- cancerous activities.

A nanocomposite electrode, obtained by combining two high performance perovskite materials, such as lanthanum strontium cobalt ferrite, La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) and gadolinium doped ceria, Ce0.85Gd0.15O1.5 (GDC), were investigated as a promising cathode for moderate temperature solid oxide fuel cells (SOFCs). The synthesized material has good conductivity and catalytic performance. The purpose of this synthesis was to prepare a stable and highly performing nanocomposite cathode material. In this research work, LSCF and GDC were separately synthesized by co-precipitation and solid-state reaction method to gain a homogeneous perovskite phase. Varying concentrations of LSCF–GDC composite with GDC (10 wt.%, 20 wt.% and 30 wt.%) were synthesized followed by calcination at 600 °C to remove water content and to achieve an adequate porous structure for oxygen absorption and desorption. These fabricated LSCF, GDC, and the nanocomposite specimens were characterized for microstructure, particle size etc. via. X-ray diffraction method (XRD), scanning electron microscope (SEM) and the laser particle size analyzer. This procedural approach helps to expand new methods for generating bi-functional duel nano-sized perovskites with great performance and stability which can be utilized for advancement of renewable energy sectors especially for rechargeable fuel batteries.

In present investigation, organic manure was produced and characterized from liquorice residues using activated Effective Microoganism (AEM). The liquorice waste residues were fermented for the period of 6 months in the presence of activated AEM at the rate of 2.5% and 5% of total fermented mixture. Nitrogen (62.5 g) was used per 10 kg of liquorice and moister was maintained at 55–60% during fermentation. The AEM manure production efficiency was evaluated on the basis of pH, C/N ratio, electrical conductivity (EC) and mineral contents. The final pH of organic manure was 6.2, C/N ratio reduced from 13.5 to 6.5, EC and the mineral contents were increased of composted liquorice. Results revealed that the AEM are effective to produce organic manure from agricultural waste matter since the organic manure physico-chemical properties were within the permissible limit and AEM could be used for the production of compost liquorice. Moreover, this technique can also be extended to other agricultural waste materials for the production of organic manure.

Rapid industrialization is polluting the water resources and is becoming a serious environmental issue. In present study, the adsorption-desorption behavior of Direct Orange-26 (DO-26), Direct Red-31 (DR-31), Direct Blue-67 (DB-67) and Ever direct Orange-3GL (EDO-3) dyes on to native, modified rice husk (MRH), polyvinyl alcohol (PVA), carboxymethyl cellulose (CMC) and alginate (ALG) immobilized biomasses were investigated under different experimental conditions. For adsorbent modification, physical and chemical treatments were performed. The results showed that HCl pre-treatment considerably increased the sorption capacity of dyes versus native biomass. The sorption data were optimized using pseudo 1st order, intra-particle diffusion, pseudo 2nd order and Elovich models. The results revealed that the two-step rate equation was followed for the desorption kinetics of dyes. The involvement of -OH (hydroxyl), -COOH (carboxylic) and -NH2 (amino) groups in the adsorption of dyes onto biomasses was shown by FTIR analysis. Studies exhibited that among adsorbents employed, the MRH has the excellent potential for the dyes degradation from textile effluents.

This study focusses on the synthesis of carboxymethyl guar gum (CMG) via monochloroacetic acid under alkaline conditions. The reaction conditions were also optimized during the course of experiment. Guar derivative with variable degree of substitution (DS) were prepared and were confirmed by Fourier transform infrared (FTIR) spectroscopy. The DS was determined quantitatively by titration method for each derivative. The synthesized guar gum derivatives, being the natural thickners, have been used in textile printing technology. Substituted guar gum has been proved environmental friendly thickener as compared to synthetic thickeners. Penetration properties, fixation ability, colour fastness, levelness and fabric handling was compared with alginate thickener (commercially available). Guar gum thickeners showed enhanced properties versus alginate thickener and can be used as an alternative to synthetic thickeners in view of its green, non-hazardous and economical derivatives. Guar gum is the outstanding natural thickener, stabilizer, gelling agent and could possibly be used in various industrial units including food, cosmetic, textile, oil fracturing and mining.

In this study, different organic (moringa and neem leaf powder) and inorganic (alum) coagulants were used for the wastewater treatment. Results revealed that all the coagulants at various doses significantly affected the pH, electrical conductivity (EC) and turbidity of wastewater. The maximum decrease in all the attributes was observed when 10 g of coagulants were used. Similarly, maximum adsorption potential was observed in case of moringa leaf powder. Maximum decrease in all physiochemical attributes such as pH (13%), EC (65%), turbidity (75%), total dissolved solids (TDS; 51%), total suspended solids (TSS; 48%), total hardness (TH; 29%), chloride contents (66%) and phosphate contents (44%) was observed. Regarding the heavy metals, maximum decrease for Cadmium (Cd; 96%), Lead (Pb; 88%), Arsenic (As; 23%), Iron (Fe; 90%), Manganese (Mn; 96%) and Zinc (Zn; 48%) was observed in same treatment. The decreasing order in terms of their adsorption potential for coagulants was moringa leaf powder > Alum > neem leaf powder. However, the maximum effect of coagulants was observed in case of textile wastewater as compared to the hospital wastewater. Based on the analyses, it is concluded that the moringa leaf powder has maximum adsorption potential for the remediation of wastewater.

Currently, the green route for synthesis of silver nanoparticles (Ag NPs) using plants leaf extract is an emerging research area in nanotechnology. The present study was explored for synthesis, characterization and catalytic application of Ag NPs using Diospyros lotus fresh leaf extracts. Factors affecting the synthesis were optimized and optimum conditions were pH of 8.6, silver nitrate (AgNO3) concentration of 1.5 mM and 10 mL leaf extract. Formation of Ag NPs was observed by change in color of reaction mixture from pale yellow to reddish brown. The synthesized Ag NPs were characterized using UV-Vis spectrophotometer, EDX, XRD and SEM analyses. UV-Vis spectrophotometer showed maximum absorbance peak in the range of 407 nm at different time intervals indicating formation of Ag NPs. SEM and XRD analysis confirmed face centered cubic structure and crystalline nature of biologically synthesized Ag NPs with average particle size of 27 nm. The purity of synthesized Ag NPs was revealed by EDX. Finally, photo catalytic activity (PCA) of Ag NPs was studied and 72.91% decolorization of industrial waste water was obtained at 54 h. Some important parameters like pH, turbidity, conductance; TSS, TDS, sulphide, sulphates, etc. were also monitored before and after treatment with Ag NPs.

The study focusses on investigation of source rock generative characteristics and nature of crude oils from Upper Indus Basin (UIB), Pakistan. The source rock sediments and crude oil samples were g...

This study focuses on application of advanced oxidation (Photo-Fenton) processes to decolorize Basic Turquise Blue (BTB) X-GB 250% and Basic Blue (BB) X-GRRL 250% dyes. The percent decolorization was studied in terms of effect of variation in intensity of UV light at optimum conditions of all the parameters (pH = 3.0, H2O2 = 4.8 mM, FeSO4 = 1.6 mM, temperature = 50 °C, time = 80 min for BTB X-GB, and pH = 5.0, H2O2 = 5.6 mM, FeSO4 = 2.0 mM, temperature = 40 °C, time = 60 min for BB X-GRRL). Maximum decolorization was obtained at maximum intensity (15660 counts/min) of UV light as 96.17% for BTB X-GB and 88.48% for BB X-GRRL. First order, 2nd order and BMG kinetic models were used to analyze the data obtained for intensity of UV light. BMG model gives us the higher values of correlation coefficients for all data of both the dyes. The results have shown that Photo-Fenton oxidation process is the beneficial and effective for oxidation treatment of waste water effluents containing dyes as main pollutants.

Biosorption is one of the effective technique for removal of metals from aqueous solutions/industrial effluents. Present work is aimed to use low cost and ecofriendly material to remove the iron metal from aqueous solution which could possibly be used at industrial level. For this purpose, Bougainvillea spectabilis leaves were used for the production of charcoal. This charcoal was activated using HCl and HNO3. The AC shows promising efficiency for the adsorption of Fe II as a function of medium pH, contact time, adsorbent dose and temperature. Maximum adsorption was observed with 0.5–0.9 g adsorbent dose, 30 min contact time and at pH 3. Adsorption showed independence of temperature in the range of 30–70 °C. Among, Freundlich and Langmuir isotherms, the adsorbate followed Langmuir isothermal model. Among kinetics models, adsorbate followed pseudo second order kinetic model with R2 values of 0.9985 and 0.9996 for HCl treated and HNO3 treated AC, respectively. These data suggest that AC synthesized from Bougainvillea leaves proved to be an excellent adsorbent for the removal of iron metal from aqueous solution.

This case documents the governance challenges faced by Namal’s Board of Governors. Namal College (Namal) was the brainchild and dream project of Imran Khan—world-renowned cricketer, philanthropist and one of the most popular politicians of Pakistan. This case narrates the journey of Namal College from its inception in 2002 until August 2014. At this juncture, Abdul Razak Dawood (ARD), the Vice Chairman of Namal’s Board, contemplated the challenges that Namal faced and the role the Board and its members could play in taking the college closer to its vision. From its humble beginnings as a technical training and diploma-awarding institute, Namal managed to achieve several milestones in one decade of its existence. One of the most notable achievement was the acquisition of a 1,000-acre land. ARD, a graduate from Columbia University, a leading industrialist and the founder of one of Pakistan’s largest engineering company, Descon Engineering, wondered what would it take to create a high-powered and effective Board? ARD was concerned about addressing Namal’s challenges, which included governance, management, funding, academics and construction issues. The question was what role could the Board play in doing so? More explicitly, what role could each Board member play? Was there a possibility of creating committees within the Board to ensure efficient functioning and accountability? In sum, the case revolves around critical governance issues that needed to be addressed to ensure Namal’s sustainability and growth.

Reflected self-efficacy, defined as one's perception of how others assess one's ability to perform a task, may be a meaningful predictor of creative performance over and above self-assessed self-efficacy. We examined if reflected self-efficacy, compared to self-assessed self-efficacy, is a more meaningful predictor of creative performance. A sample of 141 Master of Business Administration students completed measures of self-efficacy, reflected self-efficacy, proactive social management, team trust, and creative performance. Results showed that reflected self-efficacy had superior incremental validity compared to self-assessed self-efficacy, and that reflected self-efficacy affected individual creativity via the mediator of proactive social engagement. This relationship was more pronounced when a focal team member's trust toward the team was low (vs. high). Our findings support the importance of the functions of social aspects of self-efficacy in enhancing individual creativity.

Nanotechnology is an art for application and handling of materials at very small scales i.e. 1–100 nm. The materials at this scale exhibit significantly different properties compared to same materials at larger scales. There are so many physical and chemical methods for the synthesis of nanoscale materials but the most appropriate are the ones that synthesize materials using green chemistry eco-friendly techniques. Recently, the collaboration between nanotechnology and biology has opened up new horizons of nanobiotechnology that integrates the use of biological materials in a number of biochemical and biophysical processes. This approach has significantly boosted up nanoparticles (NPs) production without employing harsh and toxic conditions and chemicals. This review is aimed to provide an outline of latest developments in synthesis of NPs through biotic entities and their potential applications.

In view of low cost and efficient adsorbents exploration, present study was aimed to evaluate the possibility of Pitpapra waste biomass (roots, leaves, stem) for adsorption of Zn (II) and Co (II) metals in single metal system (SMS) and binary metal system (BMS). The process variables were optimized for the maximum adsorption of metal ions. Pitpapra stem, leaves and root biomasses showed promising efficiency for the adsorption of Co (II) and Zn (II) ions and at optimized conditions of process variable, 225 mg/g and 230 mg/g of Co (II) and Zn (II) ions were removed from aqueous media, respectively. The behavior of Zn (II) in BMS changed, however, Co (II) did not show any change in BMS versus SMS. Freundlich isotherm fitted well to the adsorption data of Co (II) and Zn (II). In view of efficient adsorption of Co (II) and Zn (II) ions, the use of Pitpapra biomass is suggested for the adsorption of heavy metals from wastewater.

The potential of an economically cheap raw material (rice husk) was evaluated in the present study to remove dyes including reactive yellow 15 (RY15) and reactive red 241 (RR241) in single and multi-component systems. The adsorbent was modified and functionalized chemically using glycidoxypropyltrimethoxysilane, sulfur and silane to enhance the removal efficiency of pollutants. The modified rice husk was evaluated by scanning electron microscope (SEM) and Fourier transform Infrared Spectroscopy (FTIR). Batch adsorption study showed that the modified rice husk with silane graft (RHSi) had highest removal efficiency of both dyes with 20% more removal compared to raw rice husk. The sorption correlated well with Langmuir, Freundlich, SIPS and Redlich-Peterson models for adsorption. Highest sorption was obtained at 10 mg L−1 of dye, 50 °C, 200 mg g−1 of adsorbent dose and pH 4. The mixture of two dyes poorly fit to the original Langmuir but fit best to the Langmuir-like model. This indicates that competitive Langmuir-like model considers that the capacities of adsorbents are equal. Results showed that the components compete for the available binding sites on adsorbent surface. It was also indicated that silane grafting can offer comparatively more binding sites compared to the raw rice husk and single-solute isotherm parameters cannot used for multi-component solute system.

Nanoparticles (NPs) of Gd1−xMxCrO3 (M = La, Co, Bi) were synthesized by microemulsion techniques, involving simultaneous single ion substitution philosophy. Structural, magnetic, dielectric properties, morphology, elemental analysis and distribution size of fabricated nano-crystalline were determined. The techniques employed for investigation are X-ray diffraction (XRD), vibrating sample magnetometer (VSM), dielectric measurement and scanning electron microscopy (SEM), energy dispersive X-ray (EDX), photoluminescence (PL) and atomic force microscopy (AFM), respectively. XRD pattern confirm that all the as-synthesized NPs have orthorhombic structure and successfully substituted of different metal ions into the regular crystal structure of GdCrO3. The lattice parameters X-ray density, bulk density, porosity and grain size were calculated from XRD pattern of Gd1−xMxCrO3 (M = La, Co, Bi) substituted and un-substituted GdCrO3. The magnetic hysteresis loop of fabricated product confirmed that the entire sample exhibits ferromagnetic behavior at room temperature. It was also found that the fabricated NPs show excellent photocatalytic activity (PCA) against Congo-red, about 78.24% after 55 min of incubation.

Our nation's nursing home industry has been in need of overhaul for decades-a situation made all the more evident by COVID-19. AMDA-The Society for Post-Acute and Long-Term Care Medicine is dedicated to quality in post-acute and long-term care process and outcomes. This special article presents 5 keys to solving the COVID-19 crisis in post-acute and long-term care, related to policy, collaboration, individualization, leadership, and reorganization. Taking action during this crisis may prevent sinking back into the complacency and habits of our pre-COVID-19 lives.

With the COVID-19 pandemic progressing, guidance on strategies to mitigate its devastating effects in nursing facilities (NFs) is critical to preventing additional tragic outcomes. Asymptomatic spread of COVID-19 from nursing facility staff and residents is a major accelerator of infection. Facility-wide point-prevalence testing is an emerging strategy in disease mitigation. Because time is not available to await the results of randomized controlled trials before implementing strategies in this high-risk setting, an expert Delphi panel composed of experienced long-term care medicine professionals has now met to provide testing guidance for SARS-Coronavirus-2 to NFs. After many email and telephone discussions, the panel responded to a questionnaire that included six different scenarios, based on varying availability of Polymerase Chain Reaction (RT-PCR) testing and personal protective equipment (PPE). The panel endorsed facility-wide testing of staff and residents without dissent when diagnostic RT-PCR was available. While the panel recognized the limitations of RT-PCR testing, it strongly recommended this testing for both staff and residents in NFs that were either COVID-19 naive or had limited outbreaks. There was also consensus on testing residents with atypical symptoms in a scenario of limited testing capability. The panel favored testing every 1 to 2 weeks if testing was readily available, reducing the frequency to every month as community prevalence declined or as the collection of additional data further informed clinical critical thinking and decision-making. The panel recognized that frequent testing would have consequences in terms of potential staff shortages due to quarantine after positive tests and increased PPE use. However, the panel felt that not testing would allow new clusters of infection to form. The resulting high mortality rate would outweigh the potential negative consequences of testing. The panel also recognized the pandemic as a rapidly evolving crisis, and that new science and increasing experience might require an updating of its recommendations. The panel hopes that its recommendations will be of value to the long-term care industry and to policy makers as we work together to manage through this challenging and stressful time.