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In this work, we are reporting results on the electrodeposition of the CuInSe 2 thin films on molybdenum thin foil substrates. We have used an aqueous non-buffered electrolyte and a careful choice of deposition parameters to ensure a good quality and composition of the deposited films. In addition, CdS was replaced in the buffer layer with a wider bandgap Zn(S,O,OH) film obtained by chemical bath deposition. The deposited films were annealed in inert atmosphere at different temperatures. The influence of annealing temperature on the properties of the films is briefly discussed. Films were also characterized by photoelectrochemical and I-V measurements. Structural characterization was carried out by XRD and Raman spectroscopy. Results show the growth of good quality films with very uniform morphology and good chemical composition.

We report on the design and the electro-optical characterization of new classes of 4H-SiC Schottky UV detectors, fabricated employing Ni 2 Si interdigitated strips. We have measured, in dark conditions, the forward and reverse I-V characteristics as a function of temperature and C-V characteristics. Responsivity measurements of the devices, as function of wavelength in the UV range, of package temperature and of applied reverse bias are reported. We also compared devices featuring different strip pitch sizes, discussing their performances, and found the device exhibiting best results.

We report on backward second-harmonic generation using ps laser pulses in congruent lithium niobate with 3.2 µm periodic poling. Three resonant peaks were measured between 1530 and 1730 nm, corresponding to 16th, 17th and 18th quasi-phase-matching orders in the backward configuration, with a conversion efficiency of 4.75 x 10(-5%)/W for the 16th order. We could also discriminate the contributions from inverted domains randomized in duty-cycle.

We report on the design and the electro-optical characterization of a novel class of 4H-SiC vertical Schottky UV detectors, based on the pinch-off surface effect and obtained employing Ni2Si interdigitated strips. We have measured, in dark conditions, the forward and reverse I–V characteristics as a function of the temperature and the C–V characteristics. Responsivity measurements of the devices, as a function of the wavelength (in the 200 – 400 nm range), of the package temperature and of the applied reverse bias are reported. We compared devices featured by different strip pitch size, and found that the 10 μm device pitch exhibits the best results, being the best compromise in terms of full depletion and space-strip width ratio.

We performed a Signal to Noise Ratio characterization, in the continuous wave regime, at different bias voltages, frequencies and temperatures, on a novel class of silicon photomultipliers fabricated in planar technology on silicon p-type substrate. Signal to Noise Ratio has been measured as the ratio of the photogenerated current, filtered and averaged by a lock-in amplifier, and the Root Mean Square deviation of the overall current flowing to the device. The measured noise takes into account the shot noise, resulting from the photocurrent and the dark current. We have also performed a comparison between our SiPMs and a photomultiplier tube in terms of Signal to Noise Ratio, as a function of the temperature of the SiPM package and at different bias voltages. Furthermore, Excess Noise Factor measurements of the SiPM, as a function of the applied bias, are shown and discussed. Our results show the outstanding performance of this novel class of SiPMs even without the need of any cooling system.

 Abstract— We report on Signal-to-Noise Ratio measurements carried out, in the continuous wave regime, at different bias voltages, frequencies and temperatures, on a class of silicon photomultipliers fabricated in planar technology on silicon p- type substrate. Signal-to-Noise Ratio has been measured as the ratio of the photogenerated current, filtered and averaged by a lock-in amplifier, and the Root Mean Square deviation of the same current. The measured noise takes into account the shot noise, resulting from the photocurrent and the dark current. We have also performed a comparison between our SiPMs and a photomultiplier tube in terms of Signal-to-Noise Ratio, as a function of the temperature of the SiPM package and at different bias voltages. Our results show the outstanding performance of this class of SiPMs even without the need of any cooling system.

In this paper, a numerical analysis of relevant electrical parameters of multilayer structures for CIGS-based solar cells was carried out, employing the simulation software wxAMPS. In particular, we have focused on thin film cells having a ZnO:Al/ZnO/CdS/CIGS structure with a Molybdenum back contact. The aim of this work is to establish good theoretical reference values for an ongoing experimental activity, where our technology of choice is the single-step electrodeposition. In detail, we have analyzed how the main electrical properties change with the bang gap and the thickness of the absorber layer, for such a type of solar cell structure. Our results show that both efficiency and fill factor strongly depend on the energy gap. Instead, the absorber thickness plays a role up to a few microns, after which the cell parameters remain almost constant. As expected, the theoretical peak efficiency was found for a band gap value of 1.40 eV, corresponding to a Ga/(In+Ga) ratio of 0.66.

We report on our Signal-to-Noise Ratio (SNR) measurements carried out, in the continuous wave regime, at different frequencies and at various temperatures, on a novel class of silicon photomultipliers (SiPMs) fabricated in planar technology on silicon p-type substrate. SNR of SiPMs is given by the ratio of the photogenerated current, filtered and averaged by a lock-in amplifier, and the Root Mean Square (RMS) deviation of the same current. In our measurements, we have employed a 10 Hz equivalent noise bandwidth, around the lock-in amplifier reference frequency. The measured noise takes into account the shot noise, resulting from the photocurrent and the dark current, while background light is not present in our setup. We have found that the SNR is independent from frequency in the evaluated range 1 - 100 kHz. Our measurements highlight a quasi-flat trend of the SiPM SNR up to an overvoltage of about 5 V (with respect to the breakdown voltage of 28.0 V). At higher overvoltages (OV), we have observed a SNR decrease, mainly because of the strong increase of the shot noise. We have also performed a comparison between the SiPM and the PhotoMultiplier Tube (PMT) SNR as a function of the temperature of the SiPM package and at different bias voltages. Our results show the outstanding performance of this novel class of SiPMs even without the need of any cooling system. Indeed, their SNR is only a few dBs below the PMT SNR at room temperature. Furthermore, cooling the SiPM at a package cell temperature of 3 °C, it reaches the PMT SNR values at room temperature despite the SiPM is biased in the range 28.7 – 33.5 V, while the PMT has a bias value up to 950 V.

In this work, we have implemented a data recovery software integrating the most recent rateless codes, i.e., RaptorQ codes. Thanks to the above-mentioned software, it is possible to recover data loss occurring on several kinds of network conditions. We have performed a statistical analysis of failure probabilities at several configurations of RaptorQ parameters. We have found a good agreement with the theoretical values of a random linear fountain code over Galois Field GF(256). Moreover, we have shown that the probability of having a certain number of failed decoded source blocks - when sending a fixed size file - follows a Poisson distribution.

This paper analyzes how the electrical characteristics of a CIGS photovoltaic module are affected by the chemical composition and by the thickness variations of the CIGS absorber. The electrical characteristics here considered are the short circuit current, the open circuit voltage, the efficiency and the power peak. The chemical composition is varied by tuning the ratio between gallium and indium. This analysis has been performed by means of the wxAMPS software, developed by the University of Illinois. The above variations have been taken into account on a PV module made of 72 cells. This analysis has been carried out employing a PV module mathematical model developed and implemented by the Authors in Matlab environment.

Free Space Optics (FSO) links are affected by several impairments and, among them, optical turbulence is the most important factor that can degrade the link quality. Due to the presence of this phenomenon, the signal irradiance detected by the receiver fluctuates, thus causing erasure errors and fading events. In this work, we present an indoor Free Space Optics link, in which several turbulence conditions are generated by using two heating elements. We show that the generated turbulence causes erasure errors and packet losses during the data transmission, and we also compare the statistical distribution of the samples with the theoretical models. Moreover, we demonstrate how the application of the most recent rateless codes, i.e., RaptorQ codes, can strongly improve the link quality. In particular, results show that the Packet Error Rate strongly decreases when employing RaptorQ codes. Finally, we conclude that, by properly setting the encoding/decoding parameters, we can correctly receive the whole transmitted data without any errors.

Functional Near Infrared Spectroscopy (fNIRS) uses near infrared sources and detectors to measure changes in absorption due to neurovascular dynamics in response to brain activation. The use of Silicon Photomultipliers (SiPMs) in a fNIRS system has been estimated potentially able to increase the spatial resolution. Dedicated SiPM sensors have been designed and fabricated by using an optimized process. Electrical and optical characterizations are presented. The design and implementation of a portable fNIRS embedded system, hosting up to 64 IR-LED sources and 128 SiPM sensors, has been carried out. The system has been based on a scalable architecture whose elementary leaf is a flexible board with 16 SiPMs and 4 couples of LEDs each operating at two wavelengths. An ARM based microcontroller has been joined with a multiplexing interface, able to control power supply for the LEDs and collect data from the SiPMs in a time-sharing fashion and with configurable temporal slots. The system will be validated by using a phantom made by materials of different scattering and absorption indices layered to mimic a human head. A preliminary characterization of the optical properties of the single material composing the phantom has been performed using the SiPM in the diffuse radial reflectance measurement technique. The first obtained results confirm the high sensitivity of such kind of detector in the detection of weak light signal even at large distance between the light source and the detector. © 2014 SPIE.

We present an analytical model describing the full electromagnetic propagation in a THz time-domain spectroscopy (THz-TDS) system, from the THz pulses via Optical Rectification to the detection via Electro Optic-Sampling. While several investigations deal singularly with the many elements that constitute a THz-TDS, in our work we pay particular attention to the modelling of the time-frequency behaviour of all the stages which compose the experimental set-up. Therefore, our model considers the following main aspects: (i) pump beam focusing into the generation crystal; (ii) phase-matching inside both the generation and detection crystals; (iii) chromatic dispersion and absorption inside the crystals; (iv) Fabry-Perot effect; (v) diffraction outside, i.e. along the propagation, (vi) focalization and overlapping between THz and probe beams, (vii) electro-optic sampling. In order to validate our model, we report on the comparison between the simulations and the experimental data obtained from the same set-up, showing their good agreement.

We describe our approach to the task of modelling, both at single cell structure and complete module levels, during the solar cell technology development process. This can give very helpful indications, in terms of global photovoltaic module characteristics, for the assessment of intermediate research results and planning of further experiments. We make reference specifically to the fabrication of thin film CIGS solar cells by means of single-step electrodeposition, a technique which appears fairly easy and low-cost but, at the same time, can lead to quite different structural and electrical properties.

Starting from the results regarding a nonvacuum technique to fabricate CIGS thin films for solar cells by means of single-step electrodeposition, we focus on the methodological problems of modeling at cell structure and photovoltaic module levels. As a matter of fact, electrodeposition is known as a practical alternative to costly vacuum-based technologies for semiconductor processing in the photovoltaic device sector, but it can lead to quite different structural and electrical properties. For this reason, a greater effort is required to ensure that the perspectives of the electrical engineer and the material scientist are given an opportunity for a closer comparison and a common language. Derived parameters from ongoing experiments have been used for simulation with the different approaches, in order to develop a set of tools which can be used to put together modeling both at single cell structure and complete module levels.

We report the electrical and optical comparison, in continuous wave regime, of two novel classes of silicon photomultipliers (SiPMs) fabricated in planar technology on silicon P-type and N-type substrate respectively. Responsivity measurements have been performed with an incident optical power from tenths of picowatts to hundreds of nanowatts and on a broad spectrum, ranging from ultraviolet to near infrared (340-820 nm). For both classes of investigated SiPMs, responsivity shows flat response versus the optical incident power, when a preset overvoltage and wavelength is applied . More in detail, this linear behavior extends up to about 10 nW for lower overvoltages, while a shrink is observed when the reverse bias voltage increases. With regards to our responsivity measurements, carried out in the abovementioned spectral range, we have found a peak around 669 nm for the N-on-P and a peak at 417 nm for the P-on-N SiPM. A physical explanation of the all experimental results is also provided in the paper.

Frequency conversion by means of Kerr nonlinearity is one of the most common and exploited nonlinear optical processes in the UV, visible, IR, and mid-IR spectral regions. Here we show that wave mixing of an optical field and a terahertz wave can be achieved in diamond, resulting in the frequency conversion of the terahertz radiation either by sum- or difference-frequency generation. In the latter case, we show that this process is phase matched and most efficient in a counterpropagating geometry.

We observe second harmonic generation via random quasi-phase-matching in a 2.0 micron periodically poled, 1-cm-long, z-cut lithium tantalate. Away from resonance, the harmonic output profiles exhibit a characteristic pattern stemming from a stochastic domain distribution and a quadratic growth with the fundamental excitation, as well as a broadband spectral response. The results are in good agreement with a simple model and numerical simulations in the undepleted regime, assuming an anisotropic spread of the random nonlinear component. (C) 2010 Optical Society of America

We demonstrate efficient first-order quasi-phase-matched second-harmonic generation in a surface periodically poled Ti:indiffused lithium niobate waveguide; 6 mW of continuous-wave blue radiation (wavelength = 412.6 nm) was produced showing the potential of surface domain inversion for efficient nonlinear waveguide interactions.

We report on bulk and guided-wave second-harmonic generation via random Quasi-Phase-Matching in Lithium Tantalate. By acquiring the far-field profiles at several wavelengths, we extract statistical information on the distribution of the quadratic nonlinearity as well as its average period, both at the surface and in the bulk of the sample. By investigating the distribution in the two regions we demonstrate a non-invasive approach to the study of poling dynamics.

Free Space Optics (FSO) links are affected by several impairments: optical turbulence, scattering, absorption, and pointing. In particular, atmospheric optical turbulence generates optical power fluctuations at the receiver that can degrade communications with fading events, especially, in high data rate links. A way to mitigate FSO link outages can be to add a coding to communications. Nevertheless, in order to study innovative solutions (software or hardware) and to improve the FSO link performance it needs accurate testing models. In this paper we describe an accurate time-correlated channel model able to predict random temporal fluctuations of optical signal irradiance caused by optical turbulence. Moreover, concerning the same channel, we also report simulation results on the error mitigation performance of Luby-Transform, Raptor, and RaptorQ codes.

We carried out second-harmonic generation in quasi-phase-matched ? -phase lithium niobate channel waveguides realized by proton exchange and surface periodic poling. Owing to a limited ferroelectric domain depth, we could observe the interplay between second-harmonic generation and self-phase modulation due to cascading and cubic effects, resulting in a nonlinear resonance shift. Data reduction allowed us to evaluate both the quadratic nonlinearity in the near infrared as well as the depth of the uninverted domains. © 2007 Optical

A promising technology for peer-to-peer connections and urban area networks is represented by wireless communications through free space using optical carrier (Free Space Optics, FSO). This technology ensures high data rates, with relatively low error rates, low power consumption and inherent security. Nevertheless FSO links are quite sensitive to atmospheric condition. Fog droplets, but also raindrops and snowflakes, may introduce severe path attenuation which drastically reduces the channel availability. A parametric model to simulate droplets scattering effects over the FSO link in terms of extinction coefficient, albedo factor and asymmetry coefficient as function of the particle water content will be presented. Both single and multiple scattering effects will be shown.

We report on recent technological improvements concerning nonlinear patterning of lithium niobate and lithium tantalate in the micrometer and submicrometer scales using surface periodic poling for ferroelectric domain inversion. The fabricated samples were employed for frequency doubling via quasiphase-matching both in bulk and guided wave geometries, including forward and backward configurations and wavelength conversion in bands C and L. We also investigated short-period quasiperiodic samples with randomly distributed mark-to-space ratios.

A report is presented on broadband second-harmonic generation in the range between 930 and 970 nm using random quasi-phase matching in a planar waveguide fabricated by soft proton exchange in congruent lithium tantalate. Bulk and waveguide measurements are compared, outlining the averaging role of guided-wave modes and their interactions with respect to spectral acceptance and near-field profile.

In this work, metal-oxide-semiconductor (MOS)-like sensors in which deoxyribonucleic acid (DNA) strands are covalently immobilized either on Si oxide or on a gold surface were electrically characterized. Si oxide fabrication process allowed us to have a surface insensitive to the solution pH. A significant shift in the flat band voltage was measured after single strand DNA immobilization (+0.47 +/- 0.04 V) and after the complementary strand binding (+0.07 +/- 0.02 V). The results show that DNA sensing can be performed using a MOS structure which can be easily integrated in a more complex design, thus avoiding the problems related to the integration of micro-electrochemical cells.

We implement a simple and powerful approach to characterize the domain distribution in the bulk of quadratic ferroelectric crystals via far-field second-harmonic spectroscopy. The approach is demonstrated in a lithium tantalate sample with periodic electric field poling and random mark-to-space ratio.

We present our investigation on the THz space-time emission characteristic induced by the non-paraxial generation regime in highly localized THz generation via optical rectification on sub-wavelength areas.

Highly localized THz emission via optical rectification in thin nonlinear crystals is a promising method for subwavelength microscopy. We present here the peculiar THz spatio-temporal characteristics induced by the non-paraxial generation regime.

A highly localized THz source is a promising candidate for sub-wavelength microscopy, due to its superior radiation power throughput with respect to others near-field techniques. Here, we report on the spatial and the spectral near-field properties of our highly localized THz source.

In this paper, the authors present the latest results on a simple and low cost method to achieve a dynamic and flexible network monitoring. By placing several fiber Bragg gratings (FBG) along the passive optical gigabit Ethernet infrastructure (GePON), the proposed modified optical time domain reflectometer (OTDR) is able to monitor the entire system by simply tuning its working wavelength. Furthermore, the optical network terminals (ONT), at the end users premises, have been interconnected to the trunk via an innovative cable able to both carry the optical signal as well as the power supply.

We introduce and test a simple approach for the characterization of domain distribution in bulk quadratic ferroelectric crystals, specifically periodically poled Lithium Tantalate with random mark-to space ratio.

We report on backward second-harmonic-generation in bulk periodically poled congruent lithium niobate with a 3.2 microns period. A tunable continuous-wave Ti:sapphire laser allowed us exciting two resonant quasi-phase-matching orders in the backward configuration. The resonances were also resolved by temperature tuning and interpolated with standard theory to extract relevant information on the sample.

We introduce and test a simple approach for the characterization of domain distribution in bulk quadratic ferroelectric crystals, such as periodically poled Lithium Tantalate with random mark-to space ratio.

We report on stable optical waveguides fabricated by soft-proton exchange in periodically-poled congruent lithium tantalate in the a-phase. The channel waveguides are characterized in the telecom wavelength range in terms of both linear properties and frequency doubling. The measurements yield a nonlinear coefficient of about 9.5pm/V, demonstrating that the nonlinear optical properties of lithium tantalate are left nearly unaltered by the process. (C) 2010 Optical Society of America

We demonstrated broadband second-harmonic generation via random Quasi-Phase-Matching in periodically poled Lithium Tantalate.

We report the characterization of single-mode optical waveguides at telecom wavelength, realized in congruent lithium-tantalate. We demonstrate that waveguides realized by proton-exchange show a nonlinear coefficient matching that expected in a bulk crystal.

A frequency shifting device is fabricated and tested in a ferroelectric waveguide in a low-photorefractivity crystal. Periodic poling for quasi-phase-matching and channels for operation in the near-infrared C-band were obtained in congruent lithium tantalate, demonstrating for the first time both wave confinement and two-stage parametric conversion in such waveguides.

Domain engineering technology in lithium tantalate is a well studied approach for nonlinear optical applications. However, for several cases of interest, the realization of short period structures (< 2 ��m) is required, which make their characterization difficult with standard techniques. In this work, we show that high resolution x-ray diffraction is a convenient approach for the characterization of such structures, allowing us to obtain in a nondestructive fashion information such as the average domain period, the domain wall inclination, and the overall structure quality.

Second harmonic generation is investigated in lithium niobate channels realized by proton exchange and quasi-phase-matched by surface periodic-poling. The reduction in conversion efficiency at high powers is interpreted in terms of multi-photon absorption via two-color terms, yielding an estimate of the dominating three-photon process., Comment: 2 pages, 6 figures

alpha, beta(1), and kappa(2) phases are investigated for planar waveguide fabrication by proton exchange in congruent lithium tantalate. The effective indices of planar waveguide eigenmodes were monitored over time, revealing that the exchange process induces aging instabilities in all phases except alpha.

In this work, continuous-wave laser action at 1084.5 nm at room temperature in LiNbO 3 :Nd 3+ channel waveguides, fabricated by reverse proton exchange (RPE), is reported. The sample was pumped at λ = 808 nm in either σ or π-polarized configurations, TE- and TM-pumping schemes, being the laser emission π-polarized at all power levels. The laser characteristics, as function of the pumping scheme (TE or TM), have been obtained. In both cases, the laser emission was stable, without any reduction in the output power even under continuous pump operation at maximum power at room temperature, indicating high resistance to photorefractive damage.

The surface plasmon resonance (SPR) technique is an optical method that can be used to measure the refractive index of organic nano-layers adsorbed on a thin metal film. Although there are many techniques for measuring biomolecular interactions, SPR-based techniques play a central role in many current biosensing experiments, since they are most suited to sensitive and quantitative kinetic measurements. Here we give some results from the analysis and numerical elaboration of SPR data regarding the flow of different solutions with refractive indexes in the range of interest (1-1.4). After a brief discussion of the principles of SPR and of waveguide fabrication technique, we give a description of system setup and some results regarding the real time waveguide output intensity monitoring to measure the interaction between the gold thin film and the analyte.

Simultaneous generation of four spectral emission lines has been achieved in Nd-doped lithium niobate reverse proton exchange optical waveguide cavities. Using a pump at 800 nm, the four lines were found and they are due to lasing at 1.3735 combined with parametric conversion at 0.687, 0.574 and 0.4 mum.

First experiments of proton exchange channel waveguides compatible with electric field surface periodic poling of congruent lithium niobate crystals are addressed. Picosecond nonlinear copropagating QPM-SHG measurements have been carried out on such structures.

In this work, laser action in RPE Nd3+:LiNbO3 is modelled by using the overlapping integrals method. Different pumping schemes, TE or TM, have been considered in order to reproduce the experimental measurements. Calculated results indicate that the slope efficiency remains basically independent on the pumping scheme while the threshold pump power increases for TE pumping.

First experiments with the novel electric field Surface Periodic Poling technique have been carried out on Lithium Tantalate. Optimal poling parameters gave 50:50 mark-to-space ratio in the micron scale with good uniformity and high repeatability.

We report on recent results by surface periodic poling on lithium niobate and lithium tantalate. Such approach allows periodic inversion of the second order susceptibility with nanoscale features using insulating masks. We achieved a world-best 200 nm feature size, as well as good compatibility with alpha-phase proton exchanged channel waveguides in lithium niobate. Preliminary results of surface periodic poling in lithium tantalate also show similar characteristics. Surface poling is best suited for integrated optics devices in technologically-demanding configurations such as backward second harmonic generation and counter propagating optical parametric amplification

Periodic Poling of Lithium Niobate crystals (PPLN) by means of electric field has revealed the best technique for finely tailoring PPLN structures and parameters, which play a central role in many current researches in the field of nonlinear integrated optics. Besides the most studied technique of bulk poling, recently a novel technique where domain inversion occurs just in a surface layer using photoresist or silica masks has been devised and studied. This surface periodic poling (SPP) approach is best suited when light is confined in a thin surface guiding layer or stripe, as in the case of optical waveguide devices. Also, we found that SPP respect to bulk poling offers two orders of magnitude reduction on the scale of periodicity, so that even nanostructures can be obtained provided an high resolution holographic mask writing technique is adopted. We were able to demonstrate 200 nm domain size, and also good compatibility with alpha-phase proton exchange channel waveguide fabrication. Our first experiments on Lithium Tantalate have also shown that the SPP technology appears to be applicable to this crystal (SPPLT), whose properties can allow to overcome limitations such as optical damage or UV absorption still present in PPLN devices. Finally, the issue of SPP compatibility with proton exchange waveguide fabrication will be addressed

Surface periodic poling of congruent lithium niobate was performed with the aid of photolithographically defined silica masks. The latter helped improving the control of duty cycle in the periodic domain poling, with 50:50 mark-to-space ratios. The role of silica was ascertained by numerically solving the Poisson equation.