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Superconducting qubits are a leading system for realizing large scale quantum processors, but overall gate fidelities suffer from coherence times limited by microwave dielectric loss. Recently discovered tantalum-based qubits exhibit record lifetimes exceeding 0.3 ms. Here we perform systematic, detailed measurements of superconducting tantalum resonators in order to disentangle sources of loss that limit state-of-the-art tantalum devices. By studying the dependence of loss on temperature, microwave photon number, and device geometry, we quantify materials-related losses and observe that the losses are dominated by several types of saturable two level systems (TLSs), with evidence that both surface and bulk related TLSs contribute to loss. Moreover, we show that surface TLSs can be altered with chemical processing. With four different surface conditions, we quantitatively extract the linear absorption associated with different surface TLS sources. Finally, we quantify the impact of the chemical processing at single photon powers, the relevant conditions for qubit device performance. In this regime we measure resonators with internal quality factors ranging from 5 to 15 x 10^6, comparable to the best qubits reported. In these devices the surface and bulk TLS contributions to loss are comparable, showing that systematic improvements in materials on both fronts will be necessary to improve qubit coherence further.

There is a class of binary post-asymptotic giant branch (post-AGB) stars that exhibit remarkable near-infrared (NIR) excess. These stars are surrounded by disks with Keplerian or quasi-Keplerian dynamics and outflows composed of gas escaping from the rotating disk. Depending on the dominance of these components, there are two subclasses of binary post-AGB stars: disk-dominated and outflow-dominated. We aim to properly study the hourglass-like structure that surrounds the Keplerian disk around 89 Her. We present total-power on-the-fly maps of $^{12}$CO and $^{13}$CO $J$=2-1 emission lines in 89 Her. Previous studies are known to suffer from flux losses in the most extended components. We merge these total-power maps with previous NOEMA maps. The resulting combined maps are expected to detect the whole nebula extent of the source. Our new combined maps contain the entirety of the detectable flux of the source and at the same time are of high spatial resolution thanks to the interferometric observations. We find that the hourglass-like extended outflow around the rotating disk is larger and more massive than suggested by previous works. The total nebular mass of this very extended nebula is 1.8E-2 solar masses, of which 65% comes from the outflow. The observational data and model results lead us to classify the envelope around 89 Her as an outflow-dominated nebula, together with R Sct and IRAS 19125+0343 (and very probably AI CMi, IRAS 20056+1834, and IRAS 18123+0511). The updated statistics on the masses of the two post-AGB main components reveal that there are two distinct subclasses of nebulae around binary post-AGB stars depending on which component is the dominant one. We speculate that the absence of an intermediate subclass of sources is due to the different initial conditions of the stellar system and not because both subclasses are in different stages of the post-AGB evolution., Comment: Accepted 5 January 2023 in Astronomy & Astrophysics. 17 pages

Over the past decades, superconducting qubits have emerged as one of the leading hardware platforms for realizing a quantum processor. Consequently, researchers have made significant effort to understand the loss channels that limit the coherence times of superconducting qubits. A major source of loss has been attributed to two level systems that are present at the material interfaces. We recently showed that replacing the metal in the capacitor of a transmon with tantalum yields record relaxation and coherence times for superconducting qubits, motivating a detailed study of the tantalum surface. In this work, we study the chemical profile of the surface of tantalum films grown on c-plane sapphire using variable energy X-ray photoelectron spectroscopy (VEXPS). We identify the different oxidation states of tantalum that are present in the native oxide resulting from exposure to air, and we measure their distribution through the depth of the film. Furthermore, we show how the volume and depth distribution of these tantalum oxidation states can be altered by various chemical treatments. By correlating these measurements with detailed measurements of quantum devices, we can improve our understanding of the microscopic device losses.

Atomic defects in the solid state are a key component of quantum repeater networks for long-distance quantum communication. Recently, there has been significant interest in rare earth ions, in particular Er$^{3+}$ for its telecom-band optical transition, but their application has been hampered by optical spectral diffusion precluding indistinguishable single photon generation. In this work we implant Er$^{3+}$ into CaWO$_4$, a material that combines a non-polar site symmetry, low decoherence from nuclear spins, and is free of background rare earth ions, to realize significantly reduced optical spectral diffusion. For shallow implanted ions coupled to nanophotonic cavities with large Purcell factor, we observe single-scan optical linewidths of 150 kHz and long-term spectral diffusion of 63 kHz, both close to the Purcell-enhanced radiative linewidth of 21 kHz. This enables the observation of Hong-Ou-Mandel interference between successively emitted photons with high visibility, measured after a 36 km delay line. We also observe spin relaxation times $T_1$ = 3.7 s and $T_2$ > 200 $\mu$s, with the latter limited by paramagnetic impurities in the crystal instead of nuclear spins. This represents a significant step towards the construction of telecom-band quantum repeater networks with single Er$^{3+}$ ions.

A previously unreported layered spin 1/2 triangular lattice polymorph of TiI3 is described, synthesized under 6 GPa of applied pressure at 900 C, but stable at atmospheric pressure. This air-sensitive material has a CdI2-type layered structure (P-3m1 (#164), a = 4.012 A and c = 6.641 A at 120 K, Z = 1 of Ti0.667I2) with an in-plane triangular lattice, related to that of TiI4 (Ti0.5I2). Although the TiI3 formula is consistent with expectations for a layered honeycomb lattice of spin 1/2 Ti(III), there appears to be disorder in the crystal structure. Magnetic susceptibility and heat capacity measurements suggest that the material undergoes several low temperature phase transitions.

Fair calibration is a widely desirable fairness criteria in risk prediction contexts. One way to measure and achieve fair calibration is with multicalibration. Multicalibration constrains calibration error among flexibly-defined subpopulations while maintaining overall calibration. However, multicalibrated models can exhibit a higher percent calibration error among groups with lower base rates than groups with higher base rates. As a result, it is possible for a decision-maker to learn to trust or distrust model predictions for specific groups. To alleviate this, we propose \emph{proportional multicalibration}, a criteria that constrains the percent calibration error among groups and within prediction bins. We prove that satisfying proportional multicalibration bounds a model's multicalibration as well its \emph{differential calibration}, a fairness criteria that directly measures how closely a model approximates sufficiency. Therefore, proportionally calibrated models limit the ability of decision makers to distinguish between model performance on different patient groups, which may make the models more trustworthy in practice. We provide an efficient algorithm for post-processing risk prediction models for proportional multicalibration and evaluate it empirically. We conduct simulation studies and investigate a real-world application of PMC-postprocessing to prediction of emergency department patient admissions. We observe that proportional multicalibration is a promising criteria for controlling simultaneous measures of calibration fairness of a model over intersectional groups with virtually no cost in terms of classification performance., Comment: Published in the 2023 Conference on Health, Inference, and Learning (CHIL). Best paper award

Recently, compounds with noncentrosymmetric crystal structure have attracted much attention for providing a rich playground in search for unconventional superconductivity. NbIr$_2$B$_2$ is a new member to this class of materials harboring superconductivity below $T_{\rm c} = 7.3(2)$~K and very high upper critical field that exceeds Pauli limit. Here we report on muon spin rotation ($\mu$SR) experiments probing the temperature and field dependence of effective magnetic penetration depth in this compound. Our transverse-field -$\mu$SR results suggest a fully gaped $s$-wave superconductvity. Further, the estimated high value of upper critical field is also supplemented by high field transport measurements. Remarkably, the ratio $T_{\rm c}$/$\lambda^{-2}(0)$ obtained for NbIr$_2$B$_2$ ($\sim$2) is comparable to those of unconventional superconductors. Zero-field $\mu$SR data reveals no significant change in the muon spin relaxation rate above and below $T_{\rm c}$, evincing that time-reversal symmetry is preserved in the superconducting state. The presented results will stimulate theoretical investigations to obtain a microscopic understanding of the origin of superconductivity with preserved time reversal symmetry in this unique noncentrosymmetric system., Comment: 8 pages, 4 figures. arXiv admin note: text overlap with arXiv:2101.08234

There is a class of binary post-AGB stars (binary system including a post-AGB star) that are surrounded by Keplerian disks and outflows resulting from gas escaping from the disk. To date, there are seven sources that have been studied in detail through interferometric millimeter-wave maps of CO lines (ALMA/NOEMA). For the cases of the Red Rectangle, IW Carinae, IRAS 08544-4431, and AC Herculis, it is found that around greater than 85% of the total nebular mass is located in the disk with Keplerian dynamics. The remainder of the nebular mass is located in an expanding component. This outflow is probably a disk wind consisting of material escaping from the rotating disk. These sources are the disk-dominated nebulae. On the contrary, our maps and modeling of 89 Herculis, IRAS 19125+0343, and R Scuti, which allowed us to study their morphology, kinematics, and mass distribution, suggest that, in these sources, the outflow clearly is the dominant component of the nebula (around 75% of the total nebular mass), resulting in a new subclass of nebulae around binary post-AGB stars: the outflow-dominated sources.Besides CO, the chemistry of this type of source has been practically unknown thus far. We also present a very deep single-dish radio molecular survey in the 1.3, 2, 3, 7, and 13 mm bands (around 600 h of telescope time). Our results and detections allow us to classify our sources as O- or C-rich. We also conclude that the calculated abundances of the detected molecular species other than CO are particularly low, compared with AGB stars. This fact is very significant in those sources where the rotating disk is the dominant component of the nebula., Comment: Accepted 2 August 2022 in Astronomy. 11 pages

In a topological insulator the metallic surface states are easily distinguished from the insulating bulk states (FuKane07). By contrast, in a topological superconductor (FuKane08,Qi,FuBerg,Oppen), much less is known about the relationship between an edge supercurrent and the bulk pair condensate. Can we force their pairing symmetries to be incompatible? In the superconducting state of the Weyl semimetal MoTe$_2$, an edge supercurrent is observed as oscillations in the current-voltage (\emph{I-V}) curves induced by fluxoid quantization (Wang). We have found that the $s$-wave pairing potential of supercurrent injected from niobium contacts is incompatible with the intrinsic pair condensate in MoTe$_2$. The incompatibility leads to strong stochasticity in the switching current $I_c$ as well as other anomalous properties such as an unusual antihysteretic behavior of the ``wrong'' sign. Under supercurrent injection, the fluxoid-induced edge oscillations survive to much higher magnetic fields \emph{H}. Interestingly, the oscillations are either very noisy or noise-free depending on the pair potential that ends up dictating the edge pairing. Using the phase noise as a sensitive probe that eavesdrops on the competiting bulk states, we uncover an underlying blockade mechanism whereby the intrinsic condensate can pre-emptively block proximitization by the Nb pair potential depending on the history., Comment: 11 pages, 6 figures

Bulk CsEuBr$_3$ and CsEuCl$_3$ are experimentally shown to be magnetic semiconductors that order antiferromagnetically at Neel temperatures of 2.0 K and 1.0 K respectively. Given that nanoparticles and thin films of CsEuCl$_3$ have been reported to order ferromagnetically at a similar temperature, our observation of antiferromagnetic ordering in CsEuBr$_3$ and CsEuCl$_3$ expands the possible applications of halide perovskites to now include spintronic devices where both ferromagnetic and antiferromagnetic devices can be fabricated from a single material. The conclusion that CsEuCl$_3$ can be used as a switchable magnetic material is also supported by our density-functional theory calculations., Comment: 21 pages, 3 figures, 6 additional figures

The strange metal (SM) state, characterized by a linear-in-temperature resistivity, is often seen in the normal state of high temperature superconductors. It is believed that the SM state is one of the keys to understand the underlying mechanism of high-Tc superconductivity. Here we report the first observation of the concurrent breakdown of the SM normal state and superconductivity at a pressure-induced quantum critical point in an iron-pnictide superconductor, Ca10(Pt4As8)((Fe0.97Pt0.03)2As2)5. We find that, upon suppressing the superconducting state by applying pressure, the power exponent changes from 1 to 2, and the corresponding coefficient A, the slope of the temperature-linear resistivity per FeAs layer, gradually diminishes. At a critical pressure (12.5 GPa), A and Tc go to zero concurrently,where a quantum phase transition (QPT) from a superconducting state with a SM normal state to a non-superconducting Fermi liquid state takes place. Scaling analysis on the results obtained from the pressurized 1048 superconductor reveals that A and Tc have a positive relation, which exhibits a similarity with that is seen in other chemically-doped unconventional superconductors, regardless of the type of the tuning method (doping or pressurizing), the crystal structure, the bulk or film superconductors and the nature of dopant. These results suggest that there is a simple but powerful organizational principle of connecting the SM normal state with the high-Tc superconductivity., Comment: 16 pages, 4 figures

Neutral silicon vacancy centers (SiV0) in diamond are promising candidates for quantum networks because of their long spin coherence times and stable, narrow optical transitions. However, stabilizing SiV0 requires high purity, boron doped diamond, which is not a readily available material. Here, we demonstrate an alternative approach via chemical control of the diamond surface. We use low-damage chemical processing and annealing in a hydrogen environment to realize reversible and highly stable charge state tuning in undoped diamond. The resulting SiV0 centers display optically detected magnetic resonance and bulk-like optical properties. Controlling the charge state tuning via surface termination offers a route for scalable technologies based on SiV0 centers, as well as charge state engineering of other defects.

Layered ferromagnets are thrilling materials from both a fundamental and technological point of view. VI3 is an interesting example, with a complex magnetism that differentiates it from the first reported Cr based layered ferromagnets. Here, we show in an indirect way through Angle Resolved Photoemission Spectroscopy (ARPES) experiments, the importance of spin-orbit coupling setting the electronic properties of this material. Our light polarized photoemission measurements point to a ground state with a half-filled e'_+- doublet, where a gap opening is triggered by spin-orbit coupling enhanced by electronic correlations.

Deep Learning (DL) models achieve great successes in many domains. However, DL models increasingly face safety and robustness concerns, including noisy labeling in the training stage and feature distribution shifts in the testing stage. Previous works made significant progress in addressing these problems, but the focus has largely been on developing solutions for only one problem at a time. For example, recent work has argued for the use of tunable robust loss functions to mitigate label noise, and data augmentation (e.g., AugMix) to combat distribution shifts. As a step towards addressing both problems simultaneously, we introduce AugLoss, a simple but effective methodology that achieves robustness against both train-time noisy labeling and test-time feature distribution shifts by unifying data augmentation and robust loss functions. We conduct comprehensive experiments in varied settings of real-world dataset corruption to showcase the gains achieved by AugLoss compared to previous state-of-the-art methods. Lastly, we hope this work will open new directions for designing more robust and reliable DL models under real-world corruptions., Comment: 10 pages, 6 figures, 6 tables

Recently, Co-based honeycomb magnets have been proposed as promising candidate materials to host the Kitaev spin liquid state. One of the front-runners is BaCo$_2$(AsO$_4$)$_2$ (BCAO), where it was suggested that the exchange processes between Co$^{2+}$ ions via the surrounding edge-sharing oxygen octahedra could give rise to bond-dependent Kitaev interactions. In this work, we present and analyze comprehensive inelastic neutron scattering studies of BCAO with fields in the honeycomb plane. Combining the constraints from the magnon excitations in the high-field polarized state and the inelastic spin structure factor measured in zero magnetic field, we examine two leading theoretical models: the Kitaev-type \JKG model and the \XXZ model. We show that the existing experimental data can be consistently accounted for by the \XXZ model but not by the \JKG model, and we discuss the implications of these results for the realization of a spin liquid phase in BCAO and more generally for the realization of the Kitaev model in cobaltates., Comment: 15 pages, 10 figures

We report a comprehensive study on the elastic properties of a hexanary high-entropy alloy superconductor (ScZrNbTa)$_{0.685}$[RhPd]$_{0.315}$ at room and cryogenic temperatures, by Resonant Ultrasound Spectroscopy experiments. The derived elastic constants are bulk modulus $K=132.7$ GPa, Young's modulus $E=121.0$ GPa, shear modulus $G=44.9$ GPa, and Poisson's ratio $\nu$=0.348 for room temperature. The Young's and shear moduli are $\sim 10\%$ larger than those in NbTi superconductor with similar $T_c$, while the ductility is comparable. Moreover, the mechanical performance is further enhanced at cryogenic temperature. Our work confirms the advantageous mechanical properties of high-entropy alloy superconductors and suggests the application prospects., Comment: 11 pages, 3 figures, 1 table

In this paper we investigate why the running time of lexicase parent selection is empirically much lower than its worst-case bound of O(N*C). We define a measure of population diversity and prove that high diversity leads to low running times O(N + C) of lexicase selection. We then show empirically that genetic programming populations evolved under lexicase selection are diverse for several program synthesis problems, and explore the resulting differences in running time bounds., Comment: 12 pages, 3 figures

Decentralized Online Social Networks (DOSNs) represent a growing trend in the social media landscape, as opposed to the well-known centralized peers, which are often in the spotlight due to privacy concerns and a vision typically focused on monetization through user relationships. By exploiting open-source software, DOSNs allow users to create their own servers, or instances, thus favoring the proliferation of platforms that are independent yet interconnected with each other in a transparent way. Nonetheless, the resulting cooperation model, commonly known as the Fediverse, still represents a world to be fully discovered, since existing studies have mainly focused on a limited number of structural aspects of interest in DOSNs. In this work, we aim to fill a lack of study on user relations and roles in DOSNs, by taking two main actions: understanding the impact of decentralization on how users relate to each other within their membership instance and/or across different instances, and unveiling user roles that can explain two interrelated axes of social behavioral phenomena, namely information consumption and boundary spanning. To this purpose, we build our analysis on user networks from Mastodon, since it represents the most widely used DOSN platform. We believe that the findings drawn from our study on Mastodon users' roles and information flow can pave a way for further development of fascinating research on DOSNs., Comment: Preprint of article published with Online Social Networks and Media, vol. 30:100220, June 2022. Elsevier

VO2, of interest for decades due to both its phenomenology and its potential applications, has a monoclinic distortion of the rutile crystal structure at ambient temperature that is coupled to its metal-insulator transition (MIT). In contrast, RuO2 has three electrons more per formula unit, is a metallic conductor, and has an undistorted rutile structure. Here we report a systematic study of Ru-doped VO2 (V1-xRuxO2); generally characterizing its crystal structure, magnetic and electronic properties, and heat capacity. The composition-dependent Wilson ratio is determined. We find that an unusually high Ru doping value (x=0.8) is required to achieve a metallic state in V1-xRuxO2. No superconductivity was observed down to 0.1 K in the metallic materials. We propose a possible understanding for how the insulating state can exist in V1-xRuxO2 at high Ru contents., Comment: 23 pages, 10 figures

The synthesis of IrI$_3$ at high pressure in its layered honeycomb polymorph is reported. Its crystal structure is refined by single crystal X-ray diffraction. Faults in the honeycomb layer stacking are observed by single crystal diffraction, synchrotron powder diffraction, and transmission electron microscopy. A previously unreported hyperhoneycomb polymorph of IrI$_3$ ($\beta$-IrI$_3$), is also described. Its structure in space group Fddd is determined by single crystal XRD. Both materials are highly-resistive diamagnetic semiconductors, consistent with a low spin d$^6$ configuration for Ir(III). The two- and three-dimensional Ir arrays in these polymorphs of IrI$_3$ are analogous to those found in the $\alpha$- and $\beta$- polymorphs of Li$_2$IrO$_3$, although the Ir electron configurations are different.

Context. There is a class of binary post-asymptotic giant branch (post-AGB) stars that exhibit remarkable near-infrared (NIR) excess. Such stars are surrounded by Keplerian or quasi-Keplerian disks, as well as extended outflows composed of gas escaping from the disk. This class can be subdivided into disk- and outflow-dominated sources, depending on whether it is the disk or the outflow that represents most of the nebular mass, respectively. The chemistry of this type of source has been practically unknown thus far. Methods. We focused our observations on the 1.3, 2, 3 mm bands of the 30 m IRAM telescope and on the 7 and 13 mm bands of the 40 m Yebes telescope. Our observations add up around 600 hours of telescope time. Results. We present the first single-dish molecular survey of mm-wave lines in nebulae around binary post-AGB stars. We conclude that the molecular content is relatively low in nebulae around binary post-AGB stars, as their molecular lines and abundances are especially weaker compared with AGB stars. This fact is very significant in those sources where the Keplerian disk is the dominant component of the nebula. The study of their chemistry allows us to classify nebulae around AC Her, the Red Rectangle, AI CMi, R Sct, and IRAS 20056+1834 as O-rich, while that of 89 Her is probably C-rich. The calculated abundances of the detected species other than CO are particularly low compared with AGB stars. The initial stellar mass derived from the 17O/18O ratio for the Red Rectangle and 89 Her is compatible with the central total stellar mass derived from previous mm-wave interferometric maps. The very low 12CO/13CO ratios found in binary post-AGB stars reveal a high 13CO abundance compared to AGB and other post-AGB stars.