1051. Location of radiation-induced crosslinks and damage in melt-crystallized polyethylene
- Author
-
Yaolie Lu, Bingzheng Jiang, Yunxia Luo, Nanyu Chen, and Guoyin Wang
- Subjects
Radiation ,Materials science ,Morphology (linguistics) ,Small-angle X-ray scattering ,technology, industry, and agriculture ,macromolecular substances ,Polyethylene ,Crystal ,Crystallinity ,chemistry.chemical_compound ,chemistry ,Polymer chemistry ,Radiation damage ,Irradiation ,Composite material ,Small-angle scattering - Abstract
The effect of radiation on the morphology and the effect of morphology on crosslinking of melt-crystallized polyethylene were studied with DSC, WAXD, SAXS and gel fraction determination. The increase of “a” dimension in unit cell of polyethylene crystal and the integral invariant of small angle scattering could be better explained by “lamellae core damage” mechanism than by “lamellae surface damage” mechanism. The dependence of G-value of crosslinking on irradiation temperature and crystallinity were also studied. There existed the contribution of crystalline region to crosslinking. Crosslinking might occur within lamellae.
- Published
- 1985