51. Dual-modal optical temperature sensing based on Sb3+/Mn2+ co-doped Cs2NaYCl6 double perovskites.
- Author
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Tao, Huabiao, Fang, Yuyin, Zhang, Yuanpeng, Zhang, Yuepin, and Hu, Jianxu
- Subjects
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DOPING agents (Chemistry) , *PEROVSKITE , *TEMPERATURE , *ENERGY transfer , *EXCITON theory , *THERMOMETERS - Abstract
Optical temperature sensing based on luminescence intensity ratio shows significant potential in achieving accurate temperature detection. In this work, Sb3+/Mn2+ co-doped Cs 2 NaYCl 6 double perovskites were synthesised via a hydrothermal method. Introducing Sb3+ ions to the host significantly enhances the radiative recombination of self-trapped excitons (STEs), resulting in a broad blue emission. The co-doping of Mn2+ ions to the composition leads to a tunable dual-emission in the spectra, originating from the energy transfer between the STEs and Mn2+ ions. The dependence of the dual-emission on temperature is employed for optical temperature sensing. The maximum relative sensitivity, optimal thermal resolution, and optimal thermal repeatability are determined as 1.40 % K−1, 0.002 K and 99.3% at 250 K, respectively. The results indicate that the synthesised Cs 2 NaYCl 6 : Sb3+/Mn2+ double perovskites are promising candidates for high-sensitivity optical thermometers. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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