51. Magnetic Domain States and Critical Sizes in the Titanomagnetite Series.
- Author
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Cych, Brendan, Paterson, Greig A., Nagy, Lesleis, Williams, Wyn, and Moskowitz, Bruce
- Subjects
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MAGNETIC domain , *GEOMAGNETISM , *THERMOREMANENT magnetization , *MAGNETIC structure , *MAGNETIC flux density - Abstract
The minerals carrying the magnetic remanence in geological samples are commonly a solid solution series of iron‐titanium spinels known as titanomagnetites. Despite the range of possible compositions within this series, micromagnetic studies that characterize the magnetic domain structures present in these minerals have typically focused on magnetite. No studies systematically comparing the domain‐states present in titanomagnetites have been undertaken since the discovery of the single vortex (SV) structure and the advent of modern micromagnetism. The magnetic properties of the titanomagnetite series are known to vary strongly with composition, which may influence the domain states present in these minerals, and therefore the magnetic stability of the samples bearing them. We present results from micromagnetic simulations of titanomagnetite ellipsoids of varying shape and composition to find the size ranges of the single domain (SD) and SV structures. These size ranges overlap, allowing for regions where the SD and SV structures are both available. These regions are of interest as they may lead to magnetic instability and "partial thermal remanent magnetization (pTRM) tails" in paleointensity experiments. We find that although this SD + SV zone occupies a narrow range of sizes for equidimensional magnetite, it is widest for intermediate (TM30‐40) titanomagnetite compositions, and increases for both oblate and prolate particles, with some compositions and sizes having an SD + SV zone up to 100s of nm wide. Our results help to explain the prevalence of pTRM tail‐like behavior in paleointensity experiments. They also highlight regions of particles with unusual domain states to target for further investigation into the definitive mechanism behind paleointensity failure. Plain Language Summary: Rocks that record Earth's magnetic field often contain the mineral magnetite. The crystal structure of magnetite allows titanium atoms to substitute for iron, giving rise to a range of minerals known as titanomagnetites. The internal magnetic structure of titanomagnetite particles in rocks, known as the "domain structure," controls the ability of that particle to record magnetic fields. Particles with certain kinds of domain structure are unstable magnetic recorders, which can cause problems for experiments trying to determine Earth's magnetic field strength in the past (paleointensity experiments). Although the domain structures in magnetite are well understood, there are no recent studies which describe them in titanomagnetites. In this paper, we simulate the domain structures in small titanomagnetite particles and map these out as a function of size, shape and chemical composition. In doing so, we identify types of magnetic particles with multiple possible domain structures that may give rise to unstable magnetizations. Our results indicate that some titanomagnetite particles may have unstable magnetizations over a much larger range of sizes than has previously been seen in magnetite. This wide range of sizes could explain the high failure rates of paleointensity experiments. Key Points: We systematically map out the domain states in titanomagnetite as a function of shape and compositionOur results highlight ranges of compositions, shapes and sizes which contain unreliable paleomagnetic recordersFor certain shapes and compositions, these regions span hundreds of nanometers, representing a significant proportion of remanence carriers [ABSTRACT FROM AUTHOR]
- Published
- 2024
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