51. Effects of oil dispersants on settling of marine sediment particles and particle-facilitated distribution and transport of oil components
- Author
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Wen Liu, Zhengqing Cai, S.E. O’Reilly, Dongye Zhao, Jie Fu, and Kunming Fu
- Subjects
Geologic Sediments ,Salinity ,010504 meteorology & atmospheric sciences ,010501 environmental sciences ,Aquatic Science ,Oceanography ,01 natural sciences ,Dispersant ,chemistry.chemical_compound ,Surface-Active Agents ,Settling ,Oil dispersants ,Petroleum Pollution ,Seawater ,Polycyclic Aromatic Hydrocarbons ,0105 earth and related environmental sciences ,Environmental engineering ,Temperature ,Sediment ,Sedimentation ,Hydrogen-Ion Concentration ,Models, Theoretical ,Pollution ,Kinetics ,Petroleum ,chemistry ,Environmental chemistry ,Particle ,Corexit ,Water Pollutants, Chemical - Abstract
This work investigated effects of three model oil dispersants (Corexit EC9527A, Corexit EC9500A and SPC1000) on settling of fine sediment particles and particle-facilitated distribution and transport of oil components in sediment-seawater systems. All three dispersants enhanced settling of sediment particles. The nonionic surfactants (Tween 80 and Tween 85) play key roles in promoting particle aggregation. Yet, the effects varied with environmental factors (pH, salinity, DOM, and temperature). Strongest dispersant effect was observed at neutral or alkaline pH and in salinity range of 0–3.5 wt%. The presence of water accommodated oil and dispersed oil accelerated settling of the particles. Total petroleum hydrocarbons in the sediment phase were increased from 6.9% to 90.1% in the presence of Corexit EC9527A, and from 11.4% to 86.7% for PAHs. The information is useful for understanding roles of oil dispersants in formation of oil-sediment aggregates and in sediment-facilitated transport of oil and PAHs in marine eco-systems.
- Published
- 2016