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Interfacial interaction plays a crucial rule in catalysis over supported catalysts, and the catalyst-support interaction needs to be explored at microscopic scale. Here, we use the scanning tunneling microscope (STM) tip to manipulate Cr 2 O 7 dinuclear clusters on Au(111) and find that the Cr 2 O 7 -Au interaction can be weakened by an electric field in the STM junction, facilitating rotation and translation of the individual clusters at the imaging temperature (78 K). Surface alloying with Cu makes the manipulation of the Cr 2 O 7 clusters hard due to the enhanced Cr 2 O 7 -substrate interaction. Density functional theory calculations reveal that barrier for translation of a Cr 2 O 7 cluster on the surface can be increased by surface alloying, influencing the tip manipulation. Our study demonstrates that the oxide-metal interfacial interaction can be probed by STM tip manipulation of supported oxide clusters, which provides a new method to investigate the interfacial interaction.

In this work, a novel core-shell structure material, NiFe layered double hydroxide (NiFe LDH) loaded on SiO2 microspheres (SiO2@NiFe LDH), was synthesized by a one-step hydrothermal method, and the spontaneous electrostatic self-assembly process. The morphology, structure, and microwave absorption properties of SiO2@NiFe LDH nanocomposites with different NiFe element ratios were systematically investigated. The results show that the sample of SiO2@NiFe LDH-3 nanocomposite has excellent microwave absorption properties. It exhibits broadband effective absorption bandwidth (RL < −10 dB) of 8.24 GHz (from 9.76 GHz to 18.0 GHz) and the reflection loss is −53.78 dB at the matched thickness of 6.95 mm. It is expected that this SiO2@NiFe-LDH core-shell structural material can be used as a promising non-precious, metal-based material microwave absorber to eliminate electromagnetic wave contamination.