51. Multicomponent separations by a combined extraction/electrostatic pseudo-liquid membrane
- Author
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X.J. Yang, Z.M. Gu, and Anthony G. Fane
- Subjects
Aqueous solution ,Chromatography ,Stripping (chemistry) ,Chemistry ,Metal ions in aqueous solution ,Extraction (chemistry) ,Metals and Alloys ,Analytical chemistry ,Hydrochloric acid ,Industrial and Manufacturing Engineering ,chemistry.chemical_compound ,Membrane ,Phase (matter) ,Materials Chemistry ,Phosphoric acid - Abstract
The paper reports the results of the development of a combined extraction/electrostatic pseudo-liquid membrane (ESPLIM) concept for the mutual separation of multi–component ( n >2) metal ionic mixtures. Multiple sets of single two-cell ESPLIM equipment were linked up in order to achieve multi-metal separation. The principle of separation is described. A practical demonstration of this concept has been carried out by applying it to a typical mixture of metal ions present in ion-sorbing rare earth ore leachate solution, i.e., Al 3+ , La 3+ , Sm 3+ , and Y 3+ : an aqueous solution containing in mg/l Al 200–360, La 250–460, Sm 40–60, and Y 160–340 was used as the feed solution and 20% (v/v) di-(2-ethylhexyl) phosphoric acid (HDEHP) in kerosene was employed as organic membrane phase. The feed solution stream passed through the extraction cell at a flow rate of 1 l/h in once-through mode and the stripping solution passed through the stripping cell at a flow rate of 0.2 l/h in recirculation mode. By controlling the feed pH, organic membrane phase flow rate, and the hydrochloric acid concentration in stripping phase, the separation of Al, La, Sm and Y was obtained.
- Published
- 1998
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