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Stable fluid bodies, such as the ocean and atmosphere, are composed of a series of increasingly dense layers, defined by density stratification interfaces in which the medium properties (e.g., temperature, salinity) change. The intensity of the stratification between the layers influences the internal mixing dynamics and entrainment, facilitating the transport of dissolved constituents within the fluid medium. Acoustic systems offer the means for high resolution observations of these interfaces, which allow for continuous data collection over broad spatial scales. Here, a one-dimensional acoustic scattering model is presented for predicting acoustic backscatter from stratification interfaces, which is widely applicable to the acoustic water column data collected with ship-mounted sonars. Model predictions based on hydrographic profiles suggest that in many oceanic cases, the density gradient perturbations can be disregarded, and sound speed perturbations alone drive the majority of the acoustic scattering. A frequency-dependent scattering intensity based on the sharpness of the stratification interface is predicted by the model, suggesting a path to remote estimations of the physical medium properties through broadband acoustic inversion.

Due to the brittle nature of poly(lactic acid) many attempts have been made to flexibilize this polyester for applications such as thin films and foils. However, due to complex phase behavior, many drawbacks for plasticizer and blend components are described. To overcome miscibility, post crystallization and migration issues a principle of click-chemistry was employed to change the molecular characteristics from external to internal plasticization by fixation of a plastisizing unit with help of a stereocomplex crystallization. Hydroxyl terminated polycaprolactone oligomers were used as a macroinitiator for the ring opening polymerization of d-lactide, resulting in blockcopolymers with plasticizing unit polycaprolactone and compatibilizing poly(d-lactic acid)-blocks. The generated block copolymers were blended with a poly(l-lactic acid)-matrix and formed so called stereocomplex crystals. In comparison to unbound polycaprolactone the polycaprolactone blocks show a lower migration tendency regarding a solution test in toluene. Besides that, trapping the plasticizing units via stereocomplex also improves the efficiency of the plasticizer. In comparison to polymer blends with the same amount of non-bonded polycaprolactone oligomers of the same molecular weight, block copolymers with poly(d-lactic acid) and polycaprolactone can shift the glass transition temperature to lower values. This effect can be explained by the modulated crystallization of the polycaprolactone-blocks trapped into the matrix, so that a higher effective amount can interact with the poly(l-lactic acid)-matrix.

Representatives of the genus Anncaliia are known as natural parasites of dipteran and coleopteran insects, amphipod crustaceans, but also humans, primarily with immunodeficiency. Anncaliia algerae-caused fatal myositis is considered as an emergent infectious disease in humans. A. (=Nosema, Brachiola) algerae, the best studied species of the genus, demonstrates the broadest among microsporidia range of natural and experimental hosts, but it has never been propagated in Drosophila. We present ultrastructural analysis of development of A. algerae in visceral muscles and adipocytes of Drosophila melanogaster 2 wk after per oral experimental infection. We observed typical to Anncaliia spp. features of ultrastructure and cell pathology including spore morphology, characteristic extensions of the plasma membrane, and presence of "ridges" and appendages of tubular material at proliferative stages. Anncaliia algerae development in D. melanogaster was particularly similar to one of A. algerae and A.(Brachiola) vesicularum in humans with acute myositis. Given D. melanogaster is currently the most established genetic model, with a fully sequenced genome and easily available transgenic forms and genomic markers, a novel host-parasite system might provide new genetic tools to investigate host-pathogen interactions of A. algerae, as well to test antimicrosporidia drugs., (© 2019 International Society of Protistologists.)

Scientific development has increased the awareness of water pollutant forms and has reawakened the need for its effective purification. Oxyanions are created by a variety of redox-sensitive metals and metalloids. These species are harmful to living matter due to their toxicity, nondegradibility, and mobility in aquatic environments. Among a variety of water treatment techniques, adsorption is one of the simplest, cheapest, and most effective. Since metal-oxide-based adsorbents poses a variety of functional groups onto their surface, they were widely applied in ions sorption. In this paper adsorption of harmful oxyanions by metal oxide-based materials according to literature survey was studied. Characteristic of oxyanions originating from As, V, B, W and Mo, their probable adsorption mechanisms and comparison of their sorption affinity for metal-oxide-based materials such as iron oxides, aluminum oxides, titanium dioxide, manganium dioxide, and various oxide minerals and their combinations are presented in this paper.

X-ray diffraction patterns of decagonal Al[sub 70]Co[sub 15]Ni[sub 15], Al[sub 72]Ni[sub 12]Co[sub 16] and Al[sub 62]Cu[sub 20]Co[sub 15]Si[sub 3] show, apart from 'sharp' reflections, prominent diffuse maxima and diffuse streaks. From an analysis of high-resolution synchrotron data, arguments are given in favour of a more uniform interpretation of all these phenomena in terms of linear phason strain and phason fluctuations. Thus structural modifications, including one-dimensional quasicrystalline domains and periodic domains (approximants) can be conveniently described as transient ordering states, depending on temperature and composition. [ABSTRACT FROM AUTHOR]

Diffuse layers which are observed in different decagonal quasicrystals perpendicular to the unique 'periodic' axis are explained by one-dimensional (1D) columns of icosahedral Al clusters along this axis. From results of X-ray and purely elastic neutron diffraction experiments we give a qualitative explanation by basically off-layer atomic displacements which are grossly uncorrelated in different columnar clusters. A reversible temperature behaviour of the 1D superstructure which vanishes at high temperatures can be understood in the framework of this interpretation. Diffuse intensity modulations within the diffuse layers are discussed in terms of atomic displacements and chemical ordering within the icosahedral clusters which are the basic structural units of the columns. Computer simulations of different columnar models are carried out, their Fourier transforms are compared with the observed patterns. [ABSTRACT FROM AUTHOR]

Microsporidia comprise a large phylum of single-cell and obligate intracellular parasites that can infect a wide range of invertebrate and vertebrate hosts including humans. These fungal-related parasites are characterized by a highly reduced genome, a strong energy dependence on their host, but also by their unique invasion organelle known as the polar tube which is coiled within the resistant spore. Upon appropriate environmental stimulation, the long hollow polar tube (ranging from 50 to 500 μm in length) is extruded at ultra-fast speeds (300 μm/s) from the spore acting as a harpoon-like organelle to transport and deliver the infectious material or sporoplasm into the host cell. To date, seven polar tube proteins (PTPs) with distinct localizations along the extruded polar tube have been described. For example, the specific location of PTP4 and PTP7 at the tip of the polar tube supports their role in interacting with cellular receptor(s). This chapter provides a brief overview on the current understanding of polar tube structure and dynamics of extrusion, primarily through recent advancements in cryo-tomography and 3D reconstruction. It also explores the various mechanisms used for host cell invasion. Finally, recent studies on the structure and maturation of sporoplasm and its moving through the tube are discussed., (© 2024 International Society of Protistologists.)