62 results on '"Salas-Colera, Eduardo"'
Search Results
52. Stabilization of Epitaxial α-Fe2O3Thin Films Grown by Pulsed Laser Deposition on Oxide Substrates
- Author
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Serrano, Aida, Rubio-Zuazo, Juan, López-Sánchez, Jesús, Arnay, Iciar, Salas-Colera, Eduardo, and Castro, Germán R.
- Abstract
We have grown epitaxial incommensurate α-Fe2O3thin films on α-Al2O3(0001), SrTiO3(111), and LaAlO3(001) substrates, identifying hematite as single iron oxide phase stabilized. We demonstrate that a different lattice coupling behavior as a function of the selected oxide substrate mediates the epitaxial character. Single-oriented α-Fe2O3(0001) layers are obtained on α-Al2O3(0001) and SrTiO3(111) substrates, whereas on the LaAlO3(001) substrate, the hematite layer is found to grow along the r-plane to adapt its hexagonal lattice on the cubic lattice of the substrate, evidencing a single-oriented (11̅02) layer. In the film plane, crystallographic axes of α-Fe2O3(0001) are collinear with the α-Al2O3(0001) ones, while a rotation of 30° is found between those of α-Fe2O3(0001) and SrTiO3(111). On LaAlO3(001), α-Fe2O3(11̅02) adopts an in-plane orthorhombic structure rotated 45° respect to the substrate lattice. The crystallographic domain size and the crystalline order are dependent on the incommensurate lattice coupling mechanism. Larger values are obtained for layers grown on α-Al2O3(0001), while lower values correspond to the hematite deposited on LaAlO3(001). Moreover, an Fe–O elongation and Fe–Fe contraction of first neighbors distances as well as a dependency on surface flatness as a function of the substrate lattice parameter is also found.
- Published
- 2018
- Full Text
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53. Searching for relevant criteria to distinguish natural vs.anthropogenic TiO2nanoparticles in soilsElectronic supplementary information (ESI) available. See DOI: 10.1039/c8en00386f
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Pradas del Real, Ana Elena, Castillo-Michel, Hiram, Kaegi, Ralf, Larue, Camille, de Nolf, Wout, Reyes-Herrera, Juan, Tucoulou, Rémi, Findling, Nathaniel, Salas-Colera, Eduardo, and Sarret, Géraldine
- Abstract
Nanosized TiO2is one of the most produced nanomaterials. Agricultural soils are a major compartment of accumulation of TiO2-NPs after release from consumer products into the sewer system, due to the use of sewage sludge as a soil amendment. TiO2is naturally present in soils, and distinguishing between anthropogenic and natural TiO2in soils is thus important to assess the risks associated with the increased use of nano-TiO2. Methods to distinguish these materials in complex matrices such as soils are currently lacking. The purpose of this study was, therefore, to search for characteristic physical and chemical properties of natural and engineered nano-TiO2, based on a combination of bulk, micro and nanofocused X-ray fluorescence and X-ray absorption spectroscopy, transmission electron microscopy, X-ray diffraction and chemical analyses. Digested sewage sludge, agricultural soil and sludge-amended soil were studied by these techniques. The particle size distribution was not a relevant criterion since the sludge and the sludge-amended soil contained a variety of nanometer- and micrometer sized Ti-containing particles. Both the sludge and the soil contained a mixture of rutile and anatase, with a minor proportion of amorphous TiO2. In the sludge, there was no trend relating particle size and Ti mineralogy. The morphology of the TiO2particles proved to be different in the two matrices, with smooth faceted particles in the sludge and rough irregular ones in the soil. In addition, natural TiO2particles were included in micro and macroaggregates of the soil and formed intricate assemblages with minerals and organic compounds. In the sludge, TiO2formed homo and heteroaggregates of simpler structure, richer in organic matter. Thus, the study of the morphology of TiO2particles and their status in unperturbed mineral–organic assemblages may provide some insights into their origin. The observed differences may attenuate over time, due to the incorporation of the sludge material within the soil structure.
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- 2018
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54. Design and development of a controlled pressure/temperature set-up for in situ studies of solid-gas processes and reactions in a synchrotron X-ray powder diffraction station.
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Salas-Colera, Eduardo, Muñoz-Noval, Álvaro, Heyman, Catherine, Ania, Conchi O., Parra, José B., García-Granda, Santiago, Calero, Sofía, Rubio-Zuazo, Juan, and Castro, Germán R.
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SYNCHROTRONS , *X-ray diffraction , *X-ray reflection , *RADIOGRAPHY , *ELECTROMAGNETIC waves - Abstract
A novel set-up has been designed and used for synchrotron radiation X-ray high-resolution powder diffraction (SR-HRPD) in transmission geometry (spinning capillary) for in situ solid-gas reactions and processes in an isobaric and isothermal environment. The pressure and temperature of the sample are controlled from 10−3 to 1000 mbar and from 80 to 1000 K, respectively. To test the capacities of this novel experimental set-up, structure deformation in the porous material zeolitic imidazole framework (ZIF-8) by gas adsorption at cryogenic temperature has been studied under isothermal and isobaric conditions. Direct structure deformations by the adsorption of Ar and N2 gases have been observed in situ, demonstrating that this set-up is perfectly suitable for direct structural analysis under in operando conditions. The presented results prove the feasibility of this novel experimental station for the characterization in real time of solid-gas reactions and other solid-gas processes by SR-HRPD. [ABSTRACT FROM AUTHOR]
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- 2015
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55. Correction: Bandgap-adjustment and enhanced surface photovoltage in Y-substituted LaTaIVO2N.
- Author
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Bubeck, Cora, Widenmeyer, Marc, De Denko, Alexandra T., Richter, Gunther, Coduri, Mauro, Salas Colera, Eduardo, Goering, Eberhard, Zhang, Hongbin, Yoon, Songhak, Osterloh, Frank E., and Weidenkaff, Anke
- Abstract
Correction for 'Bandgap-adjustment and enhanced surface photovoltage in Y-substituted LaTa
IV O2 N' by Cora Bubeck et al., J. Mater. Chem. A, 2020, 8, 11837–11848, DOI: 10.1039/D0TA02136A. [ABSTRACT FROM AUTHOR]- Published
- 2020
- Full Text
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56. Correlation of Electrical Response and Structural Phase Transitions in Bi2O3 Nanowires.
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Vila, María, Rivera‐Calzada, Alberto, Salas‐Colera, Eduardo, Castro, Germán R., and Díaz‐Guerra, Carlos
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X-ray absorption spectra ,X-ray diffraction ,STATISTICAL correlation ,ELECTRIC properties of nanowires ,ELECTRIC admittance - Abstract
The electric response of Bi2O3 nanowires is studied by means of impedance spectroscopy at high temperatures and compared to a reference bulk Bi2O3 ceramic. Nanowires present the α to δ phase transition at a similar temperature than the ceramic (1007 vs. 1010 K), showing an increase of over two orders of magnitude in the conductance. On cooling, nanowires change directly to the α phase instead of presenting metastable phases, like the bulk sample. Both samples present a dominant ionic contribution in the δ phase which is also present in the α phase at the highest temperatures. X‐ray absorption spectroscopy (XAS) measurements reveal no differences in the short range structural order of both kinds of samples at room temperature, while a detailed analysis by high temperature X‐ray diffraction (HTXRD) confirms the transitions observed in the conductance measurements. The authors relate the direct phase transition δ → α in nanowires to a lower thermal conductivity in these nanostructures. The ionic transport properties of Bi2O3 nanowires and ceramics as a function of temperature are investigated and correlated with a structural study of the samples. An α → δ phase transition is observed in both materials, but a direct δ → α transition, without the formation of metastable phases, is observed on cooling the nanowires, probably due to their lower thermal conductivity. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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57. Large coincidence lattice on Au/Fe3O4 incommensurate structure for spintronic applications.
- Author
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Muñoz-Noval, Alvaro, Rubio-Zuazo, Juan, Salas-Colera, Eduardo, Serrano, Aida, Rubio-Marcos, Fernando, and Castro, Germán R.
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IRON oxide nanoparticles , *COINCIDENCE circuits , *SPINTRONICS , *PULSED laser deposition , *NANOCRYSTALS - Abstract
The design of metallic hybrid systems for spintronics has been widely studied during the past decade, motivated by the promising technological applications of these materials. Nevertheless, the importance of preserving the native structure and properties of the interfaces is often ignored. Here, we present the fabrication of nanocrystalline Au (0 0 1) onto a single oriented Fe 3 O 4 (0 0 1) thin film as a promising hybrid system to develop spintronic devices by growing Au over the Fe 3 O 4 by using a simple one-pot Pulsed Laser Deposition (PLD) approach. The structural coupling between Au nanocrystals and Fe 3 O 4 layer results in the development of an incommensurate structure based on a coincidence lattice of order 35, which preserves the intrinsic properties of the Au nanocrystals, the Fe 3 O 4 matrix and the interface between them. The general strategy described in the present work preserves the structure and main intrinsic properties of the constituting materials, being a fundamental issue for the future development of spintronic devices. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
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58. Self-assembly of iron oxide precursor micelles driven by magnetic stirring time in sol–gel coatings
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Germán R. Castro, Noemi Carmona, Eduardo Salas-Colera, Pilar Marín, José F. Marco, M. Abuín, Aida Serrano, Álvaro Muñoz-Noval, Jesús López-Sánchez, A. del Campo, O. Rodríguez de la Fuente, J. de la Figuera, European Commission, Agencia Estatal de Investigación (España), Ministerio de Economía y Competitividad (España), Comunidad de Madrid, Consejo Superior de Investigaciones Científicas (España), López-Sánchez, Jesús, Serrano, Aida, Salas- Colera, Eduardo, Rodríguez-de- la-Fuente, Oscar, Ministerio de Economía, Industria y Competitividad (España), Ministerio de Ciencia, Innovación y Universidades (España), Ministerio de Ciencia e Innovación (España), López-Sánchez, Jesús [0000-0002-2670-9347], Serrano, Aida [0000-0002-6162-0014], Salas- Colera, Eduardo [0000-0001-7812-268X], and Rodríguez-de- la-Fuente, Oscar [0000-0002-6888-459X]
- Subjects
Materials science ,General Chemical Engineering ,Iron oxide ,Nanoparticle ,02 engineering and technology ,Sol–gel ,010402 general chemistry ,01 natural sciences ,Micelle ,chemistry.chemical_compound ,Pulmonary surfactant ,Sol-gel ,Física de materiales ,Física ,General Chemistry ,021001 nanoscience & nanotechnology ,Microstructure ,3. Good health ,0104 chemical sciences ,chemistry ,Chemical engineering ,Física del estado sólido ,Alkoxide ,Self-assembly ,Microstructures ,0210 nano-technology - Abstract
[EN] The purpose of this work is to fabricate self-assembled microstructures by the sol–gel method and study the morphological, structural and compositional dependence of 3-Fe2O3 nanoparticles embedded in silica when glycerol (GLY) and cetyl-trimethylammonium bromide (CTAB) are added as steric agents simultaneously. The combined action of a polyalcohol and a surfactant significantly modifies the morphology of the sample giving rise to a different microstructure in each of the studied cases (1, 3 and 7 days of magnetic stirring time). This is due to the fact that the addition of these two compounds leads to a considerable increase in gelation time as GLY can interact with the alkoxide group on the surface of the iron oxide precursor micelle and/or be incorporated into the hydrophilic chains of CTAB. This last effect causes the iron oxide precursor micelles to be interconnected forming aggregates whose size and structure depend on the magnetic stirring time of the sol–gel synthetic route. In this paper, crystalline structure, composition, purity and morphology of the sol–gel coatings densified at 960 ºC are examined. Emphasis is placed on the nominal percentage of the different iron oxides found in the samples and on the morphological and structural differences. This work implies the possibility of patterning 3-Fe2O3 nanoparticles in coatings and controlling their purity by an easy one-pot sol–gel method., Spanish Ministry of Industry, Economy and Competitiveness for financing the project MAT2015-65445-C2-1-R, MAT2017-86450-C4-1-R, MAT2015-67557-C2-1-P, by the Comunidad de Madrid S2013/MIT-2850 NANOFRONTMAG and H2020 AMPHIBIAN Project ID: 720853. The authors are also grateful to the BM25-SpLine staff for their valuable technical support beyond their duties and for the financial support from the Spanish Ministry of Science, Innovation and Universities (MICIU) and The Spanish National Research Council (CSIC) under Grant No. PIE 2010- 6OE-013, The ESRF – The European Synchrotron, MICIU and CSIC are acknowledged for provision of synchrotron radiation facilities. A. S. acknowledges the Financial support from the Comunidad de Madrid for an “Atracción de Talento Investigador” contract (No. 2017-t2/IND5395).
- Published
- 2019
59. In operando evidence of deoxygenation in ionic liquid gating of YBa2Cu3O7-X.
- Author
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Rivera-Calzada, Alberto, Garcia-Barriocanal, Javier, Perez-Muñoz, Ana M., Schio, Pedro, Leon, Carlos, Santamaria, Jacobo, Cezar, Julio C., Poloni, Roberta, Fernandez-Martinez, Alejandro, Salas-Colera, Eduardo, Castro, German R., Kinney, Joseph, and Goldman, Allen M.
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DEOXYGENATION , *IONIC liquids , *DENSITY functional theory , *ELECTRIC double layer , *SEMICONDUCTOR doping - Abstract
Field-effect experiments on cuprates using ionic liquids have enabled the exploration of their rich phase diagrams [Leng X, et al. (2011) Phys Rev Lett 107(2):027001]. Conventional understanding of the electrostatic doping is in terms of modifications of the charge density to screen the electric field generated at the double layer. However, it has been recently reported that the suppression of the metal to insulator transition induced in VO2 by ionic liquid gating is due to oxygen vacancy formation rather than to electrostatic doping [Jeong J, et al. (2013) Science 339(6126):1402–1405]. These results underscore the debate on the true nature, electrostatic vs. electrochemical, of the doping of cuprates with ionic liquids. Here, we address the doping mechanism of the high-temperature superconductor YBa2Cu3O7-X (YBCO) by simultaneous ionic liquid gating and X-ray absorption experiments. Pronounced spectral changes are observed at the Cu K-edge concomitant with the superconductor-to-insulator transition, evidencing modification of the Cu coordination resulting from the deoxygenation of the CuO chains, as confirmed by first-principles density functional theory (DFT) simulations. Beyond providing evidence of the importance of chemical doping in electric double-layer (EDL) gating experiments with superconducting cuprates, our work shows that interfacing correlated oxides with ionic liquids enables a delicate control of oxygen content, paving the way to novel electrochemical concepts in future oxide electronics. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
60. Determination of the local structure of Sr 2-x M x IrO 4 (M = K, La) as a function of doping and temperature.
- Author
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Terashima K, Paris E, Salas-Colera E, Simonelli L, Joseph B, Wakita T, Horigane K, Fujii M, Kobayashi K, Horie R, Akimitsu J, Muraoka Y, Yokoya T, and Saini NL
- Abstract
The local structure of correlated spin-orbit insulator Sr2-xMxIrO4 (M = K, La) has been investigated by Ir L3-edge extended X-ray absorption fine structure measurements. The measurements were performed as a function of temperature for different dopings induced by substitution of Sr with La or K. It is found that Ir-O bonds have strong covalency and they hardly show any change across the Néel temperature. In the studied doping range, neither Ir-O bonds nor their dynamics, measured by their mean square relative displacements, show any appreciable change upon carrier doping, indicating the possibility of nanoscale phase separation in the doped system. On the other hand, there is a large increase of the static disorder in Ir-Sr correlation, larger for K doping than La doping. Similarities and differences with respect to the local lattice displacements in cuprates are briefly discussed.
- Published
- 2018
- Full Text
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61. Singlet Orbital Ordering in Bilayer Sr_{3}Cr_{2}O_{7}.
- Author
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Jeanneau J, Toulemonde P, Remenyi G, Sulpice A, Colin C, Nassif V, Suard E, Salas Colera E, Castro GR, Gay F, Urdaniz C, Weht R, Fevrier C, Ralko A, Lacroix C, Aligia AA, and Núñez-Regueiro M
- Abstract
We perform an extensive study of Sr_{3}Cr_{2}O_{7}, the n=2 member of the Ruddlesden-Popper Sr_{n+1}Cr_{n}O_{3n+1} system. An antiferromagnetic ordering is clearly visible in the magnetization and the specific heat, which yields a huge transition entropy, Rln(6). By neutron diffraction as a function of temperature we have determined the antiferromagnetic structure that coincides with the one obtained from density functional theory calculations. It is accompanied by anomalous asymmetric distortions of the CrO_{6} octahedra. Strong coupling and Lanczos calculations on a derived Kugel-Khomskii Hamiltonian yield a simultaneous orbital and moment ordering. Our results favor an exotic ordered phase of orbital singlets not originated by frustration.
- Published
- 2017
- Full Text
- View/download PDF
62. In operando evidence of deoxygenation in ionic liquid gating of YBa2Cu3O7-X.
- Author
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Perez-Muñoz AM, Schio P, Poloni R, Fernandez-Martinez A, Rivera-Calzada A, Cezar JC, Salas-Colera E, Castro GR, Kinney J, Leon C, Santamaria J, Garcia-Barriocanal J, and Goldman AM
- Abstract
Field-effect experiments on cuprates using ionic liquids have enabled the exploration of their rich phase diagrams [Leng X, et al. (2011) Phys Rev Lett 107(2):027001]. Conventional understanding of the electrostatic doping is in terms of modifications of the charge density to screen the electric field generated at the double layer. However, it has been recently reported that the suppression of the metal to insulator transition induced in VO
2 by ionic liquid gating is due to oxygen vacancy formation rather than to electrostatic doping [Jeong J, et al. (2013) Science 339(6126):1402-1405]. These results underscore the debate on the true nature, electrostatic vs. electrochemical, of the doping of cuprates with ionic liquids. Here, we address the doping mechanism of the high-temperature superconductor YBa2 Cu3 O7-X (YBCO) by simultaneous ionic liquid gating and X-ray absorption experiments. Pronounced spectral changes are observed at the Cu K-edge concomitant with the superconductor-to-insulator transition, evidencing modification of the Cu coordination resulting from the deoxygenation of the CuO chains, as confirmed by first-principles density functional theory (DFT) simulations. Beyond providing evidence of the importance of chemical doping in electric double-layer (EDL) gating experiments with superconducting cuprates, our work shows that interfacing correlated oxides with ionic liquids enables a delicate control of oxygen content, paving the way to novel electrochemical concepts in future oxide electronics., Competing Interests: The authors declare no conflict of interest.- Published
- 2017
- Full Text
- View/download PDF
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