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The calculation of work distributions in a quantum many-body system is of significant importance and also of formidable difficulty in the field of nonequilibrium quantum statistical mechanics. To solve this problem, inspired by Schwinger-Keldysh formalism, we propose the contour-integral formulation of the work statistics. Based on this contour integral, we show how to do the perturbation expansion of the characteristic function of work (CFW) and obtain the approximate expression of the CFW to the second order of the work parameter for an arbitrary system under a perturbative protocol. We also demonstrate the validity of fluctuation theorems by utilizing the Kubo-Martin-Schwinger condition. Finally, we use noninteracting identical particles in a forced harmonic potential as an example to demonstrate the powerfulness of our approach., Comment: 6 pages, 1 figure

Usually the calculation of work distributions in an arbitrary nonequilibrium process in a quantum system, especially in a quantum many-body system is extremely cumbersome. For all quantum systems described by quadratic Hamiltonians, we invent a universal method for solving the work distribution of quantum systems in an arbitrary driving process by utilizing the group-representation theory. This method enables us to efficiently calculate work distributions where previous methods fail. In some specific models, such as the time-dependent harmonic oscillator, the dynamical Casimir effect, and the transverse XY model, the exact and analytical solutions of work distributions in an arbitrary nonequilibrium process are obtained. Our work initiates the study of quantum stochastic thermodynamics based on group-representation theory.

Work statistics characterizes important features of a non-equilibrium thermodynamic process. But the calculation of the work statistics in an arbitrary non-equilibrium process is usually a cumbersome task. In this work, we study the work statistics in quantum systems by employing Feynman's path-integral approach. We derive the analytical work distributions of two prototype quantum systems. The results are proved to be equivalent to the results obtained based on Schr\"{o}dinger's formalism. We also calculate the work distributions in their classical counterparts by employing the path-integral approach. Our study demonstrates the effectiveness of the path-integral approach to the calculation of work statistics in both quantum and classical thermodynamics, and brings important insights to the understanding of the trajectory work in quantum systems.

The standard definition of quantum fluctuating work is based on the two-projective energy measurement, which however does not apply to systems with initial quantum coherence because the first projective energy measurement destroys the initial coherence, and affects the subsequent evolution of the system. To address this issue, several alternative definitions, such as those based on the full counting statistics and the Margenau-Hill distribution, have been proposed recently. These definitions seem ad hoc because justifications for them are still lacking. In the current study, by utilizing the quantum Feynman-Kac formula and the phase space formulation of quantum mechanics, we prove that the leading order of work distributions is equal to the classical work distribution. Thus we prove the validity of the quantum-classical correspondence of work distributions for initial states with quantum coherence, and provide some justification for those definitions of work. We use an exactly solvable model of the linearly dragged harmonic oscillator to demonstrate our main results., Comment: 12 pages, 1 figure

We study the joint probability distribution function of the work and the change of photon number of the nonequilibrium process of driving the electromagnetic (EM) field in a three-dimensional cavity with an oscillating boundary. The system is initially prepared in a grand canonical equilibrium state and we obtain the analytical expressions of the characteristic functions of work distributions in the single-resonance and multiple-resonance conditions. Our study demonstrates the validity of the fluctuation theorems of the grand canonical ensemble in nonequilibrium processes with particle creation and annihilation. In addition, our work illustrates that in the high temperature limit, the work done on the quantized EM field approaches its classical counterpart; while in the low temperature limit, similar to Casimir effect, it differs significantly from its classical counterpart., Comment: 14 pages, 3 figures

Stochastic thermodynamics provides an important framework to explore small physical systems where thermal fluctuations are inevitable. In the studies of stochastic thermodynamics, some thermodynamic quantities, such as the trajectory work, associated with the complete Langevin equation (the Kramers equation) are often assumed to converge to those associated with the overdamped Langevin equation (the Smoluchowski equation) in the overdamped limit under the overdamped approximation. Nevertheless, a rigorous mathematical proof of the convergence of the work distributions to our knowledge has not been reported so far. Here we study the convergence of the work distributions explicitly. In the overdamped limit, we rigorously prove the convergence of the extended Fokker-Planck equations including work using a multiple timescale expansion approach. By taking the linearly dragged harmonic oscillator as an exactly solvable example, we analytically calculate the work distribution associated with the Kramers equation, and verify its convergence to that associated with the Smoluchowski equation in the overdamped limit. We quantify the accuracy of the overdamped approximation as a function of the damping coefficient. In addition, we experimentally demonstrate that the data of the work distribution of a levitated silica nanosphere agrees with the overdamped approximation in the overdamped limit, but deviates from the overdamped approximation in the low-damping case. Our work fills a gap between the stochastic thermodynamics based on the complete Langevin equation (the Kramers equation) and the overdamped Langevin equation (the Smoluchowski equation), and deepens our understanding of the overdamped approximation in stochastic thermodynamics., Comment: 15 pages, 6 figures

We examine the effects of the Dzyaloshinsky-Moriya (DM) interaction on the nonequilibrium thermodynamics in an anisotropic $XY$ spin chain, which is driven out of equilibrium by a sudden quench of the control parameter of the Hamiltonian. By analytically evaluating the statistical properties of the work distribution and the irreversible entropy production, we investigate the influences of the DM interaction on the nonequilibrium thermodynamics of the system with different parameters at various temperatures. We find that depending on the anisotropy of the system and the temperature, the DM interaction may have different impacts on the nonequilibrium thermodynamics. Interestingly, the critical line induced by the DM interaction can be revealed via the properties of the nonequilibrium thermodynamics. In addition, our results suggest that the strength of the DM interaction can be detected experimentally by studying the nonequilibrium thermodynamics., Comment: 9 pages, 7 figures

We study the heat statistics of a quantum Brownian motion described by the Caldeira-Leggett model. By using the path integral approach, we introduce a novel concept of the quantum heat functional along every pair of Feynman paths. This approach has an advantage of improving our understanding about heat in quantum systems. First, we demonstrate the microscopic reversibility of the system by connecting the heat functional to the forward and its time-reversed probabilities. Second, we analytically prove the quantum-classical correspondence of the heat functional and their statistics, which allows us to obtain better intuitions about the difference between classical and quantum heat., Comment: 11 pages, 1 figure

We investigate quantum corrections to the classical work characteristic function (CF) as a semiclassical approximation to the full quantum work CF. In addition to explicitly establishing the quantum-classical correspondence of the Feynman-Kac formula, we find that these quantum corrections must be in even powers of $\hbar$. Exact formulas of the lowest corrections ($\hbar^2$) are proposed, and their physical origins are clarified. We calculate the work CFs for a forced harmonic oscillator and a forced quartic oscillator respectively to illustrate our results., Comment: Phys.Rev.E, in press

Feynman's ratchet is a microscopic machine in contact with two heat reservoirs, at temperatures $T_A$ and $T_B$, that was proposed by Richard Feynman to illustrate the second law of thermodynamics. In equilibrium ($T_A=T_B$), thermal fluctuations prevent the ratchet from generating directed motion. When the ratchet is maintained away from equilibrium by a temperature difference ($T_A \ne T_B$), it can operate as a heat engine, rectifying thermal fluctuations to perform work. While it has attracted much interest, the operation of Feynman's ratchet as a heat engine has not been realized experimentally, due to technical challenges. In this work, we realize Feynman's ratchet with a colloidal particle in a one dimensional optical trap in contact with two heat reservoirs: one is the surrounding water, while the effect of the other reservoir is generated by a novel feedback mechanism, using the Metropolis algorithm to impose detailed balance. We verify that the system does not produce work when $T_A=T_B$, and that it becomes a microscopic heat engine when $T_A \ne T_B$. We analyze work, heat and entropy production as functions of the temperature difference and external load. Our experimental realization of Feynman's ratchet and the Metropolis algorithm can also be used to study the thermodynamics of feedback control and information processing, the working mechanism of molecular motors, and controllable particle transportation.

Work belongs to the most basic notions in thermodynamics but it is not well understood in quantum systems, especially in open quantum systems. By introducing a novel concept of work functional along individual Feynman path, we invent a new approach to study thermodynamics in the quantum regime. Using the work functional, we derive a path-integral expression for the work statistics. By performing the $\hbar$ expansion, we analytically prove the quantum-classical correspondence of the work statistics. In addition, we obtain the quantum correction to the classical fluctuating work. We can also apply this approach to an open quantum system in the strong coupling regime described by the quantum Brownian motion model. This approach provides an effective way to calculate the work in open quantum systems by utilizing various path integral techniques. As an example, we calculate the work statistics for a dragged harmonic oscillator in both isolated and open quantum systems., Comment: 7 pages, 3 figures (supplemental material: 6 pages). (v2) removed the discussion about heat, which appears in arXiv:1805.02815 . Changed the title

Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo decoherence but not dissipation, we argue that it is natural to define quantum work exactly as for isolated quantum systems, using the two-point measurement protocol. Complementing previous theoretical analysis using quantum channels, we show that the nonequilibrium work relation remains valid in this situation, and we test this assertion experimentally using a system engineered from an optically trapped ion. Our experimental results reveal the work relation's validity over a variety of driving speeds, decoherence rates, and effective temperatures and represent the first confirmation of the work relation for non-unitary dynamics., Comment: 21 pages, 7 figures

We extend the well-known static duality \cite{girardeau1960relationship, cheon1999fermion} between 1-D Bosons and 1-D Fermions to the dynamical version. By utilizing this dynamical duality we find the duality of non-equilibrium work distributions between interacting 1-D bosonic (Lieb-Liniger model) and 1-D fermionic (Cheon-Shigehara model) systems with dual contact interactions. As a special case, the work distribution of the Tonks-Girardeau (TG) gas is identical to that of 1-D free fermionic system even though their momentum distributions are significantly different. In the classical limit, the work distributions of Lieb-Liniger models (Cheon-Shigehara models) with arbitrary coupling strength converge to that of the 1-D noninteracting distinguishable particles, although their elemetary excitations (quasi-particles) obey different statistics, e.g. the Bose-Einstein, the Fermi-Dirac and the fractional statistics. We also present numerical results of the work distributions of Lieb-Liniger model with various coupling strengths, which demonstrate the convergence of work distributions in the classical limit., Comment: 8 pages, 2 figure, 2 tables

Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium processes, collectively known as fluctuation theorems, have been discovered and provided critical insights. These fluctuation theorems are generalizations of the second law, and can be unified by a differential fluctuation theorem. Here we perform the first experimental test of the differential fluctuation theorem, using an optically levitated nanosphere in both underdamped and overdamped regimes, and in both spatial and velocity spaces. We also test several theorems that can be obtained from it directly, including a generalized Jarzynski equality that is valid for arbitrary initial states, and the Hummer-Szabo relation. Our study experimentally verifies these fundamental theorems, and initiates the experimental study of stochastic energetics with the instantaneous velocity measurement., Comment: accepted by Phys. Rev. Lett

By analyzing the probability distributions of the Loschmidt echo (LE) and quantum work, we examine the nonequilibrium effects of a quantum many-body system, which exhibits an excited-state quantum phase transition (ESQPT). We find that depending on the value of the controlling parameter the distribution of the LE displays different patterns. At the critical point of the ESQPT, both the averaged LE and the averaged work show a cusplike shape. Furthermore, by employing the finite-size scaling analysis of the averaged work, we obtain the critical exponent of the ESQPT. Finally, we show that at the critical point of ESQPT the eigenstate is a highly localized state, further highlighting the influence of the ESQPT on the properties of the many-body system., Comment: 10 pages, 13 figures; accepted for publication in Physical Review E

In this article, we introduce two kinds of Fluctuation Theorems (FT) containing information for autonomous Maxwell's demon-assisted machines. Using Jensen's Inequality, we obtain Landauer's principle formulation of the second law for the whole process of the machine. Finally we make use of our results to analyze a new information device. \pacs{05.70.Ln, 05.40.-a, 89.70.Cf}, Comment: submitted to Physical Review E

Based on previous studies in a single particle system in both the integrable [Jarzynski, Quan, and Rahav, Phys.~Rev.~X {\bf 5}, 031038 (2015)] and the chaotic systems [Zhu, Gong, Wu, and Quan, Phys.~Rev.~E {\bf 93}, 062108 (2016)], we study the the correspondence principle between quantum and classical work distributions in a quantum many-body system. Even though the interaction and the indistinguishability of identical particles increase the complexity of the system, we find that for a quantum many-body system the cumulative quantum work distribution still converges to its classical counterpart in the semiclassical limit. Our results imply that there exists a correspondence principle between quantum and classical work distributions in an interacting quantum many-body system, especially in the large particle number limit, and further justify the definition of quantum work via two point energy measurements in quantum many-body systems., Comment: 10 pages, 11 figures, Published in Phys. Rev. E

In conventional thermodynamics, it is widely acknowledged that the realization of an isothermal process for a system requires a quasi-static controlling protocol. Here we propose and design a strategy to realize a finite-rate isothermal transition from an equilibrium state to another one with same temperature, which is named shortcut to isothermality~(STI). By using STI, we unexpectedly derive three nonequilibrium work relations, including an identity between the free energy difference and the mean work due to the potential of the original system, a generalized Jarzynski equality, and the inverse relationship between the irreversible work and the total driving time. We numerically confirm these three relations by considering the motion of a Brownian particle trapped in a harmonic potential and dragged by a time-dependent force., Comment: accepted by Phys. Rev. E

The piston system (particles in a box) is the simplest and paradigmatic model in traditional thermodynamics. However, the recently established framework of stochastic thermodynamics (ST) fails to apply to this model system due to the embedded singularity in the potential. In this Letter we study the stochastic thermodynamics of a particle in a box by adopting a novel coordinate transformation technique. Through comparing with the exact solution of a breathing harmonic oscillator, we obtain analytical results of work distribution for an arbitrary protocol in the linear response regime, and verify various predictions of the Fluctuation-Dissipation Relation. When applying to the Brownian Szilard's engine model, we obtain the optimal protocol $\lambda_t = \lambda_0 2^{t/\tau}$ for a given sufficiently long total time $\tau$. Our study not only establishes a paradigm for studying ST of a particle in a box, but also bridges the long-standing gap in the development of ST., Comment: 6+3 pages, 3+2 figures

We numerically study the work distributions in a chaotic system and examine the relationship between quantum work and classical work. Our numerical results suggest that there exists a correspondence principle between quantum and classical work distributions in a chaotic system. This correspondence was proved for one-dimensional (1D) integrable systems in a recent work [Jarzynski, Quan, and Rahav, Phys. Rev. X 5, 031038 (2015)]. Our investigation further justifies the definition of quantum work via two point energy measurements.

After a brief historical review of ergodicity and mixing in dynamics, particularly in quantum dynamics, we introduce definitions of quantum ergodicity and mixing using the structure of the system's energy levels and spacings. Our definitions are consistent with usual understanding of ergodicity and mixing. Two parameters concerning the degeneracy in energy levels and spacings are introduced. They are computed for right triangular billiards and the results indicate a very close relation between quantum ergodicity (mixing) and quantum chaos. At the end, we argue that, besides ergodicity and mixing, there may exist a third class of quantum dynamics which is characterized by a maximized entropy., Comment: 10 pages, 6 figures and 1 table

For closed quantum systems driven away from equilibrium, work is often defined in terms of projective measurements of initial and final energies. This definition leads to statistical distributions of work that satisfy nonequilibrium work and fluctuation relations. While this two-point measurement definition of quantum work can be justified heuristically by appeal to the first law of thermodynamics, its relationship to the classical definition of work has not been carefully examined. In this paper we employ semiclassical methods, combined with numerical simulations of a driven quartic oscillator, to study the correspondence between classical and quantal definitions of work in systems with one degree of freedom. We find that a semiclassical work distribution, built from classical trajectories that connect the initial and final energies, provides an excellent approximation to the quantum work distribution when the trajectories are assigned suitable phases and are allowed to interfere. Neglecting the interferences between trajectories reduces the distribution to that of the corresponding classical process. Hence, in the semiclassical limit, the quantum work distribution converges to the classical distribution, decorated by a quantum interference pattern. We also derive the form of the quantum work distribution at the boundary between classically allowed and forbidden regions, where this distribution tunnels into the forbidden region. Our results clarify how the correspondence principle applies in the context of quantum and classical work distributions, and contribute to the understanding of work and nonequilibrium work relations in the quantum regime., Comment: 22 pages, 9 figures

By taking full advantage of the dynamic property imposed by the detailed balance condition, we derive a new refined unified fluctuation theorem (FT) for general stochastic thermodynamic systems. This FT involves the joint probability distribution functions of the final phase space point and a thermodynamic variable. Jarzynski equality, Crooks fluctuation theorem, and the FTs of heat as well as the trajectory entropy production can be regarded as special cases of this refined unified FT, and all of them are generalized to arbitrary initial distributions. We also find that the refined unified FT can easily reproduce the FTs for processes with the feedback control, due to its unconventional structure that separates the thermodynamic variable from the choices of initial distributions. Our result is heuristic for further understanding of the relations and distinctions between all kinds of FTs, and might be valuable for studying thermodynamic processes with information exchange., Comment: 15 pages, 1 table

Motivated by the recent proposed models of the information engine [D. Mandal and C. Jarzynski, Proc. Natl. Acad. Sci. 109, 11641 (2012)] and the information refrigerator [D. Mandal, H. T. Quan, and C. Jarzynski, Phys. Rev. Lett. 111, 030602 (2013)], we propose a minimal model of the information pump and the information eraser based on enzyme kinetics. This device can either pump molecules against the chemical potential gradient by consuming the information encoded in the bit stream or (partially) erase the information encoded in the bit stream by consuming the Gibbs free energy. The dynamics of this model is solved exactly, and the "phase diagram" of the operation regimes is determined. The efficiency and the power of the information machine is analyzed. The validity of the second law of thermodynamics within our model is clarified. Our model offers a simple paradigm for the investigating of the thermodynamics of information processing involving the chemical potential in small systems.