51. Effective closure temperature in leaky and/or saturating thermochronometers
- Author
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Andrew S. Murray, Pierre G. Valla, Benny Guralnik, Frédéric Herman, Richard B. Paris, Mayank Jain, Edward J. Rhodes, and T. Mark Harrison
- Subjects
Arrhenius equation ,Time constant ,Thermal boundary conditions ,Thermodynamics ,Mineralogy ,NO storage ,symbols.namesake ,Geophysics ,Space and Planetary Science ,Geochemistry and Petrology ,Earth and Planetary Sciences (miscellaneous) ,symbols ,Gas constant ,Incomplete gamma function ,General expression ,Closure temperature ,Geology - Abstract
The classical equation of closure temperature ( T C ) in thermochronometry ( Dodson, 1973 ), assumed (i) no storage limitation for the accumulating radiogenic product, (ii) a negligible product concentration at the initial temperature of cooling T 0 , and (iii) a negligible product loss at the final (present-day) temperature T P . A subsequent extension ( Ganguly and Tirone, 1999 ) provided a simple correction for systems cooling from an arbitrary T 0 , at which presence of an initial concentration profile may affect final concentrations. Here, we use a combination of analytical and numerical solutions to derive a general expression for the effective closure temperature in (i) systems which cool between arbitrary initial and final temperatures, potentially still suffering from thermal product loss at T P (termed ‘leaky’), and (ii) systems which may contain a physical limit on the maximum amount of product that can be stored (termed ‘saturating’). While all conservative results can be easily reproduced, an extended use of our formulation provides meaningful effective closure temperatures even when the standard calculation schemes fail. For a first-order loss radiometric system governed by K ( T ) = s exp ( − E / R T ) , where E [J mol−1] and s [s−1] are the Arrhenius parameters and R is the gas constant, we find that the effective closure temperature T C ( T 0 , T P ) is given by: T C ( T 0 , T P ) = { 1 T P − R / E τ λ − τ K P ln [ 1 + τ λ − τ K P ( τ K P ) τ λ e − τ K P ( Γ ( τ λ , τ K P ) − Γ ( τ λ , τ K 0 ) ) ] } − 1 where K 0 and K P [s−1] are shorthand for K ( T 0 ) and K ( T P ) , respectively, λ [s−1] the production rate, τ [s] a time constant, and Γ ( a , z ) the upper incomplete gamma function. Under conventional conditions, our solution reduces to Dodsonʼs formula. Although the solution strictly applies only to systems where 1 / T increases linearly with time, it is nevertheless a useful approximation for a broad range of cooling functions in systems where closure occurs close to the systemʼs initial/final thermal boundary conditions. We clarify the use and the meaning of T C ( T 0 , T P ) by drawing a comparison between (i) a hypothetical application of apatite U–Pb dating ( T C ≈ 450 ° C ) on Venus (mean surface temperature of 450 °C, leaky behaviour), and (ii) the recently introduced thermochronometric application of optically stimulated luminescence (OSL) dating on Earth (both leaky and saturating behaviour).
- Published
- 2013
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