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51. Structure of ethyl 2-chloro-4-methyl-6-(1-pyrrolidinyl)benzoate.

Author

Schlicksupp L, Quincy DA, and Natale NR

Subjects
Chemical Phenomena, Chemistry, Physical, Molecular Structure, X-Ray Diffraction, Pyrrolidines
Abstract

C14H18ClNO2, Mr = 267.7, orthorhombic, Pbca, a = 10.571 (3), b = 12.081 (5), c = 21.384 (6) A, V = 2731 A3, Z = 8, Dx = 1.30 g cm-3, Mo K alpha, lambda = 0.71069 A, mu = 3.59 cm-1, F(000) = 1136, T = 293 K, R = 0.0357 for 716 observed reflections. In molecules of the title compound the ester substituent is forced from conjugation with the aromatic ring and nitrogen long pair by steric interaction with the adjacent chlorine.

Published
1989
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