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The mixing ratio profile of N2O5 has been inferred from high-resolution emission spectra obtained with a balloon-borne Fourier spectrometer. The observations were taken for the period from midnight to predawn on September 16, 1986 at 32 deg N latitude. The inferred volume mixing ratio from nighttime average spectra has a peak of about 1.8 x 10 to the -9th in the 32-35 altitude range. The inferred mixing ratio is generally less than the theoretical predictions from a one-dimensional model.

A liquid-nitrogen cooled Fourier transform spectrometer (SIRIS) measures thermal limb-emission of the stratosphere from a balloon platform at a nominal altitude of 40 km, under night and day conditions, with a 3 km vertical resolution. N2O5 and HNO3 mixing ratios inferred from emission spectra are compared with previous measurements and with the predictions from a one-dimensional photochemical model.

ClONO2 was observed in high-resolution infrared emission spectra obtained on Nov. 6, 1984, by a balloon-borne Fourier spectrometer. The observations took place near 0300 LT at a latitude of 35 N. Spectral simulations are used to determine the mixing ratios of ClONO2. This analysis incorporates line by line calculations and new ClONO2 cross sections measured in the laboratory at 223 K. The inferred mixing ratios of ClONO2 are 1.3 + or - 0.45 ppb and 0.98 + or - 0.35 ppb at 14 and 34 mbar. One-dimensional photochemical model predictions are compared to the observations. The ClONO2 mixing ratio at 34 mbar appears to be larger than theory, while there is agreement at 14 mbar.

Thermal emission measurements of the earth's stratospheric limb were made with a cryogenically cooled high-resolution Michelson interferometer on a balloon flight launched from Palestine, TX, on Nov. 6, 1984. Infrared spectra for complete limb sequences were obtained over portions of the 700-1940/cm range with an unapodized spectral resolution of 0.03/cm for tangent heights varying from 13 to 39 km. The observed data from 1125 to 1425/cm have been analyzed for simultaneous measurement of O3, H2O, CH4, and N2O profiles. The analysis employs line-by-line and layer-by-layer radiative-transfer calculations, including curvature and refraction effects. The optimum use of geometric and spectral effects is made to obtain sharply peaked weighting functions. Contributions from stratospheric aerosol are included by measuring the light extinction within the window regions of the observed spectra. The retrieved constituent profiles are compared with measurements made with a variety of techniques by other groups. The comparison shows good agreement with the published data for all gases, indicating the capability of retrieving trace gas profiles from high-resolution thermal emission limb measurements.

Energetic electron bombardment of the H2 atmosphere in the Jovian auroral zone was studied using a theoretical model for the vibrational-ratational excitation processes. A non-relativistic electron energy deposition program originally developed by Peterson et al. was used. Assuming an incident energy electron spectrum from IUE observations, the calculated intensities of the two micron quadrupole lines from the Jovian auroral zone are shown to be comparable to the intensities of infrared objects in the Orion nebula. Jupiter is fairly dark in the 2 to 2.5 micron spectral range because of strong absorption of cH4 and NH3 vibrational-rotational bands. Consequently, assuming no significant decrease in Jovian auroral activity since the Voyager encounter with Jupiter in 1979, the two micron quadrupole emission of H2 may be observable by ground-based telescope through the two micron atmospheric window.

High resolution infrared spectra of planets from ground-based observatories were analyzed and instrumentation to improve sensitivity was developed. A cryogenic postdisperser (a narrow bandpass spectral filter) for use with Fourier transform spectrometers (FTS's) at facility observatories was constructed. This instrument has improved the sensitivity of FTS observations at 8 to 20 microns by about an order of magnitude. Spectra of Jupiter, Saturn and Comet Halley were obtained using the postdisperser with FTS facilities at the Kitt Peak 4-meter and McMath telescopes. Spectral resolution as high as 0.01/cm was achieved.

It is pointed out that the technique of thermal emission spectroscopy provides an effective means for remote sounding of stratospheric temperature structure and constituent distributions. One procedure for measuring the stratospheric infrared spectrum involves the conduction of observations along ray paths tangent to the stratospheric limb. Thermal emission limb tangent observations have certain advantages compared to other types of observations. The techniques for determining temperature and trace gas distributions from limb thermal emission radiances are based on the assumption that the bulk of opacity lies near the tangent point. Ideally, the field of view (FOV) of the observing instrument should be very small. The effect of a finite FOV is to reduce the spatial resolution of the retrieved temperature and constituent profiles. The present investigation is concerned with the effects of the FOV on the inversion of infrared thermal emission measurements for balloon platforms. Attention is given to a convenient method for determining the weighting functions.

Thermal emission measurements of the earth's stratospheric limb from space platforms require an accurate knowledge of the observation angles for retrieval of temperature and constituent distributions. Without the use of expensive stabilizing systems, however, most observational instruments do not meet the required pointing accuracies, thus leading to large errors in the retrieval of atmospheric data. This paper describes a self-constituent method of correcting errors in pointing angles by using information contained in the observed spectrum. Numerical results based on temperature inversions of synthetic thermal emission spectra with assumed random errors in pointing angles are presented.

A sharp stratospheric emission feature at 667/cm in the Voyager infrared spectra of Titan is associated with the nu2 Q branch of CO2. A coupling of photochemical and radiative-transfer theory yields an average mole fraction above the 110 mbar level of (1.5 + 1.5 or - 0.8) x 10 to the -9th, with most of the uncertainty being due to imprecise knowledge of the vertical distribution. CO2 is found to be in a steady state, with its abundance being regulated principally by the 72 K cold trap near the tropopause and secondarily by the rate at which water-bearing meteoritic material enters the top of the atmosphere. An influx of water about 0.4 times that at the top of the terrestrial atmosphere is consistent with a combination of the observed CO2 abundance and a steady-state CO mole fraction of 0.00011; the thoeretical value for CO is close to the value observed by Lutz et al. (1983), although there are large margins for error in both numbers. If steady-state conditions for CO prevail, little information is available regarding the evolution of Titan's atmosphere.

(Previously announced in STAR as N82-20103)

Spectroscopic work in acetylene, ethylene and ethane, are of particular interest since the Voyager IRIS observations of Jupiter. Acetylene and ethane but not ethylene were observed in the Jovian spectrum. Two fundamental bands of the observed gases are used to determine the spatial distribution of these hydrocarbons on Jupiter and to illuminate the photochemistry of these species. The 100 to 1000 cm region is discussed and selected examples of current laboratory work are given.

The 200-600/cm continuum opacity in the troposphere and lower stratosphere of Titan is inferred from thermal emission spectra from the Voyager 1 IR spectrometer (IRIS). The surface temperature and mean molecular weight are between 94 and 97 K and between 28.3 and 29.2 AMU, respectively. The mole fraction of molecular hydrogen is 0.002 + or - 0.001, which is equivalent to an abundance of approximately 0.2 + or - 0.1 km amagat.

Voyager 1 took IR measurements of the atmosphere of Titan, and obtained an average of 346 spectra, mostly from the center of the disk. The compounds C4H2, HC3N, and C2N2 were detected in the atmosphere of Titan. The identification of two compounds containing nitrogen, in addition to HCN, provides further evidence for the abundance of free N2 on Titan. The organic compounds observed in the atmosphere of Titan are summarized in a table, which also indicates the approximate mole fraction for each compound identified previously. The observed compounds originate by reactions of methane and nitrogen radicals in a predominantly nitrogen atmosphere.

Four bands of propane C3H8 and two of methyl acetylene C3H4 have been identified in the Voyager IR spectrum of Titan. Stratospheric abundances of 2 x 10 to the -5 for C3H8 and 3 x 10 to the -8 for C3H4 have been determined for the mid-latitude region. A feature at 1,154/cm, previously assigned solely to CH3D, is now identified at least in part due to C3H8.

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO2 and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is inferred from the infrared spectrum of the planet between 450 and 1250 per cm. Volume extinction coefficients varying from 0.000005 to 0.000015 per cm, depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 0.000005 and a particle concentration of about 900 particles per cu cm at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.

A transmittance model has been developed for interpretation of high spectral resolution measurements of laboratory absorption and of planetary thermal emission. The high spectral resolution requires transmittances to be computed monochromatically by summing the contribution of individual molecular absorption lines. A magnetic tape atlas of H2O, O3, and CO2 molecular line parameters serves as input to the transmittance model with simple empirical representations used for continuum regions wherever suitable laboratory data exist. The theoretical formulation of the transmittance model and the computational procedures used for the evaluation of the transmittances are discussed, and application of the model to several homogeneous-path laboratory absorption examples is demonstrated.

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO2 and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is inferred from the infrared spectrum of the planet between 450 and 1250/cm. Justification for applying the homogeneous cloud model is found in the fact that numerous polarization and infrared data are mutually consistent within the framework of such a model; on the other hand, dense cloud models are not satisfactory. Volume extinction coefficients varying from 0.000005 to 0.000015/cm depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 0.000005 and a particle concentration of about 900 particles per cu cm at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.

The Nimbus 4 infrared interferometer spectrometer (IRIS) measured the thermal emission of the earth's atmosphere and surface from 400-1600 wavelengths/cm with an apodized spectral resolution of 2.8 wavelengths/cm. A comparison of theoretical radiances, computed from in situ measurements and using a direct integration slant path atmospheric transmittance model, with the observed IRIS radiances has been made to verify the radiometric and spectral performance of the instrument and to assess the accuracy of the atmospheric transmittances. The radiance comparison has indicated a relatively constant difference of less than 5% in the water vapor continuum in the 425 to 550 wavelengths/cm and 750 to 1200 wavelengths/cm atmospheric 'window' regions, whereas in the 667 wavelengths/cm CO2 band the difference was 5-10%.

The identification of gaseous sulfur dioxide on Io by Voyager 1 is reported, and preliminary upper limits for other atmospheric gases are presented. Averaged spectra taken by the Voyager IRIS experiment in the range of 1,000 to 1,200/cm are interpreted as containing three fundamental sulfur dioxide bands, with intensities most nearly corresponding to an atmospheric model with a sulfur dioxide abundance of 0.2 cm atm. Upper limits for COS, CS2, SO3, H2S, CO2, O3, N2O, H2O, CH4, NH3 and HC1, not detected in the spectra, were calculated on the basis of the radiative transfer equation for temperatures of 130 and 250 K; a depletion of hydrogen, carbon and nitrogen is noted. It is suggested that a SO2 outgassing from a cooling sulfur extrusion is the major source of the observed atmospheric SO2.

A retrospective look at the operation and results of the experiment is presented. The design and performance of the infrared interferometer spectrometer are discussed along with the results obtained concerning the atmospheric and surface properties.

A transmittance model was developed for the 200-2000/cm region for interpretation of high spectral resolution measurements of laboratory absorption and of planetary thermal emission. The high spectral resolution requires transmittances to be computed monochromatically by summing the contribution of individual molecular absorption lines. A magnetic tape atlas of H2O,O3, and CO2 molecular line parameters serves as input to the transmittance model with simple empirical representations used for continuum regions wherever suitable laboratory data exist. The theoretical formulation of the transmittance model and the computational procedures used for the evaluation of the transmittances are discussed. Application is demonstrated of the model to several homogenous path laboratory absorption examples.

During the almost 1-year operational lifetime of Mariner 9 the infrared spectroscopy experiment obtained data over a large portion of Mars. Between June and October 1972, improvements were made in the CO2 transmittances, which are necessary for the interpretation of the thermal emission spectra. Recently obtained spectra indicate that strong seasonal variations in the water vapor distribution occurred over both polar regions. The wettest atmospheric conditions observed so far contain 20 to 30 precipitable microns of water over the north polar cap during northern spring. A low-resolution pressure map is presented that covers that portion of the planet between latitudes -60 and +25 deg. A more detailed study of the Coprates canyon indicates that, at its lowest point, the canyon floor must be at least 5 km below the rim. Applications of tidal theory to temperature fields derived from the spectra indicate diurnal surface pressure fluctuations of as much as 12% during the Great Dust Storm of 1971-1972.

The Nimbus 4 infrared interferometer spectrometer (IRIS) measured the thermal emission of the earth's atmosphere and surface from 400-1600/cm with an apodized spectral resolution of 2.8/cm. A comparison of theoretical radiances, computed from in-situ measurements and using a direct integration slant path atmospheric transmittance model, with the observed IRIS radiances has been made to verify the radiometeric and spectral performance of the instrument and to assess the accuracy of the atmospheric transmittances. The radiance comparison has indicated a relatively constant difference of less than 5% in the water vapor continuum in the 425-550/cm and 750-1200/cm atmospheric window regions while in the 667/cm CO2 band the difference was 5-10%. The absolute accuracy was found to be approximately 5-10% for each of the parameters; measured radiances, in-situ measurements, and the atmospheric transmittances, thus it is not possible to uniquely specify the degree of error arising from each parameter in the total resultant difference.

Preliminary analysis of Mariner 9 IR spectroscopic data through May 1972 shows spectral features due to carbon dioxide, water vapor, and silicate dust suspended in the atmosphere. Measurements obtained during and after the planet-wide dust storm indicate that large diurnal variations in atmospheric temperature existed up to at least 30 km. Analysis of spectral features due to the atmospheric dust provides a SiO2 content of 60 (plus or minus 10)%, implying substantial geochemical differentiation. Water vapor estimates yield abundances of 10 to 20 precipitable microns, and no water vapor was detected over the north polar region.

Measurements obtained during and after the planet-wide dust storm indicate that large diurnal variations in atmospheric temperature existed up to at least 30 km; winds inferred from the temperature fields show a strong tidal component and significant ageostrophic behavior. With the dissipation of the dust, the daily maximum in the atmospheric temperature field moved from approximately latitude -60 and late afternoon local time to near the subsolar point in latitude and time. Analysis of spectral features due to the atmospheric dust indicates as SIO2 content of 60 ? 10%, implying that substantial geochemical differentiation has occurred. Water vapor estimates indicate abundances of 10 to 20 precipitable micrometers. Between November 1971 and April 1972 no gross latitudinal or temporal dependence in the water vapor distribution was detected from the south polar region to the equator. Water vapor was not detected over the north polar regions. Surface pressure mapping was carried out from which topographic relief of nearly two pressure scale heights is inferred. Extensive regions were found where the surface pressure exceeds the triple point pressure of water.

A theoretical calculation was made of the CO2 infrared spectra of Earth and Venus atmospheres. The calculations cover line intensity, line shape, and line position. Theoretical results were compared with those observed by Nimbus 3 satellite and were found to be in reasonable agreement.