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A novel nanomaterial, bacterial cellulose (BC), has become noteworthy recently due to its better physicochemical properties and biodegradability, which are desirable for various applications. Since cost is a significant limitation in the production of cellulose, current efforts are focused on the use of industrial waste as a cost-effective substrate for the synthesis of BC or microbial cellulose. The utilization of industrial wastes and byproduct streams as fermentation media could improve the cost-competitiveness of BC production. This paper examines the feasibility of using typical wastes generated by industry sectors as sources of nutrients (carbon and nitrogen) for the commercial-scale production of BC. Numerous preliminary findings in the literature data have revealed the potential to yield a high concentration of BC from various industrial wastes. These findings indicated the need to optimize culture conditions, aiming for improved large-scale production of BC from waste streams.

Cross arm is the main component used to lift the electric cable in a transmission tower. Recently, a synthetic cross arm was proposed to substitute the wooden cross arm due to the extreme creep deformation, which can induce a structural collapse. Several creep studies were conducted on a coupon scale for the synthetic cross arm. However, there is a lack of study on the assessment of creep properties for the actual size cross arm. Thus, the development of a special rig is required to accommodate the creep test. The paper explains the development of creep testing rig for a full-scale cross arm using the integration of theory of inventive problem solving (TRIZ), morphological chart, and analytic network process (ANP). In the beginning, the finding of principle solutions was conducted using the TRIZ contradiction matrix. The characterisation of the design concepts was elaborated using the morphological chart. Finally, the ANP principle was exploited to select the best design via the pairwise comparison technique. The results show that Concept Design 5 (hybrid bracing design) scored the highest value and ranked first. Lastly, challenges on the design of creep testing machine and the improving criteria in concurrent engineering is presented. Keywords: TRIZ, ANP, Morphological chart, Creep testing rig, Full-scale cross arm

This study was carried out to produce low-emitting biomass pellets biofuel from selected forest trees such as (Cedrus deodara and Pinus wallichiana) and agricultural crop residues such as (Zea mays and Triticum aestivum) in Gilgit-Baltistan, Pakistan using indigenously developed technology called pelletizer machine. Characterization, environmental life cycle impact assessment, and cumulative energy demand of biomass pellets biofuel produced from selected agriculture crops and forest tree residues were conducted. The primary data for biomass pellets production was collected by visiting various wood processing factories, sawmills, and agricultural crop fields in the study area. Biomass pellets are a type of biofuel that is often made by compressing sawdust and crushing biomass material into a powdery form. The particles are agglomerated as the raw material is extensively compressed and pelletized. Biomass pellets have lower moisture content, often less than 12%. Physically, the produced pellets were characterized to determine moisture content, pellet dimensions, bulk density, higher heating value, ash content, lower heating value, and element analysis. A functional unit of one kilogram (kg) biomass pellets production was followed in this study.The life cycle impact assessment of one kg biomass pellets biofuel produced from selected agro-forest species revealed environmental impact categories such as acidification (0.006 kg SO2 eq/kg pellets), abiotic depletion (0.018 kg Sb eq/kg pellets), marine aquatic ecotoxicity (417.803 kg 1,4-DB eq/kg pellets), human toxicity (1.107 kg 1,4-DB eq/kg pellets), freshwater aquatic ecotoxicity (0.191 kg 1,4-DB eq/kg pellets), eutrophication (0.001 kg PO4 eq/kg pellets), global warming (0.802 kg CO2 eq/kg pellets), and terrestrial ecotoxicity (0.008 kg 1,4-DB eq/kg pellets). Fossil fuel consumption was the hotspot source to all environmental impacts investigated. To measure the cumulative energy demand of biomass pellets made from different agroforestry species leftovers showed that the maximum cumulative energy was from wheat straw pellets (13.737 MJ), followed by corncob pellets (11.754 MJ), deodar sawdust pellets (10.905 MJ) and blue pine sawdust pellets (10.877 MJ). Among the various production activities, collection and transportation of primary raw material, crushing, screening, adding adhesives, pelletizing, cooling, final screening, and packing have the maximum contribution to the water scarcity index, followed by lubricating oil (0.00147m3). In contrast, the minimum contribution to water footprint was from electricity (0.00008m3) and wheat starch (0.00005m3). The highest contribution to the ecological footprint impact categories such as carbon dioxide, nuclear, and land occupation was lubricating oil and less contribution of wheat starch and electricity for manufacturing one kg pellets biofuel. It is concluded that physico-mechanical and combustion properties of the biomass pellets biofuel developed in the present study were following the Italian recommended standards. Therefore, it is strongly recommended that the Government of Pakistan should introduce the renewable biomass pellets industry in the country to reduce dependency on fossil fuels for cooking and heating purposes.

“Synthetic and Natural Fiber Reinforced Polymer Matrix Composites for Advanced Applications” is a recently opened Special Issue (SI) of Materials that focuses on the fundamentals, characterization, and applications of fiber-reinforced polymer composites [...]

The purpose of this study is to evaluate the value derived by the local community from cultural heritage and natural heritage in Jugra, Kuala Langat, as it has the potential to be a recognized heritage tourism site. The quantitative approach was used by conducting a survey study. A total of 392 respondents among the local community were selected through a purposive sampling technique. The collected data were processed with SPSS software and analyzed using cross tabulation analysis. Then, several hypotheses were tested using AMOS software. The result showed that Jugra’s unique heritage elements positively influenced the respondent’s willingness to accept and fund its tourism development. Socioeconomic factors also influenced the respondents’ disposition to preserve heritage. The findings revealed that there was priceless value when respondents agreed with the development, although they had never visited the heritage sites. Their physical, economic, and social valuation made them proud of the heritage, as it is a reflection of their identity. This study also aims to emphasize the role of local community as one of the stakeholders, as they should also be able to benefit from tourism development. All these would help boost the tourism industry, particularly through the archaeo-tourism and eco-tourism perspectives.

Biocomposites are materials that are easy to manufacture and environmentally friendly. Sugar palm fibre (SPF) is considered to be an emerging reinforcement candidate that could provide improved mechanical stiffness and strength to the biocomposites. Numerous studies have been recently conducted on sugar palm biocomposites to evaluate their physical, mechanical and thermal properties in various conditions. Sugar palm biocomposites are currently limited to the applications of traditional household products despite their good thermal stability as a prospective substitute candidate for synthetic fibres. Thus, thermal analysis methods such as TGA and DTG are functioned to determine the thermal properties of single fibre sugar palm composites (SPCs) in thermoset and thermoplastic matrix as well as hybrid SPCs. The biocomposites showed a remarkable change considering thermal stability by varying the individual fibre compositions and surface treatments and adding fillers and coupling agents. However, literature that summarises the thermal properties of sugar palm biocomposites is unavailable. Particularly, this comprehensive review paper aims to guide all composite engineers, designers, manufacturers and users on the selection of suitable biopolymers for sugar palm biocomposites for thermal applications, such as heat shields and engine components.

Developments in the synthesis and scalable manufacturing of carbon nanomaterials like carbon nanotubes (CNTs) have been widely used in the polymer material industry over the last few decades, resulting in a series of fascinating multifunctional composites used in fields ranging from portable electronic devices, entertainment and sports to the military, aerospace, and automotive sectors. CNTs offer good thermal and electrical properties, as well as a low density and a high Young’s modulus, making them suitable nanofillers for polymer composites. As mechanical reinforcements for structural applications CNTs are unique due to their nano-dimensions and size, as well as their incredible strength. Although a large number of studies have been conducted on these novel materials, there have only been a few reviews published on their mechanical performance in polymer composites. As a result, in this review we have covered some of the key application factors as well as the mechanical properties of CNTs-reinforced polymer composites. Finally, the potential uses of CNTs hybridised with polymer composites reinforced with natural fibres such as kenaf fibre, oil palm empty fruit bunch (OPEFB) fibre, bamboo fibre, and sugar palm fibre have been highlighted.

In the determination of the bioavailability of drugs administered orally, the drugs’ solubility and permeability play a crucial role. For absorption of drug molecules and production of a pharmacological response, solubility is an important parameter that defines the concentration of the drug in systemic circulation. It is a challenging task to improve the oral bioavailability of drugs that have poor water solubility. Most drug molecules are either poorly soluble or insoluble in aqueous environments. Polymer nanocomposites are combinations of two or more different materials that possess unique characteristics and are fused together with sufficient energy in such a manner that the resultant material will have the best properties of both materials. These polymeric materials (biodegradable and other naturally bioactive polymers) are comprised of nanosized particles in a composition of other materials. A systematic search was carried out on Web of Science and SCOPUS using different keywords, and 485 records were found. After the screening and eligibility process, 88 journal articles were found to be eligible, and hence selected to be reviewed and analyzed. Biocompatible and biodegradable materials have emerged in the manufacture of therapeutic and pharmacologic devices, such as impermanent implantation and 3D scaffolds for tissue regeneration and biomedical applications. Substantial effort has been made in the usage of bio-based polymers for potential pharmacologic and biomedical purposes, including targeted deliveries and drug carriers for regulated drug release. These implementations necessitate unique physicochemical and pharmacokinetic, microbiological, metabolic, and degradation characteristics of the materials in order to provide prolific therapeutic treatments. As a result, a broadly diverse spectrum of natural or artificially synthesized polymers capable of enzymatic hydrolysis, hydrolyzing, or enzyme decomposition are being explored for biomedical purposes. This summary examines the contemporary status of biodegradable naturally and synthetically derived polymers for biomedical fields, such as tissue engineering, regenerative medicine, bioengineering, targeted drug discovery and delivery, implantation, and wound repair and healing. This review presents an insight into a number of the commonly used tissue engineering applications, including drug delivery carrier systems, demonstrated in the recent findings. Due to the inherent remarkable properties of biodegradable and bioactive polymers, such as their antimicrobial, antitumor, anti-inflammatory, and anticancer activities, certain materials have gained significant interest in recent years. These systems are also actively being researched to improve therapeutic activity and mitigate adverse consequences. In this article, we also present the main drug delivery systems reported in the literature and the main methods available to impregnate the polymeric scaffolds with drugs, their properties, and their respective benefits for tissue engineering.

Natural fiber such as bamboo fiber, oil palm empty fruit bunch (OPEFB) fiber, kenaf fiber, and sugar palm fiber-reinforced polymer composites are being increasingly developed for lightweight structures with high specific strength in the automotive, marine, aerospace, and construction industries with significant economic benefits, sustainability, and environmental benefits. The plant-based natural fibers are hydrophilic, which is incompatible with hydrophobic polymer matrices. This leads to a reduction of their interfacial bonding and to the poor thermal stability performance of the resulting fiber-reinforced polymer composite. Based on the literature, the effect of chemical treatment of natural fiber-reinforced polymer composites had significantly influenced the thermogravimetric analysis (TGA) together with the thermal stability performance of the composite structure. In this review, the effect of chemical treatments used on cellulose natural fiber-reinforced thermoplastic and thermosetting polymer composites has been reviewed. From the present review, the TGA data are useful as guidance in determining the purity and composition of the composites’ structures, drying, and the ignition temperatures of materials. Knowing the stability temperatures of compounds based on their weight, changes in the temperature dependence is another factor to consider regarding the effectiveness of chemical treatments for the purpose of synergizing the chemical bonding between the natural fiber with polymer matrix or with the synthetic fibers.

Six different solvents were used as extraction medium (water, methanol, ethanol, acidified methanol, benzene and acetone) to check their phenolics extraction efficacy from flour of two rye cultivars. Rye extracts with different solvents were further analyzed for the estimation of phytochemicals and antioxidant properties. Different tests (TPC, TAC, DPPH, FRAP, ABTS, RPA and CTC) were performed to check the antioxidant properties and tannin contents in extracts. A bioactive profile of a rye cultivar indicated the presence of total phenolic compounds (0.08–2.62 mg GAE/g), total antioxidant capacity (0.9–6.8 mg AAE/g) and condensed tannin content (4.24–9.28 mg CE/100 g). HPLC was done to check phenolics in rye extract with the best solvent (water), which indicated the presence of Catechol (91.1–120.4 mg/100 g), resorcinol (52–70.3 mg/100 g), vanillin (1.3–5.5 mg/100 g), ferulic acid (1.4–1.5 mg/100 g), quercetin (4.6–4.67 mg/100 g) and benzoic acid (5.3 mg/100 g) in rye extracts. The presence of DNA damage protection potential in rye extracts indicates its medicinal importance. Rye flour could be utilized in the preparation of antioxidant-rich health-benefiting food products.

Natural fibers have attracted great attention from industrial players and researchers for the exploitation of polymer composites because of their “greener” nature and contribution to sustainable practice. Various industries have shifted toward sustainable technology in order to improve the balance between the environment and social and economic concerns. This manuscript aims to provide a brief review of the development of the foremost natural fiber-reinforced polymer composite (NFRPC) product designs and their applications. The first part of the manuscript presents a summary of the background of various natural fibers and their composites in the context of engineering applications. The behaviors of NFPCs vary with fiber type, source, and structure. Several drawbacks of NFPCs, e.g., higher water absorption rate, inferior fire resistance, and lower mechanical properties, have limited their applications. This has necessitated the development of good practice in systematic engineering design in order to attain optimized NRPC products. Product design and manufacturing engineering need to move in a mutually considerate manner in order to produce successful natural fiber-based composite material products. The design process involves concept design, material selection, and finally, the manufacturing of the design. Numerous products have been commercialized using natural fibers, e.g., sports equipment, musical instruments, and electronic products. In the end, this review provides a guideline for the product design process based on natural fibers, which subsequently leads to a sustainable design.

Polymer composites filled with metal derivatives have been widely used in recent years, particularly as flame retardants, due to their superior characteristics, including high thermal behavior, low environmental degradation, and good fire resistance. The hybridization of metal and polymer composites produces various favorable properties, making them ideal materials for various advanced applications. The fire resistance performance of polymer composites can be enhanced by increasing the combustion capability of composite materials through the inclusion of metallic fireproof materials to protect the composites. The final properties of the metal-filled thermoplastic composites depend on several factors, including pore shape and distribution and morphology of metal particles. For example, fire safety equipment uses polyester thermoplastic and antimony sources with halogenated additives. The use of metals as additives in composites has captured the attention of researchers worldwide due to safety concern in consideration of people’s life and public properties. This review establishes the state-of-art flame resistance properties of metals/polymer composites for numerous industrial applications.

Nowadays, pultruded glass fiber-reinforced polymer composite (PGFRPC) structures have been used widely for cross-arms in high transmission towers. These composite structures have replaced cross-arms of conventional materials like wood due to several factors, such as better strength, superior resistance to environmental degradation, reduced weight, and comparatively cheaper maintenance. However, lately, several performance failures have been found on existing cross-arm members, caused by moisture, temperature changes in the atmosphere, and other environmental factors, which may lead to a complete failure or reduced service life. As a potential solution for this problem, enhancing PGFRPC with honeycomb-filled composite structures will become a possible alternative that can sustain a longer service life compared to that of existing cross-arms. This is due to the new composite structures’ superior performance under mechanical duress in providing better stiffness, excellence in flexural characteristics, good energy absorption, and increased load-carrying capacity. Although there has been a lack of previous research done on the enhancement of existing composite cross-arms in applications for high transmission towers, several studies on the enhancement of hollow beams and tubes have been done. This paper provides a state-of-the-art review study on the mechanical efficiency of both PGFRPC structures and honeycomb-filled composite sandwich structures in experimental and analytical terms.

Over recent years, enthusiasm towards the manufacturing of biopolymers has attracted considerable attention due to the rising concern about depleting resources and worsening pollution. Among the biopolymers available in the world, polylactic acid (PLA) is one of the highest biopolymers produced globally and thus, making it suitable for product commercialisation. Therefore, the effectiveness of natural fibre reinforced PLA composite as an alternative material to substitute the non-renewable petroleum-based materials has been examined by researchers. The type of fibre used in fibre/matrix adhesion is very important because it influences the biocomposites’ mechanical properties. Besides that, an outline of the present circumstance of natural fibre-reinforced PLA 3D printing, as well as its functions in 4D printing for applications of stimuli-responsive polymers were also discussed. This research paper aims to present the development and conducted studies on PLA-based natural fibre bio-composites over the last decade. This work reviews recent PLA-derived bio-composite research related to PLA synthesis and biodegradation, its properties, processes, challenges and prospects.

A novel class of carbon nanotube (CNT)-based nanomaterials has been surging since 1991 due to their noticeable mechanical and electrical properties, as well as their good electron transport properties. This is evidence that the development of CNT-reinforced polymer composites could contribute in expanding many areas of use, from energy-related devices to structural components. As a promising material with a wide range of applications, their poor solubility in aqueous and organic solvents has hindered the utilizations of CNTs. The current state of research in CNTs—both single-wall carbon nanotubes (SWCNT) and multiwalled carbon nanotube (MWCNT)-reinforced polymer composites—was reviewed in the context of the presently employed covalent and non-covalent functionalization. As such, this overview intends to provide a critical assessment of a surging class of composite materials and unveil the successful development associated with CNT-incorporated polymer composites. The mechanisms related to the mechanical, thermal, and electrical performance of CNT-reinforced polymer composites is also discussed. It is vital to understand how the addition of CNTs in a polymer composite alters the microstructure at the micro- and nano-scale, as well as how these modifications influence overall structural behavior, not only in its as fabricated form but also its functionalization techniques. The technological superiority gained with CNT addition to polymer composites may be advantageous, but scientific values are here to be critically explored for reliable, sustainable, and structural reliability in different industrial needs.

In this decade, all researchers and industry players compete to develop sustainable product design by exploring natural fibre composites in product design development. One of the essential methodologies in creating composite products is concurrent engineering (CE). Industrial design and production engineering should be involved in the development of ballistic helmets. This publication aims to provide a quick overview of the evolution of natural fibre composite ballistic helmet designs. This manuscript is still in its early stages, but it already includes a summary of the progress of ballistic helmet design from 1915 to the present. Renewable materials, such as natural fibre, should be highlighted as an alternative to synthetic composites in developing a sustainable ballistic helmet design. Furthermore, launching the design development process for a ballistic helmet demands a CE strategy that includes multi-disciplinary knowledge. Computational modelling aids in the development of ballistic helmet designs, reducing the time and cost of manufacturing ballistic helmets. The ergonomic component of ballistic helmet design is also crucial, as is the thermal comfort factor, which can be handled using natural fibre composites with thermal solid insulating characteristics. The development of natural fibre composite ballistic helmets can be used as a consideration in the future as a revolution to create a sustainable design. Finally, this review can be used as a guide for industrial designers. In conclusion, this review might be utilized as a reference for industrial designers due to a shortage of studies, especially in producing product-related natural fibre.

Previously, numerous creep studies on wood materials have been conducted in various coupon-scale tests. None had conducted research on creep properties of full-scale wooden cross-arms under actual environment and working load conditions. Hence, this research established findings on effect of braced arms on the creep behaviors of Virgin Balau (Shorea dipterocarpaceae) wood timber cross-arm in 132 kV latticed tower. In this research, creep properties of the main members of both current and braced wooden cross-arm designs were evaluated under actual working load conditions at 1000 h. The wooden cross-arm was assembled on a custom-made creep test rig at an outdoor area to simulate its long-term mechanical behaviours under actual environment of tropical climate conditions. Further creep numerical analyses were also performed by using Findley and Burger models in order to elaborate the transient creep, elastic and viscoelastic moduli of both wooden cross-arm configurations. The findings display that the reinforcement of braced arms in cross-arm structure significantly reduced its creep strain. The inclusion of bracing system in cross-arm structure enhanced transient creep and stress independent material exponent of the wooden structure. The addition of braced arms also improved elastic and viscoelastic moduli of wooden cross-arm structure. Thus, the outcomes suggested that the installation of bracing system in wooden cross-arm could extend the structure’s service life. Subsequently, this effort would ease maintenance and reduce cost for long-term applications in transmission towers.

The interest in using natural fiber reinforced composites is now at its highest. Numerous studies have been conducted due to their positive benefits related to environmental issues. Even though they have limitations for some load requirements, this drawback has been countered through fiber treatment and hybridization. Sandwich structure, on the other hand, is a combination of two or more individual components with different properties, which when joined together can result in better performance. Sandwich structures have been used in a wide range of industrial material applications. They are known to be lightweight and good at absorbing energy, providing superior strength and stiffness-to-weight ratios, and offering opportunities, through design integration, to remove some components from the core element. Today, many industries use composite sandwich structures in a range of components. Through good design of the core structure, one can maximize the strength properties, with a low density. However, the application of natural fiber composites in sandwich structures is still minimal. Therefore, this paper reviewed the possibility of using a natural fiber composite in sandwich structure applications. It addressed the mechanical properties and energy-absorbing characteristics of natural fiber-based sandwich structures tested under various compression loads. The results and potential areas of improvement to fit into a wide range of engineering applications were discussed.

The reliance on nonrenewable resources in developing new product toward sustaining the ecological balance can be reduced by utilizing natural fiber reinforced composites. In this chapter, the design for sustainability approach is implemented to design and fabricate a prototype of an environmentally friendly trophy plaque (used as an award and gift) using kenaf fiber reinforced unsaturated polyester polymer composites. The kenaf composites trophy plaque development processes involved in this project are market investigation, creating the product design specification, developing the plaque conceptual design, detail design including plaque mold, manufacturing of the plaque mold and plaque component, and finally product assembly. In addition to its environmentally friendly properties, the final kenaf composites trophy plaque product development in this project also successfully achieved other design intents including lightweight, easy to fabricate, low cost, and having an acceptable balance between aesthetics and functionality.

Roselle has attained huge attention as a jute substitute, and attempts are being made to extend its cultivation in areas that are not favorable for the cultivation of jute. The roselle plant is classified as a rapid-growing plant and renewable natural bioresource that can be found growing in Malaysia, India, Panama, Indonesia, Jamaica, Mexico, Guatemala, Australia, Philippines, Kenya, Madagascar, Mozambique, Malawi, Uganda, Somalia, Tanzania, Djibouti, Cambodia, Vietnam, Namibia, Gabon, Congo, Burundi, Rwanda, DR Congo, Myanmar, Thailand, Belize, China, Sudan, South Sudan, Egypt, Gambia, Senegal, Saudi Arabia, Bangladesh, Laos, Sri Lanka, Ghana, Nigeria, Brazil, and Cuba. This chapter discusses the origin, distribution, taxonomy, benefits, production, product development, and composites of the roselle plant. Roselle is an astringent, aromatic, and refreshing herb that is commonly used in the tropics. The roselle plant has been utilized in folk medicine as a mild laxative and diuretic and in the treatment of nerve and cardiac diseases. The leaves taste strongly mucilaginous and are used as a moisturizer and for cough relief. Similar to the leaves, the fruits also have antiscorbutic property. The flowers contain anthocyanin, the glycoside hibiscin, and gossypetin. The findings of this chapter showed that the incorporation and hybridization of roselle hybrid composites had improved the mechanical properties of polymer composites. Roselle can be utilized in either medical products or massive-scale industrial applications as a result of its excellent mechanical properties when reinforced with polymer composites.

Over the following years, the number of scientific articles and patents published in nanocellulose has significantly risen. Nanocellulose has grown as a sustainable and promising nanomaterial owing to its superb properties, unique structures, low density, excellent mechanical performances, high aspect ratio, biocompatibility, and natural abundance. Nanocellulose has received massive attention in various applications as a nanoreinforcement for polymer matrices (i.e., optically transparent materials, coating films, biomimetic materials, aerogels, sensor, 3D printing, rheology modifiers, energy harvesters, filtration, textiles, printed and flexible electronics, composites, paper and board, packaging, oil and gas, and medical and healthcare). There are three types of nanocellulose, including nanofibrillated cellulose (NFC), nanocrystalline cellulose (NCC), and bacterial nanocellulose (BNC). These nanocellulose types can be obtained through top-down or bottom-up techniques. NFC and NCC are usually produced through the top-down approaches, such as chemical, mechanical, chemomechanical, and enzymatic processes for extraction and isolation from crops, higher plants, and by-products of forestry and agricultural residue. However, BNC is produced via the bottom-up approach, utilizes the fermentation of low-molecular-weight sugar by cellulose-producing bacteria. Natural fibers such as roselle fiber (Hibiscus sabdariffa) are abundantly found in nature and roselle is cultivated in Borneo, Guyana, Malaysia, Sri Lanka, Togo, Indonesia, and Tanzania. In Malaysia, after a year, the roselle plant will be cut to preserve the quality of the fruit and it subsequently becomes an agro-waste. The fiber is utilized as reinforcing material for polymer composites for more efficient use of this plant. This chapter focuses on the development and characterization of roselle nanocellulose and its potential in reinforced nanocomposites. This chapter also focuses on top-down techniques, such as acid hydrolysis, used in the preparation of roselle nanocellulose from agro-waste roselle fiber.

Currently, high-strength fibers such as kevlar, carbon, spectra, glass fiber, carbon nanotube and zylon reinforced composite materials are commonly used in advanced transport structures. However, the world is changing and green material is at the forefront due to the depletion of inorganic materials such as petroleum and other mineral sources. Natural fibers can be classified as green materials, that is, defined as renewable materials. This chapter describes the recent advancements in biocomposites, specifically natural fiber polymer composites (NFPC). This is a material with significant mechanical and barrier properties that is also economical, biodegradable, renewable, and has a low density character. The above properties make NFPC promising for various advanced applications in such fields as automotive parts, papermaking, flexible optoelectronics, scaffolds, optical devices, pharmaceutical products, substitutes/medical biomaterials, spacecraft, aircraft, and tissue repair (wound dressing). In this chapter, the automotive applications of the natural fiber reinforced polymer composites are summarized. The present review covers reinforcement of macro- to nanoscale natural fibers with polymer composites for automotive applications.

The application of pultruded glass fiber-reinforced polymer composites (PGFRPCs) as a replacement for conventional wooden cross-arms in transmission towers is relatively new. Although numerous studies have conducted creep tests on coupon-scale PGFRPC cross-arms, none had performed creep analyses on full-scale PGFRPC cross-arms under actual working load conditions. Thus, this work proposed to study the influence of an additional bracing system on the creep responses of PGFRPC cross-arms in a 132 kV transmission tower. The creep behaviors and responses of the main members in current and braced PGFRPC cross-arm designs were compared and evaluated in a transmission tower under actual working conditions. These PGFRPC cross-arms were subjected to actual working loads mimicking the actual weight of electrical cables and insulators for a duration of 1000 h. The cross-arms were installed on a custom test rig in an open area to simulate the actual environment of tropical climate conditions. Further creep analysis was performed by using Findley and Burger models on the basis of experimental data to link instantaneous and extended (transient and viscoelastic) creep strains. The addition of braced arms to the structure reduced the total strain of a cross-arm’s main member beams and improved elastic and viscous moduli. The addition of bracing arms improved the structural integrity and stiffness of the cross-arm structure. The findings of this study suggested that the use of a bracing system in cross-arm structures could prolong the structures’ service life and subsequently reduce maintenance effort and cost for long-term applications in transmission towers.

Currently, the development and manufacturing of enhanced performance product with high-performance bio-based materials has been one of the aspiring purposes by engineers and researchers throughout the globe. For the past several decades, the conventional-based product was shown an increasing trend due to the significant growth of the global demand towards the material, which was attributed to its diverse and universal properties to be used in the development of science and technology. The materials are widely used, especially, for structural purposes in the automotive, marine, aerospace, food packaging, and construction sectors due to their lightweight properties such as higher strength and durability. Around 140 million tons of petroleum-based polymers is manufactured globally. However, petroleum-based polymers show negative effects on the environment, which leads to several issues, including health problems and pollution. Moreover, the majority of conventional plastics that are used end up in landfill areas. These observations showed that the synthetic plastics contribute to the major solid waste environmental pollutants. Subsequently, the increased cost and the negative effect on environment make the engineers and researchers show high interest in polymer biodegradation.

The hydrogels responding to pH synthesized by graft copolymerization only and then concurrent grafting and crosslinking of monomer N-isopropyl acrylamide (NIPAAM) and binary comonomers acrylamide, acrylic acid and acrylonitrile (AAm, AA and AN) onto chitosan support were explored for the percent upload and release study for anti-inflammatory diclofenac sodium drug (DS), w.r.t. time and pH. Diclofenac sodium DS was seized in polymeric matrices by the equilibration process. The crosslinked-graft copolymers showed the highest percent uptake than graft copolymers (without crosslinker) and chitosan itself. The sustainable release of the loaded drug was studied with respect to time at pH 2.2, 7.0, 7.4 and 9.4. Among graft copolymers (without crosslinking), Chit-g-polymer (NIPAAM-co-AA) and Chit-g-polymer (NIPAAM-co-AN) exhibited worthy results for sustainable drug deliverance, whereas Crosslink-Chit-g-polymer (NIPAAM-co-AA) and Crosslink-Chit-g-polymer (NIPAAM-co-AAm) presented the best results for controlled/sustained release of diclofenac sodium DS with 93.86 % and 96.30 % percent release, respectively, in 6 h contact time. Therefore, the grafted and the crosslinked graft copolymers of the chitosan showed excellent delivery devices for the DS with sustainable/prolonged release in response to pH. Drug release kinetics was studied using Fick’s law. The kinetic study revealed that polymeric matrices showed the value of n as n > 1.0, hence drug release took place by non-Fickian diffusion. Hence, the present novel findings showed the multidirectional drug release rate. The morphological changes due to interwoven network structure of the crosslinked are evident by the Scanning electron microscopy (SEM) analysis.

This paper reviews the mechanical performance of bamboo fibre reinforced polymer composites (BFRPs) for structural applications. Bamboo fibres are very promising reinforcements for polymer composites production due to their high aspect ratio, renewability, environmentally friendly, non-toxicity, cheap cost, non-abrasives, full biodegradability, and strong mechanical performances. Besides, bamboo has its own prospects and good potential to be used in biopolymer composites as an alternative for petroleum-based materials to be used in several advanced applications in the building and construction industry. For bamboo fibre to be reinforced with polymer, they must have good interfacial bond between the polymer, as better fibre and matrix interaction results in good interfacial adhesion between fibre/matrix and fewer voids in the composite. Several important factors to improve matrix-fibre bonding and enhance the mechanical properties of BFRP are by fibre treatment, hybridisation, lamination, and using coupling agent. Moreover, mechanical properties of BFRP are greatly influenced by few factors, such as type of fibre and matrix used, fibre-matrix adhesion, fibre dispersion, fibre orientation, composite manufacturing technique used, void content in composites, and porosity of composite. In order to better understand their reinforcing potential, the mechanical properties of this material is critically discussed in this review paper. In addition, the advantages of bamboo fibres as the reinforcing phase in polymer composites is highlighted in this review paper. Besides that, the bamboo-based products such as laminated bamboo lumber, glued-laminated bamboo, hybrid bamboo polymer composites, parallel bamboo strand lumber, parallel strand bamboo, bamboo-oriented strand board, and bamboo-scrimber have lately been developed and used in structural applications.

Natural cellulosic fibres, such as kenaf, can be used in polymeric composites in place of synthetic fibres. The rapid depletion of synthetic resources such as petroleum and growing awareness of global environmental problems associated with synthetic products contribute to the acceptance of natural fibres as reinforcing material in polymer composite structures. In Africa and Asia, kenaf is considered a major crop used for various cordage products such as rope, twine, and burlap and in construction, it is used for thermal insulation of walls, floors, and roofs and soundproofing solutions. In the furniture and automotive industry, it is used to manufacture medium-density fibreboard and other composite materials for structural applications. Kenaf is primarily composed of cellulose (approximately 40%–80%), which accounts for its superior mechanical performance. Kenaf fibres are chemically treated before mixing with the polymer matrix to improve their fibre interaction and composite performance. The alkaline treatment with sodium hydroxide (NaOH) solution is the most frequently used chemical treatment, followed by a silane treatment. Numerous chemical concentrations of NaOH and silane solutions are investigated and several combined treatments such as alkaline-silane. The present review discusses the effect of silane treatments on the surface of kenaf fibre on the fabrication of polymer composites and their mechanical properties.

In the recent past, significant research effort has been dedicated to examining the usage of nanomaterials hybridized with lignocellulosic fibers as reinforcement in the fabrication of polymer nanocomposites. The introduction of nanoparticles like montmorillonite (MMT) nanoclay was found to increase the strength, modulus of elasticity and stiffness of composites and provide thermal stability. The resulting composite materials has figured prominently in research and development efforts devoted to nanocomposites and are often used as strengthening agents, especially for structural applications. The distinct properties of MMT, namely its hydrophilicity, as well as high strength, high aspect ratio and high modulus, aids in the dispersion of this inorganic crystalline layer in water-soluble polymers. The ability of MMT nanoclay to intercalate into the interlayer space of monomers and polymers is used, followed by the exfoliation of filler particles into monolayers of nanoscale particles. The present review article intends to provide a general overview of the features of the structure, chemical composition, and properties of MMT nanoclay and lignocellulosic fibers. Some of the techniques used for obtaining polymer nanocomposites based on lignocellulosic fibers and MMT nanoclay are described: (i) conventional, (ii) intercalation, (iii) melt intercalation, and (iv) in situ polymerization methods. This review also comprehensively discusses the mechanical, thermal, and flame retardancy properties of MMT-based polymer nanocomposites. The valuable properties of MMT nanoclay and lignocellulose fibers allow us to expand the possibilities of using polymer nanocomposites in various advanced industrial applications.

Currently, the harmful gas emission, rapid climate change, air and water pollution, and deterioration of earth's land surface are mainly produced by the aggressive utilization of petroleum-based plastic and the unmanaged garbage disposal including dumping and burning of polymeric products and substances. Many experts from throughout the globe revealed that the dumping of petroleum-based plastic and undecomposed materials is the main principle problem of environmental pollution. Hence, in order to overcome these challenging issues, biopolymers, such as starch, cellulosic-based polymer, and other biodegradable materials, are considered the most promising materials and as alternatives to non-biodegradable petroleum-based materials. This is due to their long shelf life properties such as resistance to enzymatic or chemical reaction and as they are biodegradable in nature. Starch is an abundantly available, highly biodegradable, cheap, and renewable biopolymer. However, some studies have found that the properties of starch biopolymer such as mechanical and water barrier are comparatively low than petroleum-based plastic. Therefore, nanofillers such as nanocellulose are introduced in order to overcome this issue. Nanocellulose has attracted huge attention due to its good physical and mechanical behaviors. In recent years, nanocellulose has also attracted the interest among researchers, since the technology capable to cater the environmental issues. This chapter explains the outline of current development in this particular field, including the isolation, characterization, behaviors, and various applications of nanocellulose reinforced starch biopolymer nanocomposites. Followed by explaining the distinctive properties of nanocellulose and its numerous preparation methods, an arranged introduction of various sources of nanocellulose reinforced biodegradable starch polymers is provided. Herein, nanocellulose reinforced starch biopolymer for engineering and interdisciplinary applications, comprising approaches for the transformation of various sources of cellulose to nanocellulose, and the technique of fabrication for their composites have been studied. Furthermore, the results of nanocellulose on the behavior of starch biopolymers are presented. Finally, the chapter summarizes with a new finding and innovation researches on nanocellulose reinforced starch biopolymer composites. In certain circumstances, an evaluation study was conducted between cellulose nanofiber and cellulose nanocrystals reinforced starch biodegradable polymers. Considering the vast amount of research on nanocellulose reinforced starch biopolymer composites, special highlights on such composites are allowed at the end of the review.

Most of transmission line (TL) towers are designed and fabricated in the form of lattice using galvanized steel. The crossarm of the TL is made of Neobalanocarpus or Chengal wood. Recently, it has been reported by an electrical corporation situated in Malaysia that mechanical performance of the wooden crossarm declined below their service life of 40 years due to the extreme tropical weather in Malaysia. At present, composite crossarm made of glass fibre reinforced polymer composite were introduced as substitute in the 132 kV TL tower. However, the research findings lack of information on creep life estimation for the full-scale crossarm. Hence, a new test rig has to be developed to cater the testing operation using the uniaxial tension creep test. The primary objective of this review is to provide an overview of the creep theory and the existing creep testing methodology.

In the field of hybrid natural fiber polymer composites, there has been a recent surge in research and innovation for structural applications. To expand the strengths and applications of this category of materials, significant effort was put into improving their mechanical properties. Hybridization is a designed technique for fiber-reinforced composite materials that involves combining two or more fibers of different groups within a single matrix to manipulate the desired properties. They may be made from a mix of natural and synthetic fibers, synthetic and synthetic fibers, or natural fiber and carbonaceous materials. Owing to their diverse properties, hybrid natural fiber composite materials are manufactured from a variety of materials, including rubber, elastomer, metal, ceramics, glasses, and plants, which come in composite, sandwich laminate, lattice, and segmented shapes. Hybrid composites have a wide range of uses, including in aerospace interiors, naval, civil building, industrial, and sporting goods. This study intends to provide a summary of the factors that contribute to natural fiber-reinforced polymer composites’ mechanical and structural failure as well as overview the details and developments that have been achieved with the composites.

Despite growing urban electricity consumption, information on actual energy use in the household sector is still limited and causal factors leading to electricity consumption remain speculative due to urban expansion and its growing complexity, particularly in developing countries such as Malaysia. This study aims to examine the critical determinants of household electricity consumption by evaluating the patterns and flows of consumption and analysing relationships and their effects on electricity usage among 620 urban households in Seremban, Malaysia. Results suggest that the average urban household electricity consumption is 648.31 kWh/month, this value continues to grow with the increase in the household monthly income (r = 0.360, p &lt, 0.01) and number of rooms (r = 0.360, 0.01) as quality of life improves. A large portion of electricity is allocated for kitchen/home consumption, followed by cooling and lighting. Multiple linear regressions revealed that married households with a high monthly income and living in spacious houses together with three to five people are important predictors of electricity consumption in Seremban. This study empirically identified that the number of rooms is the most critical factor of electricity consumption and strategies to increase energy efficiency, maintain resource sustainability and minimise greenhouse gas threat on the urban ecosystem are vital. Therefore, promoting low carbon initiatives for energy conservation and technology improvement and implementing policies in the domestic sector are essential to achieve the greatest potential energy consumption reduction in urban regions.

Even though natural fiber reinforced polymer composites (NFRPCs) have been widely used in automotive and building industries, there is still a room to promote them to high-level structural applications such as primary structural component specifically for bullet proof and ballistic applications. The promising performance of Kevlar fabrics and aramid had widely implemented in numerous ballistic and bullet proof applications including for bullet proof helmets, vest, and other armor parts provides an acceptable range of protection to soldiers. However, disposal of used Kevlar products would affect the disruption of the ecosystem and pollutes the environment. Replacing the current Kevlar fabric and aramid in the protective equipment with natural fibers with enhanced kinetic energy absorption and dissipation has been significant effort to upgrade the ballistic performance of the composite structure with green and renewable resources. The vast availability, low cost and ease of manufacturing of natural fibers have grasped the attention of researchers around the globe in order to study them in heavy armory equipment and high durable products. The possibility in enhancement of natural fiber’s mechanical properties has led the extension of research studies toward the application of NFRPCs for structural and ballistic applications. Hence, this article established a state-of-the-art review on the influence of utilizing various natural fibers as an alternative material to Kevlar fabric for armor structure system. The article also focuses on the effect of layering and sequencing of natural fiber fabric in the composites to advance the current armor structure system.

The high demand for plastic and polymeric materials which keeps rising every year makes them important industries, for which sustainability is a crucial aspect to be taken into account. Therefore, it becomes a requirement to makes it a clean and eco-friendly industry. Cellulose creates an excellent opportunity to minimize the effect of non-degradable materials by using it as a filler for either a synthesis matrix or a natural starch matrix. It is the primary substance in the walls of plant cells, helping plants to remain stiff and upright, and can be found in plant sources, agriculture waste, animals, and bacterial pellicle. In this review, we discussed the recent research development and studies in the field of biocomposites that focused on the techniques of extracting micro- and nanocellulose, treatment and modification of cellulose, classification, and applications of cellulose. In addition, this review paper looked inward on how the reinforcement of micro- and nanocellulose can yield a material with improved performance. This article featured the performances, limitations, and possible areas of improvement to fit into the broader range of engineering applications.