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Electron dynamics in water are of fundamental importance for a broad range of phenomena1-3, but their real-time study faces numerous conceptual and methodological challenges4-6. Here we introduce attosecond size-resolved cluster spectroscopy and build up a molecular-level understanding of the attosecond electron dynamics in water. We measure the effect that the addition of single water molecules has on the photoionization time delays7-9 of water clusters. We find a continuous increase of the delay for clusters containing up to four to five molecules and little change towards larger clusters. We show that these delays are proportional to the spatial extension of the created electron hole, which first increases with cluster size and then partially localizes through the onset of structural disorder that is characteristic of large clusters and bulk liquid water. These results indicate a previously unknown sensitivity of photoionization delays to electron-hole delocalization and indicate a direct link between electronic structure and attosecond photoionization dynamics. Our results offer new perspectives for studying electron-hole delocalization and its attosecond dynamics.

The integration and automation of industrial processes has brought significant gains in efficiency and productivity but also elevated cybersecurity risks, especially in the process industry. This paper introduces a methodology utilizing process mining and digital twins to enhance anomaly detection in Industrial Control Systems (ICS). By converting raw device logs into event logs, we uncover patterns and anomalies indicative of cyberattacks even when such attacks are masked by normal operational data. We present a detailed case study replicating an industrial process to demonstrate the practical application of our approach. Experimental results confirm the effectiveness of our method in identifying cyber–physical attacks within a realistic industrial setting.

Two different in-row soil management techniques were compared in the Olive Orchard Innovation Long-term experiment of the Council for Agricultural Research and Economics, Research Centre for Olive, Fruit, and Citrus Crops in Rome, Italy. Rows were managed with an in-row rotary tiller and with synthetic mulching using permeable polypropylene placed after cultivar Maurino olive trees planting. The effects of the two treatments were assessed through weed soil coverage and the growth of the olive trees. Results showed better agronomic performance associated with synthetic mulching. The weed control effect along the row of a young high-density olive orchard was higher with the synthetic mulching compared to hoeing. The effect of the synthetic mulching seemed to disappear when removed from the ground (spring 2023) since no significant differences were found for tree size and yield in the two tested in-row soil management systems at the end of 2023. Finally, the growth of the young olive trees (Trunk Cross Sectional Area, Height, and Canopy expansion) measured across the three years, was higher for the synthetic mulched row than the hoed one. The use of synthetic mulching along the row positively forced the vegetative growth of the young olive trees and anticipated the onset of fruit production compared to periodical hoeing: a significantly higher fruit production was registered three years after planting. Root diameter was higher under synthetic mulching one year after planting, and no differences were observed in the following sampling dates showing similar fluctuations linked to the seasonal growth pattern. The life cycle assessment and costing highlighted that the application of mulching had a higher eco- and economic-efficiency than the periodical in-row soil hoeing.

The objective of the research was to analyze the scientific production regarding accident prevention in early child rearing institutions. An integrative literature review, referring to the years between 2011 and 2021, whose research was carried out in May 2021 in seven information resources, raised the following issue: it was found that not all educators considered their knowledge about accident prevention satisfactory. However, most of them had already witnessed cases of injuries of this nature at schools. The first aid actions of these professionals were sometimes inefficient and many of them were not able to perform it due to the lack of appropriate materials and/or training to handle them, showing a need for qualification. The findings show weaknesses related to the knowledge and training of professionals from day care centres and preschools about accident prevention and first aid in early child rearing institutions, which makes a health-education interface crucial.

IntroductionThe use of Information and Communication Technology (ICT) for assessing and treating cognitive and motor disorders is promoting home-based telerehabilitation. This approach involves ongoing monitoring within a motivating context to help patients generalize their skills. It can also reduce healthcare costs and geographic barriers by minimizing hospitalization. This systematic review focuses on investigating key aspects of telerehabilitation protocols for children with neurodevelopmental or neurological disorders, including technology used, outcomes, caregiver involvement, and dosage, to guide clinical practice and future research.MethodThis systematic review adhered to PRISMA guidelines and was registered in PROSPERO. The PICO framework was followed to define the search strategy for technology-based telerehabilitation interventions targeting the pediatric population (aged 0–18) with neurological or neurodevelopmental disorders. The search encompassed Medline/PubMed, EMBASE, and Web of Science databases. Independent reviewers were responsible for selecting relevant papers and extracting data, while data harmonization and analysis were conducted centrally.ResultsA heterogeneous and evolving situation emerged from our data. Our findings reported that most of the technologies adopted for telerehabilitation are commercial devices; however, research prototypes and clinical software were also employed with a high potential for personalization and treatment efficacy. The efficacy of these protocols on health or health-related domains was also explored by categorizing the outcome measures according to the International Classification of Functioning, Disability, and Health (ICF). Most studies targeted motor and neuropsychological functions, while only a minority of papers explored language or multi-domain protocols. Finally, although caregivers were rarely the direct target of intervention, their role was diffusely highlighted as a critical element of the home-based rehabilitation setting.DiscussionThis systematic review offers insights into the integration of technological devices into telerehabilitation programs for pediatric neurologic and neurodevelopmental disorders. It highlights factors contributing to the effectiveness of these interventions and suggests the need for further development, particularly in creating dynamic and multi-domain rehabilitation protocols. Additionally, it emphasizes the importance of promoting home-based and family-centered care, which could involve caregivers more actively in the treatment, potentially leading to improved clinical outcomes for children with neurological or neurodevelopmental conditions.Systematic review registrationPROSPERO (CRD42020210663).

Water rockets can be used in a variety of ways, from schools to planetariums, with very young kids or adults. We propose here simple forms to work with water rockets, going one step further than a simple launch. A smartphone can be used to film the launch and analyze its motion with video analysis or it can even be attached to the rocket, using its acceleration sensor. We present both experimental techniques, theory, and a discussion about the propelling phase of the rocket's motion. The results show amazing features that are frequently neglected when discussing parabolic motion.

Dans les années 1930, les entraîneurs français ont joué un rôle important dans le développement du rugby italien avec notamment Julien Saby qui devient l’entraîneur des Amatori Milano et de l’équipe nationale. Les tensions internationales mettent fin à partir de 1938 à ce magistère qui reprend à partir des années 1950. Saby revient en Italie à Rovigo et forme de nombreux joueurs et entraîneurs italiens autour d’un rugby de conquête et de possession. Dans les années 1970, Pierre Villepreux devient un nouveau maestro d’oltrealpe autour d’un rugby de mouvement et de liberté. Saby comme Villepreux veulent ouvrir une voie italienne du rugby. D’autres entraîneurs français font fructifier leur héritage comme Georges Coste, Pierre Berbizier, Jacques Brunel même si l’Italie se tourne aussi vers des entraîneurs de l’hémisphère sud. Ils contribuent à la participation des Azzurri au Tournoi des Six Nation.

Objective: The aim of this study is to translate and validate the Nutritional Pathway for Infants with Congenital Heart Disease before Surgery British nutritional protocol into Brazilian Portuguese and test its clinical feasibility for specialized clinicians in Brazilian hospitals. Method: The translation and validation process followed strict methodological standards over the following steps: 1) initial translation; 2) synthesis; 3) back-translation; 4) expert committee content validation, and pre-test clinical feasibility with 30 health professionals. Data were collected through the Research Electronic Data Capture software data system, and then extracted and analyzed through statistical analysis software. Results: The culturally adapted version was considered equivalent to the original. In the first round, 82% agreement was achieved, and after consensus, there was 100% agreement among the experts. Regarding the ease of use of the protocol in clinical practice, the instrument obtained a minimum agreement rate of 93.4% and a 0.92 content validity index. Conclusions: The results indicate that the instrument adapted to Brazilian Portuguese has high content validity, and high reliability among the experts, suggesting a high level of accuracy of the instrument and cultural adaptation for Brazilian culture and medical systems. It was easily understandable by health professionals, as well as simple to apply in clinical practice. The Nutritional protocol for preoperative infants with congenital heart disease can reproduce the outcomes found in the pilot of this instrument carried out in the United Kingdom, which may promote better pre-surgical nutritional status for infants with congenital heart disease in Brazil.

Photoemission, in which photons cause atoms or molecules to emit electrons, is not an instantaneous process. The emitted electron may take hundreds of attoseconds to traverse the local potential of its parent atom or molecule after photoabsorption. The exact time is sensitive to the potential landscape the electron encounters, which causes a delay in when the photoelectron’s wave packet emerges from different parts of the molecule. Here, we experimentally explore this delay in the hitherto elusive frame of reference of the molecule, which allows us to observe photoelectron emission relative to specific orientations of the molecule.As a prototype process, we choose the photoionization of the inner valence electron of the NO molecule. During the photoelectron’s excursion, it experiences an asymmetric molecular potential landscape and a dynamical centrifugal potential. We introduce an approach to clock the photoionization dynamics of the NO molecule in its molecular frame. A key finding is an asymmetric photoemission delay difference, around 150 attoseconds, at the opposite ends of the molecule. Our theoretical simulation illustrates that the asymmetric delay originates from the interference between multiple photoionization pathways.Despite being demonstrated in a heteronuclear diatomic molecule, our methods and findings are applicable to the photoemission dynamics in many molecules, surfaces, and interfaces with asymmetric potentials. Our approach opens a new avenue for exploring the attosecond photoelectron dynamics in complex systems and investigating the time-resolved quantum dynamics in solutions, complex materials, and biologic tissues.

The double photoionization of a molecule by one photon ejects two electrons and typically creates an unstable dication. Observing the subsequent fragmentation products in coincidence can reveal a surprisingly detailed picture of the dynamics. Determining the time evolution and quantum mechanical states involved leads to deeper understanding of molecular dynamics. Here in a combined experimental and theoretical study, we unambiguously separate the sequential breakup via D+ + OD+ intermediates, from other processes leading to the same D+ + D+ + O final products of double ionization of water by a single photon. Moreover, we experimentally identify, separate, and follow step by step, two pathways involving the b 1Σ+ and a 1Δ electronic states of the intermediate OD+ ion. Our classical trajectory calculations on the relevant potential energy surfaces reproduce well the measured data and, combined with the experiment, enable the determination of the internal energy and angular momentum distribution of the OD+ intermediate.

D2 molecules, excited by linearly cross-polarized femtosecond extreme ultraviolet (XUV) and near-infrared (NIR) light pulses, reveal highly structured D+ ion fragment momenta and angular distributions that originate from two different four-step dissociative ionization pathways after four-photon absorption (one XUV + three NIR). We show that, even for very low dissociation kinetic energy release ≤ 240 meV, specific electronic excitation pathways can be identified and isolated in the final ion momentum distributions. With the aid of ab initio electronic structure and time-dependent Schrödinger equation calculations, angular momentum, energy, and parity conservation are used to identify the excited neutral molecular states and molecular orientations relative to the polarization vectors in these different photoexcitation and dissociation sequences of the neutral D2 molecule and its D2+ cation. In one sequential photodissociation pathway, molecules aligned along either of the two light polarization vectors are excluded, while another pathway selects molecules aligned parallel to the light propagation direction. The evolution of the nuclear wave packet on the intermediate B1ςu+ electronic state of the neutral D2 molecule is also probed in real time.