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Aerosol optical depth (AOD) has been widely used to estimate near-surface particulate matter (PM). In this study, ground-measured data from the Campaign on Atmospheric Aerosol Research network of China (CARE-China) and the Aerosol Robotic Network (AERONET) were used to evaluate the accuracy of Visible Infrared Imaging Radiometer Suite (VIIRS) AOD data for different aerosol types. These four aerosol types were from dust, smoke, urban, and uncertain and a fifth “type” was included for unclassified (i.e., total) aerosols. The correlation for dust aerosol was the worst (R2 = 0.15), whereas the correlations for smoke and urban types were better (R2 values of 0.69 and 0.55, respectively). The mixed-effects model was used to estimate the PM2.5 concentrations in Beijing−Tianjin−Hebei (BTH), Sichuan−Chongqing (SC), the Pearl River Delta (PRD), the Yangtze River Delta (YRD), and the Middle Yangtze River (MYR) using the classified aerosol type and unclassified aerosol type methods. The results suggest that the cross validation (CV) of different aerosol types has higher correlation coefficients than that of the unclassified aerosol type. For example, the R2 values for dust, smoke, urban, uncertain, and unclassified aerosol types BTH were 0.76, 0.85, 0.82, 0.82, and 0.78, respectively. Compared with the daily PM2.5 concentrations, the air quality levels estimated using the classified aerosol type method were consistent with ground-measured PM2.5, and the relative error was low (most RE was within ±20%). The classified aerosol type method improved the accuracy of the PM2.5 estimation compared to the unclassified method, although there was an overestimation or underestimation in some regions. The seasonal distribution of PM2.5 was analyzed and the PM2.5 concentrations were high during winter, low during summer, and moderate during spring and autumn. Spatially, the higher PM2.5 concentrations were predominantly distributed in areas of human activity and industrial areas.

Satellite aerosol optical depth (AOD) products have been widely used in estimating fine particulate matter (PM2.5) concentrations near the surface at a regional scale, and perform well compared with ground measurements. However, the influence of limitations such as retrieval frequency and the spatial resolution of satellite AODs on the applicability of predicted PM2.5 values has been rarely considered. With three widely used MODIS AOD products, including Multi-Angle Implementation of Atmospheric Correction (MAIAC), Deep Blue (DB) and Dark Target (DT), here we evaluate the influence of their spatial resolution and sampling frequency by estimating daily PM2.5 concentrations in the Beijing-Tianjin-Hebei (BTH) region of northern China during 2017 utilizing a mixed effects model. The daily concentrations of PM2.5 derived from MAIAC, DB and DT AOD all have high correlations (R2: 0.78, 0.8, and 0.78) with the observed values, but the predicted annual PM2.5 exhibits a distinct spatial distribution. DT estimation obviously underestimates annual PM2.5 in polluted areas due to lower sampling of heavy pollution events. By contrast, the retrieval frequency (~40-60%) of MAIAC and DB AOD can represent well annual PM2.5 in nearly all 83 sites tested. However, MAIAC and DB-derived PM2.5 have a larger bias compared with observed values than DT, indicating that the large spatial variation of aerosol properties can exert an influence on the reliability of the statistical AOD-PM2.5 relationship. Also, there is notable difference between MAIAC and DB PM2.5 due to their different cloud screening methods. The MAIAC PM2.5 with high spatial resolution at 1 km can capture much finer hotpots than DB and DT at 10 km. Our results suggest that it is crucial to consider the applicability of satellite-predicted PM2.5 values derived from different aerosol products according to the specific requirements besides modeling the AOD-PM2.5 relationship.

The clean air actions of the Chinese government since 2013 have led to rapid reduction in anthropogenic emissions during the last five years. In this study, we present a regional-scale insight into the transition of aerosol properties during this special period based on integrated Moderate Resolution Imaging Spectroradiometer (MODIS), Multi-angle Imaging Spectroradiometer (MISR), and ground-based AERONET (AErosol RObotic NETwork) observations. As a response, aerosols in eastern China have exhibited notable reversal in both the amount and optical properties. Regional haze pollution with Aerosol Optical Depth (AOD) > 1.0 in northern China declined from more than ~80 days per year to less than ~30 days. While fine-mode particles exhibited a continuous decrease by ~30-40% during the time period of 2013−2018, the levels of coarse aerosols had no regular variations. MISR fraction AOD of different size modes shows that there has been an obvious overall decline in coarse particles over eastern China, but natural sources such as long-range dust transport make a considerable contribution. The Single Scattering Albedo (SSA) increased steadily from 2001 to 2012 by more than ~0.05. In contrast, aerosol absorption has been getting stronger since 2013, with SSA increasing by ~0.03, due to a much larger reduction in sulfate and nitrate. The drastic transition of aerosol properties has greatly changed aerosol radiative forcing (ARF) in eastern China. The negative ARF at the top (TOA) and bottom (BOA) of the atmosphere decreased by ~30 and ~50 W/m2, respectively, in Beijing during the 2001−2012 period. Although aerosol loading continued to decline after 2013, the magnitudes of TOA and BOA ARF have increased by ~10 and ~30 W/m2, respectively, since 2013, due largely to the enhanced aerosol absorption. Our results suggest that more comprehensive observations are needed to improve understanding of the intense climate and environment effects of dramatic aerosol properties in eastern China.

This study evaluated the impacts of different grazing treatments (continuous (C) and rotational (R) grazing) on tallgrass prairie landscape, using high-spatial-resolution aerial imagery (1-m at RGB and near-infrared bands) of experimental C and R pastures within two replicates (Rep A and Rep B) in the southern Great Plains (SGP) of the United States. The imagery was acquired by the National Agriculture Imagery Program (NAIP) during the agricultural growing season of selected years (2010, 2013, 2015, and 2017) in the continental United States. Land cover maps were generated by combining visual interpolation, a support vector machine, and a decision tree classifier. Landscape metrics (class area, patch number, percentage of landscape, and fragmentation indices) were calculated from the FRAGSTATS (a computer software program designed to compute a wide variety of landscape metrics for categorical map patterns) based on land cover results. Both the metrics and land cover results were used to analyze landscape dynamics in the experiment pastures. Results showed that both grass and shrubs of different pastures differed largely in the same year and had significant annual dynamics controlled by climate. High stocking intensity delayed grass growth. A large proportion of bare soil occurred in sub-paddocks of rotational grazing that were just grazed or under grazing. Rep A experienced rapid shrub encroachment, with a large proportion of shrub at the beginning of the experiment. Shrub may occupy 41% of C and 15% of R in Rep A by 2030, as revealed by the linear regression analysis of shrub encroachment. In contrast, shrub encroachment was not significant in Rep B, which only had a small number of shrub patches at the beginning of the experiment. This result indicates that the shrub encroachment is mainly controlled by the initial status of the pastures instead of grazing management. However, the low temporal resolution of the NAIP imagery (one snapshot in two or three years) limits our comparison of the continuous and rotational grazing at the annual scale. Future studies need to combine NAIP imagery with other higher temporal resolution imagery (e.g., WorldView), in order to better evaluate the interannual variabilities of grass productivity and shrub encroachment.

It has been found that the concentration of atmospheric methane (CH4) has rapidly increased since 2007 after a decade of nearly constant concentration in the atmosphere. As an important greenhouse gas, such an increase could enhance the threat of global warming. To better quantify this increasing trend, a novel statistic method, i.e. the Ensemble Empirical Mode Decomposition (EEMD) method, was used to analyze the CH4 trends from three different measurements: the mid–upper tropospheric CH4 (MUT) from the space-borne measurements by the Atmospheric Infrared Sounder (AIRS), the CH4 in the marine boundary layer (MBL) from NOAA ground-based in-situ measurements, and the column-averaged CH4 in the atmosphere (XCH4) from the ground-based up-looking Fourier Transform Spectrometers at Total Carbon Column Observing Network (TCCON) and the Network for the Detection of Atmospheric Composition Change (NDACC). Comparison of the CH4 trends in the mid–upper troposphere, lower troposphere, and the column average from these three data sets shows that, overall, these trends agree well in capturing the abrupt CH4 increase in 2007 (the first peak) and an even faster increase after 2013 (the second peak) over the globe. The increased rates of CH4 in the MUT, as observed by AIRS, are overall smaller than CH4 in MBL and the column-average CH4. During 2009–2011, there was a dip in the increase rate for CH4 in MBL, and the MUT-CH4 increase rate was almost negligible in the mid-high latitude regions. The increase of the column-average CH4 also reached the minimum during 2009–2011 accordingly, suggesting that the trends of CH4 are not only impacted by the surface emission, however that they also may be impacted by other processes like transport and chemical reaction loss associated with [OH]. One advantage of the EEMD analysis is to derive the monthly rate and the results show that the frequency of the variability of CH4 increase rates in the mid–high northern latitude regions is larger than those in the tropics and southern hemisphere.

Accurately estimating fine ambient particulate matter (PM2.5) is important to assess air quality and to support epidemiological studies. To analyze the spatiotemporal variation of PM2.5 concentrations, previous studies used different methodologies, such as statistical models or neural networks, to estimate PM2.5. However, there is little research on full-coverage PM2.5 estimation using a combination of ground-measured, satellite-estimated, and atmospheric chemical model data. In this study, the linear mixed effect (LME) model, which used the aerosol optical depth (AOD) from the Moderate Resolution Imaging Spectroradiometer (MODIS), meteorological data, normalized difference vegetation index (NDVI), and elevation data as predictors, was fitted for 2017 over Beijing–Tianjin–Hebei (BTH). The LME model was used to calibrate the PM2.5 concentration using the nested air-quality prediction modeling system (NAQPMS) simulated with ground measurements. The inverse variance weighting (IVW) method was used to fuse satellite-estimated and model-calibrated PM2.5. The results showed a strong agreement with ground measurements, with an overall coefficient (R2) of 0.78 and a root-mean-square error (RMSE) of 26.44 μg/m3 in cross-validation (CV). The seasonal R2 values were 0.75, 0.62, 0.80, and 0.78 in the spring, summer, autumn, and winter, respectively. The fusion results supplement the lack of satellite estimates and can capture more detailed information than the NAQPMS model. Therefore, the results will be helpful for pollution process analyses and health-related studies.

Formaldehyde (HCHO) is one of the most abundant hydrocarbons in the atmosphere. Its absorption features in the 320⁻360 nm range allow its concentration in the atmosphere to be retrieved from space. There are two versions of HCHO datasets derived from the Ozone Monitoring Instrument (OMI)—one provided by the Royal Belgian Institute for Space Aeronomy (BIRA-IASB) and one provided by the National Aeronautics and Space Administration (NASA)—referred to as OMI-BIRA and OMI-NASA, respectively. We conducted daily comparisons of OMI-BIRA and multi-axis differential optical absorption spectrometry (MAX-DOAS), OMI-NASA and MAX-DOAS, and OMI-BIRA and OMI-NASA and monthly comparisons of OMI-BIRA and MAX-DOAS and OMI-NASA and MAX-DOAS. Daily comparisons showed a strong impact of effective cloud fraction (eCF), and correlations were better for eCF < 0.1 than for eCF < 0.3. By contrast, the monthly and multi-year monthly mean values yielded correlations of R2 = 0.60 and R2 = 0.95, respectively, for OMI-BIRA and MAX-DOAS, and R2 = 0.45 and R2 = 0.78 for OMI-NASA and MAX-DOAS, respectively. Therefore, use of the monthly mean HCHO datasets is strongly recommended. We conducted a sensitivity test for HCHO air mass factor (AMF) calculations with respect to the HCHO profile, the aerosol extinction coefficient (AEC), the HCHO profile⁻AEC combination, the aerosol optical depth (AOD), and the single scattering albedo (SSA) to explicitly account for the aerosol optical effects on the HCHO AMF. We found that the combination of AEC and HCHO profiles can account for 23⁻39% of the HCHO AMF variation. Furthermore, a high load of absorptive aerosols can exert a considerable effect (−53%) on the AMF. Finally, we used the HCHO monthly mean profiles from Goddard Earth Observing System coupled to Chemistry (GEOS-Chem), seasonal mean AECs from Cloud-Aerosol LIDAR with Orthogonal Polarization (CALIOP) and monthly climatologies of AOD and SSA from the OMAERUV (OMI level-2 near UV aerosol data product) dataset at Xianghe station to determine the aerosol correction. The results reveal that aerosols can account for +6.37% to +20.7% of the HCHO monthly change. However, the changes are greatest in winter and are weaker in summer and autumn, indicating that the aerosol correction is more applicable under high-AAOD conditions and that there may be other reasons for the significant underestimation between satellite and MAX-DOAS observations.

East China is the ‘hotspot’ of glyoxal (CHOCHO), especially over the Pearl River Delta (PRD) region, where glyoxal is yielded from the oxidation of aromatics. To better understand the glyoxal spatial-temporal characteristics over China and evaluate the effectiveness of atmospheric prevention efforts on the reduction of volatile organic compound (VOC) emissions, we present an algorithm for glyoxal retrieval using the Ozone Monitoring instrument (OMI) over China. The algorithm is based on the differential optical absorption spectroscopy (DOAS) and accounts for the interference of the tropospheric nitrogen dioxide (NO2) spatial-temporal distribution on glyoxal retrieval. We conduct a sensitively test based on a synthetic spectrum to optimize the fitting parameters set. It shows that the fitting interval of 430–458 nm and a 4th order polynomial are optimal for glyoxal retrieval when using the daily mean value of the earthshine spectrum in the Pacific region as a reference. In addition, tropospheric NO2 pre-fitted during glyoxal retrieval is first proposed and tested, which shows a ±10% variation compared with the reference scene. The interference of NO2 on glyoxal was further investigated based on the OMI observations, and the spatial distribution showed that changes in the NO2 concentration can affect the glyoxal result depending on the NO2 spatial distribution. A method to prefix NO2 during glyoxal retrieval is proposed in this study and is referred to as OMI-CAS. We perform an intercomparison of the glyoxal from the OMI-CAS with the seasonal datasets provided by different institutions for North China (NC), South China (SC), the Yangtze River Delta (YRD) and the ChuanYu (CY) region in southwestern China in the year 2005. The results show that our algorithm can obtain the glyoxal spatial and temporal variations in different regions over China. OMI-CAS has the best correlations with other datasets in summer, with the correlations between OMI-CAS and OMI-Harvard, OMI-CAS and OMI-IUP, and OMI-CAS and Sciamachy-IUP being 0.63, 0.67 and 0.67, respectively. Autumn results followed, with the correlations of 0.58, 0.36 and 0.48, respectively, over China. However, the correlations are less or even negative for spring and winter. From the regional perspective, SC has the best correlation compared with other regions, with R reaching 0.80 for OMI-CAS and OMI-IUP in summer. The discrepancies between different glyoxal datasets can be attributed to the fitting parameters and larger glyoxal retrieval uncertainties. Finally, useful recommendations are given based on the results comparison according to region and season.

Particulate matter with an aerodynamic diameter less than 2.5 μm (PM2.5) is related to various adverse health effects. Ground measurements can yield highly accurate PM2.5 concentrations but have certain limitations in the discussion of spatial-temporal variations in PM2.5. Satellite remote sensing can obtain continuous and long-term coverage data, and many previous studies have demonstrated the relationship between PM2.5 and AOD (aerosol optical depth) from theoretical analysis and observation. In this study, a new aerosol product with a high spatial-temporal resolution retrieved from the AHI (the Advance Himawari Imager) was obtained using a vertical-humidity correction method to estimate hourly PM2.5 concentrations in Hebei. The hygroscopic growth factor ( f ( RH ) ) was fitted at each site (in a total of 137 matched sites). Meanwhile, assuming that there was little change in f ( RH ) at a certain scale, the nearest f ( RH ) of each pixel was determined to calculate PM2.5 concentrations. Compared to the correlation between AOD and PM2.5, the relationship between the “dry” mass extinction efficiency obtained by vertical-humidity correction and the ground-measured PM2.5 significantly improved, with r coefficient values increasing from 0.19–0.47 to 0.61–0.76. The satellite-estimated hourly PM2.5 concentrations were consistent with the ground-measured PM2.5, with a high r (0.8 ± 0.07) and a low RMSE (root mean square error, 30.4 ± 5.5 μg/m3) values, and the accuracy in the afternoon (13:00–16:00) was higher than that in the morning (09:00–12:00). Meanwhile, in a comparison of the daily average PM2.5 concentrations of 11 sites from different cities, the r values were approximately 0.91 ± 0.03, and the RMSEs were between 13.94 and 31.44 μg/m3. Lastly, pollution processes were analyzed, and the analysis indicated that the high spatial-temporal resolution of the PM2.5 data could continuously and intuitively reflect the characteristics of regional pollutants (such as diffusion and accumulation), which is of great significance for the assessment of regional air quality.

The temporal and spatial distributions of tropospheric ozone and its precursors (NO2, CO, HCHO) are analyzed over Guangxi (GX) in South China. We used tropospheric column ozone (TCO) from the Ozone Monitoring Instrument (OMI) and Microwave Limb Sounder (MLS) onboard the Aura satellite (OMI/MLS), NO2 and HCHO from OMI and CO from the Measurements of Pollution in the Troposphere (MOPITT) instrument in the period 2005–2016. The TCO shows strong seasonality, with the highest value in spring and the lowest value observed in the monsoon season. The seasonal variation of HCHO is similar to that of TCO, while NO2 and CO show slightly different patterns with higher values in spring and winter compared to lower values in autumn and summer. The surface ozone, NO2 and CO observed by national air quality monitoring network sites are also compared with satellite-observed TCO, NO2 and CO, showing good agreement for NO2 and CO but a different seasonal pattern for ozone. Unlike TCO, surface ozone has the highest value in autumn and the lowest value in winter. To reveal the difference, the vertical profiles of ozone and CO from the measurement of ozone and water vapor by airbus in-service aircraft (MOZAIC) observations over South China are also examined. The seasonal averaged vertical profiles of ozone and CO show obvious enhancements at 2–6 km altitudes in spring. Furthermore, we investigate the dependence of TCO and surface ozone on meteorology and transport in detail along with the ECMWF reanalysis data, Tropical Rainfall Measuring Mission (TRMM) 3BV42 dataset, OMI ultraviolet index (UV index) dataset, MODIS Fire Radiative Power (FRP) and back trajectory. Our results show that the wind pattern at 800 hPa plays a significant role in determining the seasonality of TCO over GX, especially for the highest value in spring. Trajectory analysis, combined with MODIS FRP suggests that the air masses that passed through the biomass burning (BB) region of Southeast Asia (SEA) induced the enhancement of TCO and CO in the upper-middle troposphere in spring. However, the seasonal cycle of surface ozone is associated with wind patterns at 950 hPa, and the contribution of the photochemical effect is offset by the strong summer monsoon, which results in the maximum surface ozone concentration in post-monsoon September. The variations in the meteorological conditions at different levels and the influence of transport from SEA can account for the vertical distribution of ozone and CO. We conclude that the seasonal distribution of TCO results from the combined impact of meteorology and long-term transport.

The Atmospheric Infrared Ultraspectral Sounder (AIUS), the first high-resolution (0.02 cm−1) solar occultation sounder, aboard GF5, was launched in May 2018 from China. However, relevant studies about vertical profiles of atmospheric constituents based on its operational data were not conducted until half a year later. Due to an urgent need for Hin-orbit tests, the real spectra (called reference spectra hereafter) were substituted with simulated spectra calculated from the reference forward model (RFM) plus different random noises at different altitudes. In the generation process of the reference spectra for N2O, NO2, and HF species, ACE-FTS (Atmospheric Chemistry Experiment–Fourier Transform Spectrometer instrument on the SCISAT satellite) level 2 products replace corresponding profiles included in the atmospheric background profiles. The optimal estimation method is employed to extract N2O, NO2, and HF profiles in this study. Comparing the retrieved results with ACE-FTS level 2 products, the relative deviations for these three species are calculated. For N2O, the average relative deviation is less than 6% at altitudes below 25 km, while larger deviations are observed in the range of 25–45 km, with the maximum being at ~25%. Additionally, the difference for NO2 is less than 5% in the 20–45 km range, with a larger discrepancy found below 20 km and above 45 km; the maximum deviation reaches ±40%. For HF, the relative deviation is less than 6% for all tangent heights, implying satisfactory retrieval. The vertical resolution, averaging kernel, and number of degrees of freedom are used to assess the retrieval algorithm, which indicate that the retrieved information content is much more attributable to the reference spectra contribution than to the a priori profile. Finally, a large number of retrieval tests are performed for N2O, NO2, and HF in selected areas covering the Arctic region, northern middle latitude, tropics, southern middle latitude, and Antarctic region, and reliable results are obtained. Thus, to a great extent, the algorithm adopted in the AIUS system can process retrievals reliably and precisely.

Precipitation is a key aspect of the climate system. In this paper, the dependability of five satellite precipitation products (TRMM [Tropical Rainfall Measuring Mission] 3BV42, PERSIANN [Precipitation Estimation from Remotely Sensed Information using Artificial Neural Networks] CDR, GSMaP [Global Satellite Mapping of Precipitation] RENALYSIS, CMORPH [Climate Prediction Center’s morphing technique] BLD and CMORPH_RAW) were compared with in situ measurements over China for the period of 2005 to 2013. To completely evaluate these precipitation products, the annual, seasonal and monthly precipitation averages were calculated. Overall, the Huaihe River and Qinlin mountains are shown to have heavy precipitation to the southeast and lighter precipitation to the northwest. The comparison results indicate that Gauge correction (CMORPH_BLD) improves the quality of the original satellite products (CMORPH_RAW), resulting in the higher correlation coefficient (CC), the low relative bias (BIAS) and root mean square error (RMSE). Over China, the GSMaP_RENALYSIS outperforms other products and shows the highest CC (0.91) and lowest RMSE (0.85 mm/day) and all products except for PERSIANN_CDR exhibit underestimation. GSMaP_RENALYSIS gives the highest of probability of detection (81%), critical success index (63%) and lowest false alarm ratio (36%) while TRMM3BV42 gives the highest of frequency bias index (1.00). Over Tibetan Plateau, CMORPH_RAW demonstrates the poorest performance with the biggest BIAS (4.2 mm/month) and lowest CC (0.22) in December 2013. GSMaP_RENALYSIS displays quite consistent with in situ measurements in summer. However, GSMaP_RENALYSIS and CMORPH_RAW underestimate precipitation over South China. CMORPH_BLD and TRMM3BV42 show consistent with high CC (>0.8) but relatively large RMSE in summer.