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55. Metallic and complex hydride-based electrochemical storage of energy

Author

Cuevas, Fermin, primary, Amdisen, Mads B, additional, Baricco, Marcello, additional, Buckley, Craig E, additional, Cho, Young Whan, additional, de Jongh, Petra, additional, de Kort, Laura M, additional, Grinderslev, Jakob B, additional, Gulino, Valerio, additional, Hauback, Bjørn C, additional, Heere, Michael, additional, Humphries, Terry, additional, Jensen, Torben R, additional, Kim, Sangryun, additional, Kisu, Kazuaki, additional, Lee, Young-Su, additional, Li, Hai-Wen, additional, Mohtadi, Rana, additional, Møller, Kasper T, additional, Ngene, Peter, additional, Noréus, Dag, additional, Orimo, Shin-ichi, additional, Paskevicius, Mark, additional, Polanski, Marek, additional, Sartori, Sabrina, additional, Skov, Lasse N, additional, Sørby, Magnus H, additional, Wood, Brandon C, additional, Yartys, Volodymyr A, additional, Zhu, Min, additional, and Latroche, Michel, additional

Published
2022
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56. Des matériaux qui stockent de l'hydrogène sans effort

Author

Cuevas, Fermin, Latroche, Michel, Institut de Chimie et des Matériaux Paris-Est (ICMPE), Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), and CUEVAS, Fermin

Subjects
[CHIM.MATE] Chemical Sciences/Material chemistry, [CHIM.MATE]Chemical Sciences/Material chemistry
Abstract

International audience

Published
2022

62. Mechanochemistry and hydrogen storage properties of 2Li3N+Mg mixture.

Author

Li, Zhi-Nian, Qiu, Hao-Chen, Wang, Shu-Mao, Jiang, Li-Jun, Du, Jun, Zhang, Jun-Xian, Latroche, Michel, and Cuevas, Fermin

Abstract

The Li–Mg–N–H hydrogen storage system is a promising hydrogen storage material due to its moderate operation temperature, good reversibility, and relatively high capacity. In this work, the Li–Mg–N–H composite was directly synthesized by reactive ball milling (RBM) of Li3N and Mg powder mixture with a molar ratio of 2:1 under hydrogen pressure of 9 MPa. More than 8.8 wt% hydrogen was absorbed during the RBM process. The phases and structural evolution during the in situ hydrogenation process were analyzed by means of in situ solid–gas absorption and ex situ X-ray diffraction (XRD) measurements. It is determined that the hydrogenation can be divided into two steps, leading to mainly the formation of a lithium magnesium imide phase and a poorly crystallized amide phase, respectively. The H-cycling properties of the as-milled composite were determined by temperature-programmed dehydrogenation (TPD) method in a closed system. The onset dehydrogenation temperature was detected at 125 °C, and it can reversibly desorb 3.1 wt% hydrogen under a hydrogen back pressure of 0.2 MPa. The structural evolution during dehydrogenation was further investigated by in situ XRD measurement. It is found that Mg(NH2)2 phase disappears at about 200 °C, and Li2Mg2N3H3, LiNH2, and Li2MgN2H2 phases coexist at even 300 °C, revealing that the dehydrogenation process is step-wised and only partial hydrogen can be desorbed. [ABSTRACT FROM AUTHOR]

Published
2022
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63. Materials for hydrogen-based energy storage – past, recent progress and future outlook

Author

Hirscher, Michael, Yartys, Volodymyr A., Baricco, Marcello, Bellosta von Colbe, Jose, Blanchard, Didier, Bowman, Robert C., Broom, Darren P., Buckley, Craig E., Chang, Fei, Chen, Ping, Cho, Young Whan, Crivello, Jean Claude, Cuevas, Fermin, David, William I.F., de Jongh, Petra E., Denys, Roman V., Dornheim, Martin, Felderhoff, Michael, Filinchuk, Yaroslav, Froudakis, George E., Grant, David M., Gray, Evan Mac A., Hauback, Bjørn C., He, Teng, Humphries, Terry D., Jensen, Torben R., Kim, Sangryun, Kojima, Yoshitsugu, Latroche, Michel, Li, Hai Wen, Lototskyy, Mykhaylo V., Makepeace, Joshua W., Møller, Kasper T., Naheed, Lubna, Ngene, Peter, Noréus, Dag, Nygård, Magnus Moe, Orimo, Shin ichi, Paskevicius, Mark, Pasquini, Luca, Ravnsbæk, Dorthe B., Veronica Sofianos, M., Udovic, Terrence J., Vegge, Tejs, Walker, Gavin S., Webb, Colin J., Weidenthaler, Claudia, Zlotea, Claudia, Sub Inorganic Chemistry and Catalysis, Inorganic Chemistry and Catalysis, Hirscher, Michael, Yartys, Volodymyr A., Baricco, Marcello, Bellosta von Colbe, Jose, Blanchard, Didier, Bowman, Robert C., Broom, Darren P., Buckley, Craig E., Chang, Fei, Chen, Ping, Cho, Young Whan, Crivello, Jean-Claude, Cuevas, Fermin, David, William I.F., de Jongh, Petra E., Denys, Roman V., Dornheim, Martin, Felderhoff, Michael, Filinchuk, Yaroslav, Froudakis, George E., Grant, David M., Gray, Evan MacA., Hauback, Bjørn C., He, Teng, Humphries, Terry D., Jensen, Torben R., Kim, Sangryun, Kojima, Yoshitsugu, Latroche, Michel, Li, Hai-Wen, Lototskyy, Mykhaylo V., Makepeace, Joshua W., Møller, Kasper T., Naheed, Lubna, Ngene, Peter, Noréus, Dag, Nygård, Magnus Moe, Orimo, Shin-ichi, Paskevicius, Mark, Pasquini, Luca, Ravnsbæk, Dorthe B., Veronica Sofianos, M., Udovic, Terrence J., Vegge, Tej, Walker, Gavin S., Webb, Colin J., Weidenthaler, Claudia, Zlotea, Claudia, UCL - SST/IMCN/MOST - Molecular Chemistry, Materials and Catalysis, Max Planck Institute for Intelligent Systems, Max-Planck-Gesellschaft, Institute for Energy Technology, PO Box 40, 2007, Kjeller, Norway (INSTITUTE FOR ENERGY TECHNOLOGY, PO BOX 40, 2007, KJELLER, NORWAY), Institute for Energy Technology, PO Box 40, 2007, Kjeller, Norway, Chemistry Department and NIS, University of Turin, Helmholtz-Zentrum Geesthacht (GKSS), Risø National Laboratory for Sustainable Energy (Risø DTU), Technical University of Denmark [Lyngby] (DTU), RCB Hydrides, LLC, Hiden Isochema, 422 Europa Blvd, Warrington WA5 7TS, Cheshire, England, Curtin University [Perth], Planning and Transport Research Centre (PATREC), Debye Institute for Nanomaterials Science, Utrecht University [Utrecht], Dalian Institute of Chemical Physics - Chinese Academy of Sciences, Korea Institute of Science and Technology, Institut de Chimie et des Matériaux Paris-Est (ICMPE), Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), University of Oxford [Oxford], Max-Planck-Institut für Kohlenforschung (Coal Research), Institut de la matière condensée et des nanosciences / Institute of Condensed Matter and Nanosciences (IMCN), Université Catholique de Louvain = Catholic University of Louvain (UCL), University of Crete [Heraklion] (UOC), University of Nottingham, UK (UON), Griffith University [Brisbane], Aarhus University [Aarhus], Interdisciplinary Nanoscience Center (iNANO), Institute for Materials Research, Tohoku University, Institute for Materials Research, Hiroshima University, Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University, Fukuoka (DMS), Kyushu University [Fukuoka], University of the Western Cape, Stockholm University, Institute for Energy Technology (IFE), Tohoku University, WPI AIMR, Sendai, Tohoku University [Sendai], University of Bologna, Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense, Denmark, National Institute of Standards and Technology [Gaithersburg] (NIST), Centre National de la Recherche Scientifique (CNRS)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12), University of Oxford (University of Oxford), Université Catholique de Louvain (UCL), Max Planck Institute for Intelligent Systems [Tübingen], Università degli studi di Torino = University of Turin (UNITO), Danmarks Tekniske Universitet = Technical University of Denmark (DTU), University of Bologna/Università di Bologna, University of Southern Denmark (SDU), Sub Inorganic Chemistry and Catalysis, and Inorganic Chemistry and Catalysis

Subjects
RARE-EARTH R, Magnesium based materials, Hydrogen, 02 engineering and technology, Complex metal hydrides, Liquid hydrogen carriers, 01 natural sciences, 7. Clean energy, DENSITY-FUNCTIONAL THEORY, X-RAY-DIFFRACTION, Magnesium-based materials, SDG 13 - Climate Action, Cryogenic liquids, Materials Chemistry, Climate change, Porous materials, Hydrogen storage materials, Heat storage, Process engineering, ComputingMilieux_MISCELLANEOUS, Liquid hydrogen, Condensed Matter - Materials Science, Metals and Alloys, [CHIM.MATE]Chemical Sciences/Material chemistry, Renewable energy resources, 021001 nanoscience & nanotechnology, Renewable energy, Condensed Matter - Other Condensed Matter, Mechanics of Materials, Hydrogen fuel, Electrochemical energy storage, 0210 nano-technology, TRANSITION-METAL HYDRIDES, Efficient energy use, Magnesium-based hydrides, applications, Intermetallics, Intermetallic hydrides, Low dimensional hydrides, Hydrogen energy systems, FOS: Physical sciences, chemistry.chemical_element, Low dimensional, 010402 general chemistry, Thermal energy storage, IN-SITU NEUTRON, Energy storage, nanostructuring, hydrogen storage, Hydrogen storage, high pressures, SDG 7 - Affordable and Clean Energy, NUCLEAR-MAGNETIC-RESONANCE, ddc:620.11, catalysis, energy storage, business.industry, Hydrides, Mechanical Engineering, Materials Science (cond-mat.mtrl-sci), RE-BOROHYDRIDES RE, HIGH-ENTROPY ALLOYS, 0104 chemical sciences, chemistry, kinetics, 13. Climate action, MEDIATED NITROGEN TRANSFER, AMMONIA DECOMPOSITION CATALYSTS, business, Complex metal hydrides, Electrochemical energy storage, heat strage, Hydrogen energy systems, hydrogen storage materials, Intermetallic hydrides, Liquid hydrogen carriers, Low dimensional hydrides, Magnesium based materials, Porous materials, Liquefied gases, Other Condensed Matter (cond-mat.other)
Abstract

Globally, the accelerating use of renewable energy sources, enabled by increased efficiencies and reduced costs, and driven by the need to mitigate the effects of climate change, has significantly increased research in the areas of renewable energy production, storage, distribution and end-use. Central to this discussion is the use of hydrogen, as a clean, efficient energy vector for energy storage. This review, by experts of Task 32, “Hydrogen-based Energy Storage” of the International Energy Agency, Hydrogen TCP, reports on the development over the last 6 years of hydrogen storage materials, methods and techniques, including electrochemical and thermal storage systems. An overview is given on the background to the various methods, the current state of development and the future prospects. The following areas are covered; porous materials, liquid hydrogen carriers, complex hydrides, intermetallic hydrides, electrochemical storage of energy, thermal energy storage, hydrogen energy systems and an outlook is presented for future prospects and research on hydrogen-based energy storage. © 2020 The Authors

Published
2020

68. Characterisation of powder and pellets

Author

Dematteis, Erika Michela, Cuevas, Fermin, and Latroche, Michel

Subjects
industrial production, TiFe, metal hydride, intermetallic compound, hydrogen storage
Abstract

Summary of deliverable D3.2. In this deliverable the characterisations of powder and pellets produced for the HyCARE system and performed by the partners are discussed. GKN produced at the industrial scale up to 200 kg as a first batch for the prototype tank and afterwards up to 4 tons for the final demonstration tank the powder material of the selected composition. The produced material that includes 2% of binder (Lot IX-20015, 200 kg) has been distributed among the partners in form of powder and pellets for its characterization and the development of a first prototype module of the integrated system. Furthermore, the large 4 t production has been characterized at GKN (Lot 570119000/1-4, 4 tons) and related results are also presented. In details: structure, microstructure, particle size, density, thermal conductivity, heat capacity, composition, hydrogen storage properties (reversible capacity, thermodynamics, kinetics), poisoning and cycling properties have been reported.

Published
2021

71. Des terres rares moins polluantes ?

Author

Latroche, Michel, Institut de Chimie et des Matériaux Paris-Est (ICMPE), Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), and Latroche, Michel

Subjects
[CHIM.MATE] Chemical Sciences/Material chemistry, [CHIM.MATE]Chemical Sciences/Material chemistry, ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2019

72. Les terres rares, et après ?

Author

Latroche, Michel and Latroche, Michel

Subjects
[CHIM.MATE] Chemical Sciences/Material chemistry, ComputingMilieux_MISCELLANEOUS
Published
2019

73. Processing parameters

Author

Dematteis, Erika Michela, Cuevas, Fermin, Latroche, Michel, Marcello Baricco, Jussara Barale, Bettina Neumann, Giovanni Capurso, and Stefano Deledda

Subjects
industrial production, TiFe, metal hydride, intermetallic compound, hydrogen storage
Abstract

Summary of deliverable D2.3. After the studies conducted at CNRS, the optimised composition was selected by the consortium for the HyCARE project, owing to its easy activation, good thermodynamics, kinetics, high reversible capacity at 55 °C and good cycling performances, as shown in Deliverable 2.2. A first 5 kg industrial batch was produced by GKN. Here details on processing parameters and characteristics of the industrially produced alloy are resumed thanks to a muti-laboratory testing of the material.

Published
2020
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74. Investigation of H Sorption and Corrosion Properties of Sm2MnxNi7-x (0

Author

Madern, Nicolas, Charbonnier, Veronique, Monnier, Judith, Zhang, Junxian, Paul-Boncour, Valerie, and Latroche, Michel

Subjects
Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences
Abstract

Intermetallic compounds are key materials for energy transition as they form reversible hydrides that can be used for solid state hydrogen storage or as anodes in batteries. ABy compounds (A = Rare Earth (RE); B = transition metal; 2 < y < 5) are good candidates to fulfill the required properties for practical applications. They can be described as stacking of AB5 and AB2 sub-units along the c crystallographic axis. The latter sub-unit brings a larger capacity, while the former one provides a better cycling stability. However, ABy binaries do not show good enough properties for applications. Upon hydrogenation, they exhibit multiplateau behavior and poor reversibility, attributed to H induced amorphization. These drawbacks can be overcome by chemical substitutions on the A and/or the B sites leading to stabilized reversible hydrides. The present work focuses on the pseudo-binary Sm2MnxNi7-x system (0 0.3 leading to larger and flatter isotherm curves, allowing for reversible capacity >1.4 wt %. Regarding corrosion, the binary compound corrodes in alkaline medium to form rare earth hydroxide and nanoporous nickel. As for the Mn-substituted compounds, a new corrosion product is formed in addition to those above mentioned, as manganese initiates a sacrificial anode mechanism taking place at the early corrosion stage., Special Issue : Hydrogen Storage Properties of Materials

Published
2020
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75. Materials for hydrogen-based energy storage – past, recent progress and future outlook

Author

Sub Inorganic Chemistry and Catalysis, Inorganic Chemistry and Catalysis, Hirscher, Michael, Yartys, Volodymyr A., Baricco, Marcello, Bellosta von Colbe, Jose, Blanchard, Didier, Bowman, Robert C., Broom, Darren P., Buckley, Craig E., Chang, Fei, Chen, Ping, Cho, Young Whan, Crivello, Jean Claude, Cuevas, Fermin, David, William I.F., de Jongh, Petra E., Denys, Roman V., Dornheim, Martin, Felderhoff, Michael, Filinchuk, Yaroslav, Froudakis, George E., Grant, David M., Gray, Evan Mac A., Hauback, Bjørn C., He, Teng, Humphries, Terry D., Jensen, Torben R., Kim, Sangryun, Kojima, Yoshitsugu, Latroche, Michel, Li, Hai Wen, Lototskyy, Mykhaylo V., Makepeace, Joshua W., Møller, Kasper T., Naheed, Lubna, Ngene, Peter, Noréus, Dag, Nygård, Magnus Moe, Orimo, Shin ichi, Paskevicius, Mark, Pasquini, Luca, Ravnsbæk, Dorthe B., Veronica Sofianos, M., Udovic, Terrence J., Vegge, Tejs, Walker, Gavin S., Webb, Colin J., Weidenthaler, Claudia, Zlotea, Claudia, Sub Inorganic Chemistry and Catalysis, Inorganic Chemistry and Catalysis, Hirscher, Michael, Yartys, Volodymyr A., Baricco, Marcello, Bellosta von Colbe, Jose, Blanchard, Didier, Bowman, Robert C., Broom, Darren P., Buckley, Craig E., Chang, Fei, Chen, Ping, Cho, Young Whan, Crivello, Jean Claude, Cuevas, Fermin, David, William I.F., de Jongh, Petra E., Denys, Roman V., Dornheim, Martin, Felderhoff, Michael, Filinchuk, Yaroslav, Froudakis, George E., Grant, David M., Gray, Evan Mac A., Hauback, Bjørn C., He, Teng, Humphries, Terry D., Jensen, Torben R., Kim, Sangryun, Kojima, Yoshitsugu, Latroche, Michel, Li, Hai Wen, Lototskyy, Mykhaylo V., Makepeace, Joshua W., Møller, Kasper T., Naheed, Lubna, Ngene, Peter, Noréus, Dag, Nygård, Magnus Moe, Orimo, Shin ichi, Paskevicius, Mark, Pasquini, Luca, Ravnsbæk, Dorthe B., Veronica Sofianos, M., Udovic, Terrence J., Vegge, Tejs, Walker, Gavin S., Webb, Colin J., Weidenthaler, Claudia, and Zlotea, Claudia

Published
2020

76. Synthesis of MIL-102, a chromium carboxylate metal-organic framework, with gas sorption analysis

Author

Surble, Suzy, Millange, Franck, Serre, Christian, Duren, Tina, Latroche, Michel, Bourrelly, Sandrine, Llewellyn, Philip L., and Ferey, Gerard

Subjects
Chromium compounds -- Chemical properties, Chromium compounds -- Structure, Zeolites -- Chemical properties, Zeolites -- Structure, Naphthalene -- Chemical properties, Naphthalene -- Structure, Chemistry
Abstract

The synthesis, structure determination and sorption properties ([H.sub.2], C[O.sub.2], C[H.sub.4], and [N.sub.2]) of the metal-naphthalene-1,4,5,8-tetracarboxylate complex [Cr.sub.3.sup.III]O[([H.sub.2]O).sub.2]F[{[C.sub.10][H.sub.4][(C[O.sub.2]).sub.4]}.sub.1.5].6[H.sub.2]O, containing trivalent chromium (MIL-102) are described. MIL-102 is a new example of a porous chromium carboxylate that has a trimeric inorganic subnetwork, shows zeolite behavior with no pore contraction and has a small hydrogen storage capacity.

Published
2006

87. Pseudo-ternary LiBH4·LiCl·P2S5 system as structurally disordered bulk electrolyte for all-solid-state lithium batteries

Author

El Kharbachi, Abdelouahab, primary, Wind, Julia, additional, Ruud, Amund, additional, Høgset, Astrid B., additional, Nygård, Magnus M., additional, Zhang, Junxian, additional, Sørby, Magnus H., additional, Kim, Sangryun, additional, Cuevas, Fermin, additional, Orimo, Shin-ichi, additional, Fichtner, Maximilian, additional, Latroche, Michel, additional, Fjellvåg, Helmer, additional, and Hauback, Bjørn C., additional

Published
2020
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88. Electrochemical properties of MgH 2 – TiH 2 nanocomposite as active materials for all-solid-state lithium batteries

Author

Dao, Anh Ha, Berti, Nicola, López-Aranguren, Pedro, Zhang, Junxian, Cuevas, Fermin, Jordy, Christian, Latroche, Michel, Latroche, Michel, Institut de Chimie et des Matériaux Paris-Est (ICMPE), Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), SAFT, Direction de la Recherche, Université de Bordeaux (UB), SAFT [Bordeaux], and Société des accumulateurs fixes et de traction (SAFT)

Subjects
[CHIM.MATE] Chemical Sciences/Material chemistry, [CHIM.MATE]Chemical Sciences/Material chemistry, ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2018

89. Full-cell hydride-based solid-state Li batteries for energy storage

Author

Latroche, Michel, Blanchard, Didier, Cuevas, Fermín, El Kharbachi, Abdelouahab, Hauback, Bjørn C., Jensen, Torben R., de Jongh, Petra E., Kim, Sangryun, Nazer, Nazia S., Ngene, Peter, Orimo, Shin ichi, Ravnsbæk, Dorthe B., Yartys, Volodymyr A., Inorganic Chemistry and Catalysis, Sub Inorganic Chemistry and Catalysis, Institut de Chimie et des Matériaux Paris-Est (ICMPE), Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), Department of Energy Conversion and Storage, Danmarks Tekniske Universitet = Technical University of Denmark (DTU), Institute for Energy Technology, PO Box 40, 2007, Kjeller, Norway (INSTITUTE FOR ENERGY TECHNOLOGY, PO BOX 40, 2007, KJELLER, NORWAY), Institute for Energy Technology, PO Box 40, 2007, Kjeller, Norway, Department of Chemistry and Interdisciplinary Nanoscience Center, Aarhus University, Debye Institute for Nanomaterials Science, Utrecht University [Utrecht], Institute for Materials Research, Tohoku University, Institute for Materials Research, WPI Advanced Institute for Materials Research (WPI-AIMR), Tohoku University [Sendai], University of Southern Denmark (SDU), Inorganic Chemistry and Catalysis, Sub Inorganic Chemistry and Catalysis, Technical University of Denmark [Lyngby] (DTU), and Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense, Denmark

Subjects
Battery (electricity), Materials science, Energy Engineering and Power Technology, chemistry.chemical_element, Battery, 02 engineering and technology, Electrolyte, Lithium, 010402 general chemistry, 7. Clean energy, 01 natural sciences, Energy storage, chemistry.chemical_compound, Metallic and complex hydrides, Taverne, Fast ion conductor, Renewable Energy, Operando, Sustainability and the Environment, Renewable Energy, Sustainability and the Environment, Titanium disulfide, Hydride, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 0104 chemical sciences, Anode, Fuel Technology, chemistry, Chemical engineering, 0210 nano-technology
Abstract

Metallic and complex hydrides may act as anode and solid electrolytes in next generation of lithium batteries. Based on the conversion reaction with lithium to form LiH, Mg- and Ti-based anode materials have been tested in half-cell configuration with solid electrolytes derived from the hexagonal high temperature modification of the complex hydride LiBH 4 . These anode materials show large first discharge capacities demonstrating their ability to react with lithium. Reversibility remains more challenging though possible for a few dozen cycles. The work has been extended to full-cell configuration by coupling metallic lithium with positive electrodes such as sulfur or titanium disulfide through complex hydride solid electrolytes. Beside pure LiBH 4 which works only above 120 °C, various strategies like substitution, nanoconfinement and sulfide addition have allowed to lower the working temperature around 50 °C. In addition, use of lithium closo-boranes has been attempted. These results break new research ground in the field of solid-state lithium batteries. Finally, operando and in-situ neutron scattering methods applied to full-cells are presented as powerful tools to investigate and understand the reaction mechanisms taking place in working batteries.

Published
2019

90. Full-cell hydride-based solid-state Li batteries for energy storage

Author

Inorganic Chemistry and Catalysis, Sub Inorganic Chemistry and Catalysis, Latroche, Michel, Blanchard, Didier, Cuevas, Fermín, El Kharbachi, Abdelouahab, Hauback, Bjørn C., Jensen, Torben R., de Jongh, Petra E., Kim, Sangryun, Nazer, Nazia S., Ngene, Peter, Orimo, Shin ichi, Ravnsbæk, Dorthe B., Yartys, Volodymyr A., Inorganic Chemistry and Catalysis, Sub Inorganic Chemistry and Catalysis, Latroche, Michel, Blanchard, Didier, Cuevas, Fermín, El Kharbachi, Abdelouahab, Hauback, Bjørn C., Jensen, Torben R., de Jongh, Petra E., Kim, Sangryun, Nazer, Nazia S., Ngene, Peter, Orimo, Shin ichi, Ravnsbæk, Dorthe B., and Yartys, Volodymyr A.

Published
2019

91. In operando neutron diffraction study of LaNdMgNi 9 H 13 as a metal hydride battery anode

Author

Nazer, N.S., Denys, R.V., Yartys, V.A., Hu, Wei-Kang, Latroche, Michel, Cuevas, F., Hauback, B.C., Henry, F., Arnberg, L., Institute for Energy Technology, PO Box 40, 2007, Kjeller, Norway (INSTITUTE FOR ENERGY TECHNOLOGY, PO BOX 40, 2007, KJELLER, NORWAY), Institute for Energy Technology, PO Box 40, 2007, Kjeller, Norway, Institut de Chimie et des Matériaux Paris-Est (ICMPE), Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Latroche, Michel, and Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS)

Subjects
[CHIM.MATE] Chemical Sciences/Material chemistry, [CHIM.MATE]Chemical Sciences/Material chemistry, ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2017

94. Mechanochemistry of Metal Hydrides: Recent Advances

Author

Huot, Jacques, primary, Cuevas, Fermín, additional, Deledda, Stefano, additional, Edalati, Kaveh, additional, Filinchuk, Yaroslav, additional, Grosdidier, Thierry, additional, Hauback, Bjørn C., additional, Heere, Michael, additional, Jensen, Torben R., additional, Latroche, Michel, additional, and Sartori, Sabrina, additional

Published
2019
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96. An International Laboratory Comparison Study of Volumetric and Gravimetric Hydrogen Adsorption Measurements

Author

Hurst, Katherine E., primary, Gennett, Thomas, additional, Adams, Jesse, additional, Allendorf, Mark D., additional, Balderas‐Xicohténcatl, Rafael, additional, Bielewski, Marek, additional, Edwards, Bryce, additional, Espinal, L., additional, Fultz, Brent, additional, Hirscher, Michael, additional, Hudson, M. Sterlin L., additional, Hulvey, Zeric, additional, Latroche, Michel, additional, Liu, Di‐Jia, additional, Kapelewski, Matthew, additional, Napolitano, Emilio, additional, Perry, Zachary T., additional, Purewal, Justin, additional, Stavila, Vitalie, additional, Veenstra, Mike, additional, White, James L., additional, Yuan, Yuping, additional, Zhou, Hong‐Cai, additional, Zlotea, Claudia, additional, and Parilla, Philip, additional

Published
2019
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98. Study of the ternary system Al-H-RE (RE = Er, La and Y) in liquid state

Author

Prigent, Jocelyn, Joubert, Jean-Marc, Latroche, Michel, Constellium CRV, CRV Voreppe, Institut de Chimie et des Matériaux Paris-Est (ICMPE), Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), This work was financially supported by ANR under the contract Project ANR-2010-RMNP-007-01 PRINCIPIA in partnership with Constellium, Saint-Gobain, University of Lorraine, Ecole Centrale de Paris and ICMPE., ANR: PRINCIPIA,ANR-2010-RMNP-007-01, Latroche, Michel, Matériaux Fonctionnels et Procédés Innovants - PRocédés INdustriels de Coulée Innovants Pour l'Industrie Aéronautique - - PRINCIPIA2010 - ANR-10-RMNP-0007 - MatetPro - VALID, Constellium Technology Center (C-TEC), Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), and ANR-10-RMNP-0007,PRINCIPIA,PRocédés INdustriels de Coulée Innovants Pour l'Industrie Aéronautique(2010)

Subjects
rare earth hydrides, Calphad, [CHIM.MATE] Chemical Sciences/Material chemistry, aluminum, ternary phase diagram, [CHIM.MATE]Chemical Sciences/Material chemistry, hydrogen solubility, Thermodynamic modelling
Abstract

Hydrogen is the only gas able to dissolve in aluminum. The solubility S of hydrogen in Al obeys the Sieverts’ law and S is much larger in the liquid phase (above 660.4°C) than in the solid one. This might lead to the formation of porosity during aluminum casting. In the present work, the ternary system Al-H-RE (RE= Er, La, Y) is investigated. The equilibria between the different phases are determined in the presence of liquid Al, RE and H2 gas by both experimental measurements and phase diagram calculations. The possible formation of metallic hydrides and the change in the hydrogen solubility S are discussed regarding pressure and temperature determining the thermodynamics of the system.

Published
2016

99. Pseudo-ternary LiBH4·LiCl·P2S5 system as structurally disordered bulk electrolyte for all-solid-state lithium batteries.

Author

El Kharbachi, Abdelouahab, Wind, Julia, Ruud, Amund, Høgset, Astrid B., Nygård, Magnus M., Zhang, Junxian, Sørby, Magnus H., Kim, Sangryun, Cuevas, Fermin, Orimo, Shin-ichi, Fichtner, Maximilian, Latroche, Michel, Fjellvåg, Helmer, and Hauback, Bjørn C.

Abstract

The properties of the mixed system LiBH4–LiCl–P2S5 are studied with respect to all-solid-state batteries. The studied material undergoes an amorphization upon heating above 60 °C, accompanied with increased Li+ conductivity beneficial for battery electrolyte applications. The measured ionic conductivity is ∼10−3 S cm−1 at room temperature with an activation energy of 0.40(2) eV after amorphization. Structural analysis and characterization of the material suggest that BH4 groups and PS4 may belong to the same molecular structure, where Cl ions interplay to accommodate the structural unit. Thanks to its conductivity, ductility and electrochemical stability (up to 5 V, Au vs. Li+/Li), this new electrolyte is successfully tested in battery cells operated with a cathode material (layered TiS2, theo. capacity 239 mA h g−1) and Li anode resulting in 93% capacity retention (10 cycles) and notable cycling stability under the current density ∼12 mA g−1 (0.05C-rate) at 50 °C. Further advanced characterisation by means of operando synchrotron X-ray diffraction in transmission mode contributes explicitly to a better understanding of the (de)lithiation processes of solid-state battery electrodes operated at moderate temperatures. [ABSTRACT FROM AUTHOR]

Published
2020
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