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Iram 30-m Observations towards eight protostellar outflow sources were taken in the 96-\SI{176}{\giga\hertz} range. Transitions of CH$_3$OH and CH$_3$CHO were detected in seven of them. The integrated emission of the transitions of each species that fell into the observed frequency range were measured and fit using RADEX and LTE models. Column densities and gas properties inferred from this fitting are presented. The ratio of the A and E-type isomers of CH$_3$OH indicate that the methanol observed in these outflows was formed on the grain surface. Both species demonstrate a reduction of terminal velocity in their line profiles in faster outflows, indicating destruction in the post-shock gas phase. This destruction, and a near constant ratio of the CH$_3$OH and CH$_3$CHO column densities imply it is most likely that CH$_3$CHO also forms on the grain surface., Comment: Accepted for publication in ApJ

The main carrier of sulfur in dense clouds, where it is depleted from the gas phase, remains a mystery. Shock waves in young molecular outflows disrupt the ice mantles and allow us to directly probe the material that is ejected into the gas phase. A comprehensive study of sulfur-bearing species towards L1157-B1, a shocked region along a protostellar outflow, has been carried out as part of the IRAM-30m large program ASAI. The dataset contains over 100 lines of CCS, H$_2$CS, OCS, SO, SO$_2$ and isotopologues. The results of these observations are presented, complementing previous studies of sulfur-bearing species in the region. The column densities and fractional abundances of these species are measured and together these species account for 10\% of the cosmic sulfur abundance in the region. The gas properties derived from the observations are also presented, demonstrating that sulfur bearing species trace a wide range of different gas conditions in the region., Comment: Accepted for publication in ApJ

To probe the initial conditions for high-mass star and cluster formation, we investigate the properties of dense filaments within the infrared dark cloud G035.39-00.33 (IRDC G035.39) in a combined Very Large Array (VLA) and the Green Bank Telescope (GBT) mosaic tracing the NH3 (1,1) and (2,2) emission down to 0.08 pc scales. Using agglomerative hierarchical clustering on multiple line-of-sight velocity component fitting results, we identify seven extended velocity-coherent components in our data, likely representing spatially coherent physical structures, some exhibiting complex gas motions. The velocity gradient magnitude distribution peaks at its mode of 0.35 km/s/pc and has a long tail extending into higher values of 1.5 - 2 km/s/pc, and is generally consistent with those found toward the same cloud in other molecular tracers and with the values found towards nearby low-mass dense cloud cores at the same scales. Contrary to observational and theoretical expectations, we find the non-thermal ammonia line widths to be systematically narrower (by about 20%) than those of N2H+ (1-0) line transition observed with similar resolution. If the observed ordered velocity gradients represent the core envelope solid-body rotation, we estimate the specific angular momentum to be about 2 x 10^21 cm^2/s, similar to the low-mass star-forming cores. Together with the previous finding of subsonic motions in G035.39, our results demonstrate high levels of similarity between kinematics of a high-mass star-forming IRDC and the low-mass star formation regime., Comment: 22 pages, 14 figures, accepted to ApJ

We present the first detection of extragalactic hydrogen recombination line maser emission in the H26alpha transition toward the inner 13.5 pc nuclear region of the starburst galaxy NGC 253 using ALMA data. In regions with complex continuum emission (dust, free-free and synchrotron) we propose to use the recombination line spectral index, $\alpha_\mathrm{L}$ ($S_\mathrm{L}\cdot \Delta v \propto \nu^{\alpha_\mathrm{L}}$), between the H30alpha and the H26alpha lines to study the structure of ultra-compact HII regions and to identify maser emission ($\alpha_\mathrm{L}> 2.1$) from ionized winds. The measured values of $\alpha_\mathrm{L}$ ranged from 1.0 to 2.9. The largest $\alpha_\mathrm{L}$ can only be explained by maser emission. The measured flux density in the H26$\alpha$ maser in NGC 253 suggests that we are observing hundreds of stars like MWC349A, a prototypical stellar wind where maser emission arises from its circumstellar disk. We briefly discuss the implication of the detection of maser emission in starburst galaxies like NGC 253., Comment: 3 figures

Recent high-sensitivity observations carried out with ALMA have revealed the presence of complex organic molecules (COMs) such as methyl cyanide (CH$_{\rm 3}$CN) and methanol (CH$_{\rm 3}$OH) in relatively evolved protoplanetary discs. The behaviour and abundance of COMs in earlier phases of disc evolution remains unclear. Here we combine a smoothed particle hydrodynamics simulation of a fragmenting, gravitationally unstable disc with a gas-grain chemical code. We use this to investigate the evolution of formamide (NH$_{\rm 2}$CHO), a pre-biotic species, in both the disc and in the fragments that form within it. Our results show that formamide remains frozen onto grains in the majority of the disc where the temperatures are $<$100 K, with a predicted solid-phase abundance that matches those observed in comets. Formamide is present in the gas-phase in three fragments as a result of the high temperatures ($\geq$200\,K), but remains in the solid-phase in one colder ($\leq$150 K) fragment. The timescale over which this occurs is comparable to the dust sedimentation timescales, suggesting that any rocky core which is formed would inherit their formamide content directly from the protosolar nebula., Comment: 10 pages, 5 figures, accepted for publication in ApJ

We report new, $\sim$1000 AU spatial resolution observations of 225 GHz dust continuum emission towards the OB cluster-forming molecular clump G33.92+0.11. On parsec scales, this molecular clump presents a morphology with several arm-like dense gas structures surrounding the two central massive ($\gtrsim$100 $M_{\odot}$) cores. From the new, higher resolution observations, we identified 28 localized, spatially compact dust continuum emission sources, which may be candidates of young stellar objects. Only one of them is not embedded within known arm-like (or elongated) dense gas structures. The spatial separations of these compact sources can be very well explained by Jeans lengths. We found that G33.92+0.11 may be consistently described by a marginally centrifugally supported, Toomre unstable accretion flow which is approximately in a face-on projection. The arm-like overdensities are natural consequence of the Toomre instability, which can fragment to form young stellar objects in shorter time scales than the timescale of the global clump contraction. On our resolved spatial scales, there is not yet evidence that the fragmentation is halted by turbulence, magnetic field, or stellar feedback., Comment: 24 pages, 18 figures. Accepted to publish on December 04, 2018; updated to arXiv on December 05, 2018

For decades, the detection of phosphorus-bearing molecules in the interstellar medium was restricted to high-mass star-forming regions (as e.g. SgrB2 and Orion KL) and the circumstellar envelopes of evolved stars. However, recent higher-sensitivity observations have revealed that molecules such as PN and PO are present not only toward cold massive cores and low-mass star-forming regions with PO/PN ratios >1, but also toward the Giant Molecular Clouds in the Galactic Center known to be exposed to highly energetic phenomena such as intense UV radiation fields, shock waves and cosmic rays. In this paper, we carry out a comprehensive study of the chemistry of phosphorus-bearing molecules across different astrophysical environments which cover a range of physical conditions (cold molecular dark clouds, warm clouds, hot cores/hot corinos) and are exposed to different physical processes and energetic phenomena (proto-stellar heating, shock waves, intense UV radiation and cosmic rays). We show how the measured PO/PN ratio (either >1 as in e.g. hot molecular cores, or <1 as in UV strongly illuminated environments) can provide constraints on the physical conditions and energetic processing of the source. We propose that the reaction P + OH --> PO + H, not included in previous works, could be an efficient gas-phase PO formation route in shocks. Our modelling provides a template with which to study the detectability of P-bearing species not only in regions in our own Galaxy but also in extragalactic sources., Comment: 16 pages, 4 tables, 15 figures, accepted for ApJ

High-mass star forming regions are typically thought to be dominated by supersonic motions. We present combined Very Large Array and Green Bank Telescope (VLA+GBT) observations of NH$_3$ (1,1) and (2,2) in the infrared dark cloud (IRDC) G035.39-00.33, tracing cold and dense gas down to scales of 0.07 pc. We find that, in contrast to previous similar studies of IRDCs, more than a third of the fitted ammonia spectra show subsonic non-thermal motions (mean line width of 0.71 $\mathrm{km~s^{-1}}$), and the sonic Mach number distribution peaks around $\mathcal{M} = 1$. As possible observational and instrumental biases would only broaden the line profiles, our results provide strong upper limits to the actual value of $\mathcal{M}$, further strengthening our findings of narrow line widths. This finding calls for a reevaluation of the role of turbulent dissipation and subsonic regions in massive-star and cluster formation. Based on our findings in G035.39, we further speculate that the coarser spectral resolution used in the previous VLA NH$_3$ studies may have inhibited the detection of subsonic turbulence in IRDCs. The reduced turbulent support suggests that dynamically important magnetic fields of the 1 mG order would be required to support against possible gravitational collapse. Our results offer valuable input into the theories and simulations that aim to recreate the initial conditions of high-mass star and cluster formation., Comment: 5 pages, 3 figures; accepted for publication in A&A Letters; arxiv revision matches accepted version

Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of the NOEMA Large Project SOLIS (Seeds of Life in Space), the CH$_3$OH peak has been spatially resolved to study its kinematics and physical structure and to investigate the cause behind the local enhancement. We find that methanol emission is distributed in a ridge parallel to the main axis of the dense core. The centroid velocity increases by about 0.2~km~s$^{-1}$ and the velocity dispersion increases from subsonic to transonic towards the central zone of the core, where the velocity field also shows complex structure. This could be indication of gentle accretion of material onto the core or interaction of two filaments, producing a slow shock. We measure the rotational temperature and show that methanol is in local thermodynamic equilibrium (LTE) only close to the dust peak, where it is significantly depleted. The CH$_3$OH column density, $N_{tot}({\rm CH_3OH})$, profile has been derived with non-LTE radiative transfer modelling and compared with chemical models of a static core. The measured $N_{tot}({\rm CH_3OH})$ profile is consistent with model predictions, but the total column densities are one order of magnitude lower than those predicted by models, suggesting that the efficiency of reactive desorption or atomic hydrogen tunnelling adopted in the model may be overestimated; or that an evolutionary model is needed to better reproduce methanol abundance., Comment: 19 pages, 18 figures. Accepted by ApJ

Peptide bonds (N-C=O) play a key role in metabolic processes since they link amino acids into peptide chains or proteins. Recently, several molecules containing peptide-like bonds have been detected across multiple environments in the interstellar medium (ISM), growing the need to fully understand their chemistry and their role in forming larger pre-biotic molecules. We present a comprehensive study of the chemistry of three molecules containing peptide-like bonds: HNCO, NH$_2$CHO, and CH$_3$NCO. We also included other CHNO isomers (HCNO, HOCN), and C$_2$H$_3$NO isomers (CH$_3$OCN, CH$_3$CNO) to the study. We have used the \uclchem gas-grain chemical code and included in our chemical network all possible formation/destruction pathways of these peptide-like molecules recently investigated either by theoretical calculations or in laboratory experiments. Our predictions are compared to observations obtained toward the proto-star IRAS16293$-$2422 and the L1544 pre-stellar core. Our results show that some key reactions involving the CHNO and C$_2$H$_3$NO isomers need to be modified to match the observations. Consistently with recent laboratory findings, hydrogenation is unlikely to produce NH$_2$CHO on grain surfaces, while a combination of radical-radical surface reactions and gas-phase reactions is a better alternative. In addition, better results are obtained for NH$_2$CHO when a slightly higher activation energy of 25$\,$K is considered for the gas-phase reaction $\rm NH_2 + H_2CO \rightarrow NH_2CHO + H$. Finally, our modelling shows that the observed correlation between NH$_2$CHO and HNCO in star-forming regions may come from the fact that HNCO and NH$_2$CHO react to temperature in the same manner rather than from a direct chemical link between the two species., Comment: 18 pages, 5 figures, accepted for publication in MNRAS

Proxima Centauri, the star closest to our Sun, is known to host at least one terrestrial planet candidate in a temperate orbit. Here we report the ALMA detection of the star at 1.3 mm wavelength and the discovery of a belt of dust orbiting around it at distances ranging between 1 and 4 au, approximately. Given the low luminosity of the Proxima Centauri star, we estimate a characteristic temperature of about 40 K for this dust, which might constitute the dust component of a small-scale analog to our solar system Kuiper belt. The estimated total mass, including dust and bodies up to 50 km in size, is of the order of 0.01 Earth masses, which is similar to that of the solar Kuiper belt. Our data also show a hint of warmer dust closer to the star. We also find signs of two additional features that might be associated with the Proxima Centauri system, which, however, still require further observations to be confirmed: an outer extremely cold (about 10 K) belt around the star at about 30 au, whose orbital plane is tilted about 45 degrees with respect to the plane of the sky; and additionally, we marginally detect a compact 1.3 mm emission source at a projected distance of about 1.2 arcsec from the star, whose nature is still unknown., Comment: 9 pages, 4 figures, accepted for publication in The Astrophysical Journal Letters

Aims. Infrared dark clouds represent the earliest stages of high-mass star formation. Detailed observations of their physical conditions on all physical scales are required to improve our understanding of their role in fueling star formation. Methods. We investigate the large-scale structure of the IRDC G035.39-00.33, probing the dense gas with the classical ammonia thermometer. This allows us to put reliable constraints on the temperature of the extended, pc-scale dense gas reservoir and to probe the magnitude of its non-thermal motions. Available far-infrared observations can be used in tandem with the observed ammonia emission to estimate the total gas mass contained in G035.39-00.33. Results. We identify a main velocity component as a prominent filament, manifested as an ammonia emission intensity ridge spanning more than 6 pc, consistent with the previous studies on the Northern part of the cloud. A number of additional line-of-sight components are found, and a large scale, linear velocity gradient of ~0.2 km s$^{-1}$ pc$^{-1}$ is found along the ridge of the IRDC. In contrast to the dust temperature map, an ammonia-derived kinetic temperature map, presented for the entirety of the cloud, reveals local temperature enhancements towards the massive protostellar cores. We show that without properly accounting for the line of sight contamination, the dust temperature is 2-3 K larger than the gas temperature measured with NH$_3$. Conclusions. While both the large scale kinematics and temperature structure are consistent with that of starless dark filaments, the kinetic gas temperature profile on smaller scales is suggestive of tracing the heating mechanism coincident with the locations of massive protostellar cores., Comment: 11 pages, 10 figures, accepted to A&A

We present a publicly available, open source version of the time dependent gas-grain chemical code UCLCHEM. UCLCHEM propagates the abundances of chemical species through a large network of chemical reactions in a variety of physical conditions. The model is described in detail along with its applications. As an example of possible uses, UCLCHEM is used to explore the effect of protostellar collapse on commonly observed molecules and to study the behaviour of molecules in C-type shocks. We find the collapse of a simple Bonnor-Ebert sphere successfully reproduces most of the behaviour of CO,CS and NH$_3$ from cores observed by \citet{Tafalla2004} but cannot predict the behaviour of N$_2$H$^+$. In the C-shock application, we find that molecules can be categorized so that they can be useful observational tracers of shocks and their physical properties. Whilst many molecules are enhanced in shocked gas, we identify two groups of molecules in particular. A small number of molecules are enhanced by the sputtering of the ices as the shock propagates and then remain high in abundance throughout the shock. A second, larger set are also enhanced by sputtering but then are destroyed as the gas temperature rises. Through these applications the general applicability of UCLCHEM is demonstrated., Comment: 14 pages, Accepted for publication in AJ

We present the results of chemical modeling of complex organic molecules (COMs) under conditions typical for prestellar cores. We utilize an advanced gas-grain astrochemical model with updated gas-phase chemistry, with a multilayer approach to ice-surface chemistry and an up-to-date treatment of reactive desorption based on recent experiments of Minissale et al. (2016). With the chemical model, radial profiles of molecules including COMs are calculated for the case of the prototypical prestellar core L1544 at the timescales when the modeled depletion factor of CO becomes equal to that observed. We find that COMs can be formed efficiently in L1544 up to the fractional abundances of 10(-10) wrt. total hydrogen nuclei. Abundances of many COMs such as CH3OCH3, HCOOCH3, and others peak at similar radial distances of ~2000-4000 AU. Gas-phase abundances of COMs depend on the efficiency of reactive desorption, which in turn depends on the composition of the outer monolayers of icy mantles. In prestellar cores, the outer monolayers of mantles likely include large fractions of CO and its hydrogenation products, which may increase the efficiency of reactive desorption according to Minissale et al. (2016), and makes the formation of COMs efficient under conditions typical for prestellar cores, although this assumption is yet to be confirmed experimentally. The hydroxyl radical (OH) appears to play an important role in gas-phase chemistry of COMs, which makes it deserving further detailed studies., Comment: 59 pages, 11 figures, 4 tables. Accepted to The Astrophysical Journal

We report on subarcsecond observations of complex organic molecules (COMs) in the high-mass protostar IRAS20126+4104 with the Plateau de Bure Interferometer in its most extended configurations. In addition to the simple molecules SO, HNCO and H2-13CO, we detect emission from CH3CN, CH3OH, HCOOH, HCOOCH3, CH3OCH3, CH3CH2CN, CH3COCH3, NH2CN, and (CH2OH)2. SO and HNCO present a X-shaped morphology consistent with tracing the outflow cavity walls. Most of the COMs have their peak emission at the putative position of the protostar, but also show an extension towards the south(east), coinciding with an H2 knot from the jet at about 800-1000 au from the protostar. This is especially clear in the case of H2-13CO and CH3OCH3. We fitted the spectra at representative positions for the disc and the outflow, and found that the abundances of most COMs are comparable at both positions, suggesting that COMs are enhanced in shocks as a result of the passage of the outflow. By coupling a parametric shock model to a large gas-grain chemical network including COMs, we find that the observed COMs should survive in the gas phase for about 2000 yr, comparable to the shock lifetime estimated from the water masers at the outflow position. Overall, our data indicate that COMs in IRAS20126+4104 may arise not only from the disc, but also from dense and hot regions associated with the outflow., Comment: accepted in MNRAS. Figures of Appendix A upon request to first author

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry at low temperatures has provided new insight into these processes predicting that COM formation depends strongly on parameters such as visual extinction and the level of CO freeze out. We report deep observations of COMs toward two positions in the L1544 pre-stellar core: the dense, highly-extinguished continuum peak with Av>=30 mag within the inner 2700 au; and a low-density shell with average Av~7.5-8 mag located at 4000 au from the core's center and bright in CH3OH. Our observations show that CH3O, CH3OCH3 and CH3CHO are more abundant (by factors ~2-10) toward the low-density shell than toward the continuum peak. Other COMs such as CH3OCHO, c-C3H2O, HCCCHO, CH2CHCN and HCCNC show slight enhancements (by factors <=3) but the associated uncertainties are large. This suggests that COMs are actively formed and already present in the low-density shells of pre-stellar cores. The modelling of the chemistry of O-bearing COMs in L1544 indicates that these species are enhanced in this shell because i) CO starts freezing out onto dust grains driving an active surface chemistry; ii) the visual extinction is sufficiently high to prevent the UV photo-dissociation of COMs by the external interstellar radiation field; and iii) the density is still moderate to prevent severe depletion of COMs onto grains., Comment: 16 pages, 3 figures, 2 tables. Accepted for publication in ApJ Letters

Sulfur-bearing molecules are highly reactive in the gas phase of the ISM. However, the form in which most of the sulfur is locked onto interstellar dust grains is unknown. By taking advantage of the short time-scales of shocks in young molecular outflows, one could track back the main form of sulfur in the ices. In this paper, six transitions of H$_2$S and its isotopologues in the L1157-B1 bowshock have been detected using data from the Herschel-CHESS survey and the IRAM-30m ASAI large program. These detections are used to calculate the properties of H$_2$S gas in L1157-B1 through use of a rotation diagram and to explore the possible carriers of sulfur on the grains. The isotopologue detections allow the first calculation of the H$_2$S deuteration fraction in an outflow from a low mass protostar. The fractional abundance of H$_2$S in the region is found to be 6.0$\times$10$^{-7}$ and the deuteration fraction is 2$\times$10$^{-2}$. In order to investigate the form of sulfur on the grains, a chemical model is run with four different networks, each with different branching ratios for the freeze out of sulfur bearing species into molecules such as OCS and H$_2$S. It is found that the model best fits the data when at least half of each sulfur bearing species hydrogenates when freezing. We therefore conclude that a significant fraction of sulfur in L1157-B1 is likely to be locked in H$_2$S on the grains., Comment: 10 Pages, 7 Figures. Accepted for publication in MNRAS

Investigations into the substructure of massive star forming regions are essential for understanding the observed relationships between core mass distributions and mass distributions in stellar clusters, differentiating between proposed mechanisms of massive star formation. We study the substructure in the two largest fragments (i.e. cores) MM1 and MM2, in the infrared dark cloud complex SDC13. As MM1 appears to be in a later stage of evolution than MM2, comparing their substructure provides an insight in to the early evolution of massive clumps. We report the results of high resolution SMA dust continuum observations towards MM1 and MM2. Combining these data with Herschel observations, we carry out RADMC-3D radiative transfer modelling to characterise the observed substructure. SMA continuum data indicates 4 sub-fragments in the SDC13 region. The nature of the second brightest sub-fragment (B) is uncertain as it does not appear as prominent at the lower MAMBO resolution or at radio wavelengths. Statistical analysis indicates that it is unlikely to be a background source, an AGB star, or the free-free emission of a HII region. It is plausible that B is a runaway object ejected from MM1. MM1, which is actively forming stars, consists of two sub-fragments A and C. This is confirmed by 70 micron Herschel data. While MM1 and MM2 appear quite similar in previous low resolution observations, at high resolution, the sub-fragment at the centre of MM2 (D) is much fainter than sub-fragment at the centre of MM1 (A). RADMC-3D models of MM1 and MM2 are able to reproduce these results, modelling MM2 with a steeper density profile and higher mass than is required for MM1. The relatively steep density profile of MM2 depends on a significant temperature decrease in its centre, justified by the lack of star formation in MM2. A final stellar population for MM1 was extrapolated, indicating a ..., Comment: 13 pages, 4 tables, 9 figures

IRAS 22134+5834 was observed in the centimeter with (E)VLA, 3~mm with CARMA, 2~mm with PdBI, and 1.3~mm with SMA, to study the continuum emission as well as the molecular lines, that trace different physical conditions of the gas to study the influence of massive YSOs on nearby starless cores, and the possible implications in the clustered star formation process. The multi-wavelength centimeter continuum observations revealed two radio sources within the cluster, VLA1 and VLA2. VLA1 is considered to be an optically thin UCHII region with a size of 0.01~pc and sits at the edge of the near-infrared (NIR) cluster. The flux of ionizing photons of the VLA1 corresponds to a B1 ZAMS star. VLA2 is associated with an infrared point source and has a negative spectral index. We resolved six millimeter continuum cores at 2~mm, MM2 is associated with the UCHII region VLA1, and other dense cores are distributed around the UCH{\sc ii} region. Two high-mass starless clumps (HMSC), HMSC-E (east) and HMSC-W (west), are detected around the NIR cluster with N$_2$H$^+$(1--0) and NH$_3$ emission, and show different physical and chemical properties. Two N$_2$D$^+$ cores are detected on an NH$_3$ filament close to the UCHII region, with a projected separation of $\sim$8000~AU at the assumed distance of 2.6~kpc. The kinematic properties of the molecular line emission confirm the expansion of the UCHII region and that the molecular cloud around the near infrared (NIR) cluster is also expanding. Our multi-wavelength study has revealed different generations of star formation in IRAS 22134+5834. The formed intermediate- to massive stars show strong impact on nearby starless clumps. We propose that while the stellar wind from the UCHII region and the NIR cluster drives the large scale bubble, the starless clumps and HMPOs formed at the edge of the cluster., Comment: 22 pages, 17 figures, Accepted by A&A in Oct. 2015

How rapidly collapsing parsec-scale massive molecular clumps feed high-mass stars, and how they fragment to form OB clusters, have been outstanding questions in the field of star-formation. In this work, we report the resolved structures and kinematics of the approximately face-on, rotating massive molecular clump, G33.92+0.11. Our high resolution Atacama Large Millimeter/submillimeter Array (ALMA) images show that the spiral arm-like gas overdensities form in the eccentric gas accretion streams. First, we resolved that the dominant part of the $\sim$0.6 pc scale massive molecular clump (3.0$^{+2.8}_{-1.4}$$\cdot$10$^{3}$ $M_{\odot}$) G33.92+0.11 A is tangled with several 0.5-1 pc size molecular arms spiraling around it, which may be connected further to exterior gas accretion streams. Within G33.92+0.11 A, we resolved the $\sim$0.1 pc width gas mini-arms connecting with the two central massive (100-300 $M_{\odot}$) molecular cores. The kinematics of arms and cores elucidate a coherent accretion flow continuing from large to small scales. We demonstrate that the large molecular arms are indeed the cradles of dense cores, which are likely current or future sites of high-mass star formation. Since these deeply embedded massive molecular clumps preferentially form the highest mass stars in the clusters, we argue that dense cores fed by or formed within molecular arms play a key role in making the upper end of the stellar and core mass functions., Comment: 20 pages, formally published by ApJ

We present the first high-angular resolution study of the MonR2 star-forming complex carried out with the Submillimeter Array at (sub-)millimeter wavelengths. We image the continuum and molecular line emission toward the young stellar objects in MonR2 at 0.85mm and 1.3mm, with resolutions ranging from 0.5" to ~3". While free-free emission dominates the IRS1 and IRS2 continuum, dust thermal emission prevails for IRS3 and IRS5, giving envelope masses of ~0.1-0.3 M_Sun. IRS5 splits into at least two sub-arcsecond scale sources, IRS5B and the more massive IRS5A. Our 12CO(2-1) images reveal 11 previously unknown molecular outflows in the MonR2 clump. Comparing these outflows with known IR sources in the IRS5 and IRS3 subclusters allows for tentative identification of driving stars. Line images of molecular species such as CH3CN or CH3OH show that, besides IRS3 (a well-known hot molecular core), IRS5 is also a chemically active source in the region. The gas excitation temperature derived from CH3CN lines toward IRS5 is 144 \pm 15 K, indicating a deeply embedded protostar at the hot-core evolutionary stage. SED fitting of IRS5 gives a mass of ~7 M_Sun and a luminosity of 300 L_Sun for the central source. The derived physical properties of the CO outflows suggest that they contribute to the turbulent support of the MonR2 complex and to the gas velocity dispersion in the clump's center. The detection of a large number of CO outflows widespread across the region supports the competitive accretion scenario as origin of the MonR2 star cluster., Comment: 41 pages, 9 figures

Sufficiently massive clumps of molecular gas collapse under self-gravity and fragment to spawn a cluster of stars that have a range of masses. We investigate observationally the early stages of formation of a stellar cluster in a massive filamentary infrared dark cloud, G28.34+0.06 P1, in the 1.3mm continuum and spectral line emission using the ALMA. Sensitive continuum data reveal further fragmentation in five dusty cores at a resolution of several 10^3 AU. Spectral line emission from C18O, CH3OH, 13CS, H2CO and N2D+ are detected for the first time toward these dense cores. We found that three cores are chemically more evolved as compared with the other two; interestingly though, all of them are associated with collimated outflows as suggested by evidence from the CO, SiO, CH3OH, H2CO and SO emissions. The parsec-scale kinematics in NH3 exhibit velocity gradients along the filament, consistent with accretion flows toward the clumps and cores. The moderate luminosity and the chemical signatures indicate that the five cores harbor low- to intermediate-mass protostars that likely become massive ones at the end of the accretion. Despite the fact that the mass limit reached by the 1\sigma dust continuum sensitivity is 30 times lower than the thermal Jeans mass, there is a lack of a distributed low-mass protostellar population in the clump. Our observations indicate that in a protocluster, low-mass stars form at a later stage after the birth of more massive protostars., Comment: Accepted for publication in Astrophysical Journal

Glycine (NH2CH2COOH) is the simplest amino acid relevant for life. Its detection in the interstellar medium is key to understand the formation mechanisms of pre-biotic molecules and their subsequent delivery onto planetary systems. Glycine has extensively been searched for toward hot molecular cores, although these studies did not yield any firm detection. In contrast to hot cores, low-mass star forming regions, and in particular their earliest stages represented by cold pre-stellar cores, may be better suited for the detection of glycine as well as more relevant for the study of pre-biotic chemistry in young Solar System analogs. We present 1D spherically symmetric radiative transfer calculations of the glycine emission expected to arise from the low-mass pre-stellar core L1544. Water vapour has recently been reported toward this core, indicating that a small fraction of the grain mantles in L1544 (~0.5%) has been injected into the gas phase. Assuming that glycine is photo-desorbed together with water in L1544, and considering a solid abundance of glycine on ices of ~1E-4 with respect to water, our calculations reveal that several glycine lines between 67 GHz and 80 GHz have peak intensities larger than 10 mK. These results show for the first time that glycine could reach detectable levels in cold objects such as L1544. This opens up the possibility to detect glycine, and other pre-biotic species, at the coldest and earliest stages in the formation of Solar-type systems with near-future instrumentation such as the Band 2 receivers of ALMA., Comment: 5 pages, 2 figures, 1 tables. Accepted for publication in ApJ Letters

Infrared Dark Clouds (IRDCs) are unique laboratories to study the initial conditions of high-mass star and star cluster formation. We present high-sensitivity and high-angular resolution IRAM PdBI observations of N2H+ (1-0) towards IRDC G035.39-00.33. It is found that G035.39-00.33 is a highly complex environment, consisting of several mildly supersonic filaments (sigma_NT/c_s ~1.5), separated in velocity by <1 km s^-1 . Where multiple spectral components are evident, moment analysis overestimates the non-thermal contribution to the line-width by a factor ~2. Large-scale velocity gradients evident in previous single-dish maps may be explained by the presence of substructure now evident in the interferometric maps. Whilst global velocity gradients are small (<0.7 km s^-1 pc^-1), there is evidence for dynamic processes on local scales (~1.5-2.5 km s^-1 pc^-1 ). Systematic trends in velocity gradient are observed towards several continuum peaks. This suggests that the kinematics are influenced by dense (and in some cases, starless) cores. These trends are interpreted as either infalling material, with accretion rates ~(7 \pm 4)x10^-5 M_sun yr^-1 , or expanding shells with momentum ~24 \pm 12 M_sun km s^-1 . These observations highlight the importance of high-sensitivity and high-spectral resolution data in disentangling the complex kinematic and physical structure of massive star forming regions., Comment: 25 pages, 23 figures, accepted for publication in MNRAS

We have observed the IRDC G028.23-00.19 at 3.3 mm using CARMA. In its center, the IRDC hosts one of the most massive (~1520 Msun) quiescent, cold (12 K) clumps known (MM1). The low temperature, high NH_2D abundance, narrow molecular line widths, and absence of embedded IR sources (from 3.6 to 70 mu) indicate that the clump is likely prestellar. Strong SiO emission with broad line widths (6-9 km s^-1) and high abundances (0.8-4 x 10^-9) is detected in the northern and southern regions of the IRDC, unassociated with MM1. We suggest that SiO is released to the gas phase from the dust grains through shocks produced by outflows from undetected intermediate-mass stars or clusters of low-mass stars deeply embedded in the IRDC. A weaker SiO component with narrow line widths (~2 km s^-1) and low abundances (4.3 x 10^-11) is detected in the center-west region, consistent with either a "subcloud-subcloud" collision or an unresolved population of a few low-mass stars. We report widespread CH_3OH emission throughout the whole IRDC and the first detection of extended narrow methanol emission (~2 km s^-1) in a cold, massive prestellar clump (MM1). We suggest that the most likely mechanism releasing methanol into the gas phase in such a cold region is the exothermicity of grain-surface reactions. HN^13C reveals that the IRDC is actually composed of two distinct substructures ("subclouds") separated in velocity space by ~1.4 km s^-1. The narrow SiO component arises where the subclouds overlap. The spatial distribution of C_2H resembles that of NH_2D, which suggests that C_2H also traces cold gas in this IRDC., Comment: Accepted to ApJ. 16 pages

We present 450 {\mu}m polarimetric observations of the M17 molecular cloud obtained with the SHARP polarimeter at the Caltech Submillimeter Observatory. Across the observed region, the magnetic field orientation is consistent with previous submillimeter and far-infrared polarization measurements. Our observations are centered on a region of the molecular cloud that has been compressed by stellar winds from a cluster of OB stars. We have compared these new data with previous 350 {\mu}m polarimetry and find an anti-correlation between the 450 to 350 {\mu}m polarization magnitude ratio and the ratio of 21 cm to 450 {\mu}m intensity. The polarization ratio is lower near the east end of the studied region where the cloud is exposed to stellar winds and radiation. At the west end of the region, the polarization ratio is higher. We interpret the varying polarization spectrum as evidence supporting the radiative alignment torque (RAT) model for grain alignment, implying higher alignment efficiency in the region that is exposed to a higher anisotropic radiation field., Comment: 24 pages, 10 figures

Infrared Dark Clouds (IRDCs) host the initial conditions under which massive stars and stellar clusters form. We have obtained high sensitivity and high spectral resolution observations with the IRAM 30m antenna, which allowed us to perform detailed analysis of the kinematics within one IRDC, G035.39-00.33. We focus on the 1-0 and 3-2 transitions of N2H+, C18O (1-0), and make comparison with SiO (2-1) observations and extinction mapping. Three interacting filaments of gas are found. We report large-scale velocity coherence throughout the cloud, evidenced through small velocity gradients and relatively narrow line widths. This suggests that the merging of these filaments is somewhat "gentle", possibly regulated by magnetic fields. This merging of filaments may be responsible for the weak parsec-scale SiO emission detected by Jimenez-Serra et al. 2010, via grain mantle vaporization. A systematic velocity shift between the N2H+ (1-0) and C18O (1-0) gas throughout the cloud of 0.18 +/- 0.04 kms^{-1} is also found, consistent with a scenario of collisions between filaments which is still ongoing. The N2H+ (1-0) is extended throughout the IRDC and it does not only trace dense cores, as found in nearby low-mass star-forming regions. The average H2 number density across the IRDC is ~ 5 x 10^4 cm^{-3}, at least one order of magnitude larger than in nearby molecular clouds where low-mass stars are forming. A temperature gradient perpendicular to the filament is found. From our study, we conclude that G035.39-00.33 (clearly seen in the extinction map and in N2H+) has been formed via the collision between two relatively quiescent filaments with average densities of ~ 5 x 10^3 cm^{-3}, moving with relative velocities of ~ 5 kms^{-1}. The accumulation of material at the merging points started > 1 Myr ago and it is still ongoing., Comment: 20 pages, 19 figures, accepted for publication in MNRAS

The initial conditions of massive star and star cluster formation are expected to be cold, dense and high column density regions of the interstellar medium, which can reveal themselves via near, mid and even far-infrared absorption as Infrared Dark Clouds (IRDCs). Elucidating the dynamical state of IRDCs thus constrains theoretical models of these complex processes. In particular, it is important to assess whether IRDCs have reached virial equilibrium, where the internal pressure balances that due to the self-gravitating weight of the cloud plus the pressure of the external environmental. We study this question for the filamentary IRDC G035.39-00.33 by deriving mass from combined NIR & MIR extinction maps and velocity dispersion from C18O (1-0) & (2-1) line emission. In contrast to our previous moderately super-virial results based on 13CO emission and MIR-only extinction mapping, with improved mass measurements we now find that the filament is consistent with being in virial equilibrium, at least in its central parsec-wide region where ~1000 M_Sun snakes along several parsecs. This equilibrium state does not require large-scale net support or confinement by magnetic fields., Comment: 4 pages, 2 figures, Accepted to ApJL

Filamentary structures are ubiquitously seen in the interstellar medium. The concentrated molecular mass in the filaments allows fragmentation to occur in a shorter timescale than the timescale of the global collapse. Such hierarchical fragmentation may further assist the dissipation of excessive angular momentum. It is crucial to resolve the morphology and the internal velocity structures of the molecular filaments observationally. We perform 0".5-2".5 angular resolution interferometric observations toward the nearly face-on OB cluster forming region G33.92+0.11. Observations of various spectral lines as well as the millimeter dust continuum emission, consistently trace several $\sim$1 pc scale, clumpy molecular arms. Some of the molecular arms geometrically merge to an inner 3.0$^{{\scriptsize{+2.8}}}_{{-\scriptsize{1.4}}}\cdot10^{3}$\,$M_{\odot}$, 0.6 pc scale central molecular clump, and may directly channel the molecular gas to the warm ($\sim$50 K) molecular gas immediately surrounding the centrally embedded OB stars. The NH$_{3}$ spectra suggest a medium turbulence line width of FWHM$\lesssim$2\,km\,s$^{-1}$ in the central molecular clump, implying a $\gtrsim$10 times larger molecular mass than the virial mass. Feedbacks from shocks and the centrally embedded OB stars and localized (proto)stellar clusters, likely play a key role in the heating of molecular gas and could lead to the observed chemical stratification. Although (proto)stellar feedbacks are already present, G33.92+0.11 chemically appears to be at an early evolutionary stage given by the low abundance limit of SO$_{2}$ observed in this region., Comment: 37 pages, 23 figures

Infrared Dark Clouds (IRDCs) are cold, high mass surface density and high density structures, likely to be representative of the initial conditions for massive star and star cluster formation. CO emission from IRDCs has the potential to be useful for tracing their dynamics, but may be affected by depleted gas phase abundances due to freeze-out onto dust grains. Here we analyze C18O J=1-0 and J=2-1 emission line data, taken with the IRAM 30m telescope, of the highly filamentary IRDC G035.39.-0033. We derive the excitation temperature as a function of position and velocity, with typical values of ~7K, and thus derive total mass surface densities, Sigma_C18O, assuming standard gas phase abundances and accounting for optical depth in the line, which can reach values of ~1. The mass surface densities reach values of ~0.07 g/cm^2. We compare these results to the mass surface densities derived from mid-infrared (MIR) extinction mapping, Sigma_SMF, by Butler & Tan, which are expected to be insensitive to the dust temperatures in the cloud. With a significance of >10sigma, we find Sigma_C18O/Sigma_SMF decreases by about a factor of 5 as Sigma increases from ~0.02 to ~0.2 g/cm^2, which we interpret as evidence for CO depletion. Several hundred solar masses are being affected, making this one of the most massive clouds in which CO depletion has been observed directly. We present a map of the depletion factor in the filament and discuss implications for the formation of the IRDC., Comment: 9 pages, accepted to ApJ, Mac users: Figure 1 is best viewed with Adobe acroread rather than preview

We present the first detection of the H40a, H34a and H31a radio recombination lines (RRLs) at millimeter wavelengths toward the high-velocity, ionized jet in the Cepheus A HW2 star forming region. From our single-dish and interferometric observations, we find that the measured RRLs show extremely broad asymmetric line profiles with zero-intensity linewidths of ~1100 kms-1. From the linewidths, we estimate a terminal velocity for the ionized gas in the jet of >500 kms-1, consistent with that obtained from the proper motions of the HW2 radio jet. The total integrated line-to-continuum flux ratios of the H40a, H34a and H31a lines are 43, 229 and 280 kms-1, clearly deviating from LTE predictions. These ratios are very similar to those observed for the RRL maser toward MWC349A, suggesting that the intensities of the RRLs toward HW2 are affected by maser emission. Our radiative transfer modeling of the RRLs shows that their asymmetric profiles could be explained by maser emission arising from a bi-conical radio jet with a semi-aperture angle of 18 deg, electron density distribution varying as r^(-2.11) and turbulent and expanding wind velocities of 60 and 500 kms-1., Comment: 6 pages, 2 figures, 3 tables, accepted for publication in ApJL

Shock modelling predicts an electron density enhancement within the magnetic precursor of C-shocks. Previous observations of SiO, H13CO+, HN13C and H13CN toward the young L1448-mm outflow showed an over-excitation of the ion fluid that was attributed to an electron density enhancement in the precursor. We re-visit this interpretation and test if it still holds when we consider different source morphologies and kinetic temperatures for the observed molecules, and also give some insight on the spatial extent of the electron density enhancement around L1448-mm. We estimate the opacities of H13CO+ and HN13C by observing the J=3\to2 lines of rarer isotopologues to confirm that the emission is optically thin. To model the excitation of the molecules, we use the large velocity gradient (LVG) approximation with updated collisional coefficients to i) re- analyse the observations toward the positions where the over-excitation of H13CO+ has previously been observed [i.e. toward L1448- mm at offsets (0,0) and (0,-10)], and ii) to investigate if the electron density enhancement is still required for the cases of extended and compact emission, and for kinetic temperatures of up to 400 K. We also report several lines of SiO, HN13C and H13CO+ toward new positions around this outflow, to investigate the spatial extent of the over-excitation of the ions in L1448-mm. From the isotopologue observations, we find that the emission of H13CO+ and HN13C from the precursor is optically thin if this emission is extended. Using the new collisional coefficients, an electron density enhancement is still needed to explain the excitation of H13CO+ for extended emission and for gas temperatures of\le 400 K toward L1448-mm (0,-10), and possibly also toward L1448-mm (0,0). For compact emission the data cannot be fitted. We do not find any evidence for the over-excitation of the ion fluid toward the newly observed positions around L1448-mm. The observed line emission of SiO, H13CO+ and HN13C toward L1448-mm (0,0) and (0,-10) is consistent with an electron density enhancement in the precursor component, if this emission is spatially extended. This is also true for the case of high gas temperatures (\le400 K) toward the (0,-10) offset. The electron density enhancement seems to be restricted to the southern, redshifted lobe of the L1448-mm outflow. Interferometric images of the line emission of these molecules are needed to confirm the spatial extent of the over-excitation of the ions and thus, of the electron density enhancement in the magnetic precursor of L1448-mm., Comment: Accepted for publication in A&A; 9 pages, 3 figures