51. Investigations on the polyimides derived from unfunctionalized symmetric cyclopentyl-containing alicyclic cardo-type dianhydride
- Author
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Wan Wenjun, Feng Liu, Jian-Cheng Lai, Li Fu, Xiao-Zeng You, Haixia Qi, and Xiaosong Li
- Subjects
chemistry.chemical_classification ,Materials science ,Polymers and Plastics ,General Chemistry ,Polymer ,Dielectric ,Cyclopentanone ,Surface energy ,Surfaces, Coatings and Films ,chemistry.chemical_compound ,Alicyclic compound ,chemistry ,Polymer chemistry ,Materials Chemistry ,Physical chemistry ,Dielectric loss ,Solubility ,Glass transition - Abstract
This study presents an investigation on polyimides derived from a unfunctionalized symmetric cyclopentyl-containing alicyclic cardo-type dianhydride with ester linkage 1,1-bis(4-(3,4-dicarboxylbenzoyloxy)phenyl)cyclopentylene dianhydride (BDPCP) that was readily accessed starting from cyclopentanone through two steps in high yield. Two series of polyimides, Cardo-type series (CPI-x) and analogous aromatic series (ArPI-x) were prepared from condensation of BDPCP and aromatic 3,3′,4,4′-Oxydiphthalic dianhydride with four aromatic diamines, respectively. Comparative studies revealed that CPI polymers show more favorable properties including better solubility in organic solvents, higher transparency with lower cut-off wavelength (λ0) ranging in 395–375 nm than 425–405 nm, lower water absorption ranging in 0.66–1.14% and surface energy 23.71–32.77 mN/m than 1.01–1.28% and 29.52–41.99 mN/m of ArPI analogs. Meanwhile, CPI series exhibit considerable mechanical properties with tensile strengths ranging in 87.6–102.9 MPa, elongations at break 6.6–8.9%. Owing to the moderate strain in cyclopentyl ring, CPI series retain good thermal properties with the glass transition temperature (Tg) in the range of 217–271°C. Dynamic dielectric measurement revealed that Cardo-type dianhydride BDPCP endows CPI-4 film with lower dielectric constant (e′) 3.34 at 1 MHz and 25°C and dielectric loss (e′′) 0.0064 at 1 kHz and 25°C than 3.49 and 0.013 for ArPI-4 film. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42670.
- Published
- 2015
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