208 results on '"Hu, Qiyang"'
Search Results
52. A Renewable Sedimentary Slurry Battery: Preliminary Study in Zinc Electrodes
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Guochun Yan, Hu Qiyang, Peng Wenjie, Xinhai Li, Liu Yue, Huajun Guo, Jing Zhong, Zhixing Wang, and Jiexi Wang
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0301 basic medicine ,Battery (electricity) ,Materials science ,chemistry.chemical_element ,02 engineering and technology ,Zinc ,Energy storage ,Article ,Energy Materials ,03 medical and health sciences ,Process engineering ,lcsh:Science ,Energy Systems ,Electrical conductor ,Multidisciplinary ,business.industry ,Energy Storage ,021001 nanoscience & nanotechnology ,Renewable energy ,030104 developmental biology ,chemistry ,Electrode ,Slurry ,Sedimentary rock ,lcsh:Q ,Materials Characterization ,0210 nano-technology ,business - Abstract
Summary Low-cost, scalable energy storage is the key to continuing growth of renewable energy technologies. Here a battery with sedimentary slurry electrode (SSE) is proposed. Through the conversion of discrete particles between sedimentary and suspending types, it not only inherits the advantages of semi-solid flow cell but also exhibits high energy density and stable conductive network. Given an example, the zinc SSE (ZSSE) delivers a large discharge capacity of 479.2 mAh g−1 at 10 mA cm−2. More importantly, by renewal of the slurry per 20 cycles, it can run for 112 and 75 cycles before falling below 80% of designed capacity under 10 mA cm−2 (20% DODZn) and 25 mA cm−2 (25% DODZn), respectively. The lost capacity after cycles is able to recover after slurry renewal and the end-of-life SSE can be easily reused by re-formation. The concept of SSE brands a new way for electrochemical energy storage., Graphical Abstract, Highlights • A renewable semi-solid sedimentary slurry battery is proposed • Lost capacity after cycles is able to recover after slurry renewal • End-of-life SSE can be easily reused by re-formation, Energy Materials; Energy Storage; Energy Systems; Materials Characterization
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- 2020
53. Performance and capacity fading reason of LiMn2O4/graphite batteries after storing at high temperature
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Liu, Yunjian, Li, Xinhai, Guo, Huajun, Wang, Zhixing, Hu, Qiyang, Peng, Wenjie, and Yang, Yong
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- 2009
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54. Unidirectional current-driven toron motion in a cylindrical nanowire
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Hu, Qiyang, primary, Lyu, Boyao, additional, Tang, Jin, additional, Kong, Lingyao, additional, Du, Haifeng, additional, and Wang, Weiwei, additional
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- 2021
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55. Learning to Take Directions One Step at a Time
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Hu, Qiyang, primary, Walchli, Adrian, additional, Portenier, Tiziano, additional, Zwicker, Matthias, additional, and Favaro, Paolo, additional
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- 2021
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56. Effects of Nb doping on the performance of 0.5Li2MnO3·0.5LiNi1/3Co1/3Mn1/3O2 cathode material for lithium-ion batteries
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Huajun Guo, Zhixing Wang, Xia Hu, Xinhai Li, Peng Wenjie, and Hu Qiyang
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Dopant ,Scanning electron microscope ,General Chemical Engineering ,Doping ,Analytical chemistry ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Analytical Chemistry ,Ion ,chemistry ,Transmission electron microscopy ,Lithium ,Cyclic voltammetry ,0210 nano-technology - Abstract
The Nb-doped Li[Li0.2Mn0.54-x/3Ni0.13-x/3Co0.13-x/3Nbx]O2 (x = 0, 0.01, 0.02, 0.03) materials are synthesized and characterized by X-ray diffractometry (XRD), transmission electron microscope (TEM), scanning electron microscopy (SEM), charge–discharge measurements, AC impedance spectroscopy as well as cyclic voltammetry. XRD results indicate that Nb-doped Li1.2Ni0.13Co0.13Mn0.54O2 materials exhibit similar XRD patterns to the pristine sample. The results of EDS mapping confirm the homogenous distribution of Nb element in the materials. The Nb substituted for transition metal ions with x = 0.02 is found to be the most effective in improving the cycling properties and in lowering the voltage fade. Particularly, it exhibits remarkably improved cycling performance with the capacity retention ratio of 83% compared with 54% for pristine one after 100 cycles at 1C. Besides, it shows much lower discharge midpoint voltage decay (0.1913 V) than that of pristine sample (0.6951 V) after 100 cycles. The improved electrochemical performance can be attributed to the better structure stability and decreased charge transfer resistance caused by dopant of Nb. These results reveal that Nb-doping can be a promising method for improving the performance of Li-rich material.
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- 2018
57. Improving the electrochemical performance of Li-rich Li1.2Ni0.13Co0.13Mn0.54O2 cathode material by LiF coating
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Huajun Guo, Xinhai Li, Hu Qiyang, Zhuolin Du, Peng Wenjie, and Zhixing Wang
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Battery (electricity) ,Materials science ,General Chemical Engineering ,General Engineering ,General Physics and Astronomy ,02 engineering and technology ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Energy storage ,Lithium-ion battery ,Cathode ,0104 chemical sciences ,law.invention ,Coating ,law ,engineering ,Surface modification ,General Materials Science ,Composite material ,0210 nano-technology ,Layer (electronics) ,Current density - Abstract
To suppress the capacity fade of Li-rich Li1.2Ni0.13Co0.13Mn0.54O2 material as cathode materials for lithium-ion battery, we introduce a LiF coating layer on the surface to improve the cycling performance of Li1.2Ni0.13Co0.13Mn0.54O2 material. The modified sample shows a capacity of 163.2 mAh g−1 with a capacity retention of 95% after 100 cycles at a current density of 250 mA g−1, while the pristine sample only delivers a capacity of 129.9 mAh g−1 with a capacity retention of 82%. Compared with the pristine material, the LiF-modified sample exhibits an obvious enhancement in the electrochemical performance, which will be very beneficial for this material to be commercialized on the new energy vehicles and other related areas.
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- 2018
58. Electrospinning-enabled SiO @TiO2/C fibers as anode materials for lithium-ion batteries
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Hu Qiyang, Xupeng Niu, Zhixing Wang, Huajun Guo, Fujin Tan, Xinhai Li, Guochun Yan, Jiexi Wang, and Peng Wenjie
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Materials science ,Mechanical Engineering ,Composite number ,Metals and Alloys ,chemistry.chemical_element ,engineering.material ,Electrospinning ,Buffer (optical fiber) ,Anode ,chemistry ,Chemical engineering ,Coating ,Mechanics of Materials ,Materials Chemistry ,engineering ,Lithium ,Current density ,Layer (electronics) - Abstract
In this paper, SiOx@TiO2/C fibers with TiO2/C composite layer were successfully prepared by one-step electrospinning. Carbon coating can enhance conductivity and act as bulk expansion buffer matrix, while TiO2 coating is beneficial to improving the mechanical stability of composite. Thus, a highly effective and stable conductive network is formed. Benefited from the protection of TiO2/C coating layer, SiOx@TiO2/C fibers demonstrates enhanced electrochemical performance. It exhibites an initial charge capacity of 1125.3 mAh g−1 at 0.1 A g−1, and a stable charge capacity of 855.0 mAh g−1 can be retained with a retention of 89.5% after 100 cycles at 0.4 A g−1, which is better than that of M-SiOx (32.3%) and SiOx@C (52.5%) materials. Moreover, SiOx@TiO2/C fibers show a high charge capacity of 640.4 mAh g−1 after 200 cycles cycled at a high current density of 1 A g−1.
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- 2021
59. New insight into the modification of Li-rich cathode material by stannum treatment
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Hu Qiyang, Xianwen Wu, Huajun Guo, Peng Wenjie, Guochun Yan, and Hao Chen
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Materials science ,Process Chemistry and Technology ,Doping ,Analytical chemistry ,02 engineering and technology ,Conductivity ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Ion ,Cathode material ,Lattice (order) ,Materials Chemistry ,Ceramics and Composites ,0210 nano-technology - Abstract
In this work, Sn is used to dope the Li-rich cathode material to improve the electrochemical performance of Li ion battery. After Sn treatment, the lattice parameters a , c and lattice volume V become larger. Compared with the pristine sample, the Sn-contained samples show longer plateaux at about 4.5 V in the first charging process, which means that Sn can activate the Li 2 MnO 3 component. Meanwhile, with appropriate content of Sn doping, the sample exhibits enhanced rate capability and cycling stability. Especially, the sample S10 shows the best electrochemical performance, with a capacity retention of 88.66% after 100 cycles at 1 C (1 C=250 mA g −1 ). The mechanisms of Sn doping have also been investigated. The increased activation of Li 2 MnO 3 is due to the improved conductivity of Li 2 MnO 3 phase by Sn doping, and the enhanced electrochemical performance is mainly ascribed to the increased ability of Li ion diffusing into bulk phase and the improved structure stability during the prolonged charge-discharge cycles. It is suggested that Sn doping is an effective way to improve the electrochemical performance of Li-rich cathode material.
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- 2017
60. Current-driven transformations of a skyrmion tube and a bobber in stepped nanostructures of chiral magnets
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Zhu, Jin, primary, Wu, YaoDong, additional, Hu, QiYang, additional, Kong, LingYao, additional, Tang, Jin, additional, Tian, MingLiang, additional, and Du, HaiFeng, additional
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- 2020
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61. Research Progress of Single‐Crystal Nickel‐Rich Cathode Materials for Lithium Ion Batteries
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Sheng Yang, Huajun Guo, Peng Wenjie, Bianzheng You, Guochun Yan, Hu Qiyang, Yijiao Chang, Chengwei Deng, Zhixing Wang, Jiexi Wang, Xinhai Li, and Fang Shen
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Materials science ,Micro cracks ,chemistry.chemical_element ,General Chemistry ,Cathode ,Ion ,law.invention ,Nickel ,chemistry ,Chemical engineering ,law ,General Materials Science ,Lithium ,Single crystal - Abstract
Single-crystal nickel-rich cathode materials (SC-NRCMs) are the most promising candidates for next-generation power batteries which enable longer driving range and reliable safety. In this review, the outstanding advantages of SC-NRCMs are discussed systematically in aspects of structural and thermal stabilities. Particularly, the intergranular-crack-free morphology exhibits superior cycling performance and negligible parasitic reactions even under severe conditions. Besides, various synthetic methods are summarized and the relation between precursor, sintering process, and final single-crystal products are revealed, providing a full view of synthetic methods. Then, challenges of SC-NRCMs in fields of kinetics of lithium diffusion and the one particularly occurred at high voltage (intragranular cracks and aggravated parasitic reactions) are discussed. The corresponding mechanism and modifications are also referred. Through this review, it is aimed to highlight the magical morphology of SC-NRCMs for application perspective and provide a reference for following researchers.
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- 2021
62. Numerical Analysis of Effect of Boundary Layer Characteristics on the Flow Field in S-shaped Inlet
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Ren Jia, Wu Naiming, Li Mingzhen, Hu Qiyang, and Liu He
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S-shaped inlet ,boundary layer ,separation ,numerical simulation ,Engineering (General). Civil engineering (General) ,TA1-2040 - Abstract
In order to explore the effect of boundary layer thickness and pressure gradient on the performance of the flow field in the inlet, we design a high offset rate S-shaped inlet based on a certain unmanned aerial vehicle (UAV), and its author has analyzed the effect of boundary layer characteristics on the inlet with numerical simulation method. The suction of boundary layer which leads to separation zone not only becomes longer in the inlet, but also moves to the center plane of symmetry, the separation point of boundary layer appears in advance as pressure gradient increases. Considering the influence of the boundary layer, various performance parameters all exceeds that of the uniform entrance inlet conditions, especially the circumferential total pressure distortion of outlet increased by 58.2% at most, obviously can’t meet the engine to work properly, so we must consider and pay attention to the effect of the boundary layer characteristics on the flow field in the S-shaped inlet.
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- 2015
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63. Treatment of aluminum and fluoride during hydrochloric acid leaching of lepidolite
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Liu, Jinlian, primary, Yin, Zhoulan, additional, Liu, Wei, additional, Li, Xinhai, additional, and Hu, Qiyang, additional
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- 2020
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64. Co 3 O 4 /Co nanoparticles enclosed graphitic carbon as anode material for high performance Li-ion batteries
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Zhixing Wang, Jiexi Wang, Zhewei Yang, Zhiliang Yan, Hangkong Li, Guochun Yan, Hu Qiyang, Xinhai Li, and Kaimin Shih
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Thermal oxidation ,Materials science ,Carbonization ,General Chemical Engineering ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Industrial and Manufacturing Engineering ,Lithium-ion battery ,0104 chemical sciences ,chemistry ,Amorphous carbon ,Chemical engineering ,Environmental Chemistry ,Pyrolytic carbon ,Graphite ,0210 nano-technology ,Cobalt ,Carbon - Abstract
The composite of Co 3 O 4 , Co and graphitized carbon is synthesized by carbonization and cobalt-catalyzed-graphitization of carboxymethyl chitosan, followed by low-temperature thermal oxidation. At the high temperature, the Co(+2) is reduced to metallic Co and the produced Co acts as a catalyst for the graphitization of the pyrolytic carbon. The low-temperature oxidation is conducted to selectively oxidize Co to Co 3 O 4 while the carbon remains unreacted. The structure analysis indicates that three crystal phases (graphite, metallic Co, Co 3 O 4 ) accompanied with amorphous carbon are co-existed in the composite. Morphological results demonstrate that a lot of graphite grains around the Co element are distributed in the carbon. The electrochemical testing results indicate that the composite shows good electrochemical performance. It delivers a reversible capacity of 843 mAh g −1 at low current density, and remains 88.9% after 60 cycles at 200 mA g −1 . Even performed at 1 A g −1 , it also exhibits 493 mAh g −1 . The performance improvement is mainly due to the high capacity of Co 3 O 4 , high conductivity of graphitic carbon and metallic cobalt, the porous structure offering enough ion transport pathways and relieving the strain during cycling.
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- 2017
65. Fluorinated solvents for high-voltage electrolyte in lithium-ion battery
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Hu Qiyang, Zhixing Wang, Xinhai Li, Peng Wenjie, Jiexi Wang, Huajun Guo, and Guochun Yan
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Chemistry ,Inorganic chemistry ,02 engineering and technology ,Electrolyte ,Conductivity ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Cathode ,Lithium-ion battery ,0104 chemical sciences ,law.invention ,Anode ,chemistry.chemical_compound ,X-ray photoelectron spectroscopy ,law ,Electrochemistry ,Carbonate ,General Materials Science ,Electrical and Electronic Engineering ,0210 nano-technology ,Ethylene carbonate - Abstract
The major obstacle for the application of high-voltage cathode materials is the anodic instability of the electrolyte. On the guidance of density functional theory calculation, we develop a new high-voltage electrolyte comprising 1 mol L−1 LiPF6 dissolved in fluoroethylene carbonate (FEC) and ethyl difluoroacetate (DFEAc) (FEC/DFEAc = 3:7 in wt.% ratio). It shows a high conductivity (9.48 mS cm−1) and high anodic stability compared with the conventional electrolyte of 1 mol L−1 LiPF6 dissolved in ethylene carbonate (EC) and ethyl-methyl carbonate (EMC) (EC/EMC = 3:7 in wt.% ratio). In addition, Li/LiNi0.5Co0.2Mn0.3O2 half-cells with the new electrolyte display an excellent cycling ability with capacity retention of 89.23% after 100 cycles at 4.6 V (vs. Li/Li+). Although the electrolyte still will be oxidized at the cathode surface, the Li2CO3 and carbon-fluoride species originated from DFEAc and FEC are beneficial to building a stable cathode/electrolyte interface as revealed by the TEM and XPS results.
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- 2017
66. Research on the Optimization of Public Spaces in Urban Villages Based on Space Syntax: A Case Study of Luochengtou Village in Handan City.
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CHEN Xiaowei, HU Qiyang, and CAI Qiang
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PUBLIC spaces , *URBAN renewal , *VILLAGES - Abstract
This paper based on the theory of space syntax took Luochengtou Village in Handan City, Hebei Province for example, tried to figure out a proper way for the renewal of urban villages, and change the current dilemma of "one-size-fits-all" and "removing all" in most cases, and put forward that local conditions and regional characteristics must be considered to propose the renewal strategies more suitable for the targeted objects. Based on the space syntax Depthmap software and field investigation, the paper analyzed the accessibility, intelligibility and throughput of public spaces in Luochengtou Village, and put forward 3 optimization strategies in view of the problems such as insufficient public spaces, poor accessibility and intelligibility of roads, and poor activity of spaces, specifically, increasing public activity spaces, sorting out public space network, and creating active space nodes, so as to optimize public environment of the village, enhance villagers' sense of belonging, sense of safety and sense of identity. [ABSTRACT FROM AUTHOR]
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- 2021
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67. Learning Controllable Representations for Image Synthesis
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Hu, Qiyang
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510 Mathematics ,000 Computer science, knowledge & systems - Abstract
In this thesis, our focus is learning a controllable representation and applying the learned controllable feature representation on images synthesis, video generation, and even 3D reconstruction. We propose different methods to disentangle the feature representation in neural network and analyze the challenges in disentanglement such as reference ambiguity and shortcut problem when using the weak label. We use the disentangled feature representation to transfer attributes between images such as exchanging hairstyle between two face images. Furthermore, we study the problem of how another type of feature, sketch, works in a neural network. The sketch can provide shape and contour of an object such as the silhouette of the side-view face. We leverage the silhouette constraint to improve the 3D face reconstruction from 2D images. The sketch can also provide the moving directions of one object, thus we investigate how one can manipulate the object to follow the trajectory provided by a user sketch. We propose a method to automatically generate video clips from a single image input using the sketch as motion and trajectory guidance to animate the object in that image. We demonstrate the efficiency of our approaches on several synthetic and real datasets.
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- 2019
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68. Synthesis of nanoparticles-assembled Co 3 O 4 microspheres as anodes for Li-ion batteries by spray pyrolysis of CoCl 2 solution
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Huajun Guo, Tao Li, Zhixing Wang, Xinhai Li, Peng Wenjie, and Hu Qiyang
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Materials science ,General Chemical Engineering ,Inorganic chemistry ,Nanoparticle ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Anode ,Ion ,chemistry ,Chlorine ,Particle size ,0210 nano-technology ,Current density ,Faraday efficiency - Abstract
Nanoparticles-assembled Co 3 O 4 microspheres with different primary particle size are synthesized via a facile one-step ultrasonic spray pyrolysis process, using CoCl 2 ·6H 2 O as precursor. The as-synthesized Co 3 O 4 powders are directly used as anode material for Li-ion batteries without further calcinations. The primary particle size is tuned by controlling the spray pyrolysis temperature and its effects on the electrochemical performance of the prepared samples are systemically investigated. The results reveal that primary particles size exerts significant effect on the initial coulombic efficiency, specific capacity and rate performance. In addition, we find that the temperature of powder collector strongly influences the chlorine content in the products, which is resulted from the chloridization of Co 3 O 4 by gaseous HCl from the off-gas. A simple and effective strategy is proposed to prevent the chloridization reaction. The sample with the smallest primary particle size and low Cl content shows the highest initial coulombic efficiency of 73% and a high reversible capacity of 1340 mA h g −1 after 50 cycles at a current density of 200 mA g −1 .
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- 2016
69. Robust synthesis of hierarchical mesoporous hybrid NiO–MnCo2O4 microspheres and their application in Lithium-ion batteries
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Xinhai Li, Zhixing Wang, Hu Qiyang, Peng Wenjie, Huajun Guo, and Tao Li
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Materials science ,General Chemical Engineering ,Non-blocking I/O ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Anode ,Metal ,Mesoporous organosilica ,chemistry ,Chemical engineering ,visual_art ,Specific surface area ,visual_art.visual_art_medium ,Lithium ,0210 nano-technology ,Mesoporous material - Abstract
Hierarchical mesoporous hybrid NiO–MnCo2O4 microspheres are synthesized by a robust one-pot spray pyrolysis process. The mesoporous hybrid NiO–MnCo2O4 microspheres are comprised of homogeneously dispersed nanoscaled NiO and MnCo2O4 subunits. Specific surface area of the mesoporous hybrid NiO–MnCo2O4 microspheres is determined to be 10.2 m2 g−1 with dominant pore size of 25.8 nm. The as-obtained material is evaluated as anode material for LIBs. The as-prepared hybrid NiO–MnCo2O4 sample demonstrate better electrochemical performances, including higher reversible capacity and superior rate capability, compared with the single-phase NiO and MnCo2O4 samples. These superior electrochemical performances should be mainly attributed to its porous microstructure characteristics and the synergistic effects between the well-dispersed NiO and MnCo2O4 nanophases. The strategy is simple and flexible, so it could be readily generalized to construct other hybrid metal oxides materials.
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- 2016
70. Synthesis and electrochemical study of Zr-doped Li[Li0.2Mn0.54Ni0.13Co0.13]O2 as cathode material for Li-ion battery
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Xinhai Li, Zhixing Wang, Huajun Guo, Zhenjiang He, Hao Chen, Hu Qiyang, and Zimo Huang
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Materials science ,Scanning electron microscope ,Process Chemistry and Technology ,Doping ,Analytical chemistry ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,Lithium-ion battery ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Ion ,Structural stability ,Materials Chemistry ,Ceramics and Composites ,Cyclic voltammetry ,0210 nano-technology ,Current density - Abstract
Li[Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 ]O 2 materials doped with different Zr contents are studied using X-ray diffractometry (XRD), energy dispersive X-ray analysis (EDX), scanning electron microscopy (SEM), charge–discharge measurements, AC impedance spectroscopy as well as cyclic voltammetry. These results demonstrate that the element Zr is distributed uniformly in these materials. With the increase of Zr content, the lattice parameters a , c and lattice volume V become larger. The discharge cycling curves of cells show that Zr doping enhances cycle life compared with the undoped one. The sample with x =0.01 shows the highest capacity and best cycling performance, especially at high current density. The Li[Li 0.2 Mn 0.54− x /3 Ni 0.13− x /3 Co 0.13− x /3 Zr x ]O 2 ( x =0.01) delivers a capacity of 133.6 mA h g −1 (after 100 cycles) at the current density of 250 mA g −1 , corresponding to the capacity retention of 83.8%. The favorable performance of the doped samples could be attributed to its enhanced structural stability and Li + mobility.
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- 2016
71. Synthesis and performance of xLiVPO4F–yLi3V2(PO4)3 composites as cathode materials for lithium ion batteries
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Hu Qiyang, Zhixing Wang, Zhaomeng Liu, Xinhai Li, Jiexi Wang, Huajun Guo, and Yulei Fan
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Materials science ,Process Chemistry and Technology ,chemistry.chemical_element ,Triclinic crystal system ,Electrochemistry ,Cathode ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Ion ,law.invention ,chemistry ,law ,Materials Chemistry ,Ceramics and Composites ,Lithium ,Calcination ,Particle size ,Composite material ,Monoclinic crystal system - Abstract
The x LiVPO 4 F– y Li 3 V 2 (PO 4 ) 3 composite cathode materials have been synthesized through a soft chemical route with mechanical activation assistance followed by low-temperature calcination. Structural analysis indicates that two phases, i.e. monoclinic Li 3 V 2 (PO 4 ) 3 and triclinic LiVPO 4 F coexist in the composites. With the addition of LVP, the average particle size becomes smaller. The prepared composite materials show good electrochemical performance, and especially a good cyclic performance, the most suitable x / y ratio being 1:5 where the sample can deliver a reversible capacity of 139 mA h g −1 .
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- 2015
72. Lithium difluoro(oxalato)borate as an additive to suppress the aluminum corrosion in lithium bis(fluorosulfony)imide-based nonaqueous carbonate electrolyte
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Huajun Guo, Xinhai Li, Hu Qiyang, Peng Wenjie, Guochun Yan, and Zhixing Wang
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Materials science ,Inorganic chemistry ,chemistry.chemical_element ,02 engineering and technology ,Electrolyte ,Lithium hexafluorophosphate ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Electrochemistry ,01 natural sciences ,Lithium-ion battery ,0104 chemical sciences ,Corrosion ,chemistry.chemical_compound ,chemistry ,General Materials Science ,Graphite ,Electrical and Electronic Engineering ,0210 nano-technology ,Imide ,Boron - Abstract
Lithium bis(fluorosulfony)imide (LiFSI) is a promising alternative lithium salt to replace lithium hexafluorophosphate (LiPF6) due to its high conductivity and excellent compatibility with electrode material. On the other hand, the aluminum corrosion caused by LiFSI hinders its application in lithium ion battery. To solve this problem, lithium difluoro(oxalato)borate (LiDFOB) is added to suppress the aluminum corrosion in LiFSI-based nonaqueous carbonate electrolyte. The electrochemical tests in three-electrode cells and graphite/LiCoO2 full cells confirm that the addition of LiDFOB is beneficial to suppress the aluminum corrosion. In addition, the mechanism is proposed that the oxidation products of LiDFOB form a passivating film at the aluminum surface to suppress the corrosion based on the experimental results from SEM and XPS tests.
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- 2015
73. Aluminum electrolysis derivative spent cathodic carbon for dendrite-free Li metal anode
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Zezhou Lin, Liu Tiancheng, Man Zhang, Dong Wang, Lei Tan, Hu Qiyang, Jiexi Wang, Xi Zhang, Yingpeng Wu, and Haitao Huang
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Materials science ,Renewable Energy, Sustainability and the Environment ,Materials Science (miscellaneous) ,Nucleation ,Energy Engineering and Power Technology ,Lithium fluoride ,02 engineering and technology ,Electrolyte ,Current collector ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Energy storage ,0104 chemical sciences ,Cathodic protection ,Anode ,chemistry.chemical_compound ,Fuel Technology ,Nuclear Energy and Engineering ,chemistry ,Chemical engineering ,0210 nano-technology ,Faraday efficiency - Abstract
Li metal anode is one of the most promising anodes for next-generation high-energy-density batteries. However, some lethal challenges, such as Li dendrite, inferior coulombic efficiency, and infinite volume change during repeated Li plating/stripping restrict its practical application. Although carbon-based materials are ideal hosts for Li deposition, unsatisfied lithiophilic property and vulnerable solid electrolyte interphase (SEI) film still remain unsolved. Herein, we report the fluorinated mesoporous carbon (FMC) nanosheets derived from spent cathodic carbon of aluminum electrolysis as a versatile dendrite-free current collector. Two types of C–F bonds are discovered in FMC. One is C(sp2)-F, which serves as lithiophilic site for Li nucleation with reduced barrier. The other is C(sp3)-F, which breaks to produce extra LiF during Li deposition, facilitating the formation of stable LiF-rich SEI film. The synergistically designed Li@FMC|LiFePO4 full cells demonstrate improved cycling performance with high coulombic efficiency. This work provides possibility for direct utilization of waste electro-carbon in energy storage application.
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- 2020
74. Revealing the fake initial coulombic efficiency of spinel/layered Li-rich cathode materials
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Zhixing Wang, Jiexi Wang, Peng Wenjie, Xinhai Li, Huajun Guo, Hu Qiyang, Guochun Yan, and Hualong Wu
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Materials science ,General Chemical Engineering ,Spinel ,chemistry.chemical_element ,02 engineering and technology ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,Cathode ,0104 chemical sciences ,Anode ,law.invention ,chemistry ,Chemical engineering ,law ,Phase (matter) ,engineering ,Lithium ,Graphite ,0210 nano-technology ,Faraday efficiency - Abstract
Synthesizing spinel/layer Li-rich materials (SLLRs) is a promising way to improve the electrochemical performance of Li-rich material. In this work, the influence of introducing spinel phase into layered one on the coulombic efficiency is studied by electrochemical method. During CV testing, the composite exhibits no oxidation peak around 2.5–3.0 V when it starts with positive scanning, while demonstrates a reduction peak at ∼2.57 V as it begins with negative scanning. This means the spinel phase formed during the synthetic process is lithium-deficient, consuming lithium from lithium metal anode during discharge in Li-half cell. Charge-discharge results show that this spinel phase contributes to extra capacities when cells are discharged below 3.0 V, leading to a higher initial coulombic efficiency (ICE) of SLLRs in half cells. However, when tested in full cell using graphite as anode, ICE of SLLRs equals to that of Li-rich material while the capacity is lower. This is because that the graphite anode in full cell is unable to provide extra lithium ions and to compensate lithium deficiency of cathode material. Strategy like electrochemical pre-lithiation is suggested to improve the electrochemical performance of SLLRs in full cell.
- Published
- 2020
75. Robust template-activator cooperated pyrolysis enabling hierarchically porous honeycombed defective carbon as highly-efficient metal-free bifunctional electrocatalyst for Zn-air batteries
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Zhixing Wang, Lingjun Li, Guochun Yan, Jiexi Wang, Hu Qiyang, Xiao Xiao, Yong Liu, Xinhai Li, and Huajun Guo
- Subjects
Materials science ,Process Chemistry and Technology ,Oxygen evolution ,chemistry.chemical_element ,02 engineering and technology ,Electrolyte ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrocatalyst ,01 natural sciences ,Oxygen ,Catalysis ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,0210 nano-technology ,Bifunctional ,Porosity ,Pyrolysis ,General Environmental Science - Abstract
Nonprecious bifunctional electrocatalysts with satisfactory cost and high catalytic performance toward oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are essential to promote the commercialization of metal-air batteries. Herein, 3D honeycombed hierarchical porous N, O-doping carbon (HHPC) is fabricated via a facile and scalable strategy of hard template-activator assisted pyrolysis. The obtained HHPC displays unique macro-meso-microporous framework, N, O-codoped effect and order-disorder hybrid characteristic, providing sufficient space for O2 and electrolyte transport, abundant defect sites, enhanced electronic conductivity and stability for oxygen conversion reaction. As such, the HHPC exhibits superior bifunctional electrocatalytic activity with a narrow ΔE value of 0.8 V. And a long-term stability and reversibility with a narrow voltage gap increasing of 0.09 V over 1165 cycles (∼388 h) at 10 mA cm−2 are achieved in the HHPC-based rechargeable Zn-air battery, outperforming most of the state-of-the-art carbon-based Zn-air batteries.
- Published
- 2020
76. Treatment of aluminum and fluoride during hydrochloric acid leaching of lepidolite
- Author
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Wei Liu, Hu Qiyang, Xinhai Li, Jinlian Liu, and Zhoulan Yin
- Subjects
Metals and Alloys ,Hydrochloric acid ,engineering.material ,Alkali metal ,Hydrogen fluoride ,Industrial and Manufacturing Engineering ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,engineering ,Lithium chloride ,Leaching (metallurgy) ,Lepidolite ,Hydrogen chloride ,Fluoride ,Nuclear chemistry - Abstract
A two stage hydrochloric acid leaching process is proposed for the treatment of lepidolite and recovery of alkali metals. The separation characteristics of aluminum and fluoride in the leachate were also determined. The transformation of lepidolite into silica-like residue was tentatively identified through X-ray diffraction measurements. The leach liquor was heated and concentrated and by evaporation to drive off to remove some of the hydrogen chloride and hydrogen fluoride from the acidic leachate, followed by cooling to deposit crystals. This yielded an overall hydrogen chloride and hydrogen fluoride removal of 25.4% and 2.52%, respectively. The main components of the crystals were aluminum and potassium chlorides, with small amounts of fluoroaluminate, polyaluminum chloride, and aluminum hydroxyfluoride. The crystals were calcined at 623 K, with a further 43.9% of hydrogen chloride and 4.33% of hydrogen fluoride being driven off and captured by adsorption equipment, which was beneficial for the subsequent separation of impurities. Investigation of the major mineral phases revealed that lower temperature calcination of the crystals tended to produce less-soluble polyaluminum chloride, aluminum hydroxyfluoride, fluoaluminate, and alumina. Water leaching of crystals after calcination at 623 K gave a leach liquor with 7.74 g/L of lithium, 0.15 g/L of aluminum and 0.25 g/L of fluoride. The fluoaluminate in the leach liquor led to the production of secondary precipitates after neutralization. The [AlFn]3-n species were partially dissociated to F− and Al(OH)4− at a strongly basic pH. The residual aluminum and fluoride concentrations were 0.01 g/L and 0.05 g/L, respectively, at the pH of 9. Since alkali chlorides such as lithium chloride are very soluble, there was less lithium loss during neutralization than in the corresponding sulfate system.
- Published
- 2020
77. FaceShop: Deep Sketch-based Image Editing
- Author
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Portenier, Tiziano, Hu, Qiyang, Szabo, Attila, Arjomand, Siavash, Favaro, Paolo, and Zwicker, Matthias
- Subjects
510 Mathematics ,ComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISION ,000 Computer science, knowledge & systems - Abstract
We present a novel system for sketch-based face image editing, enabling users to edit images intuitively by sketching a few strokes on a region of interest. Our interface features tools to express a desired image manipulation by providing both geometry and color constraints as user-drawn strokes. As an alternative to the direct user input, our proposed system naturally supports a copy-paste mode, which allows users to edit a given image region by using parts of another exemplar image without the need of hand-drawn sketching at all. The proposed interface runs in real-time and facilitates an interactive and iterative workflow to quickly express the intended edits. Our system is based on a novel sketch domain and a convolutional neural network trained end-to-end to automatically learn to render image regions corresponding to the input strokes. To achieve high quality and semantically consistent results we train our neural network on two simultaneous tasks, namely image completion and image translation. To the best of our knowledge, we are the first to combine these two tasks in a unified framework for interactive image editing. Our results show that the proposed sketch domain, network architecture, and training procedure generalize well to real user input and enable high quality synthesis results without additional post-processing.
- Published
- 2018
78. Manipulating the Composition and Structure of Solid Electrolyte Interphase at Graphite Anode by Adjusting the Formation Condition
- Author
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Zhu, Taohe, primary, Hu, Qiyang, additional, Yan, Guochun, additional, Wang, Jiexi, additional, Wang, Zhixing, additional, Guo, Huajun, additional, Li, Xinhai, additional, and Peng, Wenjie, additional
- Published
- 2019
- Full Text
- View/download PDF
79. Hydrometallurgical production of LiNi0.80Co0.15Al0.05O2 cathode material from high-grade nickel matte
- Author
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Xi, Zhao, primary, Wang, Zhixing, additional, Yan, Guochun, additional, Guo, Huajun, additional, Li, Xinhai, additional, Hu, Qiyang, additional, Peng, Wenjie, additional, and Wang, Jiexi, additional
- Published
- 2019
- Full Text
- View/download PDF
80. A decoupled Method for Lidar-based Close-range Relative Navigation of Tumbling Non-cooperative Target
- Author
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Hu, Qiyang, primary and Wang, Dayi, additional
- Published
- 2019
- Full Text
- View/download PDF
81. A novel process for the selective precipitation of valuable metals from lepidolite
- Author
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Liu, Jinlian, primary, Yin, Zhoulan, additional, Li, Xinhai, additional, Hu, Qiyang, additional, and Liu, Wei, additional
- Published
- 2019
- Full Text
- View/download PDF
82. Lithiophilic Ag/Li composite anodes via a spontaneous reaction for Li nucleation with a reduced barrier
- Author
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Liu, Tiancheng, primary, Hu, Qiyang, additional, Li, Xinhai, additional, Tan, Lei, additional, Yan, Guochun, additional, Wang, Zhixing, additional, Guo, Huajun, additional, Liu, Yong, additional, Wu, Yuping, additional, and Wang, Jiexi, additional
- Published
- 2019
- Full Text
- View/download PDF
83. A novel dried plum-like yolk–shell architecture of tin oxide nanodots embedded into a carbon matrix: ultra-fast assembly and superior lithium storage properties
- Author
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Leng, Jin, primary, Wang, Zhixing, additional, Li, Xinhai, additional, Guo, Huajun, additional, Yan, Guochun, additional, Hu, Qiyang, additional, Peng, Wenjie, additional, and Wang, Jiexi, additional
- Published
- 2019
- Full Text
- View/download PDF
84. Effects of 1-propylphosphonic acid cyclic anhydride as an electrolyte additive on the high voltage cycling performance of graphite/LiNi0.5Co0.2Mn0.3O2 battery
- Author
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Huajun Guo, Hu Qiyang, Peng Wenjie, Guochun Yan, Zhixing Wang, Jiexi Wang, and Xinhai Li
- Subjects
Battery (electricity) ,Materials science ,Chemical engineering ,General Chemical Engineering ,Electrode ,Inorganic chemistry ,Electrochemistry ,Graphite ,Electrolyte ,Lithium-ion battery ,Dielectric spectroscopy ,Electrochemical cell - Abstract
The cycling performance of graphite/LiNi 0.5 Co 0.2 Mn 0.3 O 2 battery in the electrolyte with different content (0, 0.5, 1.0, 2.0 wt.%) 1-propylphosphonic acid cyclic anhydride (PACA) is studied in this work. When 0.5 wt.% PACA additive is incorporated into the blank electrolyte, the capacity retention of graphite/LiNi 0.5 Co 0.2 Mn 0.3 O 2 battery at high voltage after 100 cycles is increased from 79.12% to 91.84%. Electrochemical impedance spectroscopy (EIS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) results reveal the mechanism that the surface film derived from PACA can decrease the surface film impedance of the cell (from 40.63 to 16.57 Ω), stabilize the structure of cathode material. Moreover, the investigation of PACA on the cycling performance of graphite electrode demonstrates that PACA function on LiNi 0.5 Co 0.2 Mn 0.3 O 2 instead of graphite.
- Published
- 2015
85. Manipulating the Composition and Structure of Solid Electrolyte Interphase at Graphite Anode by Adjusting the Formation Condition
- Author
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Huajun Guo, Peng Wenjie, Guochun Yan, Zhixing Wang, Jiexi Wang, Taohe Zhu, Xinhai Li, and Hu Qiyang
- Subjects
General Energy ,Materials science ,Graphite anode ,Chemical engineering ,Composition (visual arts) ,Interphase ,Graphite ,Electrolyte ,Current density - Published
- 2019
86. Cubic CuCo2O4 microspheres with FeO nanowires link as free-standing anode for high-performance lithium ion batteries
- Author
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Cheng, Jianliang, Li, Xinhai, Wang, Zhixing, Guo, Huajun, Peng, Wenjie, and Hu, Qiyang
- Published
- 2016
- Full Text
- View/download PDF
87. Faceshop
- Author
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Portenier, Tiziano, primary, Hu, Qiyang, additional, Szabó, Attila, additional, Bigdeli, Siavash Arjomand, additional, Favaro, Paolo, additional, and Zwicker, Matthias, additional
- Published
- 2018
- Full Text
- View/download PDF
88. Disentangling Factors of Variation by Mixing Them
- Author
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Zwicker, Matthias, primary, Hu, Qiyang, additional, Szabo, Attila, additional, Portenier, Tiziano, additional, and Favaro, Paolo, additional
- Published
- 2018
- Full Text
- View/download PDF
89. Fine-Grained Retrieval with Autoencoders
- Author
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Portenier, Tiziano, primary, Hu, Qiyang, primary, Favaro, Paolo, primary, and Zwicker, Matthias, primary
- Published
- 2018
- Full Text
- View/download PDF
90. New insight into the modification of Li-rich cathode material by stannum treatment
- Author
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Chen, Hao, primary, Hu, Qiyang, additional, Peng, Wenjie, additional, Guo, Huajun, additional, Yan, Guochun, additional, and Wu, Xianwen, additional
- Published
- 2017
- Full Text
- View/download PDF
91. Synthesis and performance of xLiVPO4F–yLi3V2(PO4)3 composites as cathode materials for lithium ion batteries
- Author
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Fan, Yulei, Liu, Zhaomeng, Hu, Qiyang, Li, Xinhai, Wang, Zhixing, Guo, Huajun, and Wang, Jiexi
- Published
- 2015
- Full Text
- View/download PDF
92. 3D Face Reconstruction with Silhouette Constraints
- Author
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Hu, Qiyang, Favaro, Paolo, and Zwicker, Matthias
- Subjects
510 Mathematics ,ComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISION ,000 Computer science, knowledge & systems ,ComputingMethodologies_COMPUTERGRAPHICS - Abstract
In this paper we introduce silhouette constraints to improve the quality of unconstrained 3D face reconstruction. Previously, state of the art unconstrained 3D face reconstruction techniques relied solely on photometric consistency and matching sparse facial landmarks. We show that constraining the silhouettes of the 3D reconstruction to match silhouettes in the input images can further improve reconstruction quality. Our technique automatically detects silhouettes and iteratively matches silhouette points computed from the current 3D reconstruction with silhouettes in the input images. We demonstrate that our results improve on the previous state of the art in unconstrained 3D face reconstruction and that our additional constraints can easily be included in the iterative reconstruction at little additional cost.
- Published
- 2016
- Full Text
- View/download PDF
93. Extraction of lithium from lepidolite by sulfation roasting and water leaching
- Author
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Peng Wenjie, Huajun Guo, Qunxuan Yan, X.Q. Wu, Zhixing Wang, Xinhai Li, Jiexi Wang, and Hu Qiyang
- Subjects
Liquid ratio ,Sulfation ,Geochemistry and Petrology ,Aluminosilicate ,Chemistry ,Inorganic chemistry ,engineering ,Leaching (metallurgy) ,Lepidolite ,engineering.material ,Geotechnical Engineering and Engineering Geology ,Roasting - Abstract
Sulfation roasting followed by water leaching process was used to extract lithium from lepidolite. Various parameters including roasting temperature, the amount of additions, and solid/liquid ratio in leaching process were optimized. The lithium extraction efficiency of 91.61% could be reached with a mass ratio of lepidolite/Na 2 SO 4 /K 2 SO 4 /CaO of 1:0.5:0.1:0.1, and roasting at 850 °C for 0.5 h. XRD analysis showed that sulfation roasting caused the decompositions of the original aluminosilicate to NaSi 3 AlO 8 , KAlSi 2 O 6 and CaAl 2 Si 2 O 8 . The phases of CaF 2 and Ca 4 Si 2 O 7 F 2 are observed due to the addition of CaO.
- Published
- 2012
94. A novel process for extracting lithium from lepidolite
- Author
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Huajun Guo, Zhixing Wang, Peng Wenjie, Hu Qiyang, Xinhai Li, Qunxuan Yan, and Zhoulan Yin
- Subjects
Novel technique ,Hydrometallurgy ,Chemistry ,Lithium carbonate ,Metals and Alloys ,Mineralogy ,engineering.material ,Industrial and Manufacturing Engineering ,chemistry.chemical_compound ,Chemical engineering ,Materials Chemistry ,engineering ,Leaching (metallurgy) ,Lepidolite - Abstract
A novel technique was developed to extract lithium from lepidolite. The lepidolite was pre-roasted at a high temperature with water steam atmosphere for defluorination. Then the defluorinated lepidolite was leached in a lime–milk autoclave. Various parameters including the defluorination percentage of lepidolite, milling time, temperature, time, lime-to-defluorinated lepidolite ratio, and liquid-to-solid ratio in the leaching process were optimized. The lithium extraction efficiency can reach 98.9% under the optimal conditions. The purity of the lithium carbonate obtained can be up to 99.9%.
- Published
- 2012
95. Preparation and electrochemical properties of submicron LiNi0.6Co0.2Mn0.2O2 as cathode material for lithium ion batteries
- Author
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Zhixing Wang, Hu Qiyang, Peng Yue, Huajun Guo, Yunhe Zhang, Peng Wenjie, Lingjun Li, and Xinhai Li
- Subjects
Materials science ,Scanning electron microscope ,Mechanical Engineering ,Metals and Alloys ,Analytical chemistry ,chemistry.chemical_element ,Condensed Matter Physics ,Cathode ,Electrochemical cell ,law.invention ,Chemical engineering ,chemistry ,Mechanics of Materials ,law ,Transmission electron microscopy ,Spray drying ,Microscopy ,General Materials Science ,Lithium ,Electron microscope - Abstract
Submicron LiNi0.6Co0.2Mn0.2O2 as a cathode material for lithium-ion batteries was prepared by a spray drying assisted solid-state method. The crystal structure, morphology and electrochemical properties of LiNi0.6Co0.2Mn0.2O2 were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscope, energy-dispersive spectroscopy and charge–discharge testing. Single-phase layered LiNi0.6Co0.2Mn0.2O2 was obtained. The material delivered a reversible charge/discharge capacity of 179.8 mAh g−1 at C/10, and showed excellent cycling performance and rate capability.
- Published
- 2011
96. Effect of pre-roasting on leaching of laterite
- Author
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Junchao Zheng, Wanrong Liu, Zhixing Wang, Hu Qiyang, Xinhai Li, Jinhui Li, Lingjun Li, and You-yuan Zhou
- Subjects
Goethite ,Hydrometallurgy ,Chemistry ,Metallurgy ,Metals and Alloys ,chemistry.chemical_element ,engineering.material ,Industrial and Manufacturing Engineering ,Nickel ,visual_art ,Materials Chemistry ,visual_art.visual_art_medium ,Laterite ,engineering ,Leaching (metallurgy) ,Porosity ,Powder diffraction ,Roasting - Abstract
The effect of pre-roasting on leaching of the gamierite laterite ore, obtained from Yunnan province, China, was investigated in this study. The phase transformation of laterite minerals roasted at different temperatures was investigated with X-ray powder diffraction (XRD). The roasting experiment results show that there are two phase transformation processes of dehydroxylation of goethite and lizardite at roasting temperatures of 277 °C and 610 °C, respectively, which accord with the result of DTA–TG analysis. Pre-roasting of the laterite not only alters its mineralogical composition but also increases its porosity and surface area, thus making it more amenable to leaching. Compared to the leaching result of raw ore and ores roasted at different temperatures, it indicates that increasing roasting temperature up to 300 °C appears to provide the optimum nickel recovery and further heating appears to be detrimental to the nickel recovery.
- Published
- 2009
97. Study of extraction and purification of Ni, Co and Mn from spent battery material
- Author
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Jinhui Li, Junchao Zheng, Lianxin Zhang, Xinhai Li, Zhixing Wang, Ling Wu, and Hu Qiyang
- Subjects
Hydrometallurgy ,Metallurgy ,Inorganic chemistry ,Metals and Alloys ,chemistry.chemical_element ,Hydrochloric acid ,Manganese ,Industrial and Manufacturing Engineering ,Iron powder ,Nickel ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,Leaching (metallurgy) ,Cobalt ,Dissolution - Abstract
In spent battery material, there are plenty of valuable metals, such as copper, nickel, cobalt, manganese. Recovery of valuable metals from spent battery material not only protects the environment but also improves the utilization of resources and decreases the cost of battery material. In this study, hydrochloric acid is used as lixivant with characteristics of faster leaching rate and being recycled easily. The optimal conditions are that hydrochloric acid concentration is 6 mol/L, reaction temperature is exactly 60 °C, liquid/solid ratio is 8:1, (H2O2)mol/(MeS)mol = 2, and the leaching time is 2 h, the results show that the dissolution yields of Ni, Co and Mn can be 95 wt.% at least. The basic purification concept of the leaching solution includes that copper is removed through replacement by iron powder followed by iron precipitation in goethite method. The results show that Cu and Fe can be removed 99 wt.% at the least. At the same time, the loss of Ni, Co and Mn is not beyond 2 wt.%, 3 wt.% and 2 wt.%, respectively. This method makes the preparation of pure NixCoyMnz ternary system precursor economical. The process seems to be able to claim base metals from waste in a reliable and feasible way.
- Published
- 2009
98. Overcharge performance of LiMn2O4/graphite battery with large capacity
- Author
-
Xinhai Li, Zhixing Wang, Huajun Guo, Yunjian Liu, Peng Wenjie, and Hu Qiyang
- Subjects
Battery (electricity) ,Overcharge ,Materials science ,Mechanical Engineering ,Spinel ,chemistry.chemical_element ,Electrolyte ,engineering.material ,Decomposition ,chemistry ,Chemical engineering ,Mechanics of Materials ,Electrode ,engineering ,General Materials Science ,Graphite ,Carbon - Abstract
The LiMn2O4/graphite battery was fabricated and its 3 C/10 V overcharge performance was studied. Spinel LiMn2O4 was synthesized by solid-state method and 325680-type size full battery was fabricated. The structure and morphology of the powders were characterized by XRD and SEM technique, respectively. The battery explodes after 3 C/10 V overcharged test, and surface temperature of the battery case arrives at 290 °C in 12 s after exploding. Black air is given out with blast. Carbon, MnO, and Li2CO3 are observed in the exploded powders. The cathode electrode remains spinel structure with 5.0 V charged. Cracks in the cathode electrode particles are detected with the increase of voltage by SEM technique. The 5.0 V charged electrode can decompose into Mn3O4 at 400 °C. It is demonstrated that the decomposition of 5.0 V charged electrode can be promoted and Mn4+ can be deoxidized to Mn2+ by carbon and electrolyte through the simulation of blast process.
- Published
- 2009
99. Performance and capacity fading reason of LiMn2O4/graphite batteries after storing at high temperature
- Author
-
Yong Yang, Huajun Guo, Hu Qiyang, Yunjian Liu, Xinhai Li, Zhixing Wang, and Peng Wenjie
- Subjects
Materials science ,Scanning electron microscope ,Metals and Alloys ,Analytical chemistry ,Energy-dispersive X-ray spectroscopy ,Electrolyte ,Condensed Matter Physics ,Cathode ,Dielectric spectroscopy ,law.invention ,Anode ,law ,Materials Chemistry ,Graphite ,Physical and Theoretical Chemistry ,Polarization (electrochemistry) - Abstract
Spinel LiMn2O4 was synthesized by a solid-state method. A 204468-size battery was fabricated and stored at 55°C. The structure and morphology of the LiMn2O4 cathode were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM) technique. Energy dispersive spectroscopy (EDS) was used to analyze the surface component of the carbon anode. The discharge capacities of LiMn2O4 stored for 0, 24, 48, and 96 h are 106, 98, 96, and 92 mAh·g−1, respectively. The cyclic performance is improved after storage. The capacity retentions of LiMn2O4 stored for 0, 24, 48, and 96 h are 83.8%, 85.8%, 86.9%, and 88.6% after 180 cycles. The intensity of all the LiMn2O4 diffraction peaks is weakened. Mn is detected from the carbon electrode when the battery is stored for 96 h. Cyclic voltammograms and electrochemical impedance spectroscopy (EIS) were used to examine the surface state of the electrode after storage. The results show that the resistance and polarization of LiMn2O4/electrolyte is increased after storage, which is responsible for the fading of capacity.
- Published
- 2009
100. Li3V2(PO4)3 cathode material synthesized by chemical reduction and lithiation method
- Author
-
Xinhai Li, Zhixing Wang, Junchao Zheng, Hu Qiyang, Peng Wenjie, and Huajun Guo
- Subjects
Renewable Energy, Sustainability and the Environment ,Oxalic acid ,Lithium carbonate ,Analytical chemistry ,Energy Engineering and Power Technology ,chemistry.chemical_element ,Amorphous solid ,chemistry.chemical_compound ,Crystallinity ,Differential scanning calorimetry ,X-ray photoelectron spectroscopy ,chemistry ,Lithium ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,Mesoporous material ,Nuclear chemistry - Abstract
The monoclinic-type Li 3 V 2 (PO 4 ) 3 cathode material was synthesized via calcining amorphous Li 3 V 2 (PO 4 ) 3 obtained by chemical reduction and lithiation of V 2 O 5 using oxalic acid as reducer and lithium carbonate as lithium source in alcohol solution. The amorphous Li 3 V 2 (PO 4 ) 3 precursor was characterized by using TG–DSC and XPS. The results showed that the V 5+ was reduced to V 3+ by oxalic acid at ambient temperature and pressure. The prepared Li 3 V 2 (PO 4 ) 3 was characterized by XRD and SEM. The results indicated the Li 3 V 2 (PO 4 ) 3 powder had good crystallinity and mesoporous morphology with an average diameter of about 30 nm. The pure Li 3 V 2 (PO 4 ) 3 exhibits a stable discharge capacity of 130.08 mAh g −1 at 0.1 C (14 mA g −1 ).
- Published
- 2009
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