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In-situ Rb–Sr geochronology using LA-ICP-MS/MS technology allows rapid dating of K-rich minerals such as micas (e.g. biotite, muscovite, phlogopite) and K-feldspar. While many studies have demonstrated the ability of the method, analytical protocols vary significantly and to date no studies have provided an in-depth comparison and synthesis in terms of precision and accuracy. Here we compare four calibration protocols based on commonly used reference materials for Rb–Sr dating. We demonstrate that downhole fractionation trends (DHF) for natural biotite, K-feldspar and phlogopite contrast with that for the commonly used Mica-Mg nano-powder reference material. Consequently, Rb–Sr dates calibrated to Mica-Mg can be up to 5 % inaccurate and the degree of inaccuracy appears to be unsystematic between analytical sessions. Calibrating to Mica-Mg also introduces excess uncertainty that can be avoided with a more consistent primary calibration material. We propose a calibration approach involving NIST-610 glass as the primary reference material (RM) and a natural mineral with similar DHF characteristics to the analysed samples as secondary RM to correct for matrix-dependent fractionation. In this work, MDC phlogopite (the source mineral for Mica-Mg nano-powder) was used as the secondary RM, consistently producing accurate Rb–Sr dates for a series of natural biotites and K-feldspars with well-characterized expected ages. However, biotite from the Banalasta Adamellite, Taratap Granodiorite and Entire Creek pegmatite are also suitable secondary RMs for Rb/Sr ratio calibration purposes with consistently <1.5 % fully propagated uncertainties in our methodological approach. Until calibration using isochronous natural standards as the primary RM becomes possible in data-reduction software, the two-step calibration approach described here is recommended. [ABSTRACT FROM AUTHOR]

Bogda Shan is a mountain belt located at the eastern extremity of the Chinese Tianshan and records a complex and debated exhumation history. Previous studies have reported a young Cenozoic thermal history for the exhumation of Bogda Shan, which is in conflict with the observation of preserved Mesozoic erosion surfaces in the area. This study re-evaluates the Meso-Cenozoic thermo-tectonic evolution of Bogda Shan using apatite fission track (AFT) thermochronology. Palaeozoic basement (meta-sandstone) samples collected from the northern and southwestern flanks of the mountain ranges reveal apparent Mesozoic AFT ages ranging from ~202 Ma to ~97 Ma. Inverse thermal history modelling results reveal slow to moderate basement cooling during the early Mesozoic, corresponding to relatively low levels of exhumation. This accounts for the preservation of low-relief Mesozoic peneplanation surfaces recognized at elevations of ~3500–4000 m. None of the presented AFT data and thermal history models show any evidence for significant deep Cenozoic exhumation. In the neighbouring Junggar Basin, a Middle Jurassic sandstone sample records partial resetting of the AFT system during the Cretaceous. This observation conflicts with previous data (from the same Jurassic strata) where complete resetting of the AFT clock during the Cenozoic was suggested. Furthermore, Lower Cretaceous and Palaeogene sediments from the Turpan-Hami Basin show non-reset detrital AFT age populations of ~197, ~135, and ~104 Ma, which are coincident with the main pulses of exhumation recorded in the Chinese North Tianshan. Based on a comprehensive summary of the published data, we argue for a Mesozoic building of the Bogda–Balikun–Harlik mountain chain in the eastern Chinese Tianshan. Subsequent Cenozoic exhumation must have been relatively modest at most (<2 km) as it was not recorded by AFT thermochronology. [ABSTRACT FROM AUTHOR]

The McArthur Basin of the North Australian Craton is one of the very few places on Earth where extensive hydrocarbons are preserved that were generated from Mesoproterozoic source rocks, prior to the development of extensive multicellular life. It is, however, unclear precisely when hydrocarbons from these source rocks matured, and if this occurred as a singular event or multiple phases. In this study, we present new apatite fission track data from a combination of outcrop and sub‐surface samples from the McArthur Basin to investigate the post‐depositional thermal history of the basin, and to explore the timing of hydrocarbon maturation. Apatite fission track data and thermal modelling suggest that the McArthur Basin experienced a basin‐wide reheating event contemporaneous with the eruption of the Cambrian Kalkarindji Large Igneous Province in the North and West Australian cratons, during which thick (>500 m) basaltic flows blanketed the basin surface. Reheating at ca. 510 Ma coinciding with Kalkarindji volcanism is consistent with a proposed timing of elevated hydrocarbon maturation, particularly in the Beetaloo Sub‐basin, and provides a mechanism for petroleum generation throughout the basin. Subsequent regional cooling was slow and gradual, most likely facilitated by gentle erosion (ca. 0.01–0.006 km/Ma) of overlying Georgina Basin sediments in the Devonian–Carboniferous with little structural reactivation. This model provides a framework in which hydrocarbons, sourced from Mesoproterozoic carbon‐rich rocks, may have experienced thermal maturation much later in the Cambrian. Preservation of these hydrocarbons was aided by a lack of widespread structural exhumation following this event. [ABSTRACT FROM AUTHOR]

Deciphering the tectono‐metamorphic evolution of Precambrian terranes can be difficult due to reworking by later superimposed events. Whole‐rock elemental and isotopic geochemistry and zircon U–Pb geochronology are often employed in those studies, but these approaches are often not sensitive to the presence of multiple events and medium‐grade metamorphic episodes. The Rio Apa Terrane (RAT), an allochthonous fragment of the Amazonian Craton, is a crustal block with a well‐characterized crustal evolution but with no detailed thermal constraints for its tectono‐metamorphic evolution. In contrast to previous studies, we show the existence of four tectono‐metamorphic events at c. 1,780, c. 1,625, c. 1,420–1,340, and c. 1,300–1,200 Ma on the basis of apatite, titanite, and rutile U–Pb, in situ white‐mica Rb–Sr, and in situ garnet Lu–Hf geochronology combined with mineral chemistry and phase‐equilibria modelling. The c. 1,780 Ma event is recorded in the basement of the Western domain, representing an extensional event coeval with the development of its Eastern domain in response to the retreat stage of the accretionary system. This is followed by juxtaposition of the Western and Eastern domains along a major crustal boundary at c. 1,625 Ma, which is defined by the magnetic profiles and zircon U–Pb–Hf data across the boundary. The third and fourth events correspond to progressive high‐pressure/medium‐temperature (HP/MT) metamorphism, characterized by an anticlockwise P–T path, suggesting a convergent‐to‐collisional tectonic setting. The RAT was accreted to the adjoining Paraguá Terrane at c. 1,420–1,340 Ma under an isobaric P–T evolution spanning ~530°C to 600°C and ~10.0 kbar. Subsequently, the combined Rio Apa and Paraguá terranes collided with the SW Amazonian Craton at c. 1,300–1,200 Ma, reaching P–T conditions of ~560–580°C and ~10.9–11.7 kbar during crustal thickening. This study reveals for the first time the existence of a HP/MT metamorphic evolution related to the growth of the SW Amazonian Craton as part of an accretionary orogenic system during Rodinia assembly in the Palaeoproterozoic to Mesoproterozoic. [ABSTRACT FROM AUTHOR]