Search

The dynamics of the release of stored energy during annealing along two different crystallographic planes i.e.{111} and {220} in deformed copper have been investigated using in-situ X-ray diffraction measurements at 458K and 473K respectively. The study has been carried out on 50% and 80% rolled Cu sheets. The microstructures of the rolled samples have been characterised using optical microscope and Electron Back Scattered Diffraction measurements. The microstructural parameters were evaluated using Scherrer equation and the modified Rietveld technique from X-ray diffractogram. The stored energy along different planes were determined using the modified Stibitz formula from the X-ray peak broadening and the bulk stored energy has been evaluated using differential scanning calorimetry. The process dynamics of recovery and recrystallization as observed through the release of stored energy has been modelled as a second order and first order process respectively., Comment: 11 figures

In the present study, an attempt has been made to understand the effect of different competing mechanisms controlling the overall degree of sensitization (DOS) of deformed austenitic stainless steel at the early stage of sensitization. The Double Loop Electrochemical Potentiokinetic Reactivation (DL-EPR) studies were performed to characterize the Degree of Sensitization (DOS) as functions of pre-defined strain and sensitization temperature. X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) were used to explain the phenomena qualitatively. A non monotonous behaviour in the variation of DOS has been observed with deformation and sensitization temperature. The presence of Deformation Induced Martensites (DIM) and their transformation into tempered martensites (alpha + Fe3C) at higher temperatures was found to play major roles in controlling the overall sensitization and desensitization processes., Comment: 6 figures

In this report we have pointed out that magnetic hysteresis loop can be used as a probe to distinguish a single layer from a many layer graphitic structure. Chemically we have synthesized graphitic oxide (GO) and reduced graphitic oxide (RGO) for this investigation. We observe ferromagnetic like hysteresis loops for both GO and RGO below a certain applied critical magnetic field and above this critical field we observe cross-over of the positive magnetization to negative magnetization leading to diamagnetic behaviour. This cross-over is more dominant for the case of many layer graphitic structure. Upon annealing of GO in air the critical cross-over field decreases and the magnetization increases for multilayer graphitic structure. Possible reasons for all these observations and phenomena is presented here., Comment: 12 pages writeup and 4 pages figures (twelve figures)

We employ the methods of atomistic simulation to investigate the climb of edge dislocation at nanovoids by analyzing the energetics of the underlying mechanism. A novel simulation strategy has been demonstrated to estimate the release of surface energy of the nanovoid during the void induced climb. The curvature of the pinned dislocation segment is found to play a key role in mediating this unique mechanism of dislocation climb. Our study reveals that the kinetics of void-induced climb process is fundamentally distinct from the conventional diffusion-mediated climb., Comment: 26 pages, 8 figures

Tensile tests were carried out by deforming polycrystalline samples of Al-2.5%Mg alloy at four different temperatures in an intermediate strain rate regime of 2x10-4s-1 to 2x10-3s-1. The Portevin-Le Chatelier (PLC) effect was observed throughout the strain rate and temperature region. The mean cumulative stress drop magnitude and the mean reloading time exhibit an increasing trend with temperature which is attributed to the enhanced solute diffusion at higher temperature. The observed stress-time series data were analyzed using the nonlinear dynamical methods. From the analyses, we could establish the presence of deterministic chaos in the PLC effect throughout the temperature regime. The dynamics goes to higher dimension at a sufficiently high temperature of 425K but the complexity of the dynamics is not affected by the temperature., Comment: 18 pages, 8 figures; accepted in Met. Mater. Trans. A

The mechanism of the evolution of the deformed microstructure at the earliest stage of annealing where the existence of the lowest length scale substructure paves the way to the formation of the so-called subgrains, has been studied for the first time. The study has been performed at high temperature on heavily deformed Ti-modified austenitic stainless steel using X-ray diffraction technique. Significant changes were observed in the values of the domain size, both with time and temperature. Two different types of mechanism have been proposed to be involved during the microstructural evolution at the earliest stages of annealing. The nature of the growth of domains with time at different temperatures has been modelled using these mechanisms. High-resolution transmission electron microscopy has been used to view the microstructure of the deformed and annealed sample and the results have been corroborated successfully with those found from the X-ray diffraction techniques., Comment: 23 pages including 8 figures

We carry out the molecular statics simulations of depinning of an edge dislocation at voids of diameters of the order of ~1 nm. We show that the dislocation-void interactions are non-trivial as the applied shear load is found to enhance the pinning strength of the nanovoid itself. This leads to the surprising observation of multiple CRSS values for a given nanovoid., Comment: 4 figures

Dislocation pinning plays a vital role in the plastic behaviour of a crystalline solid. Here we report the first observation of the damped oscillations of a mobile dislocation after it gets pinned at an obstacle in the presence of a constant static shear load. These oscillations are found to be inertial, instead of forced as obtained in the studies of internal friction of solid. The rate of damping enables us to determine the effective mass of the dislocation. Nevertheless, the observed relation between the oscillation frequency and the link length is found to be anomalous, when compared with the theoretical results in the framework of Koehler's vibrating string model. We assign this anomaly to the improper boundary conditions employed in the treatment. Finally, we propose that the inertial oscillations may offer a plausible explanation of the electromagnetic emissions during material deformation and seismic activities., Comment: 28 pages, 4 figures

In this paper, we have tried to find out the origin of magnetism in Gold nanoparticles (Au- NPs). We observe that upon incorporating Gold nanoparticles (Au-NPs) in Fe3O4 nanoparticle medium the net magnetisation increases compared to the pure Fe3O4 nanoparticle medium. This increase of magnetization can be attributed to the large orbital magnetic moment formation at the Au/magnetic particle interface indicating that magnetism observed in Au-NPs is an interfacial effect. This interfacial effect has been supported by the observation of sudden transition from positive saturated magnetisation to a negative diamagnetic contribution as a function of magnetic field on citrate coated gold Au-NPs., Comment: 7 pages double column, 6 figures, This manuscript contains more quantitative analysis of magnetization of arXiv:0906.1497v2 and additional data on citrate coated Au has been added as figure 6

Tensile tests have been carried out by deforming polycrystalline samples of substitutional Al-2.5%Mg alloy at room temperature at a range of strain rates. The Portevin - Le Chatelier (PLC) effect was observed. From an analysis of the experimental stress versus time series data we have inferred that the dynamics of the PLC effect in a local finite time is controlled by a finite number of degrees of freedom and this effective dimension becomes reduced with increasing strain., Comment: 12 pages, 5 figures

Plastic deformation of crystals is a physical phenomenon, which has immensely driven the development of human civilisation since the onset of the Chalcolithic period. This process is primarily governed by the motion of line defects, called dislocations. Each dislocation traps a quantum of plastic deformation expressible in terms of its Burgers vector[1,2]. Theorising the mechanisms of dislocation motion at the atomistic scales of length and time remains a challenging task on account of the extreme complexities associated with the dynamics. We present a new concept of modelling a moving dislocation as the dynamic distribution of the elastic field singularity within the span of the Burgers vector. Surprisingly, numerical implementation of this model for the periodic expansion-shrinkage cycle of the singularity is found to exhibit an energetics, which resembles that of a dislocation moving in the presence of the Peierls barrier[1-4]. The singularity distribution is shown to be the natural consequence under the external shear stress. Moreover, in contrast to the conventional assumption, here the calculations reveal a significant contribution of the linear elastic region surrounding the core towards the potential barrier., Comment: 10 pages, 5 figures

In this report we present systematic magnetic studies of pure iron oxide nanoparticles and gold iron oxide nanocomposite with increasing Au particle size/content. For the magnetic studies of these samples we have measured: (1) zero field cooled (ZFC) and field cooled (FC) magnetization, (2) ac susceptibility, (3) magnetization vs field at various temperatures, (4) thermoremanant magnetization relaxation (TRM) and zero field cooled magnetization relaxation (ZFCM) at fixed temperature for various wait times tw for studying the aging effect, (5) magnetization memory effect and (6) exchange bias as a function of cooling field. The detailed magnetic measurement analysis indicates that the pure Fe3O4 nanoparticles sample behaves like a superparamagnet and on incorporation of gold (Au) nanoparticles the nanocomposite system slowly evolves from superparamagnetic to superspin glass state. The memory and aging effect enhances with the increase of the Au nanoparticle size/content. The most important observation in this study is the enhancement of magnetization with the incorporation of Au nanoparticles. The enhancement increases with the increase in the Au content in the nanocomposite. We have explained the cause of this enhancement of magnetization as due to large orbital magnetic moment formation at the Au/magnetic particle interface., Comment: 12 figures, 33 pages total

This paper has been withdrawn., Comment: This paper has been withdrawn due to further modification in the model

The relation between the contact angle of a liquid drop and the morphological parameters of self-affine solid surfaces have been investigated. We show experimentally that the wetting property of a solid surface crucially depends on the surface morphological parameters such as: (1) root mean square (rms) roughness $\sigma$, (2) in-plane roughness correlation length $\xi$ and (3) roughness exponent $\alpha$ of the self-affine surface. We have shown that the contact angle monotonically decreases with the increase in the rms local surface slope $\rho$ ($\propto \sigma/\xi^\alpha$) for the cases where the liquid wets the crevices of the surface upon contact. We have shown that the same solid surface can be made hydrophobic or hydrophilic by merely tuning these self-affine surface morphological parameters., Comment: 4 page in double column format, 5 figures

In this letter we propose a model that demonstrates the effect of free surface on the lattice resistance experienced by a moving dislocation in nanodimensional systems. This effect manifests in an enhanced velocity of dislocation due to the proximity of the dislocation line to the surface. To verify this finding, molecular dynamics simulations for an edge dislocation in bcc molybdenum are performed and the results are found to be in agreement with the numerical implementations of this model. The reduction in this effect at higher stresses and temperatures, as revealed by the simulations, confirms the role of lattice resistance behind the observed change in the dislocation velocity., Comment: 4 Figures

The Portevin-Le Chatelier(PLC) effect has been investigated by deforming Al-2.5%Mg alloy in the strain rate regime where simultaneously two types (type B and type A) of serrations appear in the stress strain curve. Our analysis reveal that in this strain rate regime the entire PLC dynamics for a particular strain rate experiment is governed by a single band which changes its character during the deformation., Comment: 13 pages, 4 figures

Tensile tests were carried out by deforming polycrystalline samples of substitutional Al-2.5%Mg alloy at room temperature for a range of strain rates. The Portevin-Le Chatelier (PLC) effect was observed throughout the strain rate regime. The deformation bands in this region are found to be of type A in nature. From the analysis of the experimental stress time series data we could infer that the dynamics of type A dislocation band propagation is a Markov process., Comment: 17 pages, 8 figures, to appear in Physics Letters A