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Highly oxidative debris (OD) was obtained by aqueous ammonia wash of as-prepared graphene oxide (GO) which composed of OD and lightly oxidative GO sheets. The magnetic properties of OD and GO were studied. The results showed that OD has a low magnetization of 0.16 emu/g, and the magnetization of GO can be increased from 0.38 to 0.42 emu/g by discarding lowmagnetization OD. Thus, this study provided a reliable method to increase the magnetization of GO. Hydroxyl groups were proposed to be the magnetic source. [ABSTRACT FROM AUTHOR]

Highly efficient H2 production from water splitting has been achieved by N-doped titanate nanotubes (N-TNTs) decorated with graphene quantum dots (GQDs) in this work. In order to promote charge carrier transmission at the interface, a facile and environmentally friendly in situ growth method was employed to construct a strongly coupled N-TNT/GQD composite photocatalyst. The results revealed that N atoms were effectively doped into the crystal lattice of the TNTs in the form of both interstitial N and substitutional N, and the GQDs were decorated onto both the inner and outer surfaces of the N-TNTs through the formation of Ti–O–C chemical bonds. Photoelectrochemical measurements proved that, in N-TNT/GQD composite, N-doping can extend light response to the visible-light range, and the coupling with GQDs not only enhanced visible-light absorption, but also promoted interfacial charge carrier transfer. Due to the synergistic effect between N-doping and GQD coupling, the closely integrated N-TNT/GQD composite exhibits a much superior photocatalytic H2 production performance under UV–vis irradiation, being 2.1 times higher than that of pure TNTs. [ABSTRACT FROM AUTHOR]