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Nuclear-grade 316LN stainless steel was subjected to single and double compressions at 1173–1473 K and strain rates of 0.01–10 s⁻¹. The dynamic and postdeformation recrystallization was investigated through analysis of the stress–strain curves and microstructure evolution. The thermal deformation equation and the quantitative relationships between the critical stress for the initiation of dynamic recrystallization and the Zener–Hollomon parameter, Z, and between the dynamic recrystallization grain size D and Z were derived. Dynamic recrystallization developed through an ordinary mechanism at low Z values and through a necklace mechanism at high Z values, with a critical Z value of about 3.6 10¹⁶ . At 1273–1473 K, softening of 316LN stainless steel after deformation was characterized by an Avrami-type equation, where the Avrami parameter, n, has no appreciable temperature dependence, and an average value of n and the activation energy, Qrex , were 0.68 and 129 kJ/mol, respectively. Нержавеющая сталь 316LN ядерного класса подвергалась одно- и двукратному сжатию при 1173...1473 К и скорости деформации 0,01...10 с⁻¹. Динамическая и постдеформационная рекристаллизация изучалась с помощью анализа зависимости деформации от напряжения и развития микроструктуры. Были выведены уравнение тепловой деформации и количественные зависимости между критическим напряжением инициирования динамической рекристаллизации и параметром Зенера Холломона Z, а также между размером зерна D при динамической рекристаллизации и Z. Динамическая рекристаллизация развивалась по обычному механизму при низких значениях Z и по механизму ожерелья при высоких значениях Z, при критическом значении Z примерно 3 6 10¹⁶. При 1273...1473 К разупрочнение нержавеющей стали 316LN после деформирования описывается уравнением Аврами, где параметр Аврами n не проявляет выраженной температурной зависимости, а его среднее значение и энергия активации Qrex составляют 0,68 и 129 кДж/моль соответственно.

Four new Ln(III) complexes (Ln = Eu, Tb) with furan-2,5-dicarboxylic acid (H2FDA) as a ligand have been synthesized and characterized in the solid state. Luminescence studies indicate that the compounds exhibit line-like luminescence characteristic of the lanthanide centre upon excitation in the ligand absorption bands. Single crystal X-ray diffraction study of {[Eu(FDA)(H2O)5]·½(FDA)·3H2O}n shows the formation of an inorganic polymer with infinite Eu-FDA chains.

The three phases of the mononuclear two-step spin crossover compound [Fe(bapbpy)(NCS)2] (1) are characterized by powder X-ray diffraction, Mo¨ssbauer spectroscopy, Raman spectroscopy, calorimetry, and magnetic susceptibility measurements. Mo¨ssbauer and Raman spectroscopies confirm the results obtained from previous single crystal X-ray diffraction studies, as they show that the intermediate phase is characterized by a 1:2 high-spin/low-spin ratio and that it is not a mixture of the high-spin state (HS) and low-spin state (LS) phases. Sample preparation and sample history studies show that the spin crossover (SCO) properties of this compound are quite robust, as the two steps and hysteresis cycles are present both in the powder and in recrystallized samples and conserved when the sample is cooled and heated several times. Compound 2, a DMF solvate having the formula [Fe(bapbpy)(NCS)2] · 2DMF, shows SCO properties but no cooperative effects. The origin of the strong cooperativity found in compound 1 is discussed. Finally, external perturbations have been applied to compound 1. First, light irradiation at low temperatures promotes the LS f HS transition with reasonably good optical conversions [∼70%, T(LIESST) ) 56 K]. Second, the application of hydrostatic pressure increases both the temperature and the hysteresis width of the higher-temperature transition (HS T IP), while unexpectedly suppressing the lower-temperature transition (IP T LS).

The first examples of lanthanide complexes with a 2-hydroxyisophthalate ligand are reported; the blue-emitting ligand acts as a very efficient sensitizer of the Tb(III) green emissions and does so in the near-UV region.