Search

Phase change slurries (PCSs) have great potential as both a heat transfer fluid and an energy storage medium for cooling processes, cold energy storage, and cold energy transportation due to desirable thermophysical properties. One of the major benefits of PCSs compared to pure phase change materials is their fluidity, thus making them cooled or heated by a heat exchanger, pumped through pipes, discharged, and stored directly in a thermal energy storage tank. The use of encapsulated phase change slurries and gas hydrate slurry has thus attracted considerable interest as reflected in the literature with a rising number of publications and institutions involved in the area. The use of bibliometric techniques has found a recent interest in the literature to define the progress of different scientific topics and inspire researchers to identify novelties. In this paper, bibliometric analysis and a detailed systematic review are carried out to show the state-of-the-art development of PCSs for cooling applications. Research gaps and hotspots are identified to help define future perspectives on this topic.

Solar thermal energy coupled to a seasonal sorption storage system stands as an alternative to fossil fuels to supply residential thermal energy demand in climates where solar energy availability is high in summer and low in winter, matching with a high space heating demand. Sorption storage systems usually have a high dependency on weather conditions (ambient temperature and solar irradiation). Therefore, in this study, the technical performance of a solar-driven seasonal sorption storage system, using an innovative composite sorbent and water as working fluid, was studied under three European climates, represented by: Paris, Munich, and Stockholm. All scenarios analyses were simulation-based under optimal system control, which allowed to maximize the system competitiveness by minimizing the system operational costs. The optimal scenarios profit from just 91, 82 and 76% of the total sorption system capacity, for Paris, Munich, and Stockholm, respectively. That means that an optimal control can identify the optimal sorption storage size for each location and avoid oversizing in future systems, which furthermore involves higher investment costs. The best coefficient of performance was obtained for Stockholm (0.31), despite having the coldest climate. The sorption system was able to work at minimum temperatures of −15 °C, showing independence from ambient temperature during its discharge. In conclusion, a seasonal sorption system based on selective water materials is suitable to be integrated into a single-family house in climates of central and northern Europe as long as an optimal control based on weather conditions, thermal demand, and system state is considered.

In this study, the development and testing of a hybrid thermal energy storage (TES) including phase change material (PCM) macro-capsules inside a vertical sensible tank is presented. The storage was specifically developed for delivering hot water on board of ships. Accordingly, a commercial PCM was selected and tested. Subsequently, the hybrid TES was designed and tested under mimicked boundary conditions at lab scale, showing the possibility of increasing the volumetric energy storage density up to 30% compared to the sensible configuration. On this basis, two numerical models were developed: a detailed one, implemented in a Fluent environment, aiming at investigating the main parameters affecting the heat transfer efficiency inside the TES and a second one, implemented in an ESP-r environment to simulate the TES as a component to be implemented inside a more complex system, thus helping its accurate design and operation through a reliable modelling phase. Both models were satisfactorily validated against the experimental results, thus being made available for future investigations and design optimization.

The LiCl-based heat storage system exhibits a high-energy density, making it an attractive and one of the most investigated candidates for low-temperature heat storage applications. Nevertheless, lithium chloride, due to its hygroscopic nature, incurs the phenomenon of deliquescence, which causes some operational challenges, such as agglomeration, corrosion, and swelling problems during hydration/dehydration cycles. Here, we propose a composite material based on silicone vapor-permeable foam filled with the salt hydrate, hereafter named LiCl-PDMS, aiming at confining the salt in a matrix to prevent deliquescence-related issues but without inhibiting the vapour flow. In particular, the structural and morphological modification during hydration/dehydration cycles is investigated on the composite foam, which is prepared with a salt content of 40 wt.%. A characterization protocol coupling temperature scanned X-ray diffraction (XRD) and environmental scanning electron microscopy (ESEM) analysis is established. The operando conditions of the dehydration/hydration cycle were reproduced while structural and morphological characterizations were performed, allowing for the evaluation of the interaction between the salt and the water vapor environment in the confined silicon matrix. The material energy density was also measured with a customized coupled thermogravimetric/differential scanning calorimetric analysis (TG/DSC). The results show an effective embedding of the material, which limits the salt solution release when overhydrated. Additionally, the flexibility of the matrix allows for the volume shrinkage/expansion of the salt caused by the cyclic dehydration/hydration reactions without any damages to the foam structure. The LiCl-PDMS foam has an energy density of 1854 kJ/kg or 323 kWh/m3, thus making it a competitive candidate among other LiCl salt hydrate composites.

Abstract In the present work, adsorption performances of an innovative composite adsorber, based on SAPO-34-silicone composite macro-cellular foams, are reported. The choice of a foamed structure was assessed to improve the water vapor access towards the embedded zeolite keeping good adsorption heat pump dynamic performance. Depending on zeolite amount used as filler, zeolite/silicone foams evidenced a soft and open cell configuration (low zeolite content) or rigid and closed one (high zeolite content). Morphological analysis evidenced that the cellular structure of the foam is homogeneous and well distributed along the foam cross section. Adsorption tests showed that the adsorbent foamed samples have very effective adsorption capabilities indicating that the porous structure of the filled pure zeolite was not obstructed. SAPO-34 filler contributed actively, with an efficiency above 90%, to the adsorption performances of the composite foam. Starting from experimental equilibrium data, a simple thermodynamic analysis based on energy balances was carried out for air conditioning application. Results of the analysis demonstrated that foam technology can guarantee cooling COP up to 7% higher than that estimated for the typical adsorber solution based on loose adsorbent grains inside an aluminum finned-flat tube heat exchanger, which is very promising for practical application in adsorption heat pumps.

In order to reduce greenhouse gas emissions, current and future energy systems need to be made more efficient and sustainable. This change can be accomplished by increasing the penetration of renewable energy sources and using efficient technologies in energy generation systems. One way to improve the operation of the whole energy system is through the generation and end-use sector coupling. Power-to-heat energy conversion and storage technologies, in this view, are enabling technologies that can help in balancing and improving the efficiency of both thermal and electric grids. In the present paper, a comprehensive analysis of the role of heat pumps and thermal energy storage for sector coupling is presented. The main features of the analyzed technologies are presented in the context of smart electric grid, district heating and cooling and multi-carrier energy systems, and recent findings and developments are highlighted. Finally, the technical, social, and economic challenges in the adoption of investigated technologies are discussed.

A clear gap was identified in the literature regarding the in-depth evaluation of scaling up thermal energy storage components. To cover such a gap, a new methodological approach was developed and applied to a novel latent thermal energy storage module. The purpose of this paper is to identify some key aspects to be considered when scaling up the module from lab-scale to full-scale using different performance indicators calculated in both charge and discharge. Different normalization methods were applied to allow an appropriate comparison of the results at both scales. As a result of the scaling up, the theoretical energy storage capacity increases by 52% and 145%, the average charging power increases by 21% and 94%, while the average discharging power decreases by 16% but increases by 36% when mass and volume normalization methods are used, respectively. When normalization by the surface area of heat transfer is used, all of the above performance indicators decrease, especially the average discharging power, which decreases by 49%. Moreover, energy performance in charge and discharge decreases by 17% and 15%, respectively. However, efficiencies related to charging, discharging, and round-trip processes are practically not affected by the scaling up.

In the present paper, the numerical modeling of an innovative latent thermal energy storage unit, suitable for direct integration into the condenser or evaporator of a heat pump is presented. The Modelica language, in the Dymola environment, and TIL libraries were used for the development of a modular model, which is easily re-usable and adaptable to different configurations. Validation of the model was carried out using experimental data under different operating modes and it was subsequently used for the optimization of a design for charging and discharge. In particular, since the storage unit is made up of parallel channels for the heat transfer fluid, refrigerant, and phase change material, their number and distribution were changed to evaluate the effect on heat transfer performance.

The present work aims at the thermodynamic analysis of different working pairs in adsorption heat transformers (AdHT) for low-temperature waste heat upgrade in industrial processes. Two different AdHT configurations have been simulated, namely with and without heat recovery between the adsorbent beds. Ten working pairs, employing different adsorbent materials and four different refrigerants, have been compared at varying working boundary conditions. The effects of heat recovery and the presence of a temperature gradient for heat transfer between sinks/sources and the AdHT components have been analyzed. The achieved results demonstrate the possibility of increasing the overall performance when internal heat recovery is implemented. They also highlight the relevant role played by the existing temperature gradient between heat transfer fluids and components, that strongly affect the real operating cycle of the AdHT and thus its expected performance. Both extremely low, i.e., 40–50 °C, and low (i.e., 80 °C) waste heat source temperatures were investigated at variable ambient temperatures, evaluating the achievable COP and specific energy. The main results demonstrate that optimal performance can be achieved when 40–50 K of temperature difference between waste heat source and ambient temperature are guaranteed. Furthermore, composite sorbents demonstrated to be the most promising adsorbent materials for this application, given their high sorption capacity compared to pure adsorbents, which is reflected in much higher achievable specific energy.