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Using a difference frequency spectrometer we have measured the Q(2) to Q(38) 20[sup 0]0←01[sup 1]0,Σ←Π transitions of carbon dioxide at 296 K and pressures up to 15 kPa. These low pressure spectra were analyzed using both the Voigt model, and an empirical line shape that blends together a hard collision model and a speed dependent Lorentzian profile. The broadening coefficients were obtained with an accuracy of 1% or better. The low density or first order low pressure line mixing parameters were also determined. We have compared both our measured low pressure line-mixing parameters and the complete band spectrum at high pressures with those predicted by a relaxation matrix calculated from an EPG fitting law. Spectra at the highest pressures were recorded using both the difference frequency spectrometer and an FTIR spectrometer, the temperature for the latter experiments being 303 K. The vibrational band intensity and linear pressure shift of the branch as a whole were also measured. © 2000 American Institute of Physics. [ABSTRACT FROM AUTHOR]

The 0310 ← 0110 parallel Q branch of N2O has been studied at 297 K and over the pressure range 1–130 torr. Absorption spectra were recorded using a high resolution (1.5 MHz or 5 × 10-5 cm-1) and high signal-to-noise (>3500:1) mid-infrared spectrometer based on difference-frequency infrared generation in AgGaS2. In the low-pressure range (1–11 torr) we obtained accurate values for the line strengths, the broadening coefficients, the weak mixing coefficients, and the overall shifting of the branch. The medium pressure results, ranging from 23 to 130 torr, were analyzed by treating the band as a whole, using a relaxation matrix formalism, based on an energy gap scaling law. We find, effectively, that only 36% of the rotationally inelastic collisions are associated with Q branch mixing, the rest presumably being associated with Q–P and Q–R mixing in the same vibrational band. The pressure shifting coefficient of the 0310 ← 0110 Q branch as a whole was also determined and found to be 5.8 × 10-3 cm-1/atm towards lower frequencies. [Copyright &y& Elsevier]

A variable-temperature single-pass absorption gas cell with an optical pathlength of 147.5 cm was designed and built for spectroscopic measurements of gases of atmospheric interest. The cell is optically matched to a Bomem DA8.3 Fourier transform spectrometer. A heating/cooling system enveloping the cell, used together with a Neslab ULT-80 thermal bath, allows spectroscopic studies of gas samples at temperatures ranging from 205 to 350 K and at pressures up to 1 atm. Tests of the optical, thermal, and vacuum operation of the system were performed. Spectra of the 3←0 vibrational–rotational band of carbon monoxide were recorded from 225 to 348 K and used to determine the rotational gas temperatures. These results were compared with values obtained using thermocouples, in order to assess the thermal performance of the new system. A second temperature-controlled cell 25-cm long, able to withstand pressures up to 30 atm, was also used to record CO spectra. We have recorded high-resolution FTIR spectra of CO and CO perturbed by N2 at temperatures from 295 to 348 K. The spectra were analyzed to determine pressure broadening and pressure-induced shift coefficients, along with their temperature dependence for several transitions in the second overtone band of CO. The results, especially for self-broadening, are in excellent agreement with other recent measurements reported in the literature. [Copyright &y& Elsevier]