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Current methods for monitoring coating corrosion are limited by their inability to provide real-time data and dependence on external power sources. This study presents a novel in-situ corrosion monitoring system using a solid-liquid triboelectric nanogenerator (TENG) that converts mechanical energy into electrical signals for self-powered sensing. TENG signals and electrochemical impedance spectra were measured on a dopamine-modified lignin-polydimethylsiloxane coating on steel in 1 M NaCl solution under no corrosion, indentation, pitting, and broken conditions, respectively. We extract time-frequency features from the TENG signals to predict the coating's corrosion condition by applying a customised convolutional neural network (CNN). By extracting time-frequency features from the TENG signals and applying a custom CNN, a prediction accuracy of 99 % for corrosion classification was achieved. Furthermore, the CNN regression model predicted coating impedance values with a high coefficient of determination (R² = 0.98), demonstrating its effectiveness in tracking corrosion progression. The developed TENG also facilitates defect localisation via a matrix electrode beneath the coating. Our approach introduces a promising real-time technology for in-situ corrosion monitoring. [Display omitted] • A new real-time corrosion monitoring system was presented using a self-powered triboelectric nanogenerator (TENG). • CNN classification model using TENG current signals achieved 99 % accuracy in identifying corrosion severity. • CNN regression model accurately predicts coating impedance values during corrosion, with a high R² of 0.98. • TENG signals could indicate damage precisely and are feasible for defect localisation. [ABSTRACT FROM AUTHOR]

Corrosion and scaling in metal pipelines are the major issues in the exploitation of geothermal sources. Geothermal fluids are complex mixtures consisting of dissolved gases and high-salinity solutions. This creates very aggressive environments primarily due to the high concentrations of carbon dioxide (CO2), hydrogen sulfide (H2S), chlorides, and other chemical species. Besides, the high temperature of the brines also increases corrosion rates, which can lead to failures related to stress and fatigue corrosion. On the other hand, reinjection of cooled brine exiting the heat exchanger favors the onset of scaling, since the chemicals dissolved in geothermal waters may tend to precipitate promoting inorganic depositions on the casing. Corrosion and scaling phenomena are difficult to detect visually or monitor continuously. Standard techniques based on pH, temperature pressure, electrical resistance measurements, chemistry composition, and physical properties are habitually applied as indirect methods for corrosion rate control. These methods, however, lack enough robustness for accurate and reliable measuring of the corrosion behavior of materials. To address this issue, a novel system has been proposed for the continuous monitoring of corrosion degradation caused by the effect of the geothermal brines. The present work aims to design, develop, and validate a dedicated electrochemical-based test system for online and onsite monitoring of the corrosion rate and scaling growth occurring on different materials exposed to real operating conditions. This system uses non-standard methods based on electrochemical impedance spectroscopy (EIS) to obtain quantitative data related to the material quality. It can be used to track the condition of the pipeline, reducing the operation and maintenance (O&M) costs and shutdown times. By providing early corrosion rate data, this system allows the prediction of failures in critical units of the plant.

Atmospheric corrosion monitoring and evaluation are important means for studying the mechanism and behavior of atmospheric corrosion of metals. In view of the long cycle, cumbersome process, and poor data quality of the traditional outdoor hanging method, an innovative atmospheric corrosion data monitoring system has been designed to detect atmospheric environment data and metal corrosion data on site, and display the detection data of the equipment’s service location to users in real-time in the form of a “dynamic corrosion map”. This can provide a differentiated design for the anti-corrosion of important equipment such as power grid transmission and transformation engineering components Provide effective data support for engineering life prediction and operation and maintenance. At present, the system has been piloted and promoted in some network provinces, achieving good social and economic benefits.

The corrosion of reinforced concrete (RC) is one of the most serious durability problems in civil engineering structures, and the corrosion detection of internal reinforcements is an important basis for structural durability assessment. In this paper, the appropriate frequency required to cause excitation signals in the specimen is first analyzed by means of frequency dispersion curves. Subsequently, the effectiveness of five damage indexes (DIs) is discussed using random corrosion in finite elements. Finally, guided ultrasonic wave (GUW) tests are conducted on reinforcement and RC specimens at different corrosion degrees, and the test results are verified using a theoretical corrosion model. The results show that the larger the covered thickness is at the same frequency, the higher the modal order of the GUW in the frequency dispersion curve is, and the smaller the group velocity is. The SAD is the most sensitive to the corrosion state of the reinforcement compared with the other DIs, and it shows a linear increasing trend with the increase in the corrosion degree of the reinforcement. The SAD values of the RC specimens showed a three-stage change with the increase in the corrosion time, and the time until the appearance of corrosion cracks was increased with the increase in the covered thickness. It can be seen that increasing the covered thickness is an effective method to delay the time until the appearance of corrosion cracks in RC specimens.

Copyright of Corrosion & Protection in Petrochemical Industry is the property of Corrosion & Protection in Petrochemical Industry Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Electromagnetic techniques are widely employed for corrosion detection, and their performance for inspection of corrosion is well established. However, limited work is carried out on the development and reliability of smart corrosion monitoring devices for tracking internal or buried thickness loss due to corrosion remotely. A novel smart magnetic corrosion transducer is developed for long-term monitoring of thickness loss due to corrosion at critical locations. The reliability of the transducer is enhanced by using a dissimilar active redundancy approach. The improved corrosion monitor has been tested in the ambient environment for seven months to evaluate the stability against environmental factors and degradation. The monitor is found to show great sensitivity to detect defects due to corrosion. Detection of anomalous patterns in the time series data received from the monitors is accomplished by using Pearson's correlation coefficient. The critical component of the monitor is identified at the end of the test. Research findings reveal that, compared to the existing corrosion monitoring techniques in the industry, the detection and isolation of faulty sensor features introduced in this study can contribute to reliable monitoring of thickness loss due to corrosion in ferromagnetic structures over an extended period of time. [ABSTRACT FROM AUTHOR]

The use of fibers in Reinforced Concrete (RC) elements changes their cracking pattern, leading to narrower and more closely spaced cracks. In addition, the presence of fibers can improve the steel‐to‐concrete bond behavior reducing the steel‐to‐concrete interface damage after cracking. Cracks and steel‐to‐concrete interface damage work like paths, for aggressive agents, to reach the rebar in cracking elements, reducing the initiation period of the corrosion process, and favoring the corrosion at the intersection between cracks and reinforcement. In this context, this article discusses an experimental program on tension ties mechanically cracked and exposed to a chloride‐rich environment with the purpose to check and eventually adequate the typical electrochemical measurements, used in the case of RC elements, for Steel Fiber Reinforced Concrete (SFRC). Adjustments related to degradation morphology and interference of steel fibers are proposed and used on Fiber Reinforced Concrete (FRC) elements for monitoring the influence of cracks and fibers on corrosion propagation. Finally, these proposed modifications were checked and validated against the results obtained by monitoring SFRC beams in the cracked stage. [ABSTRACT FROM AUTHOR]

The protective behaviour of ZrO2-3%molY2O3 sol–gel coatings, deposited with an immersion coating technique on 9Cr-1Mo P91 steel, was evaluated with corrosion monitoring sensors using the electrochemical impedance spectroscopy technique. The tests were carried out in contact with solar salt at 500 °C for a maximum of 2000 h. The results showed the highly protective behaviour of the coating, with the corrosion process in the coated system being controlled by the diffusion of charged particles through the protective layer. The coating acts by limiting the transport of ions and slowing down the corrosive process. The system allowed a reduction in the corrosion rate of uncoated P91 steel. The estimated corrosion rate of 22.62 μm·year−1 is lower than that accepted for in-service operations. The proposed ZrO2-3%molY2O3 sol–gel coatings are an option to mitigate the corrosion processes caused by the molten salts in concentrated solar power plants. [ABSTRACT FROM AUTHOR]

Concrete structures are considered as durable construction material, but corrosion of the embedded steel reinforcement occurs under chloride exposure as concrete has porous properties. Herein, a cyclic drying–wetting test was performed for two years using saltwater to accelerate steel corrosion in a reinforced concrete (RC) member. The open-circuit potential (OCP) was measured using a newly developed and replaceable agar sensor. The corrosion potential was measured considering the chloride concentration, water-to-cement (w/c) ratio, and cover depth at three levels. Furthermore, its relationships with influential parameters were evaluated using averaged OCP results. The measured OCP showed a linear relationship with the cover depth, and this tendency was more distinct with increasing retention period and higher chloride concentration. For the highest w/c ratio (0.6), values below −100 mV were monitored after only six months regardless of the cover depth, and values below the critical potential level (−450 mV) were evaluated at lower cover depths (30 and 45 mm). The results of regression analysis considering the exposure environment showed a clear relationship in the case of high chloride concentration (7.0%). A linear relationship between cover depth and OCP was derived with a reasonable determination coefficient ranging from 0.614 to 0.771. [ABSTRACT FROM AUTHOR]

Corrosion Monitoring as Proof of Efficiency for the Repair Method W‐Cl/8.3 In Germany, the repair of parking and traffic infrastructure due to chloride‐induced reinforcement corrosion causes annual costs of some Billion Euros. In addition, in the case of parking structures further significant costs will arise from use restrictions and loss of earnings during this time. Therefore, there is a growing need for both fast and economic repair measures for chloride‐induced reinforcement corrosion. One possible approach is the repair method W‐Cl according to RL‐SIB [1] or method 8.3 according to TR‐IH [2] respectively, for which no chloride‐contaminated concrete needs to be removed. However, this repair method has a significantly higher risk of failure than conventional concrete repair methods and consequently, it can only be carried out in combination with an adequate corrosion monitoring system. In this report a study on the effectiveness of repair method 8.3 is presented which is based on the results of 130 corrosion sensors from five different reference objects. The sensor setup for corrosion monitoring is explained and different criteria for the assessment of the effectiveness are presented and compared. Finally, the data is analyzed with respect to the mechanism of action and limitations of the repair method. [ABSTRACT FROM AUTHOR]

A moving electrochemical probe technique is developed for probing coating damages on underground pipelines installed by horizontal directional drilling (HDD) and for assessing the efficiency of cathodic protection (CP) through measuring local polarisation currents and local electrochemical impedance spectroscopy (EIS). The capability and accuracy of the probe in detecting coating defects have been evaluated, and compared with current techniques, using a simulated HDD pipe in a borehole. Results show that the probe is able to detect the locations of coating defects over the HDD pipe and that the capacitance of coating defects calculated from EIS data is a rather accurate parameter for defect size determination. The probe has also been used to apply local CP over coating defects for enhancing local corrosion protection. Preliminary field testing on a section of simulated HDD pipe has also shown reasonable accuracy of the probe in determining coating defect locations and sizes. [ABSTRACT FROM AUTHOR]

The influence of liquid aggressive medium on a polyurethane paint coating (PC) is studied by the method of digital speckle pattern interferometry. For this purpose, we developed an experimental installation based on the Twyman–Green interferometer for the corrosion monitoring of PC. The installation was used for recording and subsequent processing of the difference patterns of speckle interferograms (SI) of the coating surface under the action of a 3% NaCl solution for 7, 14, and 21 days. It is shown that the difference patterns of SI can be used to analyze the time dependences of the deformed state of the PC surface and the growth rates of corrosion defects and exfoliations. [ABSTRACT FROM AUTHOR]

The conventional way of studying corrosion in marine environments is by installing corrosion coupons. Instead, this paper presents an experimental field study using an unattended corrosion sensor developed on the basis of ultrasound (US) technology to assess the thickness loss caused by general atmospheric corrosion on land close to the sea (coastal region). The system described here uses FPGA, low-power microcontroller, analog front-end devices in the sensor node, and a Beaglebone black wireless board for posting data to a server. The overall system is small, operates at low power, and was deployed at Gran Canaria to detect the thickness loss of an S355 steel sample and consequently estimate the corrosion rate. This experiment aims to demonstrate the system's viability in marine environments and its potential to monitor corrosion in offshore wind turbines. In a day, the system takes four sets of measurements in 6 hour intervals, and each set consists of 5 consecutive measurements. Over the course of 5 months, the proposed experiment allowed for us to continuously monitor the corrosion rate in an equivalent corrosion process to an average thickness loss rate of 0.134 mm/year. [ABSTRACT FROM AUTHOR]

For the corrosion problems of oil refinery unit, the corrosive factors, control requirements and corrosion-prone area of the facilities are analyzed. The process anticorrosion technology system and corrosion monitoring technology system are established to grasp the corrosion and control status of the facilities, which can be conducive for the adjustment and optimization of the corrosion control measures, and for the safe and long-term operation of the facilities. [ABSTRACT FROM AUTHOR]

Offshore wind turbines operating in harsh marine environments are at risk of corrosion. Thickness loss and perforation caused by corrosion can lead to component failure or structure collapse. An environmental test setup was constructed to simulate various marine corrosion zones. Several experimental studies were conducted on Q355 steel, commonly used in offshore wind turbines. The mass loss and electrochemical properties of the steel specimens were analyzed, including electrochemical impedance spectra and polarization curves. The results indicate that corrosion remains stable in the immersion and tidal zones, whereas corrosion in the splash zone is the most severe, with a corrosion rate as high as 0.70 mm/a. A significant macroscopic corrosion cell effect was observed on the vertical steel strip, accelerating corrosion in the splash zone and at the low tide line. The corrosion product compositions and corrosion morphology of each corrosion zone were characterized and analyzed. Furthermore, a corrosion monitoring sensor based on electromechanical impedance was proposed. A prediction model for the mass loss rate of vertical steel strips was developed based on the conductance peak frequency. This study elucidates the corrosion evolution of wind turbine structural steel and proposes a comprehensive steel corrosion monitoring solution. • The corrosion evolution of Q355 steel under various corrosion zones was elucidated. • Macroscopic corrosion cell effects on vertical steel strips were revealed. • A quantitative corrosion monitoring method for offshore wind turbines was proposed. [ABSTRACT FROM AUTHOR]

An electrode array probe, with a novel approach, has been specifically designed to enable the in-situ field monitoring of multiple forms of localised corrosion of steel exposed to marine environments. The initiation and propagation of localised corrosion within the crevice area as well as at the steel weldment were visualised and evaluated over one-year field exposure at two different marine locations in Australia. The results show the varied initiation and propagation behaviour of crevice corrosion and weldment corrosion on steel, which provide experimental evidence for 'bi-modal' behaviour and the change-over of corrosion modes in extended periods of marine exposure. • A novel corrosion probe enables the in-situ field monitoring of localised marine corrosion. • 61-week field monitoring of three types of co-existing localised corrosion in the sea. • Localised corrosion rates were significantly higher than general marine corrosion. • Experimental evidence has been obtained showing 'bi-modal' marine corrosion behaviour. • The new probe is a promising tool for localised corrosion monitoring in the sea. [ABSTRACT FROM AUTHOR]

Quantitative monitoring of steel corrosion plays a crucial role in evaluating structural safety and predicting structural performance. The electromechanical impedance (EMI) technique has already emerged for uniform corrosion monitoring. This study explores its potential for pitting corrosion monitoring. Specifically, two EMI-based sensor designs were proposed, namely the cylinder and the tube structures. Finite element models were developed to analyze the influence of the pit's location, morphology parameters, as well as the random distribution of multiple pits, on the conductance peak frequency of sensors. The computer numerical controlled processes were employed to create random pits on sensors. Experimental results revealed that different distributions of pits correspond to distinct conductance peak frequencies, even with the same mass loss. Additionally, the tubular sensor exhibited reduced sensitivity to pits distribution compared to the cylindrical sensor. This is beneficial for accurately predicting mass loss induced by random pitting. This paper enhances the capability of EMI-based sensors for quantitatively monitoring pitting corrosion by focusing on structural design aspects. [Display omitted] • The quantitative corrosion monitoring capability of EMI-based sensors under pitting corrosion was investigated. • The finite element models of the sensors with random pitting corrosion were established and validated by experiment. • The prediction accuracy of the sensor for mass loss was improved by optimizing its structure. [ABSTRACT FROM AUTHOR]

Monitoring the corrosion of steel rebars is paramount to ensuring the safety and serviceability of reinforced concrete (RC) structures. Conventional electro-chemical techniques can provide an overall estimate of the extent of corrosion. However, a detailed account of the extent of corrosion would help in understanding the residual strength of corroding RC structures. A passive wave-based technique such as acoustic emissions can identify the location of corrosion but always requires the presence of transducers on the structure. In active wave-based techniques, the structure is excited through a pulse excitation and their subsequent response to this excitation is measured. Thus, for active techniques, the transducers need not always be present in the structure. In guided wave ultrasonics, the excitation pulse is imparted through a waveguide to determine the state of corrosion. This technique relies on parameters such as time of flight or attenuation of the incident signal to predict the state of corrosion. These parameters can be susceptible to uncertainties in the transducer of ultrasonic coupling. In the present study, concrete specimens with embedded steel bars have been subjected to accelerated corrosion. They have been monitored with a combination of active and passive techniques. The received signals are analyzed through a modified S-Transform-based time-frequency approach to obtain a range of modes that propagate through the specimen. The changes in the modal composition of the guided wave signals due to corrosion are parameterized and correlated to various stages of corrosion. A holistic understanding of the stages of corrosion is developed by the inclusion of acoustic emission hits to guided wave parameters. Based on the Guided Wave Ultrasonics and acoustic emission parameters, corrosion has been classified into Initiation, Intermediate, and Advanced. Subsequently, destructive tests have been performed to measure the residual strength of the corroded bars. Thus, this paper presents a novel proof of concept study for monitoring corrosion with Guided Wave Ultrasonics and acoustic emissions. [ABSTRACT FROM AUTHOR]

The sulfuric acid attack is a common form of degradation of reinforced concrete in contact with industrial wastewater, mine water, acid rain, or in sewage treatment stations. In this work, new pH-sensitive IrOx electrodes were developed for monitoring the pH inside mortar or concrete. To test their ability, the pH sensors were embedded in mortar samples at different depths and the samples were exposed to sulfuric acid solution. In another set of experiments, iron wires were placed at the same depths inside similar mortar samples and their corrosion was monitored as the acid attacked the mortar. Severe acid attack led to cement dissolution and formation of gypsum. The new pH sensors succeeded in measuring the pH changes inside the mortars. The pH gradient, from the high acid environment to the high alkaline mortar interior, occurred in a narrow region. Corrosion of the iron electrodes started only when the acidic solution was in their close vicinity. [ABSTRACT FROM AUTHOR]

Various corrosion monitoring methods are used in order to monitor the corrosion state of gas object equipment. The main parameter for evaluation is corrosion rate. In addition to the main gravimetric method, two more determination methods are used: an electrical resistance ER-method, and linear polarization resistance LPR-method. In the course of testing ER- and LPR-probes the possibility of their use in corrosive-aggressive conditions of hydrocarbon processing facilities, as well as the influence of various factors on the data obtained for corrosion rate are evaluated. [ABSTRACT FROM AUTHOR]

Reinforcement corrosion is a major culprit that undermines the service life of reinforced concrete (RC) structures. It costs billions of dollars each year in the US alone and negatively impacts safety, reliability, resilience, and environmental performance of RC infrastructure. Corrosion monitoring of steel rebar is critical to provide early warning of deficiency, enable timely and effective maintenance strategies, and prevent catastrophes associated with premature failure of RC structures. To improve corrosion monitoring in the engineering practice, this work comprehensively reviews the state of the art of five major types of techniques, that is, electrochemical sensors, optical fiber sensors, sensors based on elastic wave methods, sensing based on electromagnetic methods, and untouched sensors. Each type of technique is systematically divided into sub-categories based on the sensing principle and key characteristics. For each sensor type, its maturity, application range, and the problems that hinder its application are discussed, aimed to provide guidance in selecting the appropriate sensors for specific engineering applications. This work concludes with an overview of opportunities and challenges, including the following six aspects for future research: spatial resolution, sensitivity, and measurement range; reliability and interpretation of the measurement; sensor selection based on three corrosion stages of steel rebar; long-term stability and service life; cost-efficiency of the sensing system; and monitoring of existing structure. [ABSTRACT FROM AUTHOR]

Corrosion probes designed based on an electrochemically integrated multi-electrode array have been evaluated in an extensive field and laboratory evaluation program in order to identify their capabilities in visualizing and probing critical forms of buried steel corrosion, in particular, corrosion under disbonded coatings (CDC) and stray current corrosion. Probes of different designs were installed in the pipeline field to simulate and measure the influence of stray currents and cathodic protection (CP) deficiency on corrosion as well as CDC. Accelerated laboratory tests were also performed, where electrochemical measurements can be taken more frequently and the corrosion condition can be more precisely controlled. Corrosion patterns and rates were calculated with a sensitivity in the order of 10 µm/year. Testing results correlated reasonably well with long-term pipeline corrosion behavior. On the other hand, single element electrical resistance probes were not able to simulate or measure CDC occurring on pipeline surfaces. These results demonstrate the capability and some unique advantages of the electrode array probes for monitoring pipeline corrosion.

Corrosion of metal structures is often prevented using cathodic protection systems, that employ sacrificial anodes that corrode more preferentially relative to the metal to be protected. In-situ monitoring of these sacrificial anodes during early stages of their useful life could offer several insights into deterioration of the material surrounding the infrastructure as well as serve as early warning indicator for preventive maintenance of critical infrastructure. In this article, we present an Electro-Mechanical Impedance (EMI) measurement-based technique to quantify extent of corrosion of a zinc sacrificial anode without manual intervention. The detection apparatus consists of a lead zirconate titanate (PZT) transducer affixed onto a circular zinc disc, with waterproofing epoxy protecting the transducer element when the assembly is submerged in liquid electrolyte (salt solution) for accelerated corrosion by means of impressed current. We develop an analytical model for discerning the extent of corrosion by monitoring shift in resonance frequency for in-plane radial expansion mode of the disc. The model presented here accurately captures the nonlinearity introduced by partial delamination of the corrosion product (zinc oxide) from the disc, and shows excellent agreement with experimental results. Our work establishes the efficacy of the proposed technique for monitoring the state of health of sacrificial anodes in their early stage of deterioration and could thus be widely adopted for structural health monitoring applications within the internet of things.

Collecting data from corrosion sensors in reinforced concrete structures demands intensive labor work, therefore measurements are only performed occasionally. A low-cost Wireless Sensor Network/Node (WSN) will eliminate the need for manual work and allow for continuous measurements if needed. For a distributed WSN over a large area, a concerning issue is how to power such devices. This paper, therefore, investigates the use of a reinforced concrete battery for powering WSNs. Results obtained from a real-world immersed tunnel, which has hundreds of electrochemical based corrosion sensors embedded into the reinforced concrete structure, shows that sufficient energy can be harvested from the sensors, to perform wireless transmission of corrosion data to a base-station. With an open circuit potential of 975 mV, the maximum harvested output power is $12.4~\mu \text{W}$ , while the minimum measured output power is $1~\mu \text{W}$. The results also show that $8.82~\mu \text{W}$ , with an open circuit potential of 727 mV, can be directly harvested from the reinforcement steel itself. Due to the fact that the steel volume can work as a large battery anode, a longer lifetime for the energy source is expected. Furthermore, we show that the harvested energy from the corrosion sensors will induce a galvanic corrosion rate of only $3.7~\mu \text{m}$ /year, when transmitting the corrosion data once a month. This indicates that there is no risk to the structural integrity when using this energy source. [ABSTRACT FROM AUTHOR]

This article proposes a new technique of monitoring neutral axis positions and deflection of Reinforced Concrete (RC) beam during corrosion of steel reinforcement using macro-strain measurements of distributed long-gauge sensors. A different group of distributed long-gauge Packaged Carbon Fiber Line (PCFL) sensors with self-compensation and effective packaging system is installed on the compression and tension fibers of the concrete surface and steel reinforcements of RC beam to verify the proposed method experimentally. An accelerated corrosion method utilizing a salt solution and the constant current was used to achieve the required corrosion levels. The estimated deflection measured by the developed method is compared with the results using Linear Variable Displacement Transducer (LVDTs). It has been demonstrated that long-gauge PCFL sensors could provide the same accuracy. The distributed measured strains were utilized to evaluate the deterioration of the structure's health with the advance of corrosion. Based on corrosion monitoring experimental results, it can be confirmed that using distributed PCFL sensors mounted on steel reinforcements or concrete surface, the locations and progress of the damage with corrosion time can be detected effectively. The maximum error in the estimated deflection from PCFL sensors mounted on the concrete surface compared to the LVDTs before the onset and after 24 h of accelerated corrosion was 0.5% and 2.5%, respectively. [ABSTRACT FROM AUTHOR]

Copyright of Natural Gas & Oil is the property of Editorial Department of Natural Gas & Oil and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Corrosion of water distribution system is a significant issue causing problems with quality, safety and continuity of distribution. The changes of corrosion rates of the water distribution systems in Cracow made of carbon steel were investigated by analysis of online corrosion monitoring system results. Corrosion rates were determined using the linear polarization method. The impact of rain, temperatures, conductivity, dissolved oxygen content on corrosion rate were characterized. The corrosivity of different water sources like mountain water, underground water or river water were indicated. The possible actions for reducing corrosion losses were characterized. Results show that pollution of the environment in the form of acid rain and runoff from agriculture as well as the type of the source water has significant influence on corrosion of water distribution system. Corrosion monitoring system gives possibility of controlling corrosion rate by mixing waters from different sources in the way to obtain less corrosive mixture (see Fig. 8).

Based on high-stress characteristics of prestressed anchor cables, this paper develops an axial-distributed testing method to test corrosion damage of prestressed anchor cables. The positioning accuracy and corrosion range of an axial-distributed optical fiber sensor is studied, and its mathematical model between corrosion mass loss and axial fiber strain is established. The experimental results show that the fiber strain from an axial-distributed sensor enables one to reflect the corrosion rate along a prestressed anchor. Moreover, it has a greater sensitivity when an anchored cable has a higher stress. The mathematical model between corrosion mass loss and axial fiber strain is determined to be ε=4723.64ρ+2592.95. The corrosion location along the anchor cable is characterized by axial fiber strain. Therefore, this work provides an insight for cable corrosion.

Steel corrosion in concrete infrastructures is of worldwide interest. This paper reports the monitoring of concrete prestressed bridge infrastructures by autonomous sensors based on the RFID technology. Embedded autonomous sensors in concrete were produced for this purpose and tested in a laboratory environment. Subsequent tests in real environments are in progress. [ABSTRACT FROM AUTHOR]

Abstract Frequently stainless steel AISI 316L aseptic tanks have their passivity and corrosion resistance properties degraded by biofilm formation and localized corrosion processes. Thereby, maintenance projects are performed to repair the surface in food-grade product contact to obtain an aseptic property as defined by ASME BPE. However, the on-site non-destructive testing are limited to the liquid penetrant examination and the average roughness measurement. The on-site open circuit potential and on-site cyclic polarization measurements were conducted using a portable electrochemical minicell. The level of passivation was quantified on the tank surface, and it was performed before and after the repairing maintenance protocol be made. The results of the on-site electrochemical measurements showed a clear difference between as-degraded and repaired surfaces, indicating a sensible response to aseptic surface inspection. The on-site open circuit potential together with the on-site cyclic polarization were considered an advanced tool to support the maintenance projects of the AISI 316L aseptic surfaces.

Permanently installed sensors are a cost-effective solution for corrosion monitoring due to their advantages, such as less human interference and continuous data acquisition. Some of the most widely used permanently installed corrosion sensors are ultrasonic thickness (UT) gauges. However, UT sensors are limited by the need for coupling agents between pipe surfaces and sensors. The magnetic eddy current (MEC) method, on the other hand, does not require couplant and can be used over insulations. With the development of powerful rare earth magnets, MEC sensors with low power consumption are possible, and there is the prospect of using them as permanently installed sensors. A novel wireless magnetic eddy current sensor has been designed and optimized using finite element simulation. Sensitivity studies of the sensors reveal that the excitation frequency is a critical parameter for the detection of corrosion defects. An in-depth explanation of the relationship between the sensitivity of the sensor and the excitation frequency is presented in this paper. The results of an accelerated corrosion test, conducted to simulate the service environment of the sensor, are also discussed. It was observed that the sensor signals are very sensitive to corrosion defects and show no subtle differences due to temperature and humidity changes. [ABSTRACT FROM AUTHOR]

Copyright of Coatings & Protection / Tuceng yu Fanghu is the property of Coating & Protection Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The ultrasound technique is a well-known non-destructive and efficient testing method for on-line corrosion monitoring. Wall thickness loss rate is the major parameter that defines the corrosion process in this approach. This paper presents a smart corrosion monitoring system for offshore wind turbines based on the ultrasound pulse-echo technique. The solution is first developed as an ultrasound testbed with the aim of upgrading it into a low-cost and low-power miniaturized system to be deployed inside offshore wind turbines. This paper discusses different important stages of the presented monitoring system as design methodology, the precision of the measurements, and system performance verification. The obtained results during the testing of a variety of samples show meaningful information about the thickness loss due to corrosion. Furthermore, the developed system allows us to measure the Time-of-Flight (ToF) with high precision on steel samples of different thicknesses and on coated steel samples using the offshore standard coating NORSOK 7A. [ABSTRACT FROM AUTHOR]

The aim of the study was to define the influence of microstructural properties on the electrochemical properties of copper in four different forms: copper in sheet form, copper doped with phosphorus, electroplated copper and copper wire. Open circuit potential and polarization resistance measurements were carried out in order to determine the electrochemical properties and corrosion rates of copper in 0.1 M NaCl solution in oxic conditions at ambient temperature. Statistical evaluation of the electrochemical data was performed in order to differentiate between the various forms of copper samples. Microstructural and electrochemical investigations were combined with electron microscopy and Raman analysis of the corrosion products after immersion of the copper samples in a 0.1 M NaCl solution for 30 days. The various morphologies of copper corrosion products were identified and analyzed by Raman spectroscopy for the various forms of copper. [ABSTRACT FROM AUTHOR]

This study examines the potential use of Electrolytic Manganese Dioxide (EMD) residue as a replacement of cement (20%wt by cement weight) in construction materials to provide anticorrosion protection on reinforcing steel and improve the strength of cementitious materials under sulfate attack. To assess the corrosion parameters, the constructed building materials were immersed in a 5%wt sulfate salt (Na _2 SO _4 ), while concrete samples incorporating 20%wt EMD were prepared and subjected to mechanical, porosity and thermal tests. Moreover, SEM images were obtained in order to examine the microstructure of concrete and the extent of damage caused by sulfate ions. The results demonstrate that the inclusion of EMD caused a notable rise in the corrosion of steel bars within cement mortars, as well as a decrease in the mechanical strength of the building materials. Overall, the experimental outcomes of the study suggest that the incorporation of high volume (20%wt) EMD residue leads to the degradation of all measured properties.

Globally, corrosion is the costliest cause of the deterioration of metallic and concrete structures, leading to significant financial losses and unexpected loss of life. Therefore, corrosion monitoring is vital to the assessment of structures’ residual performance and for the identification of pathologies in early stages for the predictive maintenance of facilities. However, the high price tag on available corrosion monitoring systems leads to their exclusive use for structural health monitoring applications, especially for atmospheric corrosion detection in civil structures. In this paper a systematic literature review is provided on the state-of-the-art electrochemical methods and physical methods used so far for corrosion monitoring compatible with low-cost sensors and data acquisition devices for metallic and concrete structures. In addition, special attention is paid to the use of these devices for corrosion monitoring and detection for in situ applications in different industries. This analysis demonstrates the possible applications of low-cost sensors in the corrosion monitoring sector. In addition, this study provides scholars with preferred techniques and the most common microcontrollers, such as Arduino, to overcome the corrosion monitoring difficulties in the construction industry.

Concrete structures are considered as durable construction material, but corrosion of the embedded steel reinforcement occurs under chloride exposure as concrete has porous properties. Herein, a cyclic drying–wetting test was performed for two years using saltwater to accelerate steel corrosion in a reinforced concrete (RC) member. The open-circuit potential (OCP) was measured using a newly developed and replaceable agar sensor. The corrosion potential was measured considering the chloride concentration, water-to-cement (w/c) ratio, and cover depth at three levels. Furthermore, its relationships with influential parameters were evaluated using averaged OCP results. The measured OCP showed a linear relationship with the cover depth, and this tendency was more distinct with increasing retention period and higher chloride concentration. For the highest w/c ratio (0.6), values below −100 mV were monitored after only six months regardless of the cover depth, and values below the critical potential level (−450 mV) were evaluated at lower cover depths (30 and 45 mm). The results of regression analysis considering the exposure environment showed a clear relationship in the case of high chloride concentration (7.0%). A linear relationship between cover depth and OCP was derived with a reasonable determination coefficient ranging from 0.614 to 0.771.

The multifunctional optimization of traditional coating materials represents a pivotal strategy for expanding their applicability. Herein, we introduce terbium as an electrolyte additive during the plasma electrolytic oxidation process for alumina coating fabrication, aimed at refining both the porous structure and overall performance of the coating. Notably, the core reaction concludes in just 10 min. The resultant terbium-enhanced alumina coating exhibits a more homogeneous and denser surface structure, showcasing superior corrosion resistance compared to conventional coatings. Additionally, the incorporation of terbium endows the coating with anticipated photoluminescent properties. This advantageous combination of corrosion resistance and photoluminescence makes the coating ideal for protecting metallic materials from corrosion and shows great potential for monitoring corrosion in extreme conditions on-site. The incorporation of Tb not only significantly enhances the corrosion resistance of the PEO coating but also imparts photoluminescent properties to it. This dual functionality holds promising potential for the coating's application in in-situ corrosion monitoring. [Display omitted] • A luminescent coating was grown in-situ on AA 1060 substrate through plasma electrolytic oxidation. • The core reaction involved in the synthesis process of the coating took no more than 10 min. • The introduction of Tb improved the microstructure and corrosion resistance of the PEO coating. • The Tb-reinforced coating shows its potential applications in in-situ corrosion monitoring. [ABSTRACT FROM AUTHOR]

Abstarct: —Many gas and gas condensate fields (Bovanenkovskoe, Urengoiskoe, Kirinskoe, etc.) are distinguished by the presence of corrosive carbon dioxide in the extracted products, which, in the presence of moisture, leads to the formation of local corrosion damage (pits and their accumulations). One of the methods for monitoring the corrosion state of pipelines is in-line inspection (ILI), carried out by the magnetic flux leakage method. ILI is especially relevant for underground and underwater pipelines when the use of other methods of corrosion monitoring is limited or costly. Under conditions of gas production, unlike oil production, corrosion can take place both along the lower part of the pipe (6‑hour corrosion) and during condensation of moisture on the upper part of the pipe (12-hour corrosion). An important process is the correct planning of the ILI, the subsequent processing and interpretation of the obtained data set, which should be carried out taking into account the peculiarities of the development of carbon dioxide corrosion in the gas pipeline and in a comparative analysis with other corrosion monitoring data. When interpreting the ILI data, one should take into account the mechanisms of corrosion development, operating conditions (path profile, etc.), and corrosion monitoring data obtained by other testing methods (simulation tests, results obtained at other, adjacent sections of pipelines, etc.). Correct and useful information according to ILI data will ensure reliable protection of gas pipelines and planning of measures to protect them against internal corrosion. [ABSTRACT FROM AUTHOR]

For many industrial applications, corrosion is a life-limiting phenomenon and therefore requires careful consideration and rigorous experimental testing before structural materials can be reliably deployed, particularly in harsh chemical environments. The traditional approach to measuring corrosion requires exposing many samples to the intended environment and then extracting them individually at discrete intervals for postexposure characterization. This approach does not provide a high degree of temporal resolution, nor does it provide any real-time information regarding dynamic changes in corrosion rates. Developing an online corrosion monitor capable of surviving harsh chemical environments could provide valuable information regarding the structural health of components and changing process conditions that could accelerate corrosion. To this end, a corrosion sensor was developed based on a pressure-driven Fabry-Pérot cavity (FPC). This sensor uses a pressure control system to internally pressurize the FPC formed between the sensor’s housing and a metal-embedded singlemode optical fiber. Simultaneous measurement of the change in FPC length using low-coherence interferometry and the applied pressure enables the calculation of the relative changes in the sensor’s diaphragm thickness due to corrosion on its outer surface. Measurements were made in situ while actively corroding the sensor and were validated against surveillance specimens that were corroded simultaneously. The uncertainties in the measured corrosion were analyzed using error propagation of the uncertainties in the measured pressures and displacements and were found to be <1% of the initial diaphragm thickness. [ABSTRACT FROM AUTHOR]