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Heavy metal toxicity in water is a serious problem that may have harmful effects on human health and the ecosystem. Lead [Pb(II)] and cadmium [Cd(II)] are two such heavy metal ions, present in water, whose severity is well-known and well-studied. In the current research, magnetic biochar composite (MBC) is studied as an adsorbent material for the effective removal of lead and cadmium ions from water solutions. Magnetite (Fe3O4) nanoparticles and pine-needle-derived ultrasonicated magnetic biochar were used in different weight ratios to prepare APTES (3-aminopropyl triethoxysilane)-functionalized MBC (FMBC). An average crystalline size of ~10 nm for magnetite NPs was obtained via XRD analysis. The adsorption characteristics of both Pb(II) and Cd(II) ions were investigated in a batch experiment. The FTIR spectra of raw biochar, MBC, FMBC, and metal-loaded FMBC were obtained at different stages. The decrease in the intensity of the –NH2 functional group in the FTIR spectra of the residue confirmed the successful adsorption of heavy metal ions. The SEM-EDX spectra of the residue showed the uniform adsorption of Pb(II) and Cd(II) heavy metal ions onto the surface of the adsorbent. Magnetic biochar composite (MBC) was found to be a very effective adsorbent at basic pH, as a maximum of 97% instantaneous heavy metal removal was observed for both ions in synthetic water solutions. The Langmuir isotherm model predicted the monolayer adsorption and good affinity between the metal ions and adsorbent. The prepared MBC is low-cost, environmentally friendly, and it has shown good adsorption performance. Therefore, our study suggests that the magnetic biochar composite under study is an effective adsorbent for lead and cadmium metal ion removal from aqueous solutions at normal room temperature. Only a few hundred milligrams of the adsorbent dose is sufficient to remove higher concentrations (~100 ppm) of lead and cadmium at basic pH conditions of aqueous solutions. [ABSTRACT FROM AUTHOR]

Barium titanate-polystyrene polymer composite (BaTiO3/PS) was synthesized by the solvent evaporation method while filler barium titanate was synthesized by the solid-state reaction method. The prepared sample was characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). The crystalline nature and phase of the prepared samples were confirmed by X-ray diffraction analysis. The average particle sizes of BaTiO3 and BaTiO3/PS were estimated as 161 nm and 119 nm by SEM morphographs. The Williamson–Hall (W–H), size–strain plot (SSP), and Halder–Wagner (H-W) techniques were employed to determine the crystallite size and inherent lattice strain using X-ray peak broadening analyses. The values of crystallite size computed using the modified Debye–Scherrer equation, W–H approach, and SSP are extremely similar and strongly correlated. It was also observed that crystallite size and lattice strain were not highly correlated. [ABSTRACT FROM AUTHOR]

The present trend of miniaturization in various electronic devices has caused higher heat generation per unit area. Dissipation of highly concentrated heat from these devices is essentially required to ensure their safe and prolonged use. Therefore, consistent efforts are made to upgrade the cooling technology to meet the current requirements. The microchannel heat sink (MCHS) has gained much attention due to its inherent property of a higher surface area-to-volume ratio. The thermo-hydraulic performance of MCHS has been further improved by several methods including active and passive techniques. In this work, a comprehensive review of the literature is presented to discuss the prominent design modifications done in the MCHS to enhance the heat dissipation capacity using single-phase fluid flow. It was commonly observed that heat transfer enhancement usually occurs at the cost of pressure drop penalty and other flow complications; therefore, relevant parameters have been discussed to evaluate the design's efficacy. [ABSTRACT FROM AUTHOR]

This research article aims to provide a detailed numerical study of the multifaceted impact of S-shaped and broken arc roughness on solar air heaters. Therefore, a strong comparison was made between the modified heaters and smooth heaters for Reynolds numbers ranging from 2 000-22 000. Also, the impact of two parameters, i.e. pitch and gap was analyzed to optimize the performance of the heater. The gap varies from 0.3 mm to 0.9 mm in both types of ribs with a step size of 0.2 mm. Afterwards, the pitch distance between both types of roughness was varied from 15 mm to 25 mm in the step size of 5 mm. Notably, it has been observed that among all the considered configurations, the gap length of 0.9 mm and pitch length of 25 mm have shown significant improvements in heat transfer characteristics. The specific combination of the gap of 0.9 mm and pitch of 25 mm has demonstrated better heat transfer capabilities at the expense of an increased friction factor. Lastly, the thermal performance factor of the systems was analyzed and reported. It was reported that the pitch length of 25 mm and gap length of 0.9 mm have shown a maximum thermal performance factor value from 2.9 to 3.3, while the pitch length of 25 mm and gap length of 0.3 mm have depicted the lowest thermal performance factor value. In terms of the overall performance, i.e. the thermal performance factor, the combination with a gap of 0.9 mm and pitch of 25 mm has shown the best performance, while a gap of 0.3 mm and pitch of 25 mm has yielded the worst performance. [ABSTRACT FROM AUTHOR]

As the cost of fuel rises, designing efficient solar air heaters (SAH) becomes increasingly important. By artificially roughening the absorber plate, solar air heaters' performance can be augmented. Turbulators in different forms like ribs, delta winglets, vortex generators, etc. have been introduced to create local wall turbulence or for vortex generation. In the present work, a numerical investigation on a solar air heater has been conducted to examine the effect of three distinct turbulators (namely D-shaped, reverse D- and U-shaped) on the SAH thermo-hydraulic performance. The simulation has been carried out using the computational fluid dynamics, an advanced and modern simulation technique for Reynolds numbers ranging from 4000 to 18000 (turbulent airflow). For the purpose of comparison, constant ratios of turbulator height/hydraulic diameter and pitch/turbulator height, of 0.021 and 14.28, respectively, were adopted for all SAH configurations. Furthermore, the fluid flow has also been analyzed using turbulence kinetic energy and velocity contours. It was observed that the U-shaped turbulator has the highest value of Nusselt number followed by D-shaped and reverse D-shaped turbulators. However, in terms of friction factor, the D-shaped configuration has the highest value followed by reverse D-shaped and U-shaped geometries. It can be concluded that among all SAH configurations considered, the U-shaped has outperformed in terms of thermohydraulic performance factor. [ABSTRACT FROM AUTHOR]

Thermal augmentation in flat tube of car radiator using different nanofluids has been performed more often, but use of artificial roughness has been seldom done. Artificial roughness in the form of dimple is used in the present research work. Present study shows the impact of dimple shaped roughness and nanofluid (Al2O3/pure water) on the performance of car radiator. The pitch of dimples is kept at 15 mm (constant) for all the studies performed. The Reynolds number of the flow is selected in the turbulent regime ranging from 9350 to 23 000 and the concentration of the nanofluid is taken in the range of 0.1-1%. It has been found that the heat transfer rate has improved significantly in dimpled radiator tube on the expense of pumping power. Furthermore, the heat transfer rate also increases with increase in nanoparticle concentration from 0.1% to 1.0%. The highest heat transfer enhancement of 79% is observed at Reynolds number 9350, while least enhancement of 18% is observed for Reynolds number of 23 000. [ABSTRACT FROM AUTHOR]