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Quantum metrology derives its capabilities from the careful employ of quantum resources for carrying out measurements. This advantage, however, relies on refined data postprocessing, assessed based on the variance of the estimated parameter. When Bayesian techniques are adopted, more elements become available for assessing the quality of the estimation. Here we adopt generalized classical Cram\'er-Rao bounds for looking in detail into a phase-estimation experiment performed with quantum light. In particular, we show that the third-order absolute moment can give a superior capability in revealing biases in the estimation, compared to standard approaches. Our studies point to the identification of an alternative strategy that brings a possible advantage in monitoring the correct operation of high-precision sensors., Comment: 6 pages, 5 figures

Encoding information in the time-frequency domain is demonstrating its potential for quantum information processing. It offers a novel scheme for communications with large alphabets, computing with large quantum systems, and new approaches to metrology. It is then crucial to secure full control on the generation of time-frequency quantum states and their properties. Here, we present an overview of the theoretical background and the technical aspects related to the characterization of time-frequency properties of two-photon states. We provide a detailed account of the methodologies which have been implemented for measuring frequency correlations and for the retrieval of the full spectral wavefunction. This effort has benefited enormously from the adaptation of classical metrology schemes to the needs of operating at the single-photon level.

The interest in a system often resides in the interplay among different parameters governing its evolution. It is thus often required to access many of them at once for a complete description. Assessing how quantum enhancement in such multiparameter estimation can be achieved depends on understanding the many subtleties that come into play: establishing solid foundations is key to delivering future technology for this task. In this article we discuss the state of the art of quantum multiparameter estimation, with a particular emphasis on its theoretical tools, on application to imaging problems, and on the possible avenues towards the next developments., Comment: 14 pages, 1 figure. Comments are welcome

Quantum sensors are among the most promising quantum technologies, allowing to attain the ultimate precision limit for parameter estimation. In order to achieve this, it is required to fully control and optimize what constitutes the hardware part of the sensors, i.e. the preparation of the probe states and the correct choice of the measurements to be performed. However careful considerations must be drawn also for the software components: a strategy must be employed to find a so-called optimal estimator. Here we review the most common approaches used to find the optimal estimator both with unlimited and limited resources. Furthermore, we present an attempt at a more complete characterization of the estimator by means of higher-order moments of the probability distribution, showing that most information is already conveyed by the standard bounds.

Postselection following weak measurements has long been investigated for its peculiar manifestation of quantum signatures. In particular, the postselected events can give rise to anomalous values lying outside the spectrum of the measured quantity, and may provide enhanced Fisher information. Furthermore, the Pusey inequality highlights that, for extremely weak measurements, non-contextual models can account for the outcome probabilities. It is then interesting to investigate whether these are linked in a unified framework. Here we discuss on the existence of a possible connection in the case of qubits. We show that when performing generic postselected measurements there exist no one-to-one mapping between them, an instance that leads to drawing more involved considerations.

Enzymes are essential to maintain organisms alive. Some of the reactions they catalyze are associated with a change in reagents chirality, hence their activity can be tracked by using optical means. However, illumination affects enzyme activity: the challenge is to operate at low-intensity regime avoiding loss in sensitivity. Here we apply quantum phase estimation to real-time measurement of invertase enzymatic activity. Control of the probe at the quantum level demonstrates the potential for reducing invasiveness with optimized sensitivity at once. This preliminary effort, bringing together methods of quantum physics and biology, constitutes an important step towards full development of quantum sensors for biological systems.

Describing the microscopic details of the interaction of magnets and spin-polarized currents is key to achieve control of such systems at the microscopic level. Here we discuss a description based on the Keldysh technique, casting the problem in the language of open quantum systems. We reveal the origin of noise in the presence of both field-like and damping like terms in the equation of motion arising from spin conductance.

Introducing quantum sensors as solution to real-world problem demands reliability and controllability outside laboratory conditions. Producers and operators ought to be assumed to have limited resources ready available for calibration, and yet, they should be able to trust the devices. Neural networks are almost ubiquitous for similar tasks for classical sensors: here we show the applications of this technique to calibrating a quantum photonic sensor. This is based on a set of training data, collected only relying on the available probe states, hence reducing overheads. We found that covering finely the parameter space is key to achieve uncertainties close to their ultimate level. This technique has potential to become the standard approach to calibrate quantum sensors.

Spin transport phenomena in solid materials suffer limitations from spin relaxation associated to disorder or lack of translational invariance. Ultracold atoms, free of that disorder, can provide a platform to observe phenomena beyond the usual two-dimensional electron gas. By generalizing the approach used for isotropic two-dimensional electron gases, we theoretically investigate the inverse spin galvanic effect in the two-level atomic system in the presence of anisotropic Rashba-Dresselhaus spin-orbit couplings (SOC) and external magnetic field. We show that the combination of the SOC results in an asymmetric case: the total spin polarization considered for a small momentum has a longer spin state than in a two-dimensional electron gas when the SOC field prevails over the external electric field. Our results can be relevant for advancing experimental and theoretical investigations in spin dynamics as a basic approach for studying spin state control.

The superposition of quantum states lies at the heart of physics and has been recently found to serve as a versatile resource for quantum information protocols, defining the notion of quantum coherence. In this contribution, we report on the implementation of its complementary concept, coherence from quantum measurements. By devising an accessible criterion which holds true in any classical statistical theory, we demonstrate that noncommutative quantum measurements violate this constraint, rendering it possible to perform an operational assessment of the measurement-based quantum coherence. In particular, we verify that polarization measurements of a single photonic qubit, an essential carrier of one unit of quantum information, are already incompatible with classical, i.e., incoherent, models of a measurement apparatus. Thus, we realize a method that enables us to quantitatively certify which quantum measurements follow fundamentally different statistical laws than expected from classical theories and, at the same time, quantify their usefulness within the modern framework of resources for quantum information technology., Comment: close to published version

Quantum photonics has demonstrated its potential for enhanced sensing. Current sources of quantum light states tailored to measuring, allow to monitor phenomena evolving on time scales of the order of the second. These are characteristic of product accumulation in chemical reactions of technologically interest, in particular those involving chiral compounds. Here we adopt a quantum multiparameter approach to investigate the dynamic process of sucrose acid hydrolysis as a test bed for such applications. The estimation is made robust by monitoring different parameters at once.

Classifying quantum states usually demands to observe properties such as the amount of correlation at one point in time. Further insight may be gained by inspecting the dynamics in a given evolution scheme. Here we attempt such a classification looking at single-qubit and two-qubit states at the start of thermalisation with a heat bath. The speed with which the evolution starts is influenced by quantum aspects of the state, however, such signatures do not allow for a systematic classification.

MR fingerprinting (MRF) is a rapid growing approach for fast quantitave MRI. A typical drawback of dictionary-based MRF is its explosion in size as a function of the number of reconstructed parameters, according to the curse of dimensionality. Deep Neural Networks (NNs) have been proposed as a feasible alternative, but these approaches are still in their infancy. We tested different NN pipelines on simulated data: we studied optimal training procedures by including different strategies of noise addition and parameter space sampling, to achieve better accuracy and robustness to noise. Four MRF sequences were considered, two of them designed to be more specific for $B_1^+$ parameter encoding: IR-FISP, IR-FISP-$B_1$, bSSFP and IR-bSSFP-$B_1$. A comparison between NN and the dictionary approaches was performed using a numerical brain phantom. Results demonstrated that training with random sampling and different levels of noise variance yielded the best performance. NN performance was greater or equal than dictionary-based approach in reconstructing MR parameter maps: the difference in performance increased with the number of estimated parameters, because the dictionary method suffers from the coarse resolution of the MR parameter space sampling. The NN approach resulted more efficient in terms of memory and computational burden, and thus has great potential in large-scale MRF problems.

The simplicity of a question such as wondering if correlations characterize or not a certain system collides with the experimental difficulty of accessing such information. Here we present a low demanding experimental approach which refers to the use of a metrology scheme to obtain a conservative estimate of the strength of frequency correlations. Our testbed is the widespread case of a photon pair produced per downconversion. The theoretical architecture used to put the correlation degree on a quantitative ground is also described.

Single-qubit thermometry presents the simplest tool to measure the temperature of thermal baths with reduced invasivity. At thermal equilibrium, the temperature uncertainty is linked to the heat capacity of the qubit, however the best precision is achieved outside equilibrium condition. Here, we discuss a way to generalize this relation in a non-equilibrium regime, taking into account purely quantum effects such as coherence. We support our findings with an experimental photonic simulation., Comment: 7 pages, 4 figures

Phase estimation is the most investigated protocol in quantum metrology, but its performance is affected by the presence of noise, also in the form of imperfect state preparation. Here we discuss how to address this scenario by using a multiparameter approach, in which noise is associated to a parameter to be measured at the same time as the phase. We present an experiment using two-photon states, and apply our setup to investigating optical activity of fructose solutions. Finally, we illustrate the scaling laws of the attainable precisions with the number of photons in the probe state.

The emergence of realistic properties is a key problem in understanding the quantum-to-classical transition. In this respect, measurements represent a way to interface quantum systems with the macroscopic world: these can be driven in the weak regime, where a reduced back-action can be imparted by choosing meter states able to extract different amounts of information. Here we explore the implications of such weak measurement for the variation of realistic properties of two-level quantum systems pre- and post-measurement, and extend our investigations to the case of open systems implementing the measurements.

Clausius inequality has deep implications for reversibility and the arrow of time. Quantum theory is able to extend this result for closed systems by inspecting the trajectory of the density matrix on its manifold. Here we show that this approach can provide an upper and lower bound to the irreversible entropy production for open quantum systems as well. These provide insights on the thermodynamics of the information erasure. Limits of the applicability of our bounds are discussed, and demonstrated in a quantum photonic simulator.

We consider a class of noisy, one-dimensional quantum cellular automata that allow one to shift from unitary dynamics to completely positive maps, and investigate the notion of reversibility in such a setting. To this aim, we associate an approximate reverse automaton to each noisy automaton, and assess its effect, and we define an irreversibility time based on the distance from the maximally mixed state, which is shown to be the only attractor of the automaton map in the presence of dephasing.

Quantum cellular automata are important tools in understanding quantum dynamics, thanks to their simple and effective list of rules. Here we investigate explicitly how coherence is built and lost in the evolution of one-dimensional automata subject to noise. Our analysis illustrates the interplay between unitary and noisy dynamics, and draws considerations on their behaviour in the pseudo-frequency domain.

The physics that governs quantum monitoring may involve other degrees of freedom than the ones initialised and controlled for probing. In this context we address the simultaneous estimation of phase and dephasing characterizing a dispersive medium, and we explore the role of frequency correlations within a photon pair generated via parametric down-conversion, when used as a probe for the medium. We derive the ultimate quantum limits on the estimation of the two parameters, by calculating the corresponding quantum Cram\'er-Rao bound; we then consider a feasible estimation scheme, based on the measurement of Stokes operators, and address its absolute performances in terms of the correlation parameters, and, more fundamentally, of the role played by correlations in the simultaneous achievability of the quantum Cram\'er-Rao bounds for each of the two parameters., Comment: to appear in Quantum Measurements and Quantum Metrology

We experimentally demonstrate a source of nearly pure single photons in arbitrary temporal shapes heralded from a parametric down-conversion (PDC) source at telecom wavelengths. The technology is enabled by the tailored dispersion of in-house fabricated waveguides with shaped pump pulses to directly generate the PDC photons in on-demand temporal shapes. We generate PDC photons in Hermite-Gauss and frequency-binned modes and confirm a minimum purity of 0.81, even for complex temporal shapes.

Quantum engineering now allows to design and construct multi-qubit states in a range of physical systems. These states are typically quite complex in nature, with disparate, but relevant properties that include both single and multi-qubit coherences and even entanglement. All these properties can be assessed by reconstructing the density matrix of those states - but the large parameter space can mean physical insight of the nature of those states and their coherence can be hard to achieve. Here we explore how the Wigner function of a multipartite system and its visualization provides rich information on the nature of the state, not only at illustrative level but also at the quantitative level. We test our tools in a photonic architecture making use of the multiple degrees of freedom of two photons., Comment: revtex 4.2, 6 pages, 5 figures

The metrological ability of carefully designed probes can be spoilt by the presence of noisy processes occurring during their evolution. The noise is responsible for altering the evolution of the probes in such a way that bear little or no information on the parameter of interest, hence spoiling the signal-to-noise ratio of any possible measurement. Here we show an experiment in which the introduction of an ancilla improves the estimation of an optical phase in the high-noise regime. The advantage is realised by the coherent coupling of the probe and the ancilla at the initialisation and the measurement state, which generate and then select a subset of overall configurations less affected by the noise process.

Quantum mechanics presents peculiar properties that, on the one hand, have been the subject of several theoretical and experimental studies about its very foundations and, on the other hand, provide tools for developing new technologies, the so-called quantum technologies. The nonclassicality pointed out by Leggett-Garg inequalities has represented, with Bell inequalities, one of the most investigated subject. In this letter we study the connection of Leggett-Garg inequalities with a new emerging field of quantum measurement, the weak values. In particular, we perform an experimental study of the four-time correlators Legget-Garg test, by exploiting single and sequential weak measurements performed on heralded single photons. We show violation of a four-parameters Leggett-Garg inequality in different experimental conditions, demonstrating an interesting connection between Leggett-Garg inequality violation and anomalous weak values.

A quantum theory of multiphase estimation is crucial for quantum-enhanced sensing and imaging and may link quantum metrology to more complex quantum computation and communication protocols. In this letter we tackle one of the key difficulties of multiphase estimation: obtaining a measurement which saturates the fundamental sensitivity bounds. We derive necessary and sufficient conditions for projective measurements acting on pure states to saturate the maximal theoretical bound on precision given by the quantum Fisher information matrix. We apply our theory to the specific example of interferometric phase estimation using photon number measurements, a convenient choice in the laboratory. Our results thus introduce concepts and methods relevant to the future theoretical and experimental development of multiparameter estimation., Comment: 4 pages + appendix, 2 figures

Careful tailoring the quantum state of probes offers the capability of investigating matter at unprecedented precisions. Rarely, however, the interaction with the sample is fully encompassed by a single parameter, and the information contained in the probe needs to be partitioned on multiple parameters. There exist then practical bounds on the ultimate joint-estimation precision set by the unavailability of a single optimal measurement for all parameters. Here we discuss how these considerations are modified for two-level quantum probes - qubits - by the use of two copies and entangling measurements. We find that the joint estimation of phase and phase diffusion benefits from such collective measurement, while for multiple phases, no enhancement can be observed. We demonstrate this in a proof-of-principle photonics setup.

Landauer's principle introduces a symmetry between computational and physical processes: erasure of information, a logically irreversible operation, must be underlain by an irreversible transformation dissipating energy. Monitoring micro- and nano-systems needs to enter into the energetic balance of their control; hence, finding the ultimate limits is instrumental to the development of future thermal machines operating at the quantum level. We report on the experimental investigation of a bound to the irreversible entropy associated to generalized quantum measurements on a quantum bit. We adopted a quantum photonics gate to implement a device interpolating from the weakly disturbing to the fully invasive and maximally informative regime. Our experiment prompted us to introduce a bound taking into account both the classical result of the measurement and the outcoming quantum state; unlike previous investigation, our new entropic bound is based uniquely on measurable quantities. Our results highlight what insights the information-theoretic approach can provide on building blocks of quantum information processors.

We show how the presence of entanglement in a bipartite Gaussian state can be detected by the amount of work extracted by a continuos variable Szilard-like device, where the bipartite state serves as the working medium of the engine. We provide an expression for the work extracted in such a process and specialize it to the case of Gaussian states. The extractable work provides a sufficient condition to witness entanglement in generic two-mode states, becoming also necessary for squeezed thermal states. We extend the protocol to tripartite Gaussian states, and show that the full structure of inseparability classes cannot be discriminated based on the extractable work. This suggests that bipartite entanglement is the fundamental resource underpinning work extraction., Comment: 12 pages, 8 figures

Synthesised light sources need reliable diagnostics for effective application to sub-femtosecond control and probing. However, commonly employed self-referencing techniques for pulsed-field characterisation fail in the presence of wide spectral gaps, while direct sampling methods are limited to high intensities. Here, we introduce a new approach labelled SPectral-gap Immune Characterisation of Electric Fields (SPICE), which overcomes these barriers by means of multi-spectral shearing interferometry, using an unknown reference and a reconstruction algorithm that makes use of this redundant information to simultaneously reconstruct the reference and test pulse with high precision and accuracy. We envisage that this technique will help foster new applications for broadband sources.

Quantum networks of growing complexity play a key role as resources for quantum computation; the ability to identify the quality of their internal correlations will play a crucial role in addressing the buiding stage of such states. We introduce a novel diagnostic scheme for multipartite networks of entangled particles, aimed at assessing the quality of the gates used for the engineering of their state. Using the information gathered from a set of suitably chosen multiparticle Bell tests, we identify conditions bounding the quality of the entangled bonds among the elements of a register. We demonstrate the effectiveness, flexibility, and diagnostic power of the proposed methodology by characterizing a quantum resource engineered combining two-photon hyperentanglement and photonic-chip technology. Our approach is feasible for medium-sized networks due to the intrinsically modular nature of cluster states, and paves the way to section-by-section analysis of large photonics resources., Comment: 5 pages, 3 figures, RevTex4-1

Standard thermometry employs the thermalisation of a probe with the system of interest. This approach can be extended by incorporating the possibility of using the non-equilibrium states of the probe, and the presence of coherence. Here, we illustrate how these concepts apply to the single-qubit thermometer introduced by Jevtic et al. by performing a simulation of the qubit-environment interaction in a linear-optical device. We discuss the role of the coherence, and how this affects the usefulness of non-equilibrium conditions. The origin of the observed behaviour is traced back to the propensity to thermalisation, as captured by the Helmholtz free energy., Comment: 6 pages, 6 figures

The relation between the theory of entanglement and thermodynamics is very tight: a thermodynamic theory of quantum entanglement, as well as the establishment of rigorous formal connections between the laws of thermodynamics and the phenomenology of entanglement are currently open areas of investigation. In this quest, an interesting problem is embodied by the role played by entanglement in processes of work extraction from a working medium embodied by quantum information carriers. In this work, we experimentally address the question "Is there any intrinsic advantage for work extraction given by the use of an entangled working medium?". By addressing work-extraction protocols based on a mechanism intimately linked to the paradigm of Maxwell's daemon, and implementing suitably designed multi-photon optical interferometers, we demonstrate experimentally the intrinsic advantages for such tasks provided by bipartite and genuine multipartite entanglement. We highlight the unique nature of such tests by comparing their performance to standard tests for the inseparability of multi-photon state resources. Our work contributes strongly to the ongoing efforts in establishing photonic systems as a platform for experiments for information thermodynamics., Comment: 9 pages, 7 figures, RevTex4-1