363 results on '"2,3-sigmatropic rearrangement"'
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52. ChemInform Abstract: Rh(II)-Catalyzed [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Derived from Cyclopropenes and Sulfides
53. ChemInform Abstract: Trifluoromethyl Sulfoxides from Allylic Alcohols and Electrophilic SCF3Donor by [2,3]-Sigmatropic Rearrangement
54. Synthesis of Enantiopure 3-Hydroxypiperidines from Sulfinyl Dienyl Amines by Diastereoselective Intramolecular Cyclization and [2,3]-Sigmatropic Rearrangement
55. ChemInform Abstract: [2,3] Sigmatropic Rearrangement of Propargylic Sulfinates by a Pale Ag1-USY Zeolite and Silver Salts
56. Bifunctionalized Allenes, VII: Two Methods for One‐Pot Synthesis of Sulfonyl‐Functionalized Allenecarboxylates and Phosphorylated Allenes
57. Rh(I)-catalyzed allenic Pauson–Khand reaction: first construction of the bicyclo[6.3.0]undecadienone ring system
58. A New Class of Ammonium Ylid for [2,3]-Sigmatropic Rearrangement Reactions: ene-endo-Spiro Ylids
59. Synthesis of Methyl epi-Anhydroquinate Utilizing [2,3]-Sigmatropic Rearrangement of Iodosoalkene
60. Dearomatization of furans via [2,3]-Still–Wittig rearrangement
61. Copper(II)-Catalyzed [2,3]-Sigmatropic Rearrangement of N-Methyltetrahydropyridinium Ylids
62. Catalytic asymmetric [2,3] sigmatropic rearrangement of sulfur ylides generated from carbenoids and propargyl sulfides
63. Lewis acid mediated [2,3]-sigmatropic rearrangement of allylic ammonium ylides
64. Diastereoselective rhodium(II)-catalyzed sulfonium ylide formation-[2,3]-sigmatropic rearrangement reaction of chiral non-racemic allylic sulfides
65. Synthesis of the hydroazulene portion of guanacastepene A using a [2.3]sigmatropic sulfoxide rearrangement: observations on silyl enol ether electrophilic chemistry for the introduction of the C-13 hydroxyl group
66. Studies on triacetic acid lactone-annulated heterocycles: synthesis of 3-aryloxyacetyl-6-methyl-2,3-dihydrothieno[3,2- c ]pyran-4-ones by tandem cyclization
67. The [2,3] sigmatropic rearrangement of N-benzyl-O-allylhydroxylamines
68. A NEW APPROACH TO ISOLEVOGLUCOSENONE VIA THE 2,3-SIGMATROPIC REARRANGEMENT OF AN ALLYLIC SELENIDE
69. Studies on sulfoxide rearrangement: synthesis of dimedone-annelated heterocycles
70. ChemInform Abstract: [2,3]-Sigmatropic Rearrangement of Allylic Selenimides: Strategy for the Synthesis of Peptides, Peptidomimetics, and N-Aryl Vinyl Glycines
71. [2,3]-Sigmatropic rearrangement of allylic selenimides: strategy for the synthesis of peptides, peptidomimetics, and N-aryl vinyl glycines
72. ChemInform Abstract: Rhodium-Catalyzed Denitrogenative [2,3] Sigmatropic Rearrangement: An Efficient Entry to Sulfur-Containing Quaternary Centers
73. ChemInform Abstract: Synthesis of 2,5-Disubstituted Dihydrofuran-3(2H)-ones via [2,3]-Sigmatropic Rearrangement of Oxonium Ylides Generated from α-Oxo Gold Carbenes
74. Enantioselective tandem formation and [2,3]-sigmatropic rearrangement of cyclic propargylic oxonium ylides catalyzed by dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate]
75. Application of Asymmetric Oxidation and Imidation of Organic Selenides to Organic Transformations
76. Stereospecific [2,3] sigmatropic rearrangement of allylic sulfoxides and selenoxides. Synthesis of novel polycyclic allylic alcohols and α-hydroxy ketones
77. Catalytic Asymmetric Ylide Generation and Subsequent Transformation via Chiral Metal Carbene Intermediates
78. Direct Transformations of Ketones to γ-Unsaturated Thiols via [2,3]-Sigmatropic Rearrangement of Allyl Sulfinyl Carbanions: A Combined Experimental and Computational Study
79. [2,3]-Sigmatropic rearrangement of allylic sulfur ylides derived from trimethylsilyldiazomethane (TMSD)
80. Synthesis of Conjugated Diallenes by Double [2,3]-Sigmatropic Rearrangement of Conjugated Diyne Trichloromethanesulfenates
81. Metal-catalyzed ylide formation and [2,3] sigmatropic rearrangement of allyl sulfides with trimethylsilyldiazomethane
82. Combining the [2,3] sigmatropic rearrangement and ring-closing metathesis strategies for the synthesis of spirocyclic alkaloids. A short and efficient route to (±)-perhydrohistrionicotoxin
83. Generation and Reactions of Samarium Carbanions Mediated by Samarium Iodide
84. Synthesis of isotopically labelled amino acids
85. Novel chemical behaviour of a [2,3] sigmatropic rearrangement product of 2-phenyltetrahydrothiopyranium 1-methylide
86. Ring expansion of trans-divinyl ethylene oxide by oxonium ylide [2,3] sigmatropic rearrangement
87. An Epoxide-Based Enantioselective Synthesis of the Antifungal Antibiotic (+)-Preussin
88. First synthesis of optically pure selenuranes and stereoselective alkaline hydrolysis. Their application to asymmetric [2,3] sigmatropic rearrangement of allylic selenoxides
89. Macrocyclic oxonium ylide formation and internal [2,3]-sigmatropic rearrangement. Catalyst influence on selectivity
90. Catalytic asymmetric oxonium ylide - [2,3] sigmatropic rearrangement with diazocarbonyl compounds: First use of C2-symmetry in Rh(II) carboxylates
91. Co(III)-salen catalyzed carbenoid reaction: Stereoselective [2,3]sigmatropic rearrangement of S-ylides derived from allyl aryl sulfides
92. Synthesis and Reactions of Lactam Sulfonium Salts with a Sulfonio Bridgehead. II. 1,1a,4,5,6-Pentahydro-6-oxo-2H-thiopyrano(1,6-d)-4,1-benzothiazepinium Perchlorates
93. Sigmatropic Rearrangements in Stereoselective Synthesis
94. Cycloadditions with Stereoselective CN Bond Formation in Total Syntheses
95. Rhodium-catalyzed denitrogenative [2,3] sigmatropic rearrangement: an efficient entry to sulfur-containing quaternary centers
96. ChemInform Abstract: Scope and Mechanistic Analysis of the Enantioselective Synthesis of Allenes by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement Between Donor/Acceptor Carbenoids and Propargylic Alcohols
97. Synthesis of (±)-Ambrox from (E)-Nerolidol and β-Ionone via Allylic Alcohol [2,3] Sigmatropic Rearrangement
98. ChemInform Abstract: Highly Stereoselective C-C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement Between Donor/Acceptor Carbenoids and Chiral Allylic Alcohols
99. Ab initio study of [2,3] sigmatropic rearrangement of allylic nitroxides and sulfoxides
100. Carbocyclic construction by the [2,3]sigmatropic rearrangement of cyclic sulfonium ylides. a new entry for the stereoselective synthesis of substituted cyclohexanones
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