851. Vertical profiles of CCl3F (F-11) and CCl2F2(F-12) in the central Arctic Ocean basin
- Author
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Douglas W.R. Wallace and Robert M. Moore
- Subjects
Atmospheric Science ,Soil Science ,Halocline ,Aquatic Science ,Oceanography ,law.invention ,Water column ,Geochemistry and Petrology ,law ,Earth and Planetary Sciences (miscellaneous) ,Surface layer ,Earth-Surface Processes ,Water Science and Technology ,geography ,geography.geographical_feature_category ,Ecology ,Paleontology ,Forestry ,Geophysics ,Arctic ,Space and Planetary Science ,Ventilation (architecture) ,Ridge (meteorology) ,Oceanic basin ,Geology ,Canada Basin - Abstract
The anthropogenic chlorofluoro-methanes CCl3F (F-11) and CCl2F2 (F-12) have been measured to depths of 1800 m in the Canada Basin of the Arctic Ocean (approximate position 85°50′N, 108°50′W). The measurements were made as part of the Canadian Expedition to Study the Alpha Ridge (CESAR) during April 1983. Surface layer concentrations beneath the ice were 4.79×10−12 mol/kg (F-11) and 2.11×10−12 mol/kg (F-12). Both profiles exhibit a rapid concentration decrease with depth through the halocline and very low, but detectable, concentrations at depths of 350–900 m in the Atlantic Layer. In the Arctic Ocean Deep Water (900–1800 m), concentrations are at or below our practical detection limit of 0.01×10−12 mol/kg. The profiles have been interpreted using two “extreme-case” lateral ventilation models in order to place bounds on the water column ventilation rates. The “Ventilation age” of the upper portion of the halocline (60–150 m) increases with depth from 4 to 14 years. The core of the Atlantic Layer at this location appears to have been isolated from the surface for at least 30 years.
- Published
- 1985
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