In order to carry out accurate analyses of the gases dissolved in ground-water, a method had to be devised for withdrawing water samples from the soil, free from soil particles and without allowing dissolved gases to escape. Furthermore it was required that the method should be such that successive samples could be taken from one place without disturbing the vegetation. With these points in mind a sampling probe was designed which could be left in the ground as long as needed and could then be easily withdrawn and used elsewhere, and from which ground-water samples could be obtained under conditions minimizing gaseous exchange with the air. The essential element of the probe was a porous cylindrical cup of 80 c.c capacity and with pores of 7-10 i diameter. The cups were made of a material described by the makers, Doulton Industrial Porcelains Ltd., as F10. Its characteristics are that it is highly permeable to water, while providing the necessary filtration. So permeable are these cups that water poured into them is immediately observed to flow out through the walls. Each cup was closed with a rubber bung provided with two glass capillary tubes, one with a fine (about 0-25 mm) and the other with a coarse (about 1.0 mm) bore, for filling and withdrawing water. The assembly of cup and tubes was mounted in a haft of tubular duralumin, which was cut away around the cup in such a way as to allow most of the surface of the cup to be brought into contact with the soil. The lower end of the haft was provided with a conical wooden tip. A hole could be augered into the soil to the required depth and the probe thrust into position. Details of the size and construction of the probes are shown in Fig. 1. They were made in two lengths, 30 and 60 cm, to allow different depths of sampling. They were constructed in 1948; if more were to be made at the present time it would undoubtedly be preferable to replace the glass with nylon capillary tubing, and a plastic material might also be more suitable for the haft. A length of 5 cm of the cylindrical haft immediately above the porous cup was perforated and gave access from the soil to a small chamber sealed off from the rest of the haft. This was intended for the subsidiary purpose of withdrawing soil air if the water table fell sufficiently, and a third capillary tube connected the chamber with the upper end of the haft.