551. Improving the performance of Mn2O3 electrodes by Co substitution for super capacitor applications.
- Author
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Dharani, A. P., Hariharan, G., Raja, M., Rajeshwaran, P., and Kumaran, S.
- Abstract
Nowadays, super capacitors are among the most important emerging technologies for green energy storage devices. Researchers continue to face a significant challenge in their quest to achieve both high specific capacitance and long-term stability in super capacitors. Balancing these two desirable properties remains an ongoing and difficult task for the scientific community. The utilization of transition metal-based materials as electrodes for super capacitors has garnered considerable interest, resulting in the synthesis of Co-doped porous Mn
2 O3 through a straightforward hydrothermal process. In this study, we synthesized Co-substituted Mn2 O3 with varying concentrations of cobalt, namely Mn2 O3 , Mn1 .94 Co.06 O3 , Mn1.92 Co.08 O3 , and Mn1.90 Co.10 O3 , to create a hybrid electrode. The orthorhombic Mn2 O3 crystalline phase was confirmed through powder X-ray diffraction pattern. Scanning electron microscopy analysis identified the presence of pores between the grains in Co-doped Mn2 O3 . EDAX and XPS studies provided confirmation of the presence of Mn, Co, and O elements as well as their respective oxidation states. The effect of cobalt substitution on the electrode efficiency of Mn2 O3 -based samples was thoroughly investigated through cyclic voltammetry (CV) and galvanostatic charge–discharge analyses. The CV results demonstrated that Mn1.90 Co.10 O3 exhibited a specific capacitance of 365 F g−1 at a low scan rate of 10 mV, while pristine Mn2 O3 showed only 240 Fg−1 . This indicates the higher storage capacity of Mn1.90 Co.10 O3 . Additionally, the galvanic charge–discharge results revealed that Mn1.90 Co.10 O3 displayed a specific capacitance of 296 Fg−1 at 10 A g−1 . Furthermore, the Electrochemical Impedance Spectroscopy results indicated that Mn1.90 Co.10 O3 exhibited a low resistance value of 0.80 Ω compared to other electrodes. The exceptional performance of the Co-substituted hybrid electrode can be attributed to the synergistic effects of the small-sized and highly redox-active Co and Mn2 O3 particles, as well as the high electronic conductivity they possess. Our study provides valuable insights for the design of materials employed in super capacitor electrodes, with broad implications for the energy storage research community. [ABSTRACT FROM AUTHOR]- Published
- 2023
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