285 results on '"Venditti, Richard"'
Search Results
252. WHAT HAPPENS TO CELLULOSIC FIBERS DURING PAPERMAKING AND RECYCLING? A REVIEW.
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Hubbe, Martin A., Venditti, Richard A., and Rojas, Orlando J.
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- 2007
253. Understanding the potential of bamboo fibers in the USA: A comprehensive techno‐economic comparison of bamboo fiber production through mechanical and chemical processes.
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Vivas, Keren A., Pifano, Alonzo, Vera, Ramon E., Urdaneta, Fernando, Urdaneta, Isabel, Forfora, Naycari, Abbati de Assis, Camilla, Phillips, Richard B., Dasmohapatra, Sudipta, Saloni, Daniel, Venditti, Richard A., and Gonzalez, Ronalds
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BAMBOO , *SULFATE pulping process , *PRICES , *MARKET prices , *CHEMICAL systems , *FIBERS , *CHEMICAL processes - Abstract
The growing interest in bamboo fibers for pulp, paper, and board production in the USA necessitates a comprehensive financial viability assessment. This study conducts a detailed technoeconomic analysis (TEA) of bamboo fiber production, primarily for the consumer hygiene tissue market although it is also applicable to other industrial uses. The economic viability of two pulping methods – alkaline peroxide mechanical pulping (APMP) and ammonium bisulfite chemical pulping (ABS) – was explored within three different pulp mill settings to supply pulp to two nonintegrated tissue and towel mills in South Carolina, USA. The target was to produce wet lap bamboo bleached pulp at 50% consistency and 70% ISO brightness. Despite higher initial capital invesment and operating costs, ABS achieved a lower minimum required selling price – USD 544 to 686 per bone dry metric ton (BDt = 1000 BDkg) – in comparison with USD 766 to 899 BDt−1 for APMP. This price advantage is partly due to an additional revenue stream (lignosulfonate byproduct), which not only boosts revenue but also circumvents the need for expensive chemical recovery systems. When compared with traditional kraft pulping, both methods require significantly lower capital investments, with minimum required selling prices (estimated to achieve 16% IRR) below current market rates for extensively used bleached kraft pulps in the USA tissue industry. The economic benefits derive from several factors: the low cost of bamboo as raw material, reduced capital needs for new pulping technologies, lower transportation costs from the pulp mill to tissue and towel manufacturing facilities, and the high market price of bleached kraft pulp. [ABSTRACT FROM AUTHOR]
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- 2024
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254. An economic analysis of bamboo plantations and feedstock delivered cost in the Southern US for the manufacturing of fiber‐based bioproducts.
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Vivas, Keren A., Vera, Ramon E., Phillips, Richard B., Forfora, Naycari, Azuaje, Ivana, Zering, Kelly, Chang, Hou‐Min, Delborne, Jason, Saloni, Daniel, Dasmohapatra, Sudipta, Barbieri, Carla, Venditti, Richard A., Marquez, Ronald, and Gonzalez, Ronalds
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BIOLOGICAL products , *FEEDSTOCK , *BAMBOO , *INTERNAL rate of return , *PLANTATIONS , *STARTUP costs - Abstract
Bamboo, recognized for its rapid growth, high yield, and fiber performance is prominent in the fiber‐based bioproduct industry. However, the absence of US industrial bamboo plantations for fiber production necessitates reliance on imports or locally manufactured products using imported bamboo fibers, predominantly from China. This study evaluates the economic viability of cultivating bamboo in the Southern US for fiber production, with a case study on hygiene tissue products. The supply‐chain analysis was assessed to calculate bamboo chips' minimum selling price (MSP) at the farm gate for an 8% internal rate of return (IRR). The MSP, influenced primarily by land rental costs, ranges from USD 48 to 55 per bone‐dry metric ton (BDt). Despite an initial establishment cost of ~USD 2 000 ha−1 and profitability by year 5, bamboo is a viable, long‐term fiber alternative. Successful bamboo cultivation in the US could lead to a more sustainable implementation of alternative non‐wood fibers for hygiene tissue applications. [ABSTRACT FROM AUTHOR]
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- 2024
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255. Evaluating Cotton Apparel with Dynamic Life Cycle Assessment: The Climate Benefits of Temporary Biogenic Carbon Storage.
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Pires, Steven T., Williams, Allan, Daystar, Jesse, Sagues, William Joe, Lan, Kai, and Venditti, Richard A.
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GREENHOUSE gases , *CIRCULAR economy , *PRODUCT life cycle assessment , *SUSTAINABLE agriculture , *RADIATIVE forcing - Abstract
Static life cycle assessment (LCA) methodologies fail to consider the temporal profiles of system inputs and outputs (including emission timing), such that they underestimate the benefits of temporarily stored biogenic carbon in bioproducts, such as cotton. This research focuses on greenhouse gas emission timing and applies dynamic emission accounting to the life cycle of cotton woven pants. The significance of temporary biogenic carbon storage and emission timing is illustrated by converting the 2017 Cotton Incorporated static LCA to a dynamic model using the Dynamic Carbon Footprinter (baseline scenario). A reduction in cumulative radiative forcing for dynamic relative to static modeling of 22%, 5%, and 2% are observed at 10-years, 30-years, and 100-years, respectively. Alternative scenarios analyzed include converting cotton woven pants at end of life to bioenergy, to compost, or to building insulation, an alternative cotton production scenario using regenerative agricultural practices, and two pants extended lifetime scenarios. The regenerative agricultural practice scenario provides reductions in cumulative impacts compared to the baseline scenario of 96%, 69%, and 105% after 10, 30, and 100-years, respectively. A 3x extension in the lifetime of pants provides a benefit in reduced cumulative impacts of 31%, 40%, and 41%, after 10, 30, and 100-years, respectively. This case study with cotton demonstrates that dynamic LCA is a useful tool for assessing the benefits of biobased products, and it allows for more nuanced analysis of reductions in climate impacts in both the short- and long-term time horizons. [ABSTRACT FROM AUTHOR]
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- 2024
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256. Impact of dyes and finishes on the aquatic biodegradability of cotton textile fibers and microfibers released on laundering clothes: Correlations between enzyme adsorption and activity and biodegradation rates.
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Zambrano, Marielis C., Pawlak, Joel J., Daystar, Jesse, Ankeny, Mary, and Venditti, Richard A.
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TEXTILE fibers ,COTTON fibers ,COTTON textiles ,COTTON ,MICROFIBERS ,BIODEGRADABLE plastics ,BIODEGRADATION ,MICROBIAL enzymes - Abstract
The presence and biodegradability of textile microfibers shed during laundering or use is an important environmental issue. In this research, the influence of common textile finishes on the persistence of cotton fibers in an aerobic aquatic environment was assessed. The biodegradation of cotton knitted fabrics with different finishes, silicone softener, durable press, water repellent, and a blue reactive dye was evaluated. The rate of biodegradation decreased with durable press and water repellant finishing treatments. In terms of the final extent of biodegradation, there was no significant difference between the samples. All samples reached more than 60% biodegradation in 102 days. The biodegradation rates were in agreement with observed trends of the same samples for cellulase mediated hydrolysis and cellulase adsorption experiments, indicating the finishes impact the initial adsorption of enzymes excreted by the microorganisms and the initial rates of biodegradation, however despite this the cellulosic material maintains its biodegradability. [Display omitted] • The finishes commonly applied to cotton fabrics influence the biodegradation rate. • All cotton fabrics degraded significantly under the conditions of this study. • The biodegradation was as follows: Softener > MCC > Water Repellent ~ No Finish > Dyed ~ Oak Leaves > Durable Press. • Fabrics with levels of crosslinking on the surface were more resistant to biodegradation. • The presence of the finishes affect the adsorption and activity of cellulases on cotton fabrics. [ABSTRACT FROM AUTHOR]
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- 2021
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257. EFFECT OF ENZYME PRETREATMENTS ON CONVENTIONAL KRAFT PULPING
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JACOBS-YOUNG, CHAVONDA J., VENDITTI, RICHARD A., and JOYCE, THOMAS W.
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- 1998
258. A general Life Cycle Assessment framework for sustainable bleaching: A case study of peracetic acid bleaching of wood pulp.
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Echeverria, Darlene, Venditti, Richard, Jameel, Hasan, and Yao, Yuan
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WOOD pulp bleaching , *PERACETIC acid , *PULPING , *WOOD-pulp , *ACETIC acid , *CHLORINE dioxide , *MANUFACTURING processes - Abstract
Bleaching is an important industrial operation that has significant environmental impacts. Many new bleaching technologies have been developed; nonetheless, it is challenging to quantify their potential environmental impacts due to the lack of quantitative information and robust analysis methods across different bleaching agents. This study addresses this gap by developing a general Life Cycle Assessment (LCA) framework that integrates LCA with manufacturing process simulations and lab-scale bleaching experiments. The framework was applied to a case study of Peracetic Acid (PAA), a promising bleaching agent, used in the Total Chlorine-Free (TCF) technology for wood pulp production, compared with the traditional Elemental Chlorine-Free (ECF) using chlorine dioxide. Different PAA synthetic pathways (i.e., using acetic acid or triacetin) and bleaching charges were explored using scenario analysis. Results showed that PAA-based TCF achieves a brightness similar to the conventional ECF technology with lower life-cycle impacts in categories such as global warming and eutrophication. From a process perspective, PAA-based TCF reduces the consumption of energy, water, pulping chemicals, completely avoids the use of chlorinated compounds, and provides enhanced process safety. The source of PAA significantly affects the life-cycle environmental impacts of pulp bleaching. Using PAA synthesized from triacetin rather than acetic acid leads to higher environmental impacts; however, such impacts can be mitigated by reducing excessive use of triacetin (direction for future optimization) or using bio-based glycerin in the production of the triacetin feedstock for PAA production. Although this case study focuses on PAA bleaching for wood pulp, the framework has the potential to be used for other/same bleaching agents in different industrial sectors. Image 1 • A Life Cycle Assessment framework for sustainable bleaching was developed. • The framework was applied to peracetic acid bleaching of wood pulp. • Two pulp bleaching processes using Peracetic Acid (PAA) and ClO 2 were compared. • PAA made from the traditional process was compared with a green chemistry pathway. • Bleaching with PAA eliminates chlorinated compounds and consumes fewer resources. [ABSTRACT FROM AUTHOR]
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- 2021
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259. Combined Application of Extrusion and Irradiation Technologies: A Strategy Oriented for Green and Cost- Effective Chemistry.
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Ayoub, Ali, Venditti, Richard A., Pawlak, Joel J., and Massardier, Valerie
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REACTIVE extrusion , *SUSTAINABLE chemistry , *COMPATIBILIZERS , *POLYMERS , *ADDITIVES , *IRRADIATION , *BIOMASS - Abstract
Reactive extrusion is an attractive green route for cost-effective polymer processing, which has the potential to enhance the commercial viability of biomass-derived materials. In reactive extrusion, compatibilizers can be generated in the blend preparation through polymer-polymer grafting reactions using functionalized polymers. One very interesting new green strategy for processing is the use of intense UV-irradiation to create free radicals and controllable, ultra-fast reactions. It is reasonable to expect that the use of extrusion/irradiation green technology will be an important way to improve properties and compatibility of renewable biomass-derived polymers. We believe that in the future, many more cost-effective, sustainable extrusion/irradiation reaction processes will be developed to replace inefficient conventional biomass conversion procedures and stimulate the bioproduct-based industry. [ABSTRACT FROM AUTHOR]
- Published
- 2013
260. Elucidation of temperature-induced water structuring on cellulose surfaces for environmental and energy sustainability.
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Barrios, Nelson, Parra, José G., Venditti, Richard A., and Pal, Lokendra
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CELLULOSE , *SUSTAINABILITY , *ENERGY consumption , *FOREST products industry , *MOLECULAR dynamics , *INTERMOLECULAR interactions , *SURFACE structure , *LIGNOCELLULOSE - Abstract
Optimizing drying energy in the forest products industry is critical for integrating lignocellulosic feedstocks across all manufacturing sectors. Despite substantial efforts to reduce thermal energy consumption during drying, further enhancements are possible. Cellulose, the main component of forest products, is Earth's most abundant biopolymer and a promising renewable feedstock. This study employs all-atom molecular dynamics (MD) simulations to explore the structural dynamics of a small I β -cellulose microcrystallite and surrounding water layers during drying. Molecular and atomistic profiles revealed localized water near the cellulose surface, with water structuring extending beyond 8 Å into the water bulk, influencing solvent-accessible surface area and solvation energy. With increasing temperature, there was a ∼20 % reduction in the cellulose surface available for interaction with water molecules, and a ∼22 % reduction in solvation energy. The number of hydrogen bonds increased with thicker water layers, facilitated by a "bridging" effect. Electrostatic interactions dominated the intermolecular interactions at all temperatures, creating an energetic barrier that hinders water removal, slowing the drying processes. Understanding temperature-dependent cellulose-water interactions at the molecular level will help in designing novel strategies to address drying energy consumption, advancing the adoption of lignocellulosics as viable manufacturing feedstocks. [Display omitted] [ABSTRACT FROM AUTHOR]
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- 2024
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261. Aquatic biodegradation of poly(β-hydroxybutyrate) in polylactic acid and maleic anhydride blended fibers.
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Kwon, Soojin, Zambrano, Marielis C., Pawlak, Joel J., Ford, Ericka, and Venditti, Richard A.
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MALEIC anhydride , *MALEIC acid , *BIODEGRADATION , *POLY-beta-hydroxybutyrate , *POLYLACTIC acid , *FIBERS , *POLYMER blends - Abstract
In this study PLA and PHB were melt-blended with/without maleic anhydride (MA) as a compatibilizer and melt-spun into a monofilament. The aquatic biodegradation of PLA/PHB fibers was tracked regarding the PLA and PHB components and the total carbon in the blend. Pure PLA fiber was recalcitrant to aquatic biodegradation in the present conditions, whereas PHB was readily degradable, as expected. The 75/25% and 50/50% PLA/PHB fibers showed zero biodegradation. The 25/75% PLA/PHB blend showed only an 11% final biodegradation extent and a 13% PHB biodegradation extent. It is shown that an unintended consequence of blending PLA with PHB is that after biodegradation, micro/nano plastic pollution is evolved. MA increased the miscibility, which further decreased the PHB biodegradation. The lower biodegradation extent with MA indicates that increased miscibility and more intimate coverage of the biodegradable polymer with the unbiodegradable polymer may have a negative effect on the biodegradation of biodegradable polymers. [ABSTRACT FROM AUTHOR]
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- 2024
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262. Hemicellulose and Starch Citrate Chitosan Foam Adsorbents for Removal of Arsenic and Other Heavy Metals from Contaminated Water.
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Salam, Abdus, Zambrano, Marielis C., Venditti, Richard A., and Pawlak, Joel J.
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ARSENIC , *ARSENIC removal (Water purification) , *HEAVY metals , *WATER pollution , *SECONDARY ion mass spectrometry , *HEAVY metals removal (Sewage purification) , *STARCH - Abstract
Arsenic and other heavy metal contaminants in water are a significant global health threat. In this study, low-cost, sulfur-free, sustainable, water-insoluble materials with heavy metal remediation properties were produced from renewable resources such as starch, xylan, citric acid, and chitosan. Synthesized starch citrate-chitosan (SCC) foam and xylan citrate-chitosan (XCC) foam were flexible, porous, and elastic. The foams' arsenic uptake in water was significantly greater than five different commercial metal remediating agents. The mercury and lead uptakes with the synthesized foams were similar to the performance of a commercial sulfur-based product, SorbaTech 450 (ST450). However, the cadmium and selenium uptakes were comparatively lower. The complexation of arsenic with oxygen and nitrogen of the SCC foam was shown with time-of-flight secondary ion mass spectrometry (TOF-SIMS). The XCC foam was also shown to adsorb potassium iodide (KI) at a similar rate to sodium chloride. This may be used to remediate water contaminated with radioactive materials, such as iodine 131. [ABSTRACT FROM AUTHOR]
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- 2021
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263. Enzyme-assisted dewatering and strength enhancement of cellulosic fibers for sustainable papermaking: A bench and pilot study.
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Barrios, Nelson, Smith, Madilynn M., Venditti, Richard A., and Pal, Lokendra
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SOFTWOOD , *PAPERMAKING , *FIBERS , *PAPER industry , *PILOT projects , *PAPER pulp , *CATIONIC polymers , *XYLANASES - Abstract
Water removal during paper manufacturing is of primary importance to production rate and cost efficiency for the pulp and paper industry. It is crucial to develop methods to reduce energy consumption by increasing the percent solids in the paper web entering the dryers from the presses. This research aimed to develop a fundamental understanding of the effect of bio-chemo-mechanical pretreatments on a bleached softwood fiber matrix and evaluate the impact on the percent solids of the paper web after pressing. Experiments included enzymatic, refining, and cationic polymer pretreatments on the bleached softwood pulps, followed by laboratory papermaking and determining the equilibrium moisture content (EMC) after pressing and the pulp and paper properties. The combined effect of mild refining, controlled enzymatic pretreatments, and cationic strength aids proved to enhance the water removal during wet pressing (up to 35 % reduction) and increase paper strength (up to 60 % increase). The results of increased solids after pressing were used to calculate the potential reduction in drying energy during paper manufacturing. Energy savings of around 10 % for paper drying could be achieved through fiber matrix modification by bio-chemo-mechanical pretreatment. Enzymatic pretreatments have previously been conventionally applied before refining as an energy-saving method. However, this research shows that synergistic actions of enzymes added after refining modify the fibers and create the optimal conditions for enhancement in drainage, press dewatering, and paper properties. [Display omitted] • Enzyme-assisted fiber modifications improve press dewatering and paper strength. • Enzyme blends can enhance fiber cell wall flexibility and fibrillation. • Synergistically, enzymes increased ∼35% press dewatering and ∼60% tensile strength. • Enzymes, mild refining, and cationic biopolymers enhance paper process efficiency. • This research introduces alternative methods for decarbonizing the paper industry. [ABSTRACT FROM AUTHOR]
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- 2024
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264. A modeling framework to identify environmentally greener and lower-cost pathways of nanomaterials.
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Lan, Kai, Wang, Hannah Szu-Han, Lee, Tessa, de Assis, Camilla Abbati, Venditti, Richard A., Zhu, Yong, and Yao, Yuan
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NANOSTRUCTURED materials , *SUSTAINABLE chemistry , *CELLULOSE nanocrystals , *PRODUCT life cycle assessment , *PROCESS optimization , *CELLULOSE , *ELECTRIC bicycles - Abstract
Producing environmentally benign and economically viable nanomaterials is critical for large-scale applications in energy and other industries. This study presents a modeling framework to identify environmentally greener and lower-cost pathways of large-scale nanomaterial production, which encompasses life cycle assessment, Green Chemistry principles, techno-economic analysis, and eco-efficiency analysis. The framework is demonstrated by case studies of cellulose nanomaterials produced in the U.S. For cellulose nanocrystals, the framework identifies pathways that simultaneously reduce the life-cycle global warming potential (GWP) from 17.7 to 2.6 kgCO2e per dry kg cellulose nanocrystals and the minimum selling price (MSP) from US$7540 to US$4587 per dry t cellulose nanocrystals. For cellulose nanofibrils, the strategies present trade-offs of reducing GWP from 7.8 to 0.1 kgCO2e per dry kg cellulose nanofibrils but increasing MSP slightly from US$2873 to US$2985 per dry t cellulose nanofibrils. Eco-efficiency analysis quantifies the magnitudes of co-benefits and trade-offs between the environmental and economic performance of different production strategies and supports decision making for sustainability-informed process optimization. [ABSTRACT FROM AUTHOR]
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- 2024
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265. Aquatic Aerobic Biodegradation of Commonly Flushed Materials in Aerobic Wastewater Treatment Plant Solids, Seawater, and Lakewater.
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Smith, Madilynn M., Zambrano, Marielis, Ankeny, Mary, Daystar, Jesse, Pires, Steven, Pawlak, Joel, and Venditti, Richard A.
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SEWAGE disposal plants , *BIODEGRADATION , *SEAWATER , *CARBON emissions , *KNIT goods - Abstract
Microfibers and microplastics originating from wastewater treatment plant (WWTP) effluents are significant pollutants in freshwater sources and marine environments. This research investigated the biodegradation of cotton microfibers generated from bleached cotton jersey knit fabric and commercially available flushable wipes, polypropylene-based (PP) nonwoven wipes containing a cellulose component, and tissue paper. Biodegradation was tested in wastewater treatment plants (WWTP) solids, seawater, and lakewater according to the ISO 14852 and ASTM D6691 standard methods in an ECHO respirometer. Degradation experiments continued until a plateau in CO2 emissions was reached, and the final biodegradation extent was calculated relative to the theoretical CO2 produced based on elemental analysis. The results showed that the cotton and other cellulosic materials/components biodegrade to a great extent, as expected for all conditions, whereas the PP did not degrade. In general, for the cellulose polypropylene composite wipes, the cellulose biodegraded readily; the presence of the PP did not hinder the cellulose biodegradation. [ABSTRACT FROM AUTHOR]
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- 2024
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266. Aerobic aquatic biodegradation of bio-based and biodegradable polymers: Kinetic modeling and key factors for biodegradability.
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Kwon, Soojin, Zambrano, Marielis C., Venditti, Richard A., and Pawlak, Joel J.
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BIODEGRADABLE plastics , *BIODEGRADATION , *CELLULOSE acetate , *MATERIAL biodegradation , *PLASTICS , *POLYLACTIC acid - Abstract
With the increasing concern about plastic waste, numerous efforts have been made to find substitutes for existing non-biodegradable synthetic polymers. Bio-based and/or purported petroleum-based biodegradable polymers are considered probable plastic replacement candidates. However, the durability of non-biodegradable plastic is a key feature of plastics. Thus, a balance must be achieved between biodegradation and environmental material stability. The objective of this study is to determine the impact of crystallinity, molecular chemistry, and hydrophilicity on the rate of aquatic biodegradation of biobased plastic materials. In the present study, twelve bio-based/purported biodegradable materials were investigated under aerobic aquatic biodegradation conditions for 56 days by tracking oxygen consumption. Crystallinity, hydrophobicity, chemistry, and chemical structure were varied to understand potential means for controlling the rate of biodegradation. The biodegradation kinetics were analyzed and discussed, relating to the characteristics of polymers. Polyvinyl alcohol (PVA), Chitosan, Rayon, Polyhydroxy-butyrate-co-valerate (PHBV), PHBH, and Polybutylene succinate (PBS) showed the biodegradation extents over 70% at 56 days. Cellulose acetates (CAs) and Polylactic acid (PLA) showed biodegradation extent lower than 20%. The chemistry of the polymer backbone chain, substituent structure, and degree of substitution were the dominant factors affecting biodegradation. The crystallinity of the polyesters had a negative correlation with the initial biodegradation rate and the ultimate biodegradation of polyesters, and the hydrophobicity of the polymers delayed the initiation of biodegradation. The aerobic aquatic biodegradation results related to the polymer characteristics are useful for product designers and environmental scientists to understand the fate of these polymeric materials in the environment. • Aquatic aerobic biodegradation of twelve bio-based/biodegradable polymers performed. • Ultimate biodegradation, rate, and lag phase determined by kinetic modeling. • Chemistry of polymer backbone and substituent was a dominant factor. • Negative correlations between crystallinity and biodegradation rate. • Effects of hydrophilicity on biodegradation kinetics. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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267. Organized youth sports and commuting behavior: The environmental impact of decentralized community sport facilities.
- Author
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Bunds, Kyle S., Kanters, Michael A., Venditti, Richard A., Rajagopalan, Neethi, Casper, Jonathan M., and Carlton, Troy A.
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YOUTH , *SPORTS , *COMMUTING , *INUIT , *SCIENTIFIC expeditions , *PARTICIPATION - Abstract
Highlights • Previous research has not quantified the extent of travel required for participation in organized sport. • Participants spent an average of 106 min/week in car transport accounting for 28% of the participant's average driving time per week. • The environmental impact of this youth sport program annually is about 400 tonnes of CO2eq. • Assigning children to practice at the closest facility to their homes could reduce emissions from this travel by 12% whereas upgrading vehicle gas mileage efficiency could reduce emissions by 40%. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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268. Is sugarcane-based polyethylene a good alternative to fight climate change?
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Suarez, Antonio, Ford, Ericka, Venditti, Richard, Kelley, Stephen, Saloni, Daniel, and Gonzalez, Ronalds
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ENVIRONMENTAL impact analysis , *POLYETHYLENE , *ENVIRONMENTAL indicators , *ECOLOGICAL impact , *BIODEGRADABLE plastics , *POLYETHYLENE oxide - Abstract
The need to decarbonize and reduce the impact of human activities is opening the window for new bioproducts. The industry of bioplastics has grown exponentially in the past years, and its production is expected to triple by 2026. Different bioplastics are currently produced, but bio-polyethylene constitute an interesting opportunity since its fossil counterpart is one of the most used materials worldwide, and its precursor, ethylene, is one of the highest contributors to GHG emissions in the chemical industry. The true environmental impact of this bio-based plastic remains under controversial discussions due to a wide distribution of environmental indicators values found in the literature for this material. We aim to thoroughly evaluate the environmental impact of bio-polyethylene made from sugarcane across the different production stages through a life cycle analysis. Our goal is also to assess unintended consequences (consequential effects) of producing it. It was determined that land-use change represents the main aspect affecting the environmental sustainability of bio-polyethylene. From an attributional point of view, this bioplastic could present lower carbon footprints than fossil polyethylene if no deforestation occurs. From a consequential standpoint, indirect deforestation as a response to producing more bioplastic could negatively impact the environmental profile of this material. Policies restricting deforestation are required to ensure that bio-polyethylene can constitute an alternative to reduce the carbon footprint of products in both scenarios. We expect this work to provide a robust evaluation to understand the environmental impact of bio-polyethylene, which will help the industry understand the place of this bio-based plastic and increase the offering of more sustainable products. • This study reports environmental impacts related to sugarcane-based polyethylene. • Land-use change highly influences the global warming potential of bio-polyethylene. • Bio-polyethylene can help fight climate change if no deforestation occurs. • Policies protecting forests are required to ensure benefits of bio-polyethylene. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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269. Using Activity Theory to understand the interactions of a university interdisciplinary team of scientists and science educators.
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McCance, Katherine R., Teeter, Stephanie D., Blanchard, Margaret R., and Venditti, Richard A.
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SCIENCE education , *INTERDISCIPLINARY approach to knowledge , *COLLEGE teachers , *PROJECT method in teaching , *GRADUATE students , *HIGHER education - Abstract
Interdisciplinary collaborations between different academic disciplines can create knowledge and solutions to challenges that are beyond the scope of what a single discipline can achieve. However, little is known about how interdisciplinary teams of faculty and graduate students function as a whole and the processes that guide them as they work on collaborative tasks. Using Activity Theory, this qualitative study analyzed team meeting transcripts to examine interdisciplinary team interactions involving Science/Engineering and Science Education graduate students and faculty members as they co-developed laboratory activities for a grant-funded project. Several factors contributed to the team's success: shared goals (Object), environment (Community), and clear Division of Labor. Differences (contradictions) were found in the Tools, Rules, and Division of Labor; the PI and Science/Engineering graduate students tended to focus on the needed lab materials, and the Science Education members focused more on educational standards and teachers' ideas in the lab development (Tools). The PI and Science Education members set and enforced the team meeting agendas and deadlines (Rules). The Science/Engineering grad students focused on practical considerations to ensure the labs could successfully be implemented in a class setting (Rules) and were assigned the most tasks to complete (Division of Labor). The findings provide insight into the nature of interdisciplinary team dynamics between a Science/Engineering and Education grant team. The findings also suggest the importance of shared goals (Object), community development (Rules: Team Building), and the potential of capitalizing on different strengths and knowledge (contradictions) in an interdisciplinary team. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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270. Environmental Life Cycle Assessment of Premium and Ultra Hygiene Tissue Products in the United States.
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Brito, Amelys, Suarez, Antonio, Pifano, Alonzo, Reisinger, Lee, Wright, Jeff, Saloni, Daniel, Kelley, Stephen, Gonzalez, Ronalds, Venditti, Richard, and Jameel, Hasan
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PRODUCT life cycle assessment , *HYGIENE products , *ENVIRONMENTAL impact analysis , *ECOLOGICAL impact , *SUSTAINABLE development reporting , *TISSUES - Abstract
Under the controversial concern of using virgin fibers in hygiene tissue products, mostly Bleached Eucalyptus Kraft (BEK) and Northern Bleached Softwood Kraft (NBSK), consumers are responding by purchasing selflabeled sustainable products. As of today, there are no established sustainability reported results to inform consumers about the carbon footprint of hygiene tissue. To fill this gap, this study used Life Cycle Assessment to evaluate the environmental impacts across the supply chain (cradle to gate) to produce Premium and Ultra grades of bath tissue, including the production of feedstock, pulp production, and tissue production stages, with focus on Global Warming Potential (GWP). The results showed that one air-dried metric ton (ADmt) of BEK pulp had an associated GWP of 388 kgCO2eq, whereas one ADmt of NBSK pulp presented values ranging between 448 and 596 kgCO2eq, depending on the emissions allocation methodology used. It was estimated that the GWP of one finished metric ton of tissue weighted average could range from 1,392 to 3,075 kgCO2eq depending on mill location, electricity source, and machine technology. These results provide an understanding of the factors affecting the environmental impact of hygiene tissue products, which could guide manufacturers and consumers on decisions that impact their carbon footprint. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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271. Nanoparticles and essential oils with antiviral activity on packaging and surfaces: An overview of their selection and application.
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Marquez, Ronald, Zwilling, Jacob, Zambrano, Franklin, Tolosa, Laura, Marquez, Maria E., Venditti, Richard, Jameel, Hasan, and Gonzalez, Ronalds
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PACKAGING materials , *FOOD packaging , *METAL nanoparticles , *ESSENTIAL oils , *VIRAL transmission , *TECHNOLOGICAL innovations - Abstract
Until recently, food packaging has been used as a barrier to unfavorable environmental and microbial conditions, but new technologies are arising aimed at upgrading the protective nature of these materials. Cases of bacterial and viral transmission through food and surfaces have shown the vulnerabilities of the food packaging distribution systems over the years, creating awareness about new methods to prevent the proliferation of pathogens. This has been highlighted by safety concerns due to the COVID‐19 pandemic. This work reviews the state‐of‐the‐art biobased technologies tailored for antiviral applications on surfaces, focusing on packaging materials. A survey and selection tool of essential oils (EOs) and nanoparticles that have been proven effective in reducing the proliferation or transmission of viruses through surfaces is presented. Additionally, the use of essential oil formulations or nanoparticle‐functionalized biobased materials that can be deployed to prevent virus transmission through food produce and surfaces is reviewed, including environmental and safety concerns around the use of metal nanoparticles and EOs in packaging materials. Finally, an assessment of the available technologies, challenges, opportunities and the potential role of biobased antiviral surfaces in future viral outbreaks is presented. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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272. Evaluating chemi-mechanical pulping processes of agricultural residues: High-yield pulps from wheat straw for fiber-based bioproducts.
- Author
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Urdaneta, Fernando, Kumar, Rajnish, Marquez, Ronald, Vera, Ramon E., Franco, Jorge, Urdaneta, Isabel, Saloni, Daniel, Venditti, Richard A., Pawlak, Joel J., Jameel, Hasan, and Gonzalez, Ronalds W.
- Subjects
- *
WASTE paper , *AGRICULTURAL wastes , *ETHYLENEDIAMINETETRAACETIC acid , *BIOLOGICAL products , *HYDROGEN peroxide , *WHEAT straw - Abstract
This work evaluates the feasibility of APMP (alkaline peroxide mechanical pulping) and CTMP (chemi-thermomechanical pulping) of wheat straw as small-scale, low-capital expenditure pulping process to produce high-yield pulps for fiber-based bioproducts. APMP and CTMP wheat straw pulps were characterized in terms of pulping yield, freeness, ISO brightness, and fiber morphology. Additionally, both pulps were evaluated for tissue paper applications and benchmarked against BEK (bleached eucalyptus kraft) market pulp. APMP wheat straw pulps presented higher yield (75.2 – 79.8 %) compared to CTMP (69.1 – 80.6 %), depending on cooking chemicals and chemical charge during the chemical impregnation stage. The final brightness of APMP pulps varied from 36.4 % to 37.8 % ISO when sodium hydroxide and hydrogen peroxide were used as pulping agents without additional chemical additives. However, the brightness of APMP pulps can be increased up to 49.7 % ISO by using additional chemical additives such as EDTA (chelating agent), sodium silicate (peroxide stabilizer), or by employing a multi-stage chemical impregnation strategy. Both pulps produced fibers with similar morphological properties. A comparison of tissue-making properties showed that APMP pulps produced bulkier handsheets with higher water absorption capacity and better softness than CTMP pulps. However, CTMP pulps exhibited a higher tensile index than APMP pulps for a given pulp freeness. The results indicate that non-wood fibers, such as those derived from wheat straw, could be a promising alternative for use in fiber-based bioproducts such as hygiene tissue. • Non-wood feedstock yields high-quality fibers for bio-products. • Chemo-mechanical pulping was evaluated on wheat straw. • Mechanical pulping is a small-scale process to produce high-yield non-wood pulps. • APMP wheat straw shows promise for tissue paper production. • CTMP wheat straw yields high-tensile strength fibers. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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- View/download PDF
273. Valorization of food processing waste: Utilization of pistachio shell as a renewable papermaking filler for paperboard.
- Author
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Lee, Jee-Hong, Fereidooni, Leila, Morais, Ana Rita C., Shiflett, Mark B., Hubbe, Martin A., and Venditti, Richard A.
- Subjects
- *
PISTACHIO , *WASTE recycling , *FOOD waste , *PAPERMAKING , *FOOD industry , *CARDBOARD , *FOOD industrial waste , *PACKAGING recycling - Abstract
Valorization of non-edible parts of food is an important method of reducing food processing waste. This study presents a potential application of nutshell wastes as a renewable and organic papermaking filler in paperboard packaging. Five pistachio shells particle (PSP) samples with different particle size distributions were prepared and their performance as a papermaking filler was examined relative to a conventional ground calcium carbonate (GCC) mineral filler. PSP fillers dispersed well in aqueous suspensions and showed better retention in handsheets compared to that of GCC, due to the improved retention by the larger particle sizes of PSPs. When PSP fillers had smaller particles than the pore sizes in the paper fiber network and their particle size distribution were narrow, they showed comparable mechanical properties in handsheets compared to that of GCC. Future research is suggested for successful applications of this organic and renewable filler in papermaking. [Display omitted] • Non-edible parts of food waste were valorized as papermaking fillers for paperboard. • The size of the pistachio shell particles had a significant impact on their retention and retention mechanism. • Paperboard with pistachio shell particles showed properties comparable to paperboard with mineral filler. • Pistachio shell particles used in paper are expected to provide economic and environmental advantages. • The research methods serve as a template for future research incorporating agricultural waste into paper products. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
274. Techno-economic analysis of biomass value-added processing informed by pilot scale de-ashing of paper sludge feedstock.
- Author
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Tiller, Phoenix, Park, Hyeonji, Cruz, David, Carrejo, Edgar, Johnson, David K., Mittal, Ashutosh, Venditti, Richard, and Park, Sunkyu
- Subjects
- *
FEEDSTOCK , *BIOMASS , *CORPORATE finance , *SUGAR analysis , *INDUSTRIAL costs , *SLUDGE management - Abstract
• Novel application of sidehill screen to remove ash from paper sludge. • Study of screening parameters yielded high pilot scale performance. • Process simulation of plant scale valorization demonstrated technical feasibility. • Techno-economic analysis yielded financial feasibility for sludge valorization. Paper sludge biomass represents an underutilized feedstock rich in pulped and processed cellulose which is currently a waste stream with significant disposal cost to industry for landfilling services. Effective fractionation of the cellulose from paper sludge presents an opportunity to yield cellulose as feedstock for value-added processes. A novel approach to cellulose fractionation is the sidehill screening system, herein studied at the pilot-plant scale. Composition analysis determined ash removal and carbohydrate retention of both sidehill and high-performance benchtop screening systems. Sidehill screening resulted in greater carbohydrates retention relative to benchtop screening (90% vs 66%) and similar ash removal (95% vs 98%). Techno-economic analysis for production of sugar syrup yielded a minimum selling price of $331/metric ton of sugar syrup including disposal savings, significantly less than a commercial sugar syrup without fractionation. Sensitivity analysis showed that screening conditions played a significant role in economic feasibility for cellulosic yield and downstream processes. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
275. Evaluating biomass sustainability: Why below-ground carbon sequestration matters.
- Author
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Forfora, Naycari, Azuaje, Ivana, Vivas, Keren A., Vera, Ramon E., Brito, Amelys, Venditti, Richard, Kelley, Stephen, Tu, Qingshi, Woodley, Alex, and Gonzalez, Ronalds
- Abstract
Biomass, as a raw material, has been identified as a crucial component of decarbonization strategies to mitigate climate change. Decisions on which biomass should be targeted for different purposes are dependent on variables such as availability, chemical composition, and sustainability. Consumer perception often positions non-wood sources, such as bamboo, as environmentally preferable feedstocks for fiber-based product production. Yet, this perceived environmental benefit lacks robust scientific substantiation and standardized methodologies. This study addresses this gap by conducting a cradle-to-gate life cycle assessment (LCA) of twelve biomass production systems encompassing tree plantations, dedicated crops, and agricultural residues for energy and bioproducts manufacture. The evaluated feedstocks include southern softwood, wheat straw, rice straw, rice husk, hemp hurd, sugarcane bagasse, switchgrass, biomass sorghum (United States), eucalyptus (Brazil), bamboo (China), and northern softwood (Canada). Incorporating a critical yet often overlooked factor, this LCA integrates the potential soil organic carbon sequestration (SOC) via below-ground biomass for each biomass type. This consideration significantly alters the estimated carbon intensity per ton of feedstock, potentially reshaping sustainability perceptions as certain systems emerge as carbon sinks. From a cradle-to-farm gate perspective, the assessed global warming potential for biomass production spans 12–245 kg CO 2 eq per oven-dry ton (ODt), factoring only anthropogenic emissions. However, when accounting for SOC sequestration, the range shifts to −170 to 228 kg CO 2 eq per ODt, highlighting the potential role of biomass to act as carbon sink systems. By illuminating the dynamic influence of SOC sequestration, this study contributes to a more comprehensive understanding of biomass-related carbon emissions, shedding light on pathways to mitigate environmental impact. [Display omitted] • Soil carbon shifts biomass assessment. • Holistic analysis integrates soil carbon, displaying biomass potential. • Diverse biomasses offer net-zero path, fueling sustainability. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
276. Innovation in lignocellulosics dewatering and drying for energy sustainability and enhanced utilization of forestry, agriculture, and marine resources - A review.
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Barrios, Nelson, Marquez, Ronald, McDonald, J. David, Hubbe, Martin A., Venditti, Richard A., and Pal, Lokendra
- Subjects
- *
MARINE resources , *LIGNOCELLULOSE , *FORESTS & forestry , *INDUSTRIAL energy consumption , *POWER resources , *FOREST products industry , *MARINE resources conservation , *MICROWAVE drying , *BOOSTING algorithms - Abstract
Efficient utilization of forestry, agriculture, and marine resources in various manufacturing sectors requires optimizing fiber transformation, dewatering, and drying energy consumption. These processes play a crucial role in reducing the carbon footprint and boosting sustainability within the circular bioeconomy framework. Despite efforts made in the paper industry to enhance productivity while conserving resources and energy through lower grammage and higher machine speeds, reducing thermal energy consumption during papermaking remains a significant challenge. A key approach to address this challenge lies in increasing dewatering of the fiber web before entering the dryer section of the paper machine. Similarly, the production of high-value-added products derived from alternative lignocellulosic feedstocks, such as nanocellulose and microalgae, requires advanced dewatering techniques for techno-economic viability. This critical and systematic review aims to comprehensively explore the intricate interactions between water and lignocellulosic surfaces, as well as the leading technologies used to enhance dewatering and drying. Recent developments in technologies to reduce water content during papermaking, and advanced dewatering techniques for nanocellulosic and microalgal feedstocks are addressed. Existing research highlights several fundamental and technical challenges spanning from the nano- to macroscopic scales that must be addressed to make lignocellulosics a suitable feedstock option for industry. By identifying alternative strategies to improve water removal, this review intends to accelerate the widespread adoption of lignocellulosics as feasible manufacturing feedstocks. Moreover, this review aims to provide a fundamental understanding of the interactions, associations, and bonding mechanisms between water and cellulose fibers, nanocellulosic materials, and microalgal feedstocks. The findings of this review shed light on critical research directions necessary for advancing the efficient utilization of lignocellulosic resources and accelerating the transition towards sustainable manufacturing practices. [Display omitted] • One key strategic issue facing the forest products industry is the high energy requirements. • The nature of interactions, association, and bonding of lignocelluloses is essential. • Alternative enzymatic treatments targeting the fiber surface can increase dryness while reducing the need for refining. • An understanding of floc formation and micro and nano-fines migration mechanisms is required. • Nanocellulose and microalgal dewatering is critical to enable braoder applicaitons. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
277. Effect of ash in paper sludge on enzymatic hydrolysis.
- Author
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Park, Hyeonji, Cruz, David, Tiller, Phoenix, Johnson, David K., Mittal, Ashutosh, Jameel, Hasan, Venditti, Richard, and Park, Sunkyu
- Subjects
- *
HYDROLYSIS , *PULP mills , *PAPER mills , *ALTERNATIVE fuels , *PAPER pulp , *CELLULASE , *CALCIUM carbonate - Abstract
The valorization of paper sludge is a high-potential process to develop renewable fuels and chemicals, which can be integrated with pulp and paper mills. Calcium carbonate is the main ash component in sludge, which plays a role in buffering pH and potentially lowering the conversion during enzymatic hydrolysis. Therefore, it is important to investigate the effect of ash on sugar yields and examine pH change to introduce efficient and economical enzymatic hydrolysis of sludge. Carbohydrate conversion was enhanced when the ash was removed by fractionation. On the other hand, the highest sugar recovery was obtained when the sludge contained 20% ash content. The pH change during enzymatic hydrolysis was influenced by ash and explained why sludge-derived hydrolysate showed lower carbohydrate conversion. Therefore, a high shear process with the increased acid amount is suggested to prohibit the negative effect of ash and enhance the accessibility of cellulase to fibers. This study highlights the feasibility of using wet waste streams generated by the paper industry. • Enhanced carbohydrate conversion of sludge containing low ash after fractionation. • Enhanced carbohydrate conversion by lowering the starting pH environment. • Observed pH change during hydrolysis to understand the adverse effect of ash. • Obtained maximum sugar recovery when paper sludge contained 20% ash. • Provided the efficiency of enzymatic hydrolysis depending on the ash content. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
278. Use of mechanical refining to improve the production of low-cost sugars from lignocellulosic biomass.
- Author
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Park, Junyeong, Jones, Brandon, Koo, Bonwook, Chen, Xiaowen, Tucker, Melvin, Yu, Ju-Hyun, Pschorn, Thomas, Venditti, Richard, and Park, Sunkyu
- Subjects
- *
SUGARS , *BIOMASS production , *LIGNOCELLULOSE , *PAPER industry , *BIOCONVERSION , *HYDROLYSIS - Abstract
Mechanical refining is widely used in the pulp and paper industry to enhance the end-use properties of products by creating external fibrillation and internal delamination. This technology can be directly applied to biochemical conversion processes. By implementing mechanical refining technology, biomass recalcitrance to enzyme hydrolysis can be overcome and carbohydrate conversion can be enhanced with commercially attractive levels of enzymes. In addition, chemical and thermal pretreatment severity can be reduced to achieve the same level of carbohydrate conversion, which reduces pretreatment cost and results in lower concentrations of inhibitors. Refining is versatile and a commercially proven technology that can be operated at process flows of ∼1500 dry tons per day of biomass. This paper reviews the utilization of mechanical refining in the pulp and paper industry and summarizes the recent development in applications for biochemical conversion, which potentially make an overall biorefinery process more economically viable. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
279. Micro- and nanofibrillated cellulose from virgin and recycled fibers: A comparative study of its effects on the properties of hygiene tissue paper.
- Author
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Zambrano, Franklin, Wang, Yuhan, Zwilling, Jacob D., Venditti, Richard, Jameel, Hasan, Rojas, Orlando, and Gonzalez, Ronalds
- Subjects
- *
CELLULOSE , *FIBERS , *HARDWOODS , *HYGIENE , *SOFTWOOD , *COMPARATIVE studies , *TISSUES - Abstract
• MNFC increased the tensile index of tissue paper but decreased water absorbency and softness. • MNFCs from NBSK and SBHK yielded comparable trade-offs in tissue properties. • MNFC from BEK showed the lowest improvement in tensile index and degree of fibrillation. • MNFC from DIP had a performance comparable to MNFCs from virgin fibers and the lowest manufacturing cost. • MNFCs having similar degrees of fibrillation could be used interchangeably for enhancing strength. This study aims to understand the effect of micro- and nanofibrillated cellulose (MNFC) on the tensile index, softness, and water absorbency of tissue paper. MNFC was produced from four different fiber sources. The results show that MNFC acts as an effective strength enhancer at the expense of a reduced water absorbency and softness. The impact of the fiber source on MNFC manufacturing cost and the trade-off with performance was also investigated. MNFCs produced from southern bleached hardwood kraft, northern bleached softwood kraft, and deinked pulp exhibited similar performance trends with the MNFC from the deinked pulp having a significantly lower cost. This suggests that MNFCs with similar degrees of fibrillation may be used interchangeably regardless of the fiber source, revealing the possibility to minimize MNFC manufacturing costs based on fiber selection. MNFC produced from bleached Eucalyptus kraft showed the lowest degree of fibrillation and the lowest strength improvements among the MNFCs evaluated. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
280. The global apparel industry is a significant yet overlooked source of plastic leakage.
- Author
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Kounina A, Daystar J, Chalumeau S, Devine J, Geyer R, Pires ST, Sonar SU, Venditti RA, and Boucher J
- Abstract
Plastic pollution is a global environmental threat with potentially irreversible impacts on aquatic life, ecosystems, and human health. This study is a comprehensive assessment of the global apparel industry's contribution to plastic pollution. It includes plastic leakage of packaging and end-of-life apparel waste in addition to fiber emissions during apparel production and use. We estimate that the apparel industry generated 8.3 [4.8-12.3] million tons (Mt) of plastic pollution in 2019, corresponding to 14% [5.5%-30%] of the estimated 60 Mt from all sectors. In this study, we demonstrate that the main source of plastic pollution from the apparel supply chain is synthetic clothing as mismanaged waste either in the country of its original use or in the countries receiving used apparel exports. A fundamental transformation of the apparel economy towards a circular framework and decreased synthetic apparel consumption is needed to tackle apparel-related plastic pollution., (© 2024. The Author(s).)
- Published
- 2024
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281. Survivability of Salmonella Typhimurium (ATCC 14208) and Listeria innocua (ATCC 51742) on lignocellulosic materials for paper packaging.
- Author
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Zwilling JD, Whitham J, Zambrano F, Pifano A, Grunden A, Jameel H, Venditti R, and Gonzalez R
- Abstract
Lignocellulosic materials are widely used for food packaging due to their renewable and biodegradable nature. However, their porous and absorptive properties can lead to the uptake and retention of bacteria during food processing, transportation, and storage, which pose a potential risk for outbreaks of foodborne disease. Thus, it is of great importance to understand how bacteria proliferate and survive on lignocellulosic surfaces. The aim of this research was to compare the growth and survivability of Salmonella Typhimurium and Listeria innocua on bleached and unbleached paper packaging materials. Two different paper materials were fabricated to simulate linerboard from fully bleached and unbleached market pulps and inoculated with each bacterium at high bacterial loads (10
7 CFU). The bacteria propagated during the first 48 h of incubation and persisted at very high levels (>107 CFU/cm2 ) for 40 days for all paper and bacterium types. However, the unbleached paper allowed for a greater degree of bacterial growth to occur compared to bleached paper, suspected to be due to the more hydrophobic nature of the unbleached, lignin-containing fibers. Several other considerations may also alter the behavior of bacteria on lignocellulosic materials, such as storage conditions, nutrient availability, and chemical composition of the fibers., Competing Interests: The authors declare no competing interests., (© 2023 The Authors.)- Published
- 2023
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282. Microfiber shedding from nonwoven materials including wipes and meltblown nonwovens in air and water environments.
- Author
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Kwon S, Zambrano MC, Venditti RA, Frazier R, Zambrano F, Gonzalez RW, and Pawlak JJ
- Subjects
- Wastewater, Water, Textiles, Water Pollutants, Chemical analysis
- Abstract
Nonwoven products are widely used in disposable products, such as wipes, diapers, and masks. Microfibers shed from these products in the aquatic and air environment have not been fully described. In the present study, 15 commercial single-use nonwoven products (wipes) and 16 meltblown nonwoven materials produced in a pilot plant were investigated regarding their microfiber generation in aquatic and air environments and compared to selected textile materials and paper tissue materials. Microfibers shed in water were studied using a Launder Ometer equipment (1-65 mg of microfibers per gram material), and microfibers shed in air were evaluated using a dusting testing machine that shakes a piece of the nonwoven back and forth (~ 4 mg of microfibers per gram material). The raw materials and bonding technologies affected the microfiber generation both in water and air conditions. When the commercial nonwovens contained less natural cellulosic fibers, less microfibers were generated. Bonding with hydroentangling and/or double bonding by two different bonding methods could improve the resistance to microfiber generation. Meltblown nonwoven fabrics generated fewer microfibers compared to the other commercial nonwovens studied here, and the manufacturing factors, such as DCD (die-to-collector distance) and air flow rate, affected the tendency of microfiber generation. The results suggest that it is possible to control the tendency of microfiber shedding through the choice of operating parameters during nonwoven manufacturing processes., (© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)
- Published
- 2022
- Full Text
- View/download PDF
283. Process Simulation-Based Life Cycle Assessment of Dissolving Pulps.
- Author
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Echeverria D, Venditti R, Jameel H, and Yao Y
- Subjects
- Animals, Environment, Eutrophication, Humans, Life Cycle Stages, Ecosystem, Global Warming
- Abstract
Dissolving pulp (DP) is a specialty pulp product from a variety of lignocellulosic biomass (i.e., hardwoods (HW) and softwoods (SW)) with a broad range of applications. Conducting life cycle assessment (LCA) for DP end applications (e.g., textile products, specialty plastics) is challenging due to the lack of life cycle inventory (LCI) data and environmental information associated with different grades. This research addresses this challenge using process simulations to generate LCI for different DP grades (e.g., acetate and viscose) made from HW and SW, respectively. The LCA results show that biomass feedstock directly affects the environmental impacts of DP. For instance, HW acetate grade has higher global warming potential than SW acetate but lower environmental impacts in other categories related to ecosystems and human health. This HW versus SW comparison has similar results for viscose DP in all impact categories except eutrophication. Additionally, a hotspot analysis identifies that on-site emissions and chemicals are the main contributors to the environmental impacts across all grades in this study. The results and LCI data generated in this work provide critical information to support future LCA and sustainability assessment for end-products derived from DP.
- Published
- 2022
- Full Text
- View/download PDF
284. Study of tobacco-derived proteins in paper coatings.
- Author
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Gutierrez JN, Agate S, Venditti RA, and Pal L
- Subjects
- Coated Materials, Biocompatible chemistry, Molecular Weight, Plant Leaves metabolism, Plant Proteins isolation & purification, Porosity, Protein Stability, Soybean Proteins chemistry, Viscosity, Paper, Plant Proteins chemistry, Nicotiana metabolism
- Abstract
Replacing synthetic polymers with renewable alternatives is a critical challenge for the packaging industry. This research investigated the use of leaf-based proteins as a sustainable co-binder in the coating formulations for paper-based packaging and other applications. Protein isolates from tobacco leaf and alfalfa concentrates were characterized using the Pierce protein assay, Kjeldahl nitrogen, and gel electrophoresis. The proteins were tested as co-binders in a typical latex-based paper coating formulation. The rheology and water retention properties of the wet coating and the surface, optical, structural, and strength properties of coated papers were measured. The coating performance was affected by the purity, solubility, and molecular weight of the tobacco protein and exhibited a shear-thinning behavior with lower water retention than soy protein. Analysis by scanning electron microscopy and time of flight secondary ion mass spectroscopy on the dried coating layer containing tobacco protein showed enhanced porosity (advantageous for package glueability) relative to the control latex coating. The tobacco protein offers adequate coverage and coating pigment distribution, indicating that this protein can be a suitable option in coatings for packaging applications., (© 2021 Wiley Periodicals LLC.)
- Published
- 2021
- Full Text
- View/download PDF
285. Synthesis and characterization of starch citrate-chitosan foam with superior water and saline absorbance properties.
- Author
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Salam A, Pawlak JJ, Venditti RA, and El-tahlawy K
- Subjects
- Absorption, Calorimetry, Differential Scanning, Cross-Linking Reagents chemistry, Gels, Magnetic Resonance Spectroscopy, Microscopy, Electron, Scanning, Molecular Structure, Phosphinic Acids chemistry, Starch chemistry, Temperature, Tensile Strength, Viscoelastic Substances chemistry, Chitosan chemistry, Citric Acid chemistry, Sodium Chloride chemistry, Starch analogs & derivatives, Viscoelastic Substances chemical synthesis, Water chemistry
- Abstract
The objective of this research was to synthesize and characterize high-value foam gel materials with unique absorptive and mechanical properties from starch citrate-chitosan. The effects of starch citrate concentration, pH, solid to liquid ratio, reaction time, and temperature on absorbency, weight loss in water, and strength were determined. The cross-linked starch citrate-chitosan foam is flexible and elastic and has significantly increased absorbance and strength and decreased weight loss in water compared to starch-chitosan foam. A unique characteristic of the starch citrate-chitosan foam is that it absorbs more saline solution than pure water, which is the opposite of current commercial super absorbents. An increased strength, increased degradation temperature, increased storage modulus, and decreased weight loss in water for starch citrate-chitosan relative to starch-chitosan are in agreement with amide bonds formed between the carboxyl group of starch citrate and the amino group of chitosan.
- Published
- 2010
- Full Text
- View/download PDF
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