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In this paper, we report the study of essential oils adsorption on three phosphate fertilizers: monoammonium phosphate (MAP), diammonium phosphate (DAP) and triple superphosphate (TSP), with the aim to prepare a bifunctional product which can be used as a fertilizer and biopesticide. Essential oils were isolated by steam distillation from Eucalyptus salubris and Artemisia herbaalba and analysed by GC-MS and GC-FID. About 12 and 22 constituents were identified and quantified in these oils, respectively. The kinetic adsorption study of essential oils showed that DAP and TSP exhibited high adsorption capacities compared with MAP (DAP (0.143 g/g) and TSP (0.139 g/g) for E. salubris essential oil and (DAP (0.135 g/g) and TSP (0.134 g/g) for A. herba-alba essential oil). The adsorption isotherms of all identified components in the E. salubris essential oil were determined and the Langmuir and Freundlich models were used to describe the experimental data. Langmuir model fitted well the isotherms of the majority of the essential oil components (1,8-cineole, α-pinene, β-pinene, isopinocarveol, β-eudesmol, α-phellandrene, pinocarvone, p-cymene and spathulenol) and only terpineol and globulol isotherm data followed the Freundlich model. The selectivity was affected by the abundance of each component in the crude essential oil and the polarity of terpenic components. [ABSTRACT FROM AUTHOR]

There is a growing interest in the possible environmental health impact posed by endocrine-disrupting chemicals (EDCs). A challenge to the field of endocrine disruption is that these substances are diverse and may not appear to share any structural similarity other than usually being low molecular mass (<1000 Da) compounds. Here we demonstrate the effectiveness of sensor device for the detection of low molecular weight, poorly water soluble, estrogenic compounds E1, E2 and EE2, fabricated by electropolymerization over graphene screen printed electrode (SPE). The PANI/Gr-SPE-devices displayed linear responses to estrogenic substances, in EIS assays, from 0.0975 ng/L to 200 ng/L in water samples, with a detection limit of 0.043 pg/L for E1, 0.19 ng/L for E2 and 0.070 pg/L for EE2 which is lower than other current biosensing techniques. This portable, disposable immunosensor offers a solution for immediate measurement at sample collection sites, due to its excellent sensitivity and selectivity when testing water samples obtained directly from rivers and waste water treatment facilities. The simple screen printing production method will enable the low cost, high volume production required for this type of environmental analysis. [ABSTRACT FROM AUTHOR]

Wastewater treatment plants (WWTPs) have been implicated as direct key reservoir of both antibiotic-resistant bacteria (ARB) and antibiotic-resistant genes (ARGs) associated with human infection, as high concentrations of ARBs and ARGs have been detected in recycled hospital wastewater. Among the ARBs, the carbapenem-resistant Acinetobacter baumannii has been ranked as priority 1 (critical) pathogen by the World Health Organization (WHO), due to its overwhelming burden on public health. Therefore, this study is aimed at investigating non-thermal plasma (NTP) technology as an alternative disinfection step to inactivate this bacterium and its ARGs. Culture-based method and PCR were employed in confirming the carbapenem resistance gene bla NDM-1 in A. baumannii (BAA 1605). Suspension of carbapenem-resistant A. baumannii (24 h culture) was prepared from the confirmed isolate and subjected to plasma treatment at varying time intervals (3 min, 6 min, 9 min, 12 min, and 15 min) in triplicates. The plasma-treated samples were evaluated for re-growth and the presence of the resistance gene. The treatment resulted in a 1.13 log reduction after 3 min and the highest log reduction of ≥ 8 after 15 min, and the results also showed that NTP was able to inactivate the bla NDM-1 gene. The log reduction and gel image results suggest that plasma disinfection has a great potential to be an efficient tertiary treatment step for WWTPs., (© 2024. The Author(s).)

The discovery of antibiotics, which was once regarded as a timely medical intervention now leaves a bitter aftertaste: antimicrobial resistance (AMR), due to the unregulated use of these compounds and the poor management receiving wastewaters before discharge into pristine environments or the recycling of such treated waters. Wastewater treatment plants (WWTPs) have been regarded a central sink for the mostly unmetabolized or partially metabolised antibiotics and is also pivotal to the incidence of antibiotic resistance bacteria (ARBs) and their resistance genes (ARGs), which consistently contribute to the global disease burden and deteriorating prophylaxis. In this regard, we highlighted WWTP-antibiotics consumption-ARBs-ARGs nexus, which might be critical to understanding the epidemiology of AMR and also guide the precise prevention and remediation of such occurrences. We also discovered the unsophistication of conventional WWTPs and treatment techniques for adequate treatment of antibiotics, ARBs and ARGs, due to their lack of compliance with environmental sustainability, then ultimately assessed the prospects of cold atmospheric plasma (CAP). Herein, we observed that CAP technologies not only has the capability to disinfect wastewater polluted with copious amounts of chemicals and biologicals, but also have a potential to augment bioelectricity generation, when integrated into bio electrochemical modules, which future WWTPs should be retrofitted to accommodate. Therefore, further research should be conducted to unveil more of the unknowns, which only a snippet has been highlighted in this study., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2023 Mosaka, Unuofin, Daramola, Tizaoui and Iwarere.)

This study evaluated the inactivation of SARS-CoV-2, the virus responsible for COVID-19, by ozone using virus grown in cell culture media either dried on surfaces (plastic, glass, stainless steel, copper, and coupons of ambulance seat and floor) or suspended in liquid. Treatment in liquid reduced SARS-CoV-2 at a rate of 0.92 ± 0.11 log 10 -reduction per ozone CT dose(mg min/L); where CT is ozone concentration times exposure time. On surface, the synergistic effect of CT and relative humidity (RH) was key to virus inactivation; the rate varied from 0.01 to 0.27 log 10 -reduction per ozone CT value(g min/m 3 ) as RH varied from 17% to 70%. Depletion of ozone by competitive reactions with the medium constituents, mass transfer limiting the penetration of ozone to the bulk of the medium, and occlusion of the virus in dried matrix were postulated as potential mechanisms that reduce ozone efficacy. RH70% was found plausible since it provided the highest disinfection rate while being below the critical RH that promotes mould growth in buildings. In conclusion, through careful choice of (CT, RH), gaseous ozone is effective against SARS-CoV-2 and our results are of significance to a growing field where ozone is applied to control the spread of COVID-19., (Copyright © 2022 The Authors. Published by Elsevier B.V. All rights reserved.)

In this study, Pb doped ZnO nanoparticles were synthesized by a sol-gel technique for the sorption of Reactive Black 5 (RB5) textile dye in aqueous solution. The ZnO:Pb (2 and 4%) nanoparticles have been characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and cryogenic nitrogen adsorption method. The average size of the synthesized nanoparticles was less than 100 nm and the surface areas were 18.8 and 20.8 m 2 /g, respectively for ZnO:Pb 2% and ZnO:Pb 4%. Batch sorption experiments were performed for color removal of RB5 dye at ambient temperature and 30 mg/L dye concentration. The central composite design with response surface methodology was used to study the effect of sorption condition (pH, nanoparticles dose and contact time). The significance of independent variables and their interactions was tested by analysis of variance. The optimum conditions of color removal were pH = 7, 2 g/L dose of nanoparticles and a contact time of 79 min. The color removal performance was 79.4 and 98.1% for ZnO:Pb 2 and 4% respectively. The pseudo-second-order model described well the removal rates while the Langmuir model fitted well the adsorption isotherms.

The deposition of precisely controlled clusters from the beam onto suitable supports represents a novel method to prepare advanced cluster-based catalysts. In principle, cluster size, composition, and morphology can be tuned or selected prior to deposition. The newly invented matrix assembly cluster source (MACS) offers one solution to the long-standing problem of low cluster deposition rate. Demonstrations of the cluster activities under realistic reaction conditions are now needed. We deposited elemental silver (Ag) and gold (Au) clusters onto gram-scale powders of commercial titanium dioxide (TiO 2 ) to investigate the catalytic oxidation of nitrophenol (a representative pollutant in water) by ozone in aqueous solution, as relevant to the removal of waste drugs from the water supply. A range of techniques, including scanning transmission electron microscopy (STEM), Brunauer-Emmett-Teller (BET) surface area test, and X-ray photoelectron spectroscopy (XPS), were employed to reveal the catalyst size, morphology, surface area, and oxidation state. Both the Ag and Au cluster catalysts proved active for the nitrophenol ozonation. The cluster catalysts showed activities at least comparable to those of catalysts made by traditional chemical methods in the literature, demonstrating the potential applications of the cluster beam deposition method for practical heterogeneous catalysis in solution.

Aloe gel (Alg), which is a natural extract from the Aloe sp. plant, was evaluated in this study for its potential use as a bioflocculant to treat urban wastewater sewage sludge. The gel was used alone and combined with water glass (WG) under controlled conditions in laboratory experiments. Alg was found effective to settle the flocculated sludge rapidly and remove distinctive unpleasant odours of the sludge as highlighted by gas chromatography-mass spectrometry (GC/MS) analysis. Furthermore, Alg was pH tolerant and had no effect in changing the pH of the wastewater. The optimum dose of Alg was 3% at which a sludge volume index (SVI) of 45.4 mL/g was obtained within 30 min settling time. To enhance the treatment performances of Alg, WG was also evaluated as an alkali agent to further reduce the chemical oxygen demand (COD) and ammonia (NH 4 -N) in the wastewater. At equal doses of 3% of WG and Alg each, the combined treatment outcomes showed high turbidity and NH 4 -N removals of 83 and 89%, respectively, but the overall COD removal was at best 25%. The settling rate of treated sludge with combined Alg/WG was very rapid giving an SVI of 25.4 mL/g within only 5 min.

Several Advanced Oxidation Processes (AOPs) including O 3 /H 2 O 2 , O 3 /TiO 2 , O 3 /activated carbon (AC), O 3 /Al 2 O 3 , O 3 /Fe 2+ /H 2 O 2 and UV/TiO 2 have been investigated and compared for the removal of diethyl phthalate (DEP), an endocrine disrupting compound, in aqueous solutions. Hydroxyl radicals were the main species responsible for DEP degradation and this was supported by computational chemistry calculation, scavenger experiments, and LC/MS/MS analysis. The change of the abundance of reaction products over time was determined. Organic acids as well as anhydride and hydroxylated products were found to accumulate in solution even after long reaction time (2 h). Careful choice of the operating parameters (pH, ozone concentration and catalyst dosage) was crucial to achieve enhanced performance of the combined processes above what each oxidant and catalyst can achieve alone. O 3 /AC process was found to reduce the oxidation efficiency of O 3 at high ozone concentrations. Heterogeneous catalytic ozonation with Al 2 O 3 was the most effective process for DEP removal (∼100% removal in about 15 min) and based on pseudo-first-order kinetics at pH7, the studied oxidation processes followed the order: O 3 /Al 2 O 3 (0.093 min -1 )>O 3 /H 2 O 2 /Fe 2+ (0.076 min -1 )>O 3 /AC(0.069 min -1 )>O 3 /H 2 O 2 (0.053 min -1 )>O 3 /TiO 2 (0.050 min -1 )> O 3 alone (0.039 min -1 )>UV/TiO 2 (0.009 min -1 )., (Copyright © 2018 Elsevier B.V. All rights reserved.)

While antimony has been reported to migrate from PET bottles into contents, reports on bottled water and soft drinks usage and PET bottle reuse patterns are currently unavailable in the literature. Bottle use conditions and patterns are important determinants of antimony migration. In this work a survey assessing the pattern of bottle use and reuse in Britain and Nigeria was undertaken. The survey findings influenced the design of laboratory experiments that assessed the migration of antimony from PET bottles into water and soft drinks. Typical storage durations for bottled contents between purchase and opening for use were 7 days or less. However storage of up to one year was reported. Bottle reuse was high and similar for the two countries with reuse durations being higher in Nigeria. The antimony concentration in 32 PET bottle materials from Britain and Nigeria were similar and ranged between 177 and 310 mg kg(-1). For 47 freshly purchased British bottled contents antimony concentration ranged between 0.03 and 6.61 μg L(-1) with only one sample exceeding the EU acceptable limit. Concentrations of Cd, Ge, Zn, Al, Be, Ti, Co and Pb were also measured. At realistic temperatures of 40 and 60 °C antimony concentration in deionised water in bottles remained below the EU acceptable limit even after 48 h exposure. The limit was exceeded for most exposures at 80 °C. Concentration of antimony in some bottled contents exceeded the EU limit after 11 months of storage at room temperature. Bottle aging and increase in bottle volume were associated with decreased migration of antimony from bottles.

In the search for an efficient and economical method to treat a leachate generated from a controlled municipal solid waste landfill site (Jebel Chakir) in the region of greater Tunis in Tunisia, ozone alone and ozone combined with hydrogen peroxide were studied. The leachate was characterised by high COD, low biodegradability and intense dark colour. A purpose-built reactor, to avoid foaming, was used for the study. It was found that ozone efficacy was almost doubled when combined with hydrogen peroxide at 2g/L but higher H(2)O(2) concentrations gave lower performances. Enhancement in the leachate biodegradability from about 0.1 to about 0.7 was achieved by the O(3)/H(2)O(2) system. Insignificant changes in pH that may due to buffering effect of bicarbonate was found. A small decrease in sulphate concentrations were also observed. In contrast, chloride concentration declined at the beginning of the experiment then increased to reach its initial value. Estimates of the operating costs were made for comparison purposes and it was found that the O(3)/H(2)O(2) system at 2g/L H(2)O(2) gave the lowest cost of about 3.1TND( approximately 2.3USD)/kgCOD removed.