Search

The NOMAD (“Nadir and Occultation for MArs Discovery”) spectrometer suite on board the ExoMars Trace Gas Orbiter (TGO) has been designed to investigate the composition of Mars’ atmosphere, with a particular focus on trace gases, clouds and dust. The detection sensitivity for trace gases is considerably improved compared to previous Mars missions, compliant with the science objectives of the TGO mission. This will allow for a major leap in our knowledge and understanding of the Martian atmospheric composition and the related physical and chemical processes. The instrument is a combination of three spectrometers, covering a spectral range from the UV to the mid-IR, and can perform solar occultation, nadir and limb observations. In this paper, we present the science objectives of the instrument and explain the technical principles of the three spectrometers. We also discuss the expected performance of the instrument in terms of spatial and temporal coverage and detection sensitivity. [ABSTRACT FROM AUTHOR]

Abstract: Our purpose was a qualitative assessment of the impact of dust and water ice aerosols on the retrieved temperature profiles and the retrieval process itself in the Martian atmosphere. It aims to quantify the related uncertainties in the atmospheric temperature profiles derived from radiance measurements of the Planetary Fourier Spectrometer (PFS), currently operating on the Mars Express orbiter. In this study the effects of aerosol opacities on simulated data and retrieved temperature profiles were also investigated. From the analysis of the model atmosphere including dust and water ice with different size distributions it results that the dust component affects weighting functions and brightness temperatures less than water ice. A similar situation is also observed when different vertical distributions are considered. Unlike dust, water ice with different sizes of crystals evidently influences weighting functions and brightness temperatures. The impact of the considered water ice vertical distributions on brightness temperatures is noticeable only near 840cm−1. Considering different dust opacities, the largest differences—5K maximum—between retrieved temperature profiles were observed close to the surface, regardless assumptions on a size distribution or the refractive indices. Contrary to dust, the different sizes of water ice particles assumed during retrieval stronger affected the retrieved temperature profiles than water ice opacities. Moreover, the differences in the retrieved temperature profiles were amplified while wrong optical properties for dust as well as for water ice aerosol were assumed instead of the nominal case. This means that the wrong assumption can induce an additional source of the retrieval error and lead to unreasonable temperature profiles. In the cases of expected heavily loads water ice crystals, their size distribution in the Martian atmosphere should be known from other observations before the retrieval of the temperature profile is attempted. For the analyzed examples of real PFS measurements the impact of different dust vertical distributions on the retrieval of temperature profile is prominent only in layers close to the surface. However, these differences remain comparable with retrieval errors. All influences of dust on weighting functions, brightness temperatures and during retrieval can be neglected if the noise equivalent radiance (NER) of PFS is taken into account. [Copyright &y& Elsevier]

Abstract: The condensing CO2 south polar cap of Mars and the mechanisms of the CO2 ice accumulation have been studied through the analysis of spectra acquired by the Planetary Fourier Spectrometer (PFS) during the first two years of ESA''s Mars Express (MEX) mission. This dataset spans more than half a martian year, from to , and includes the southern fall season which is found to be extremely important for the study of the residual south polar cap asymmetry. The cap expands symmetrically and with constant speed during the fall season. The maximum extension occurs sometime in the 80°–90°Ls range, when the cap edges are as low as −40° latitude. Inside Hellas and Argyre basins, frost can be stable at lower latitudes due to the higher pressure values, causing the seasonal cap to be asymmetric. Within the seasonal range considered in this paper, the cap edge recession rate is approximately half the rate at which the cap edge expanded. The longitudinal asymmetries reduce during the cap retreat, and disappear around . Two different mechanisms are responsible for CO2 ice accumulation during the fall season, especially in the 50°–70°Ls range. Here, CO2 condensation in the atmosphere, and thus precipitation, is allowed exclusively in the western hemisphere, and particularly in the longitudinal corridor of the perennial cap. In the eastern hemisphere, the cap consists mainly of CO2 frost deposits, as a consequence of direct vapor deposition. The differences in the nature of the surface ice deposits are the main cause for the residual south polar cap asymmetry. Results from selected PFS orbits have also been compared with the results provided by the martian general circulation model (GCM) of the Laboratoire de Météorologie dynamique (LMD) in Paris, with the aim of putting the observations in the context of the global circulation. This first attempt of cross-validation between PFS measurements and the LMD GCM on the one hand confirms the interpretation of the observations, and on the other hand shows that the climate modeling during the southern polar night on Mars is extremely sensitive to the dynamical forcing. [Copyright &y& Elsevier]

Abstract: The planetary fourier spectrometer (PFS) for the Mars express mission (MEX) is an infrared spectrometer operating in the wavelength range from 1.2 to 45μm by means of two spectral channels, called SWC (short wavelength channel) and LWC (long wavelength channel), covering, respectively, 1.2–5.5 and 5.5–45μm. The middle-spring Martian north polar cap (Ls∼40°) has been observed by PFS/MEX in illuminated conditions during orbit 452. The SWC spectra are here used to study the cap composition in terms of CO2 ice, H2O ice and dust content. Significant spectral variation is noted in the cap interior, and regions of varying CO2 ice grain sizes, water frost abundance, CO2 ice cover and dust contamination can be distinguished. In addition, we correlate the infrared spectra with an image acquired during the same orbit by the OMEGA imaging spectrometer and with the altimetry from MOLA data. Many of the spectra variations correlate with heterogeneities noted in the image, although significant spectral variations are not discernible in the visible. The data have been divided into five regions with different latitude ranges and strong similarities in the spectra, and then averaged. Bi-directional reflectance models have been run with the appropriate lighting geometry and used to fit the observed data, allowing for CO2 ice and H2O ice grain sizes, dust and H2O ice contaminations in the form of intimate granular mixtures and spatial mixtures. A wide annulus of dusty water ice surrounds the recessing CO2 seasonal cap. The inner cap exhibits a layered structure with a thin CO2 layer with varying concentrations of dark dust, on top of an H2O ice underneath ground. In the best-fits, the ices beneath the top layer have been considered as spatial mixtures. The results are still very good everywhere in the spectral range, except where the CO2 ice absorption coefficients are such that even a thin layer is enough to totally absorb the incoming radiation (i.e. the band is saturated). This only happens around 3800cm−1, inside the strong 2.7-μm CO2 ice absorption band. The effect of finite snow depth has been investigated through a layered albedo model. The thickness of the CO2 ice deposits increases with latitude, ranging from 0.5–1gcm−2 within region II to 60–80gcm−2 within the highest-latitude (up to 84°N) region V. Region I is at the cap edge and extends from 65°N to 72°N latitude. No CO2 ice is present in this region, which consists of relatively large grains of water ice (20μm), highly contaminated by dust (0.15wt%). The adjacent region II is a narrow region [76–79°N] right at the edge of the north residual polar cap. This region is very distinct in the OMEGA image, where it appears to surround the whole residual cap. The CO2 ice features are barely visible in these spectra, except for the strong saturated 2.7μm band. It basically consists of a thin layer of 5-mm CO2 ice on top of an H2O ice layer with the same composition as region I. A third interesting region III is found all along the shoulder of the residual cap [79–81°N]. It extends over 1.5km in altitude and over only 2° of latitude and consists of CO2 ice with a large dust content. It is an admixture of CO2 ice (3–4mm), with several tens of ppm by mass of water ice and more than 2ppt by mass of dust. The surface temperatures have been retrieved from the LWC spectra for each observation. We found an increase in the surface temperature in this region, indicating a spatial mixture of cold CO2 ice and warmer dust/H2O ice. Region IV is close to the top of the residual cap [81–84°N]; it is much brighter than region III, with a dust content 10 times lower than the latter. The CO2 grain size is 3mm and strong CO2 ice features are present in the data, indicating a thicker CO2 ice layer than in region II (1–2gcm−2). The final region V is right at the top of the residual cap (⩾84°N). It is “pure” CO2 ice (no dust) of 5mm grain sizes, with 30ppm by weight of water ice. The CO2 ice features are very pronounced and the 2.7μm band is saturated. The optical thickness is close to the semi-infinite limit (30–40gcm−2). Assuming a snowpack density of 0.5gcm−3, we get a minimum thickness of 1–2cm for the top-layer of regions II and III, 4–10cm for region IV, and ⩾60–80cm thickness for region V. These values are in close agreement with several recent results for the south seasonal polar cap. These results should provide new, useful constraints in models of the Martian climate system and volatile cycles. [Copyright &y& Elsevier]

During the Cassini–Jupiter flyby, VIMS observed Io at different phase angles, both in full sunlight and in eclipse. By using the sunlight measurements, we were able to produce phase curves in the visual through all the near infrared wavelengths covered by the VIMS instrument (0.85–5.1 μm). The phase angle spanned from ∼2° to ∼120°. The measurements, done just after Io emerged from Jupiter''s shadow, show an increase of about 15% in Io''s reflectance with respect to what would be predicted by the phase curve. This behavior is observed at wavelengths >1.2 μm. Moreover, just after emergence from eclipse an increase of about 25% is observed in the depth of SO2 frost bands at 4.07 and 4.35 μm. At 0.879<λ<1.04 μm the brightening is 10–24%. Below λ=0.879 μm the brightening, if present, should be less than the precision of our measurements (∼5%). Apparently, these observations are not explained neither by a diverse spatial distribution of SO2 on the Io'' surface nor by atmospheric SO2 condensation on the surface during the eclipse. [Copyright &y& Elsevier]

Highlights • We analyzed more than 6 Martian years of CO 2 fluorescence emission in Mars’ upper atmosphere. • CO 2 non-LTE emission on Mars was analyzed as a function of several key parameters such as altitude, season, SZA, latitude, and local time. • Several CO 2 emission bands were identified in the spectra and their vertical profiles were retrieved. • The different bands and isotopologues identified in the spectra peak at different altitudes, and are observed at different heights. Abstract We present PFS-MEX limb observations of the CO 2 non-local thermodynamic equilibrium (non-LTE) emission at 4.3 µm in the atmosphere of Mars collected in more than six Martian years. With unprecedented spatial and temporal coverage, and relatively high spectral resolution, this unique dataset promises to improve our understanding of the upper atmosphere of Mars. The former allows analyses of the emission as a function of tangent altitude, solar zenith angle, season, latitude, local time, and thermal condition of the atmosphere. The latter allows unambiguous identification of several emission bands of different isotopologues. We selected observations in the altitude range 50–200 km. No emission was detected for altitudes higher than 170 km. The spectral shape of the non-LTE emission changes dramatically with the altitude of the tangent point, reflecting the different contribution of the major and minor CO 2 bands and isotopologues to the total emission at different heights. For altitudes higher than 130 km the observed spectrum is dominated by the second hot (SH) bands of the main isotopologue 12C16O 2 (also referred to as 626 SH). At lower altitudes, the contribution of the isotopic 13C16O 2 second hot bands (636 SH) to the observed spectrum gradually increases, and is maximum around 70–80 km. Similar consideration apply to the fourth hot bands of the 12C16O 2 (626 FRH), and particularly those from the (2001x) levels, whose contribution is maximum around 80–90 km. The 626 SH bands can be observed up to an altitude 160–170 km, and their emission is peaked around 120–130 km. The 626 FRH and 636 SH bands are not observed above 130–140 km. Both the first hot (FH) and the fundamental band (FB) of the main isotopologue show a peculiar behavior. Indeed, these emissions can be observed at all altitudes, from 50 km up to 170 km. The intensity of the FH band increases linearly with decreasing height, while the intensity of the FB band is essentially constant at all altitudes, and rapidly decreases above 150 km. For a fixed altitude, the solar zenith angle (SZA) is the main parameter affecting the intensity and the spectral shape of the non-LTE emission. For SZA between 0 and 40° the intensity of the emission does not show significant variations. For SZAs larger than 40° the observed emission decreases rapidly with increasing SZA, following a cosine-like relation. The different illumination also affects the spectral shape of the non-LTE emission spectrum. High incidence angles tend to increase the relative contribution of weaker bands compared to stronger/optically thicker bands. For a fixed SZA, we found variation of the intensity of the emission with local time, in response to variations of the thermal structure of the atmosphere. Latitudinal variation of the intensity of the CO 2 non-LTE are also investigated. The maximum intensity is observed around the sub-solar latitudes, where the solar flux is maximum. The intensity of the emission and the altitude at which the maximum emission is observed also changes with the season. The altitude where the maximum intensity of the 626 SH bands is observed decreases from 120–130 km at the perihelion (Ls = 251°), down to ∼85 km at the southern winter solstice (Ls = 90°). This is explained by the variability of the thermal structure (scale heights) of the Martian atmosphere with the season, as a response to the changing solar flux. The altitude of a given pressure level depends on the thermal structure of the atmosphere which, in turn, depends on the season. On the contrary, the pressure level of the peak emission does not depend on the scale heights, as it is mainly controlled by the CO 2 column density above the peak. These results, while on one hand confirm and provide more insights and constraints to some aspects of the non-LTE processes on Mars, on the other hand further stimulate and challenge current theoretical models, possibly bringing closer the moment in which the measurements could be inverted to derive important information about the upper mesosphere and lower thermosphere of Mars. [ABSTRACT FROM AUTHOR]

The NOMAD spectrometer suite on the ExoMars Trace Gas Orbiter will map the composition and distribution of Mars׳ atmospheric trace species in unprecedented detail, fulfilling many of the scientific objectives of the joint ESA-Roscosmos ExoMars Trace Gas Orbiter mission. The instrument is a combination of three channels, covering a spectral range from the UV to the IR, and can perform solar occultation, nadir and limb observations. In this paper, we present the science objectives of the instrument and how these objectives have influenced the design of the channels. We also discuss the expected performance of the instrument in terms of coverage and detection sensitivity. [ABSTRACT FROM AUTHOR]

The Mars Express mission was launched in June 2003 and was inserted into orbit around Mars in December 2003. Its main objective is to study the Mars' subsurface, surface, atmosphere and interaction with the solar wind. A secondary objective is to study the martian moons, in particular the largest one Phobos, thanks to a near polar and elliptical orbit which allows the spacecraft to perform close flybys about every five months. The Mars Express data not only consist of high-resolution 3D color images, but also astrometric images, spectra from 0.18 to 20 μm, radar echoes, Doppler signals from gravity experiments, and ion data. A new view of the moons has emerged from this data set, favoring now the idea that they are not captured asteroids, but rather the result of a re-accretion following a major impact on Mars. This unique set of data is available in the ESA Planetary Science Archive (PSA) and mirror imaged in the NASA Planetary Data System (PDS). This paper presents an overview of the Mars Express Phobos flybys, the specificities of their operations and the scientific achievements. [ABSTRACT FROM AUTHOR]

Abstract: The origin of the Martian satellites presents a puzzle of long standing. Addressing the composition of Phobos will help constrain theories of its formation. Visible and near-infrared spectra of Phobos lack deep absorption features, making the compositional interpretation a tricky task. PFS/MEx and TES/MGS observations in the thermal infrared show several spectral features that can be used to investigate the composition of the surface. Our results show that the majority of the spectra are consistent with the presence of phyllosilicates, particularly in the area northeast of Stickney. This area corresponds to the “blue” region as defined by . Analysis of PFS and TES observations in the “red” region defined by are consistent with tectosilicates, especially feldspars/feldspathoids. We discuss several physical and chemical mechanisms that can act to eliminate or reduce the strength of bands in the VIS/NIR spectra, with possibly little or no effect in the mid-IR. Comparison of the TES and PFS data to the meteorites shows that no class of chondritic meteorites provide significant agreement with the spectral features observed. The lack of consistency of the PFS and TES spectra to analogs of ultraprimitive materials (organic residues) suggests that an origin via capture of a transneptunian object is not supported by these observations, although it cannot be completely ruled out. Derived surface temperatures from PFS and TES data are in very good agreement with brightness temperatures derived from Viking orbiter measurements, Earth-based observations, and values predicted by numerical models. Our results show that the surface temperature of Phobos varies with solar incidence angle and heliocentric distance, reconciling the different results. We collect and summarize the compositional clues for the origin of Phobos discussed in this paper, including our results. Currently, the most likely scenario is the in-situ formation of Phobos, although a capture of achrondrite-like meteorites is not ruled out. [Copyright &y& Elsevier]

Abstract: The MIPAS instrument on board Envisat, in Earth orbit, the PFS and OMEGA instruments on Mars Express, and VIRTIS on board Venus Express are currently providing a dataset of limb measurements of the CO2 atmospheric fluorescence emission at from the upper atmosphere of the three planets. These measurements represent an excellent dataset to perform comparative studies between the terrestrial planets’ upper atmospheres, and also to test our theoretical understanding of these emissions. In order to exploit these datasets, we apply a set of non-local thermodynamic equilibrium (non-LTE) models developed at the IAA/CSIC, in Granada, Spain, to a selection of data. In general, the models can explain the main spectral features of the measurements, and also the altitude and solar zenith angle variations. However, the simulations for Mars and Venus give an incorrect ratio of the emissions at two wavelengths, 4.4 and . In order to explain this deficiency, a revision of the most uncertain non-LTE energy transfer parameters has been performed. The quenching rate of quanta of high-energy CO2 states by CO2 itself could reduce the model-data discrepancy if increased by a factor 2–4, still within its current uncertainty range. This factor, however, is subject to the uncertainty in the thermal structure. A number of simulations with the non-LTE models were also used to study and compare the role of radiative transfer in this spectral region in the three terrestrial planets. Sensitivity studies of density and temperature are also presented, and they permit an analysis of how the differences between the planets and between the three instruments affect their sounding capabilities. [Copyright &y& Elsevier]

Abstract: We report here on CO limb observations in Mars, Venus and Earth and their model simulations. A comparative study of the CO emission, including the most recent spacecraft observations of the three planets’ atmospheres, has been performed. Strong daytime emissions near have been recently observed in the limb of the upper atmosphere of the three terrestrial planets by the Planetary Fourier Spectrometer on Mars Express (), the Visible and Infrared Thermal Imaging Spectrometer on Venus Express (), and the Michelson Interferometer for Passive Atmosphere Sounding on Envisat (). Those emissions are produced by solar pumping of molecular vibrations and non-local thermodynamic equilibrium (non-LTE) models are used to explain them in a consistent framework for the three atmospheres. The maximum of the emission occurs on Venus between 90 and 110km, on Mars above 60km, and on Earth around 68km. The observations show that the fundamental band dominates the CO non-LTE emission on Earth, while on Venus and Mars the larger contribution comes from the first hot band transition. The main goal of this study is to understand those differences and similarities with the help of theoretical simulations with optical thickness considerations, and compare the capability of space instrumentation for the remote sounding of the atmospheres in this spectral region. [Copyright &y& Elsevier]

Abstract: We have analyzed spectra of CO recorded with the instrument PFS onboard Mars Express in the (1–0) band. The dataset we used ranges in time from January until June 2004 ( until ; end of Mars Year 26, beginning of Mars Year 27). The aim of this work was to determine the amplitude of the CO mixing ratio departures from the mean globally averaged value currently admitted () [Kaplan, L.D., Connes, J., Connes, P., 1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187–L192] as a function of season, local time and location on the planet. We therefore processed the data from 90 calibrated orbits. The globally averaged CO mixing ratio value we derive from our dataset, , is compatible with the range found by Kaplan et al. [1969. Carbon monoxide in the martian atmosphere. Astron. J. 157, L187–L192], although somewhat higher than the “standard” value. However, the CO mixing ratio we retrieve exhibits large variations (roughly between and ). Such relative variations have been used on a statistical basis to derive main trends as a function of latitude for three ranges: –, 0– and 30–. For the first range, we seem to have an enhancement of the CO mixing ratio towards the northern latitudes, probably linked to the condensation in winter on the north polar cap. The situation for the two other ranges is not so clear, mainly as we lack data on the southern hemisphere. We roughly agree with the work of Krasnopolsky [2007. Long-term spectroscopic observations of Mars using IRTF/CSHELL: mapping of O2 dayglow, CO and search for CH4. Icarus 190, 93–102] for –, thus confirming the effect of seasonal condensation of on the north polar cap, but we have no agreement for other seasons. [Copyright &y& Elsevier]

Abstract: We present observations of a local dust storm performed by the OMEGA and PFS instruments aboard Mars Express. OMEGA observations are used to retrieve the dust single-scattering albedo in the spectral range 0.4–4.0 μm. The single-scattering albedo shows fairly constant values between 0.6 and 2.6 μm, and a sharp decrease at wavelengths shorter than 0.6 μm, in agreement with previous studies. It presents a small absorption feature due to ferric oxide at 0.9 μm, and a strong absorption feature due to hydrated minerals between 2.7 and 3.6 μm. We use a statistical method, the Independent Component Analysis, to determine that the dust spectral signature is decoupled from the surface albedo, proving that the retrieval of the single-scattering albedo is reliable, and we map the dust optical thickness with a conventional radiative transfer model. The effect of the dust storm on the atmospheric thermal structure is measured using PFS observations. We also simulate the thermal impact of the dust storm using a one-dimensional atmospheric model. A comparison of the retrieved and modeled temperature structures suggests that the dust in the storm should be confined to the 1–2 lowest scale heights of the atmosphere. However, the observed OMEGA reflectance in the CO2 absorption bands does not support this suggestion. [Copyright &y& Elsevier]

Venus Express is the first European (ESA) mission to the planet Venus. Its main science goal is to carry out a global survey of the atmosphere, the plasma environment, and the surface of Venus from orbit. The payload consists of seven experiments. It includes a powerful suite of remote sensing imagers and spectrometers, instruments for in-situ investigation of the circumplanetary plasma and magnetic field, and a radio science experiment. The spacecraft, based on the Mars Express bus modified for the conditions at Venus, provides a versatile platform for nadir and limb observations as well as solar, stellar, and radio occultations. In April 2006 Venus Express was inserted in an elliptical polar orbit around Venus, with a pericentre height of ∼250 km and apocentre distance of ∼66000 km and an orbital period of 24 hours. The nominal mission lasted from June 4, 2006 till October 2, 2007, which corresponds to about two Venus sidereal days. Here we present an overview of the main results of the nominal mission, based on a set of papers recently published in Nature, Icarus, Planetary and Space Science, and Geophysical Research Letters. [ABSTRACT FROM AUTHOR]

Abstract: New insight into the seasonal, diurnal and spatial distribution of water vapor on Mars has been obtained from analyzing the spectra of the short-wavelength channel (SW) of the Planetary Fourier Spectrometer (PFS) onboard Mars Express. The processed dataset, recorded between January 2004 and April 2005, covers the seasons from of Mars Year 26 to of the following year. In this period the mean column density around vernal equinox was 8.2 pr. μm. The maximum values during northern summer were about 65 pr. μm, located around 75° N latitude with a longitudinally inhomogeneous distribution. Regarding the atmospheric transport, the majority of polar water vapor remains in the north polar region while only about a quarter is transported southward. Geographically there are two water vapor maxima visible, over Arabia Terra and the Tharsis plateau, that are most likely caused both by atmosphere–ground interaction and by atmospheric circulation. A comparison with other instruments generally shows a good agreement, only the SPICAM results are systematically lower. Compared to the results from the PFS long-wavelength channel the results of this work are slightly higher. A strong discrepancy is visible northward of about 50° N during the northern summer that is possibly explained by a non-uniform vertical H2O mixing. In particular, a confinement of the water to the lower few kilometers yields a much better agreement between the retrieved column densities of the two PFS channels. [Copyright &y& Elsevier]

Abstract: We apply a multivariate statistical method to the Phoebe spectra collected by the VIMS experiment onboard the Cassini spacecraft during the flyby of June 2004. The G-mode clustering method, which permits identification of the most important features in a spectrum, is used on a small subset of data, characterized by medium and high spatial resolution, to perform a raw spectral classification of the surface of Phoebe. The combination of statistics and comparative analysis of the different areas using both the VIMS and ISS data is explored in order to highlight possible correlations with the surface geology. In general, the results by Clark et al. [Clark, R.N., Brown, R.H., Jaumann, R., Cruikshank, D.P., Nelson, R.M., Buratti, B.J., McCord, T.B., Lunine, J., Hoefen, T., Curchin, J.M., Hansen, G., Hibbitts, K., Matz, K.-D., Baines, K.H., Bellucci, G., Bibring, J.-P., Capaccioni, F., Cerroni, P., Coradini, A., Formisano, V., Langevin, Y., Matson, D.L., Mennella, V., Nicholson, P.D., Sicardy, B., Sotin, C., 2005. Nature 435, 66–69] are confirmed; but we also identify new signatures not reported before, such as the aliphatic CH stretch at 3.53 μm and the ∼4.4 μm feature possibly related to cyanide compounds. On the basis of the band strengths computed for several absorption features and for the homogeneous spectral types isolated by the G-mode, a strong correlation of CO2 and aromatic hydrocarbons with exposed water ice, where the uniform layer covering Phoebe has been removed, is established. On the other hand, an anti-correlation of cyanide compounds with CO2 is suggested at a medium resolution scale. [Copyright &y& Elsevier]

Abstract: The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA/Venus Express mission has technical specifications well suited for many science objectives of Venus exploration. VIRTIS will both comprehensively explore a plethora of atmospheric properties and processes and map optical properties of the surface through its three channels, VIRTIS-M-vis (imaging spectrometer in the 0.3–1μm range), VIRTIS-M-IR (imaging spectrometer in the 1–5μm range) and VIRTIS-H (aperture high-resolution spectrometer in the 2–5μm range). The atmospheric composition below the clouds will be repeatedly measured in the night side infrared windows over a wide range of latitudes and longitudes, thereby providing information on Venus''s chemical cycles. In particular, CO, H2O, OCS and SO2 can be studied. The cloud structure will be repeatedly mapped from the brightness contrasts in the near-infrared night side windows, providing new insights into Venusian meteorology. The global circulation and local dynamics of Venus will be extensively studied from infrared and visible spectral images. The thermal structure above the clouds will be retrieved in the night side using the 4.3μm fundamental band of CO2. The surface of Venus is detectable in the short-wave infrared windows on the night side at 1.01, 1.10 and 1.18μm, providing constraints on surface properties and the extent of active volcanism. Many more tentative studies are also possible, such as lightning detection, the composition of volcanic emissions, and mesospheric wave propagation. [Copyright &y& Elsevier]

Abstract: Venus Express is the first European mission to planet Venus. The mission aims at a comprehensive investigation of Venus atmosphere and plasma environment and will address some important aspects of the surface physics from orbit. In particular, Venus Express will focus on the structure, composition, and dynamics of the Venus atmosphere, escape processes and interaction of the atmosphere with the solar wind and so to provide answers to the many questions that still remain unanswered in these fields. Venus Express will enable a breakthrough in Venus science after a long period of silence since the period of intense exploration in the 1970s and the 1980s. The payload consists of seven instruments. Five of them were inherited from the Mars Express and Rosetta projects while two instruments were designed and built specifically for Venus Express. The suite of spectrometers and imaging instruments, together with the radio-science experiment, and the plasma package make up an optimised payload well capable of addressing the mission goals to sufficient depth. Several of the instruments will make specific use of the spectral windows at infrared wavelengths in order to study the atmosphere in three dimensions. The spacecraft is based on the Mars Express design with minor modifications mainly needed to cope with the thermal environment around Venus, and so a very cost-effective mission has been realised in an exceptionally short time. The spacecraft was launched on 9 November 2005 from Baikonur, Kazakhstan, by a Russian Soyuz-Fregat launcher and arrived at Venus on 11 April 2006. Venus Express will carry out observations of the planet from a highly elliptic polar orbit with a 24-h period. In 3 Earth years (4 Venus sidereal days) of operations, it will return about 2Tbit of scientific data. Telecommunications with the Earth is performed by the new ESA ground station in Cebreros, Spain, while a nearly identical ground station in New Norcia, Australia, supports the radio-science investigations. [Copyright &y& Elsevier]

Abstract: We present the seasonal and geographical variations of the martian water vapor monitored from the Planetary Fourier Spectrometer Long Wavelength Channel aboard the Mars Express spacecraft. Our dataset covers one martian year (end of Mars Year 26, Mars Year 27), but the seasonal coverage is far from complete. The seasonal and latitudinal behavior of the water vapor is globally consistent with previous datasets, Viking Orbiter Mars Atmospheric Water Detectors (MAWD) and Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES), and with simultaneous results obtained from other Mars Express instruments, OMEGA and SPICAM. However, our absolute water columns are lower and higher by a factor of 1.5 than the values obtained by TES and SPICAM, respectively. In particular, we retrieve a Northern midsummer maximum of 60 pr-μm, lower than the 100-pr-μm observed by TES. The geographical distribution of water exhibits two local maxima at low latitudes, located over Tharsis and Arabia. Global Climate Model (GCM) simulations suggest that these local enhancements are controlled by atmospheric dynamics. During Northern spring, we observe a bulge of water vapor over the seasonal polar cap edge, consistent with the northward transport of water from the retreating seasonal cap to the permanent polar cap. In terms of vertical distribution, we find that the water volume mixing ratio over the large volcanos remains constant with the surface altitude within a factor of two. However, on the whole dataset we find that the water column, normalized to a fixed pressure, is anti-correlated with the surface pressure, indicating a vertical distribution intermediate between control by atmospheric saturation and confinement to a surface layer. This anti-correlation is not reproduced by GCM simulations of the water cycle, which do not include exchange between atmospheric and subsurface water. This situation suggests a possible role for regolith–atmosphere exchange in the martian water cycle. [Copyright &y& Elsevier]

Abstract: The Short Wavelength Channel of the Planetary Fourier Spectrometer (PFS) covers the 8333–1750 cm−1 (1.2–5.7 μm) spectral range, that is well suited to study the reflectance properties of the martian soil. These properties vary with time due to the dust dynamics in the martian environment. Wind can blow off dust exposing soil and fresh rocks and can support grain mobility inducing local dust settling. We have analyzed PFS data from January 2004 to April 2005. A detailed photometric study of the radiance acquired from the planet has been performed in order to compare correctly measurements obtained at different viewing geometries and to produce a mosaic image of the planet. The results show good agreement with data from the Thermal Emission Spectrometer (on-board NASA Mars Global Surveyor orbiter), although some variations are observed. Some albedo changes could be due to small to medium scale dust storms. A very accurate estimation of the limb-darkening parameter has been computed from the analyzed data. The obtained values are compared with a surface roughness and a thermal inertia map in order to assess the relation between the limb-darkening parameter and the physical properties of surface. [Copyright &y& Elsevier]

Abstract: Saturn''s icy satellites are among the main scientific objectives of the Cassini-VIMS (Visual and Infrared Mapping Spectrometer) experiment. This paper contains a first systematic and comparative analysis of the full-disk spectral properties of Dione, Enceladus, Epimetheus, Hyperion, Iapetus, Mimas, Phoebe, Rhea and Tethys as observed by VIMS from July 2004 to June 2005. The disk integrated properties (350–5100 nm reflectance spectra and phase curves at 550–2232 nm) and images of satellites are reported and discussed in detail together with the observed geometry. In general, the spectra in the visible spectral range are almost featureless and can be classified according to the spectral slopes: from the bluish Enceladus and Phoebe to the redder Iapetus, Hyperion and Epimetheus. In the 1000–1300 nm range the spectra of Enceladus, Tethys, Mimas and Rhea are characterized by a negative slope, consistent with a surface largely dominated by water ice, while the spectra of Iapetus, Hyperion and Phoebe show a considerable reddening pointing out the relevant role played by darkening materials present on the surface. In between these two classes are Dione and Epimetheus, which have a flat spectrum in this range. The main absorption bands identified in the infrared are the 1520, 2020, 3000 nm H2O/OH bands (for all satellites), although Iapetus dark terrains show mostly a deep 3000 nm band while the 1520 and 2020 nm bands are very faint. In this spectral range, the Iapetus spectrum is characterized by a strong reddening. The CO2 band at 4260 nm and the Fresnel ice peak around 3100 nm are evident only on Hyperion, Phoebe and Iapetus. The phase curves at 550 and at 2232 nm are reported for all the available observations in the 0°–144° range; Rhea shows an opposition surge at visible wavelengths in the 0.5°–1.17° interval. The improvement on the retrieval of the full-disk reflectance spectra can be appreciated by a direct comparison with ground-based telescopic data available from literature. Finally, data processing strategies and recent upgrades introduced in the VIMS-V calibration pipeline (flat-field and destriping–despiking algorithm) are discussed in appendices. [Copyright &y& Elsevier]

Abstract: The Visual and Infrared Mapping Spectrometer (VIMS) instrument on the Cassini Saturn Orbiter returned spectral imaging data as the spacecraft undertook six close encounters with Titan beginning 7 July, 2004. Three of these flybys each produced overlapping coverage of two distinct regions of Titan''s surface. Twenty-four points were selected on approximately opposite hemispheres to serve as photometric controls. Six points were selected in each of four reflectance classes. On one hemisphere each control point was observed at three distinct phase angles. From the derived phase coefficients, preliminary normal reflectances were derived for each reflectance class. The normal reflectance of Titan''s surface units at 2.0178μm ranged from 0.079 to 0.185 for the most absorbing to the most reflective units assuming no contribution from absorbing haze. When a modest haze contribution of τ =0.1 is considered these numbers increase to 0.089–0.215. We find that the lowest three reflectance classes have comparable normal reflectance on either hemisphere. However, for the highest brightness class the normal reflectance is higher on the hemisphere encompassing longitude 14–65° compared to the same high brightness class for the hemisphere encompassing 122–156° longitude. We conclude that an albedo dichotomy observed in continental sized units on Titan is due not only to one unit having more areal coverage of reflective material than the other but the material on the brighter unit is intrinsically more reflective than the most reflective material on the other unit. This suggests that surface renewal processes are more widespread on Titan''s more reflective units than on its less reflective units. We note that one of our photometric control points has increased in reflectance by 12% relative to the surrounding terrain from July of 2004 to April and May of 2005. Possible causes of this effect include atmospheric processes such as ground fog or orographic clouds; the suggestion of active volcanism cannot be ruled out. Several interesting circular features which resembled impact craters were identified on Titan''s surface at the time of the initial Titan flyby in July of 2004. We traced photometric profiles through two of these candidate craters and attempted to fit these profiles to the photometric properties expected from model depressions. We find that the best-fit attempt to model these features as craters requires that they be unrealistically deep, approximately 70km deep. We conclude that despite their appearance, these circular features are not craters, however, the possibility that they are palimpsests cannot be ruled out. We used two methods to test for the presence of vast expanses of liquids on Titan''s surface that had been suggested to resemble oceans. Specular reflection of sunlight would be indicative of widespread liquids on the surface; we found no evidence of this. A large liquid body should also show uniformity in photometric profile; we found the profiles to be highly variable. The lack of specular reflection and the high photometric variability in the profiles across candidate oceans is inconsistent with the presence of vast expanses of flat-lying liquids on Titan''s surface. While liquid accumulation may be present as small, sub-pixel-sized bodies, or in areas of the surface which still remain to be observed by VIMS, the presence of large ocean-sized accumulations of liquids can be ruled out. The Cassini orbital tour offers the opportunity for VIMS to image the same parts of Titan''s surface repeatedly at many different illumination and observation geometries. This creates the possibility of understanding the properties of Titan''s atmosphere and haze by iteratively adapting models to create a best fit to the surface reflectance properties. [Copyright &y& Elsevier]

Abstract: Titan''s bulk density along with Solar System formation models indicates considerable water as well as silicates as its major constituents. This satellite''s dense atmosphere of nitrogen with methane is unique. Deposits or even oceans of organic compounds have been suggested to exist on Titan''s solid surface due to UV-induced photochemistry in the atmosphere. Thus, the composition of the surface is a major piece of evidence needed to determine Titan''s history. However, studies of the surface are hindered by the thick, absorbing, hazy and in some places cloudy atmosphere. Ground-based telescope investigations of the integral disk of Titan attempted to observe the surface albedo in spectral windows between methane absorptions by calculating and removing the haze effects. Their results were reported to be consistent with water ice on the surface that is contaminated with a small amount of dark material, perhaps organic material like tholin. We analyze here the recent Cassini Mission''s visual and infrared mapping spectrometer (VIMS) observations that resolve regions on Titan. VIMS is able to see surface features and shows that there are spectral and therefore likely compositional units. By several methods, spectral albedo estimates within methane absorption windows between 0.75 and 5μm were obtained for different surface units using VIMS image cubes from the Cassini-Huygens Titan Ta encounter. Of the spots studied, there appears to be two compositional classes present that are associated with the lower albedo and the higher albedo materials, with some variety among the brighter regions. These were compared with spectra of several different candidate materials. Our results show that the spectrum of water ice contaminated with a darker material matches the reflectance of the lower albedo Titan regions if the spectral slope from 2.71 to 2.79μm in the poorly understood 2.8-μm methane window is ignored. The spectra for brighter regions are not matched by the spectrum of water ice or unoxidized tholin, in pure form or in mixtures with sufficient ice or tholin present to allow the water ice or tholin spectral features to be discerned. We find that the 2.8-μm methane absorption window is complex and seems to consist of two weak subwindows at 2.7 and 2.8μm that have unknown opacities. A ratio image at these two wavelengths reveals an anomalous region on Titan that has a reflectance unlike any material so far identified, but it is unclear how much the reflectances in these two subwindows pertain to the surface. [Copyright &y& Elsevier]

Abstract: Venus Express is the first European mission to the planet Venus. Its payload consists of seven instruments and will investigate the atmosphere, the plasma environment, and the surface of Venus from orbit. Science planning is a complex process that takes into account requests from all experiments and the operational constraints. The planning of the science operations is based on synergetic approach to provide good coverage of science themes derived from the main mission goals. Typical observations in a single orbit—so-called “science cases” are used to build the mission science activity plan. The nominal science mission (from June 4, 2006 till October 2, 2007) is divided in nine phases depending on observational conditions, occurrences of the solar and Earth occultation, and particular science goals. The observation timelines for each phase were developed in a coordinated way to optimize the payload activity, maximize the overall mission science return, and to fit into the available mission budgets. [Copyright &y& Elsevier]

Abstract: The Visual Infrared Mapping Spectrometer (VIMS) onboard the CASSINI spacecraft obtained new spectral data of the icy satellites of Saturn after its arrival at Saturn in June 2004. VIMS operates in a spectral range from 0.35 to 5.2μm, generating image cubes in which each pixel represents a spectrum consisting of 352 contiguous wavebands. As an imaging spectrometer VIMS combines the characteristics of both a spectrometer and an imaging instrument. This makes it possible to analyze the spectrum of each pixel separately and to map the spectral characteristics spatially, which is important to study the relationships between spectral information and geological and geomorphologic surface features. The spatial analysis of the spectral data requires the determination of the exact geographic position of each pixel on the specific surface and that all 352 spectral elements of each pixel show the same region of the target. We developed a method to reproject each pixel geometrically and to convert the spectral data into map projected image cubes. This method can also be applied to mosaic different VIMS observations. Based on these mosaics, maps of the spectral properties for each Saturnian satellite can be derived and attributed to geographic positions as well as to geological and geomorphologic surface features. These map-projected mosaics are the basis for all further investigations. [Copyright &y& Elsevier]

Abstract: The Isidis Plantita region on Mars is a landing site favored by engineers for its inherent safety. The landing site of Beagle 2 was in this area, as was one of the prime backup landing sites for the Mars Exploration Rover Spirit. Therefore, it seems likely that for future lander missions to Mars this area will be on the shortlist. Within its first orbits Mars Express has passed over Isidis Planitia and the Beagle 2 landing site. From these passes we have derived first estimates of the surface temperature for a region covering the planned landing site of Beagle 2 using in the long wavelength channel (5–45μm) of the Planetary Fourier Spectrometer (PFS) on Mars Express. We have compared these temperatures with a map of surface temperatures for this area derived from a modeling with the Berlin Mars near Surface Thermal model (Helbert, J., Benkhoff, J. A new approach to assessing the burial depth of ground ice deposits and its application to proposed MER landing sites in Isidis Planitia. Journal of Geophysical Research 108(E12), ROV 28-1, 2003). [Copyright &y& Elsevier]

The first European mission to Venus ( Venus Express) is described. It is based on a repeated use of the Mars Express design with minor modifications dictated in the main by more severe thermal environment at Venus. The main scientific task of the mission is global exploration of the Venusian atmosphere, circumplanetary plasma, and the planet surface from an orbiting spacecraft. The Venus Express payload includes seven instruments, five of which are inherited from the missions Mars Express and Rosetta. Two instruments were specially designed for Venus Express. The advantages of Venus Express in comparison with previous missions are in using advanced instrumentation and methods of remote sounding, as well as a spacecraft with a broad spectrum of capabilities of orbital observations. [ABSTRACT FROM AUTHOR]

Observations of Saturn's satellite Enceladus using Cassini's Visual and Infrared Mapping Spectrometer instrument were obtained during three flybys of Enceladus in 2005. Enceladus' surface is composed mostly of nearly pure water ice except near its south pole, where there are light organics, C0[sub 2], and amorphous and crystalline water ice, particularly in the region dubbed the "tiger stripes." An upper limit of 5 precipitable nanometers is derived for CO in the atmospheric column above Enceladus, and 2% for NH[sub 3] in global surface deposits. Upper limits of 140 kelvin (for a filled pixel) are derived for the temperatures in the tiger stripes. [ABSTRACT FROM AUTHOR]

Spectra from Cassini's Visual and Infrared Mapping Spectrometer reveal that the horizontal structure, height, and optical depth of Titan's clouds are highly dynamic. Vigorous cloud centers are seen to rise from the middle to the upper troposphere within 30 minutes and dissipate within the next hour. Their development indicates that Titan's clouds evolve convectively; dissipate through rain; and, over the next several hours, waft downwind to achieve their great longitude extents. These and other characteristics suggest that temperate clouds originate from circulation-induced convergence, in addition to a forcing at the surface associated with Saturn's tides, geology, and/or surface composition. [ABSTRACT FROM AUTHOR]

Abstract: Daytime nadir spectra of the Martian atmosphere taken by the planetary Fourier spectrometer/Mars Express (PFS) and by the infrared space observatory (ISO) in the region are analyzed using a theoretical non-LTE model of the infrared emissions in that atmosphere. Averaged spectra from these instruments show a double peak structure which can be explained by the strong solar pumping at of the () and () vibrational states of the major isotope. After the initial absorption, these states relax radiatively by emission in the second hot bands, whose R- and P-branches produce such structure. It is shown that an LTE atmosphere could not produce such structure. A good fit to the measured spectra is obtained, particularly with PFS, using the currently assumed non-LTE parameters without special adjustments. Analysis of individual bands contributions, their dependence with the thermal structure and solar zenith angle, and the simulation of the altitude variation of the different non-LTE features are presented and discussed. These results confirm the prediction of the non-LTE model and have allowed to identify the main spectral features observed in PFS and ISO data. The dominant double maxima are due to the second hot bands while the individual lines come from the fundamental band. Also the Q-branch of the first hot band and the absence of emission lines in the center of the fundamental band in the PFS spectrum are well reproduced by the simulations. [Copyright &y& Elsevier]

Abstract: This work reports the first observations of the Martian atmosphere returned by the planetary Fourier spectrometer (PFS) on board of Mars express (MEX) satellite in the vicinity of the greatest volcanic domes of the planet. Two of the early MEX orbits have already covered the region of Olympus Mons and Ascraeus Mons. These measurements are very similar in terms of local time (14LT) and season ( and 342, respectively). The long wavelength channel (LWC) of the instrument works in the thermal IR (300–1500cm−1); its data allow the simultaneous retrieval of surface temperature, integrated content of water ice and dust suspended in the atmosphere and air thermal field up to an altitude of about 50km. Results of the code described in the companion paper by Grassi et al. for the two orbits are presented and compared with the state expected by the European Martian climate dataset v3.1. The parent global circulation model LMD-Oxford-AAS is able to take into account a wide number of physical phenomena, but the results included in EMCD are affected by a relatively coarse spatial resolution, that does not properly describe the great volcanic domes. The comparison demonstrated that observed data follow quite strictly the trends foreseen by the model in low altitude regions, while the behavior shows remarkable differences above the relief, where orography likely plays an important role. Namely, extended mid-altitude minima in air temperature fields above the summit of volcanic domes are observed. The integrated content of dust shows a minima above Olympus, as expected for a dust particle concentration that decays with height. Measurements are consistent with an exponential decay characterized by a scale height of ∼10km. Consistently, the surface temperature presents a maxima over the dome, as expected for conditions of clearer sky. Water ice clouds are clearly detected around Ascreus Mons, with a strong asymmetry in latitude. Further comparison with the results of the thermal emission spectrometer (TES) on board of Mars global surveyor (MGS) is also provided, partially supporting our observations of air temperature fields. Possible explanation of these trends is represented by thermal circulation, driven by air heating close to the surface. If confirmed by future observations, these data can represent important constraint by PFS data to mesospheric simulation, with possible implications on the Global Circulation Models. [Copyright &y& Elsevier]

Abstract: This work presents an algorithm for the scientific analysis of individual calibrated measurements from the Planetary Fourier spectrometer (PFS). The instrument, included in the scientific payload of the ESA Mars Express mission to Mars, acquires spectra in the range between 250 and 8200cm−1, with a sampling step of ∼1cm−1 and an effective resolution of ∼2cm−1. The observed radiance depends on several parameters of the atmosphere and surface of Mars as described by the radiative transfer equation. Adopting the very general formalism of Bayesian analysis, we determined which quantities are actually retrievable from individual measurements. Namely, they are: the surface temperature, the column density of dust and water ice aerosols in the atmosphere, the air temperature as a function of altitude (in the indicative range 5–45km above the surface), the surface pressure, and the column density of water vapor and carbon monoxide. These evaluations are carried out taking into account the noise equivalent radiance (NER) of the instrument and the natural variabilities of the investigated parameters in the Martian environment, as estimated from the expectations of the European Martian Climate Dataset v3.1 (EMCD). Other parameters included in the radiative transfer equation shall be assumed as known, because they are not retrievable from individual measurements due to the instrumental NER or an underconstrained inverse problem: the surface emissivity in the thermal infrared, the optical properties of suspended dust and the analytical shape of dust concentration vs. altitude. During the development of the algorithm devoted to these studies, different approaches were evaluated on the basis of formal, computational and scientific considerations, with the aim to develop the general design of an integrated software package. The resulting code was extensively tested on a wide set of simulated PFS spectra. These spectra were computed from the atmospheric and surface conditions extracted from the EMCD, assumed to be representative of the Martian environment for different values of latitude, local time and season. Their comparison with the retrievals from simulated observations allowed us to evaluate the systematic and random errors affecting the procedures with respect to the different quantities involved. The code evaluates the surface temperature with an error in the order of 1K, while the vertical air temperature profile is computed with an uncertainty less than 2K from in the region between 5 and 20km above the surface, increasing up to 7K at 50km. The column opacity of dust, measured in terms of integrated optical thickness at 1100cm−1, is computed with an error of around 0.13. The surface pressure determination is carried out with a typical uncertainty of 0.2–0.3millibar. Several auxiliary tests allowed us to study the correlations between the different retrieval errors and the possible causes of incorrect PFS data interpretation. The choice of a suitable model for the dust optical properties is demonstrated to be particularly critical. This paper also presents the first discussion about application of the procedure to actual PFS Martian data. Despite the calibration issues still affecting the determination of absolute radiance in the near-infrared, the algorithm is able to achieve a satisfactory modeling of observations in a wide range of situations. [Copyright &y& Elsevier]

Titan is the only satellite in our Solar System with a dense atmosphere. The surface pressure is 1.5 bar (ref. 1) and, similar to the Earth, N2 is the main component of the atmosphere. Methane is the second most important component, but it is photodissociated on a timescale of 107 years (ref. 3). This short timescale has led to the suggestion that Titan may possess a surface or subsurface reservoir of hydrocarbons to replenish the atmosphere. Here we report near-infrared images of Titan obtained on 26 October 2004 by the Cassini spacecraft. The images show that a widespread methane ocean does not exist; subtle albedo variations instead suggest topographical variations, as would be expected for a more solid (perhaps icy) surface. We also find a circular structure∼30 km in diameter that does not resemble any features seen on other icy satellites. We propose that the structure is a dome formed by upwelling icy plumes that release methane into Titan's atmosphere. [ABSTRACT FROM AUTHOR]

The origin of Phoebe, which is the outermost large satellite of Saturn, is of particular interest because its inclined, retrograde orbit suggests that it was gravitationally captured by Saturn, having accreted outside the region of the solar nebula in which Saturn formed. By contrast, Saturn's regular satellites (with prograde, low-inclination, circular orbits) probably accreted within the sub-nebula in which Saturn itself formed. Here we report imaging spectroscopy of Phoebe resulting from the Cassini-Huygens spacecraft encounter on 11 June 2004. We mapped ferrous-iron-bearing minerals, bound water, trapped CO2, probable phyllosilicates, organics, nitriles and cyanide compounds. Detection of these compounds on Phoebe makes it one of the most compositionally diverse objects yet observed in our Solar System. It is likely that Phoebe's surface contains primitive materials from the outer Solar System, indicating a surface of cometary origin. [ABSTRACT FROM AUTHOR]

TheCassinivisual and infrared mapping spectrometer (VIMS) investigation is a multidisciplinary study of the Saturnian system. Visual and near-infrared imaging spectroscopy and high-speed spectrophotometry are the observational techniques. The scope of the investigation includes the rings, the surfaces of the icy satellites and Titan, and the atmospheres of Saturn and Titan. In this paper, we will elucidate the major scientific and measurement goals of the investigation, the major characteristics of theCassiniVIMS instrument, the instrument calibration, and operation, and the results of the recentCassiniflybys of Venus and the Earth-Moon system. [ABSTRACT FROM AUTHOR]

The Visual and Infrared Mapping Spectrometer (VIMS) observed the Galilean satellites during the Cassini spacecraft''s 2000/2001 flyby of Jupiter, providing compositional and thermal information about their surfaces. The Cassini spacecraft approached the jovian system no closer than about 126 Jupiter radii, about 9 million kilometers, at a phase angle of , resulting in only sub-pixel observations by VIMS of the Galilean satellites. Nevertheless, most of the spectral features discovered by the Near Infrared Mapping Spectrometer (NIMS) aboard the Galileo spacecraft during more than four years of observations have been identified in the VIMS data analyzed so far, including a possible 13C absorption. In addition, VIMS made observations in the visible part of the spectrum and at several new phase angles for all the Galilean satellites and the calculated phase functions are presented. In the process of analyzing these data, the VIMS radiometric and spectral calibrations were better determined in preparation for entry into the Saturn system. Treatment of these data is presented as an example of the VIMS data reduction, calibration and analysis process and a detailed explanation is given of the calibration process applied to the Jupiter data. [Copyright &y& Elsevier]

The Cassini Visual and Infrared Mapping Spectrometer (VIMS) is an imaging spectrometer covering the wavelength range 0.3–5.2 μm in 352 spectral channels, with a nominal instantaneous field of view of 0.5 mrad. The Cassini flyby of Jupiter represented a unique opportunity to accomplish two important goals: scientific observations of the jovian system and functional tests of the VIMS instrument under conditions similar to those expected to obtain during Cassini''s 4-year tour of the saturnian system. Results acquired over a complete range of visual to near-infrared wavelengths from 0.3 to 5.2 μm are presented. First detections include methane fluorescence on Jupiter, a surprisingly high opposition surge on Europa, the first visual-near-IR spectra of Himalia and Jupiter''s optically-thin ring system, and the first near-infrared observations of the rings over an extensive range of phase angles (0–120°). Similarities in the center-to-limb profiles of H+3 and CH4 emissions indicate that the H+3 ionospheric density is solar-controlled outside of the auroral regions. The existence of jovian NH3 absorption at 0.93 μm is confirmed. Himalia has a slightly reddish spectrum, an apparent absorption near 3 μm, and a geometric albedo of 0.06±0.01 at 2.2 μm (assuming an 85-km radius). If the 3-μm feature in Himalia''s spectrum is eventually confirmed, it would be suggestive of the presence of water in some form, either free, bound, or incorporated in layer-lattice silicates. Finally, a mean ring-particle radius of 10 μm is found to be consistent with Mie-scattering models fit to VIMS near-infrared observations acquired over 0–120° phase angle. [Copyright &y& Elsevier]

We used thermal-infrared spectra returned by the Mars Express Planetary Fourier Spectrometer (PFS/MEx) to retrieve atmospheric temperature profiles, surface temperatures, and column-integrated optical depths of dust and water ice. More than 2,500,000 spectra were processed to build this new atmospheric dataset, covering the full range of season, latitude, longitude, and local time. The data presented here span more than six Martian Years (from MY 26, Ls = 331°, 10 January 2004 to MY 33, Ls = 78°, 6 December 2015). We present an overview of the seasonal and latitudinal dependence of the above atmospheric quantities for the relevant period, as well as an assessment of the interannual variability in the current Martian climate. The general effect of suspended dust on atmospheric temperatures observed during the global dust storm of MY 28 is also presented. Atmospheric temperatures and aerosol opacity were successfully retrieved over cold surface areas and in the polar regions, including the polar nights. Rather than the aphelion cloud belt, the most prominent feature one can observe in the climatology of the Martian water ice clouds is the seasonal extent, pattern and thickness of the North polar hoods (NPH), where most of the thickest clouds are observed. The NPH also shows peculiar features, observed in detail here for the first time, with characteristic spatial and seasonal patterns that repeat very similarly every Martian year. By exploiting PFS/MEx capability to perform observations at different local times (LT), this dataset allowed the characterization of how dust and ice cloud optical depths vary throughout the day on Mars. We present observations of the dust daily cycle during non-dusty seasons; the daily variation of water ice opacity in the aphelion cloud belt; and the diurnal variation of the North and South polar hoods. With unprecedented spatial and temporal coverage and details revealed, this dataset offers new challenges to the Martian global circulation models and, at the same time, a new reference for the MYs complementary to those observed by previous orbiters. • New atmospheric dataset of temperature profiles, surface temperatures, dust and water ice opacity on Mars from PFS-MEx • Successful retrieval over cold surface areas and in the polar regions, including the polar nights • Continuous monitoring of the Martian atmosphere for over 7 full Martian Years (from MY 26, Ls = 331°, to MY 33, Ls = 78°) • Peculiar features of the North Polar Hoods observed in detail for the first time • Complete daily cycle of suspended dust and water ice on Mars [ABSTRACT FROM AUTHOR]