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Sedimentary records of the Earth’s magnetic field often contain unwanted climatic overprints, distorting the reconstruction of paleomagnetic field intensity variations. In case of field reconstructions based on the cosmogenic isotope 10Be, whose production is modulated by the solar activity and the dipolar component of the geomagnetic field, environmental overprints arise from climatic modulations of the source distribution, transport, and sediment scavenging efficiencies. Although the lithological dependence of the scavenging efficiency is supposed to be removed by normalizing 10Be with the stable isotope 9Be, this normalization can introduce its own environmental effects, caused by changes in source, distribution and transport of two isotopes. These processes lead to inter-sites differences observed between 10Be/9Be and corresponding relative paleointensity records, limiting use for global magnetic field models constructions. Principal component analysis (PCA) and independent component analysis (ICA) of four 10Be/9Be records from West Pacific and North Atlantic Ocean sites, characterized by different environmental settings, allowed us to extract the common pattern controlled by the evolution of the dipole field. These observations are made on records covering the last 380 ka, including seven geomagnetic excursions.While the first component of cosmogenic 10Be records clearly reflects geomagnetic dipole changes, it seems that the second and third components are dominated by 100- and 23-ka periodic oscillations respectively, corresponding to Earth’s orbital forcing. PCA and ICA methods are shown to be a powerful tool for disentangling and assessing different components of cosmogenic beryllium records. The geomagnetic component can serve to better understand the long-term geomagnetic field evolution, thus improving our knowledge of driving mechanisms sustaining the geodynamo.

Iron accumulation in the brain is a phenomenon common to many neurodegenerative diseases, perhaps most notably Alzheimer’s disease (AD).We present here magnetic analyses of post-mortem brain tissue of patients who had severe Alzheimer’s disease, and compare the results with those from healthy controls. Isothermal remanent magnetization experiments were performed to assess the extent to which different magnetic carriers are affected by AD pathology and formalin fixation.While Alzheimer’s brain material did not show higher levels of magnetite/maghemite nanoparticles than corresponding controls, the ferrihydrite mineral, known to be found within the core of ferritin proteins and hemosiderin aggregates, almost doubled in concentration in patients with Alzheimer’s pathology, strengthening the conclusions of our previous studies. As part of this study, we also investigated the effects of sample preparation, by performing experiments on frozen tissue as well as tissue which had been fixed in formalin for a period of five months. Our results showed that the two different preparations did not critically affect the concentration of magnetic carriers in brain tissue, as observable by SQUID magnetometry.

International audience; Magnetotactic bacteria (MTB) produce single-stranded or multi-stranded chains of magnetic nanoparticles that contribute to the magnetization of sediments and rocks. Their magnetic fingerprint can be detected in ancient geological samples and serve as a unique biosignature of microbial life. However, some fossilized assemblages bear contradictory signatures pointing to magnetic components that have distinct origin(s). Here, using micromagnetic simulations and mutant MTB producing looped magnetosome chains, we demonstrate that the observed magnetofossil fingerprints are produced by a mixture of single-stranded and multi-stranded chains, and that diagenetically induced chain collapse, if occurring, must preserve the strong uniaxial anisotropy of native chains. This anisotropy is the key factor for distinguishing magnetofossils from other populations of natural magnetite particles, including those with similar individual crystal characteristics. Furthermore, the detailed properties of magnetofossil signatures depend on the proportion of equant and elongated magnetosomes, as well as on the relative abundances of single-stranded and multi-stranded chains. This work has important paleoclimatic, paleontological, and phylogenetic implications, as it provides reference data to differentiate distinct MTB lineages according to their chain and magnetosome morphologies, which will enable the tracking of the evolution of some of the most ancient biomineralizing organisms in a time-resolved manner. It also enables a more accurate discrimination of different sources of magnetite particles, which is pivotal for gaining better environmental and relative paleointensity reconstructions from sedimentary records.

Magnetotactic bacteria (MTB) rely on magnetotaxis to effectively reach their preferred living habitats, whereas experimental investigation of magnetotactic advantage in stable sediment is currently lacking. We studied two wild type MTB (cocci and rod-shaped M. bavaricum) in sedimentary environment under exposure to geomagnetic field in the laboratory, zero field and an alternating field whose polarity was switched every 24 hours. The mean concentration of M. bavaricum dropped by ~50% during 6 months in zero field, with no clear temporal trend suggesting an extinction. Cell numbers recovered to initial values within ~1.5 months after the Earth’s field was reset. Cocci displayed a larger temporal variability with no evident population changes in zero field. The alternating field experiment produced a moderate decrease of M. bavaricum concentrations and nearby extinction of cocci, confirming the active role of magnetotaxis in sediment and might point to a different magnetotactic mechanism for M. bavaricum which possibly benefited them to survive field reversals in geological periods. Our findings provide a first quantification of magnetotaxis advantage in sedimentary environment.

Changes of the Earth's magnetic field have been observed with varying spatial and temporal resolution since the middle ages by means of compasses, and later by refined mechanical inclination and intensity instruments, until the modern use of quantum mechanical devices and satellite observations. Ancient records, on the other hand, rely on the natural magnetization of archaeological artifacts and other materials, such as rocks and sediments, being therefore indirect, less accurate and sparser. The combination of such heterogeneous records into a single, self-consistent, global model of the geomagnetic field is very challenging: the highly uneven data coverage, both in space and time, requires a careful handling of data uncertainties and error correlations. Previous models dealt with this problem using separated treatments of instrumental data and indirect records, respectively, as well as a different handling of the dipole field component, with respect to non-dipole terms. Here we present a global geomagnetic field model based, for the first time, on the simultaneous inversion of historical, archaeomagnetic, and volcanic records, using a Bayesian approach with minimal-committing time regularization that minimizes the energy of secular variation. A detailed assessment of data uncertainty and error correlation is used to minimize artifacts generated by the appearance of an overwhelming number of incomplete, mostly declination-only records, associated with shipboard measurements in the early colonial period. Our model yields lower dipole energies, which better match modern values, as well as higher non-dipole energies and a stronger secular variation of the dipole moment. Some model artifacts associated with extremely heterogeneous distributions of records in time and space are not completely eliminable and might be caused by incorrect a-priori uncertainty assessments. Alternatively, they might represent an intrinsic limit that can be overcome only by adding new records at critical locations and times.

Reconstructions of the global production rate of the cosmogenic isotope 10Be from sedimentary records of authigenic 10Be/9Be ratios have been successfully used to obtain independent estimates of geomagnetic dipole moment variations caused by field excursions or reversals. In this study, we assess the reliability of 10Be/9Be as a proxy for the cosmogenic 10Be production rate by evaluating two potential biasing sources represented by sediment composition and climatic modulation. For this purpose, we compare five high-resolution 10Be/9Be records of the Matuyama-Brunhes (M-B) field reversal from sediment cores of the Indian, West Pacific, and North Atlantic oceans. Significant increase of 10Be/9Be ratios at ∼ 774 ka is explained in terms of the dominant control of geomagnetic modulation during the M-B reversal. Results do not support the existence of a direct proportionality between measured sedimentary 10Be/9Be ratio and cosmogenic 10Be production rate, as shown by 10Be/9Be records that offset relative to each other during and outside the M-B reversal. Residual differences between offset-corrected rescaled records do not appear to be related to an incomplete correction of variable sediment scavenging efficiencies by 9Be normalization. Instead, these differences can be explained by a common climatic modulation model, assuming a linear relation between 10Be/9Be and the global 10Be production rate with site- and time-dependent additive and multiplicative coefficients. These coefficients are linear functions of a single global climate proxy identified with the benthic δ 18 O record. Additive coefficients are almost constant in time and can represent up to ∼ 60% of the average 10Be/9Be value during periods of stable field polarity. Multiplicative coefficients are also site-specific, with mean values representing the bulk scavenging efficiency of the site, and variations about this mean expressing a multiplicative climatic modulation of the 10Be production rate. The amplitude of this modulation amounts to 10–15% of the maximum variations recorded during the M-B reversal and is sufficiently large to mask minor variations of the dipole moment during stable polarity periods. Reconstructions of the geomagnetic dipole intensity can benefit from the information about climatic modulation effects gained with our modelling approach. Best suited sites for magnetic field reconstructions should be characterized by minimal Be-recycling contributions from ancient 10Be reservoirs and minimal climatic modulation, as far as it can be determined from relative comparisons with other records. These conditions are most likely encountered in open basins at sites (1) with 2.8 km water depth, (2) > 200 km offshore, and (3) located underneath a large current system extending over regions with minimum terrigenous inputs. Scaling all records with respect to a chosen reference enables to produce 10Be/9Be stacks with reduced noise and short-term local environmental effects. Differences between stacks obtained in this manner highlight global climatic effects that need to be considered when generating calibrated reconstructions of the geomagnetic dipole moment.

Magnetotactic bacteria (MTB) produce single- or multi-stranded chains of magnetic nanoparticles that contribute to the magnetization of sedimentary rocks. Their magnetic fingerprint can be detected in ancient geological samples, and serve as a unique biosignature of microbial life. However, fossilized assemblages bear contradictory signatures pointing to magnetic components that have distinct origin(s). Here, we produce mutant bacteria to mimic MTB producing multi-stranded chains that cannot be cultivated in the laboratory, and show that the unresolved magnetic signatures are fully compatible with the contribution of MTB synthesizing multi-stranded nanoparticle chains and with fold-collapsed single-stranded chains. These structures generate magnetic flux-closing configurations while maintaining high remanent magnetizations. This work has important paleoclimatic, paleontological and phylogenetic implications, as it provides a novel tool to differentiate distinct MTB lineages (single- vs multi-stranded nanoparticle chains) which will enable the tracking of the evolution of some of the most ancient biomineralizing organisms in a time-resolved manner.

Near-shore marine sediments deposited during the Paleocene-Eocene Thermal Maximum at Wilson Lake, NJ, contain abundant conventional and giant magnetofossils. We find that giant, needle-shaped magnetofossils from Wilson Lake produce distinct magnetic signatures in low-noise, high-resolution first-order reversal curve (FORC) measurements. These magnetic measurements on bulk sediment samples identify the presence of giant, needle-shaped magnetofossils. Our results are supported by micromagnetic simulations of giant needle morphologies measured from transmission electron micrographs of magnetic extracts from Wilson Lake sediments. These simulations underscore the single-domain characteristics and the large magnetic coercivity associated with the extreme crystal elongation of giant needles. Giant magnetofossils have so far only been identified in sediments deposited during global hyperthermal events and therefore may serve as magnetic biomarkers of environmental disturbances. Our results show that FORC measurements are a nondestructive method for identifying giant magnetofossil assemblages in bulk sediments, which will help test their ecology and significance with respect to environmental change.

Levinson-Lessing Lake in northern Central Siberia is a sedimentary archive characterized by continuous, widely constant sedimentation at high rates (0.7 m ka−1 for >32 ka). This study provides the first evidence of the suitability of the lake′s sediments for paleomagnetic analyses using the 46-m-long core Co1401. Although the lowermost 8 m are disturbed, the upper 38 m of Co1401 provide the preconditions for an exceptional, high-resolution paleomagnetic record located within the tangent cylinder of the inner core. High-resolution analyses of magnetic susceptibility, anhysteretic remanent magnetization, isothermal remanent magnetization, and hysteresis parameters show largely uniform mineral magnetic properties. First-order reversal curves indicate magnetite particles in pseudo-single domain state are the main remanence carrier, supplemented by single-domain particles, originating likely from magnetotactic bacteria. Above 6.7 m, the bulk magnetic mineralogy is slightly harder than below and initial greigite formation occurs. However, the main remanence carriers are still of detrital origin.

Since their introduction in Earth sciences in 1990, first-order reversal curve (FORC) measurements have become an important tool for characterizing geologic materials. The visualization of irreversible magnetic processes, such as transitions between magnetic states in individual crystals, in a two-dimensional map provides a unique tool for discriminating complex mixtures of magnetic particle assemblages according to their composition and size, thereby reducing the intrinsic non-uniqueness of simpler magnetic characterization tools. The use of FORC measurements in Earth sciences has rapidly evolved, both technically (e.g., measurement resolution, data processing) and theoretically. For instance, numerical unmixing techniques have been recently implemented on FORC measurements (FORC-PCA), and micromagnetic calculations are now used to model the FORC signature of specific magnetic particle assemblages. The scope of this work is to provide, for the first time, a didactic and comprehensive review of FORC diagrams and their application in Earth sciences which includes (1) the theoretical foundations; (2) the connection with Preisach theory and with other magnetic characterization tools; (3) detailed instructions for optimal planning, execution, and processing of FORC measurements; and (4) an in-depth analysis of the fundamental FORC signatures commonly occurring in rocks and sediments.

The global production rate of the cosmogenic isotope 10Be by cosmic ray spallation is modulated by the activity of the sun and the intensity of the far-reaching component of the Earth magnetic field, which is in turn dominated by the dipolar term. Therefore, sedimentary 10Be records can be used to reconstruct past variations of the geomagnetic dipole moment. However, several environmental factors affect the transfer of 10Be atoms from the high atmosphere and soils, where it is produced, to the sediment, introducing a significant climatic modulation that can, in worst cases, completely obscure the paleomagnetic signal. These factors include variations of the continental runoff, oceanic circulation, sediment fluxes, and sediment scavenging effi­ciency. The latter is largely removed by normalizing the 10Be record with the concentration of authigenic 9Be, which is accumulated by sediment particles in the same manner as the cosmo­genic isotope. Even with this correction in place, individual 10Be/9Be records are significantly influenced by climate, to the point that only major geomagnetic events, such as the MB reversal, can be recognized. We present a model, which, for the first time, enables to deconvolve, at least partially, the climatic and magnetic components of 10Be/9Be records on a set of cores from the Atlantic, Indian, and Pacific Ocean. The climatic modulation is composed of an additive term, which reflects Be recycling through diagenetic release from sediments, and a multiplicative term, which is dominated by oceanic current patterns. Knowledge of these terms enables to remove, at least partially, site-specific environmental effects, obtaining a corrected 10Be/9Be stack that can be inverted to reconstruct variations of the dipole moment during the last geomagnetic reversal.

The period encompassing the past 40 ka is crucial to constrain the characteristic time of the axial dipole, which is computed so far from the historical period and still fails to be tested against long-term field changes. The past 7 kyr of geomagnetic history are primarily documented from archeological artefacts, yet the last 4 kyr remain relatively poorly constrained. Beyond this period, we are dealing with long-term changes of the dipole field that are relatively poorly documented by sedimentary records or by volcanic lava flows. Many measurements of absolute paleointensity do not incorporate directional information, while it is crucial to document the entire field vector and consequently can only be analyzed in terms of virtual axial dipole moments (VADM). In summary, no high resolution dataset covers the field changes which followed the Laschamp event and therefore we have poor knowledge of the pattern of fluctuations and the rate of the changes that were associated with the field recovery after the Laschamp. We have selected a set of marine sedimentary cores based on the quality of their oxygen isotope records. Their deposition rates are comprised between 10 and 20 cm/ka and therefore offer a great potential to constrain the filed intensity changes with a resolution of the order of 100 ka. during this period. We will present the results obtained from 7 marine core records and investigate their common and their discrepant features in order to identify the true paleointensity signal.

Using 12-year-long series of data (2001-2012) from geomagnetic observatories and repeat stations in Austria and its neighboring countries, a regional spatial-temporal (ST) model is developed based on the polynomial expansion consisting of latitude, longitude, and time of the geomagnetic field components and total magnetic field F. Additionally, we have used three different global models (CHAOS-5, POMME-9, and EMM2015), which are built on spherical harmonics up to a maximum degree Lmax and give the core field and crustal field separately. The normal field provided by the ST model and its “model bias”, which comprise the residuals of the differences between measured and predicted values, are calculated and the respective maps are shown. The residuals are considered an estimate of the local crustal field. In the case of global models, we have applied for each of these three methods to calculate the “model bias”: residuals of the differences between observed values and predicted values of the model, residuals of the differences between observed values and core field values of the model, and the average bias for the period 2001-2012. The normal field of the region of Austria provided by each global model is also calculated. Generally, the regional and global models yield relatively similar crustal fields for the Austrian region, especially when the first method is used. The normal fields calculated by them are in good agreement with each other. Each of the global models directly provides the crustal field, and they are compared with the aeromagnetic data provided by aeromagnetic surveys over the Austrian region. The ST model is in better agreement with aeromagnetic data. We have also analyzed the secular variation over the region, which is calculated from the rate of change of normal field given by the ST and global models.

More than 650 million tons/year of fluvial sediment are delivered from continental regions into the South China Sea (SCS). Previous studies have shown that the composition of the magnetic fraction of riverine sediments drained into the SCS is significantly variable from north to south. On the basis of this evidence, we now examine a full set of magnetic properties for a number of core‐tops taken at water depth comprised mostly between 800 and 3500 m. Room‐temperature magnetic parameters and thermal spectra are used to obtain information about the concentration and mineralogical magnetic composition. Spatial changes are observed in the relative proportion of magnetite and hematite with an increase of the latter toward the south, similarly to the observation on land. However, the N‐S contrast is much weaker in marine core tops than in river sediments, because of the role played by the shelf in partly trapping river‐borne sediments, in particular in the southern SCS. In part, sediments also reach the continental slope and the deep basins, being transported and mixed by surface and deep‐water currents, which yield the magnetite‐hematite mixing in the south. For the first time, we characterize a wide spectrum of magnetic properties of modern marine sediment in the South China Sea. Our results give important insights into the modern pathways of sediment particles, depicting the source‐to‐sink processes that affect the terrigenous sediment load.

Magnetotactic bacteria (MTB) synthesize ferrimagnetic crystals that contribute to the remanent magnetization in sediments, yet knowledge of how MTB populations vary in natural environments over time remains limited. We report abundances of three MTB morphotypes from nine sites collected and measured every month over a two-year period from a natural pond near Munich, Germany. Morphotype populations underwent coherent temporal trends among the nine sitesespecially at proximal sites with similar water depths. MTB populations varied independently of bottom water oxygen concentrations or temperature over the two-year period, except for spirilla, which flourished during the summer at some sites. Magnetic properties of the sediments did not reflect living MTB abundances, but instead varied with water depth. Deeper sites, which were also lower in organic carbon, nitrogen, and oxygen concentrations than shallower sites, had higher saturation magnetizations and were richer in single-domain particles.

Hypervelocity impacts occur on bodies throughout our solar system, and play an important role in altering the mineralogy, texture, and magnetic properties in target rocks at nanometer to planetary scales. Here we present the results of hypervelocity impact experiments conducted using a two-stage light-gas gun with 5 mm spherical copper projectiles accelerated toward basalt targets with ~6 km s−1 impact velocities. Four different types of magnetite- and titanomagnetite-bearing basalts were used as targets for seven independent experiments. These laboratory impacts resulted in the formation of agglutinate-like particles similar in texture to lunar agglutinates, which are an important fraction of lunar soil. Materials recovered from the impacts were examined using a suite of complementary techniques, including optical and scanning electron microscopy, micro-Raman spectroscopy, and high- and low-temperature magnetometry, to investigate the texture, chemistry, and magnetic properties of newly formed agglutinate-like particles and were compared to unshocked basaltic parent materials. The use of Cu-projectiles, rather than Fe- and Ni-projectiles, avoids magnetic contamination in the final shock products and enables a clearer view of the magnetic properties of impact-generated agglutinates. Agglutinate-like particles show shock features, such as melting and planar deformation features, and demonstrate shock-induced magnetic hardening (two- to seven-fold increases in the coercivity of remanence Bcr compared to the initial target materials) and decreases in low-field magnetic susceptibility and saturation magnetization. © The Meteoritical Society, 2017. Russian Science Foundation, RSF: 17-17-01279 Rochester Academy of Science, RAS Acknowledgments—We thank the anonymous reviewer for the review and constructive suggestions and Prof. Oliver Tschauner for useful suggestions and the editorial handling, which helped to improve the manuscript. The work is supported by Act 211 Government of the Russian Federation, agreement no. 02.A03.21.0006 and is performed according to the Russian Government Program of Competitive Growth of Kazan Federal University. We gratefully acknowledge support by the U.S. National Science Foundation IRM Visiting Fellowship to N.S.B. D.D.B. was supported by Program no. 7P of Presidium RAS and a Russian Science Foundation Grant 17-17-01279. D.D.B. acknowledges the staff at the Center of Microscopy and Nanotechnology of the University of Oulu (Finland) for assistance with some aspects of electron microprobe and SEM works.

Reconstructions of the past geomagnetic field provide fundamental constraints for understanding the dynamics of the Earth's interior, as well as serving as basis for magnetostratigraphic and archeomagnetic dating tools. Such reconstructions, when extending over epochs that precede the advent of instrumental measurements, rely exclusively on magnetic records from archeological artifacts, and, farther in the past, from rocks and sediments. The most critical component of such indirect records is field intensity because of possible biases introduced by material properties and by laboratory protocols, which do not reproduce exactly the original field recording conditions. Large biases are usually avoided by the use of appropriate checking procedures; however, smaller ones can remain undetected in individual studies and might significantly affect field reconstructions. We introduce a new general approach for analyzing geomagnetic databases in order to investigate the reliability of indirect records. This approach is based on the comparison of historical records with archeomagnetic and volcanic data, considering temporal and spatial mismatches with adequate weighting functions and error estimation. A good overall agreement is found between indirect records and historical measurements, while for several subsets systematic bias is detected (e.g, inclination shallowing of lava records). We also demonstrate that simple approaches to analyzing highly inhomogeneous and internally correlated paleomagnetic datasets can lead to incorrect conclusions about the efficiency of quality checks and corrections. Consistent criteria for selecting and weighting data are presented in this review and can be used to improve current geomagnetic field modeling techniques.

Hypervelocity impacts within the solar system affect both the magnetic remanence and bulk magnetic properties of planetary materials. Spherical shock experiments are a novel way to simulate shock events that enable materials to reach high shock pressures with a variable pressure profile across a single sample (ranging between ∼10 and >160 GPa). Here we present spherical shock experiments on basaltic lava flow and diabase dike samples from the Osler Volcanic Group whose ferromagnetic mineralogy is dominated by pseudo-single-domain (titano)magnetite. Our experiments reveal shock-induced changes in rock magnetic properties including a significant increase in remanent coercivity. Electron and magnetic force microscopy support the interpretation that this coercivity increase is the result of grain fracturing and associated domain wall pinning in multidomain grains. We introduce a method to discriminate between mechanical and thermal effects of shock on magnetic properties. Our approach involves conducting vacuum-heating experiments on untreated specimens and comparing the hysteresis properties of heated and shocked specimens. First order reversal curve (FORC) experiments on untreated, heated and shocked specimens demonstrate that shock and heating effects are fundamentally different for these samples: shock has a magnetic hardening effect that does not alter the intrinsic shape of FORC distributions, while heating alters the magnetic mineralogy as evident from significant changes in the shape of FORC contours. These experiments contextualize paleomagnetic and rock magnetic data of naturally shocked materials from terrestrial and extraterrestrial impact craters. This article is protected by copyright. All rights reserved.

Sediments continuously record variations of the Earth's magnetic field and thus provide an important archive for studying the geodynamo. The recording process occurs as magnetic grains partially align with the geomagnetic field during and after sediment deposition, generating a depositional remanent magnetization (DRM) or post-DRM (PDRM). (P)DRM acquisition mechanisms have been investigated for over 50 years, yet many aspects remain unclear. A key issue concerns the controversial role of bioturbation, that is, the mechanical disturbance of sediment by benthic organisms, during PDRM acquisition. A recent theory on bioturbation-driven PDRM appears to solve many inconsistencies between laboratory experiments and palaeomagnetic records, yet it lacks experimental proof. Here we fill this gap by documenting the important role of bioturbation-induced rotational diffusion for (P)DRM acquisition, including the control exerted on the recorded inclination and intensity, as determined by the equilibrium between aligning and perturbing torques acting on magnetic particles., Sediments record variations of the Earth's magnetic field via the alignment of magnetic grains during and after deposition, yet the role of post-depositional processes remains unclear. Here, the authors present experiments showing how microbially-induced bioturbation controls the alignment process.

Geomagnetically induced currents (GICs) in power systems, which can lead to transformer damage over the short and the long term, are a result of space weather events and geomagnetic variations. For a long time, only high-latitude areas were considered to be at risk from these currents, but recent studies show that considerable GICs also appear in midlatitude and equatorial countries. In this paper, we present initial results from a GIC model using a thin-sheet approach with detailed surface and subsurface conductivity models to compute the induced geoelectric field. The results are compared to measurements of direct currents in a transformer neutral and show very good agreement for short-period variations such as geomagnetic storms. Long-period signals such as quiet-day diurnal variations are not represented accurately, and we examine the cause of this misfit. The modelling of GICs from regionally varying geoelectric fields is discussed and shown to be an important factor contributing to overall model accuracy. We demonstrate that the Austrian power grid is susceptible to large GICs in the range of tens of amperes, particularly from strong geomagnetic variations in the east–west direction.

Geophysical Journal International, 168 (1), ISSN:0956-540X, ISSN:1365-246X

It is widely accepted that cooling rate can strongly influence the intensity of the thermal remanent magnetization (TRM) acquired by rocks during cooling to ambient temperatures. If ignored, this effect might lead to underestimates or overestimates of the ancient magnetic field intensity. To date, however, the cooling rate dependence of TRM acquired by particles with different domain states has never been systematically analyzed from the theoretical or experimental point of view. In this study, we present measurements of the TRM of synthetic magnetites with well-defined grain sizes that were quenched with constant cooling rates of 0.05, 0.1, 1, 3, 10, and 15 K/min. While single domain (SD) and small pseudo-single domain (PSD) samples are found to show larger TRMs after slow cooling, the TRMs of larger PSD and multidomain (MD) magnetites are not affected by an increase or decrease of the cooling rate. Overall, our results suggest that only smallest magnetite grains acquire a cooling rate-dependent TRM. Therefore, cooling rate corrections of paleointensity determinations are only necessary for samples dominated by SD remanence carriers, while rocks dominated by PSD and MD carriers, such as basalts, which are most commonly used for paleointensity studies, do not require such corrections.

[1] The widespread occurrence of magnetotactic bacteria (MTB) in several types of marine and freshwater sediment, and the role of fossil magnetosomes (magnetofossils) as main remanent magnetization carriers therein, has important paleomagnetic and paleoenvironmental implications. Despite numerous studies on MTB biology and on magnetofossil preservation in geological records, no detailed information is yet available on how magnetotaxis (i.e., the ability to navigate along magnetic field lines) is performed in sedimentary environments, and on how magnetofossils possibly record the Earth magnetic field. We provide for the first time experimental evidence for these processes. MTB living in sediment are poorly aligned with the geomagnetic field, contrary to what is observed in water. This can explain the seemingly excessive magnetic moment of most MTB. The observed alignment is sufficient for supporting magnetotaxis across the typical thickness of chemical gradients. Experiments with magnetofossil-rich sediment suggest that a natural remanent magnetization (NRM) is acquired by magnetofossils in the so-called benthic mixed layer, where natural MTB populations usually occur. The acquired NRM is proportional to the applied field at least up to ∼160 µT, and its intensity is compatible with values observed in nature for same sediment types. Therefore, if fossil magnetosome chains are not subjected to further alteration by early diagenetic processes, they can provide useful relative paleointensities. We propose a preliminary model to explain early stages of magnetofossil NRM acquisition as the result of a dynamic equilibrium between magnetic torques and randomizing forces due to sediment mixing.

High-resolution first-order reversal curve (FORC) diagrams are increasingly employed to characterize magnetic minerals in sediments, and especially as a magnetofossil detection tool. Conventional processing protocols, however, are not well suited for this purpose because the opposed needs of high resolution and smoothing of noisy data over different regions of the FORC diagram cannot be reconciled. This problem is particularly severe in samples containing non-interacting single-domain particles, whose FORC signature is described by an infinitely narrow, divergent feature called a central ridge. In this paper, a new FORC processing protocol called VARIFORC (VARIable FORC smoothing) is presented for the analysis of non-regular FORC functions, such as those featuring a central ridge. This protocol is based on weighted polynomial regression of rectangular arrays of measurement points whose size is determined by the local properties of the FORC function (i.e. small arrays where high resolution is needed and vice-versa). The resulting FORC diagram is characterized by improved signal-to-noise ratios that pass significance tests over much larger domains. This enables simultaneous quantitative analysis of FORC signatures corresponding to different magnetization processes (e.g. the central ridge produced by single-domain particles and a weak, extended background due to detrital magnetic minerals). VARIFORC has been successfully tested on a magnetofossil-bearing pelagic carbonate sample that has a non-regular FORC function, and on a volcanic ash sample with a typical pseudo-single-domain signature. An unexpected minor central ridge contribution, which is invisible to traditional processing, has been detected in the volcanic ash sample. This finding demonstrates the effectiveness of the new FORC processing protocol and potential new applications of high-resolution FORC measurements.

Massive stars, which terminate their evolution as core collapse supernovae, are theoretically predicted to eject more than 1E-5 solar masses of the radioisotope 60Fe. If such an event occurs sufficiently close to our solar system, traces of the supernova debris could be deposited on Earth. Herein, we report a time resolved 60Fe signal residing, at least partially, in a biogenic reservoir. Using accelerator mass spectrometry, this signal was found through the direct detection of live 60Fe atoms contained within secondary iron oxides, among which are magnetofossils, the fossilized chains of magnetite crystals produced by magnetotactic bacteria. The magnetofossils were chemically extracted from two Pacific Ocean sediment drill cores. Our results show that the 60Fe signal onset occurs around 2.6 Ma to 2.8 Ma, near the lower Pleistocene boundary, terminates around 1.7 Ma, and peaks at about 2.2 Ma., Figures from the Supplementary Information are not included due to file size restrictions. Download the, now open access, original article for those details (see doi)

Experimental results on the change in the Verwey transition temperature in magnetite under compression exhibit puzzling variability, with slopes ranging from − 6 to + 16 K/GPa. Our thermodynamic analysis of the Verwey transition in magnetite explains much of this variability in terms of the transformation strain as magnetite changes in crystal structure from cubic to monoclinic. Because this strain involves a much larger change in shape than in volume, the change in temperature of the phase boundary ( T v ) can be much more sensitive to nonhydrostatic stress than to hydrostatic pressure. Uniaxial compression and tension both are predicted to increase T v , an effect that is opposite in sign and, for favorable orientations, up to six times greater per gigapascal than for pressure. Moreover, because the monoclinic twin orientation with highest T v is thermodynamically favored, our treatment also shows how any desired twin may be selected uniquely by applying stress of appropriate orientation, thereby removing obstacles to understanding many kinds of low-temperature phenomena in magnetite caused by the presence of multiple twins. A similar analysis for the thermodynamic effects of strong magnetic fields is outlined, predicting that T v will generally be lowered. Again, the twin for which T v is highest (i.e., is lowered the least) will be the most stable. Twin selectivity per gigapascal of stress is up to two to three times stronger than that per Tesla of magnetic field.

There is agreement that ultrafine maghemite grains (

SUMMARY Magnetic properties of suspended material in the water columns of freshwater and marine environments provide snapshots of magnetic biomineralization that have yet to be affected by the eventual time-integration and early diagenetic effects that occur after sediment deposition. Here, we report on the magnetism, geochemistry and geobiology of uncultured magnetite- and greigite-producing magnetotactic bacteria (MB) and magnetically responsive protists (MRP) in Salt Pond (Falmouth, MA, USA), a small coastal, marine basin (∼5 m deep) that becomes chemically stratified during the summer months. At this time, strong inverse O2 and H2S concentration gradients form in the water column and a well-defined oxic–anoxic interface (OAI) is established at a water depth of about 3.5 m. At least four morphological types of MB, both magnetite and greigite producers, and several species of magnetically responsive protists are found associated with the OAI and the lower sulphidic hypolimnion. Magnetic properties of filtered water were determined through the water column across the OAI and were consistent with the occurrence of magnetite- and greigite-producing MB at different depths. Sharp peaks in anhysteretic remanent magnetization (ARM) and saturation isothermal remanent magnetization (SIRM) and single-domain (SD) values of ARM/SIRM occur within the OAI corresponding to high concentrations of MB and MRP with magnetically derived cell densities of 10 4 –10 6 ml −1 . Low-temperature ( 1 per cent) is present within magnetite magnetosomes, produced either

Natural sediments are a complex mixture of magnetic minerals with different origins and different geochemical history, each of which is called a magnetic component. Magnetic components practically never occur in isolated form, and their characterization using bulk magnetic measurements relies on the individuation of the systematic variation of some parameters within a large group of samples. These variations can be interpreted either as a mixing trend or as the result of natural processes, which affect the physical and chemical properties of the magnetic particles. An alternative approach is offered by the analysis of magnetization curves using model functions, which are supposed to represent the magnetic properties of individual components. The success of this approach relies on (1) the choice of model functions that can reproduce the natural properties of a component with sufficient accuracy by varying a minimum number of parameters and (2) on very precise and accurate measurements, which are necessary to overcome the extreme sensitivity of the method to noise. In this paper, the analysis of remanent magnetization curves proposed by Egli (2003) is applied to a large set of representative sediments from the most variable environments and to a set of artificial magnetite samples. Despite the variety of materials and natural processes involved in the formation of these sediments, seven groups of magnetic components with well-defined and consistent properties could be identified. It has been found that both lacustrine and marine sediments contain two magnetically distinct groups of magnetosomes, which react differently to changes of the redox potential. The effects of some natural processes, such as weathering, reductive dissolution and transport could be observed on the individual components.

The characterization of individual magnetic components in sediments and sedimentary rocks is difficult, as these natural materials are often a complex mixture of magnetic mineral sources. The analysis of magnetization curves with model functions is the only practicable method of unmixing the magnetic components and characterizing their magnetic properties, if a priori information is not available. Unfortunately, such analyses rely on time consuming measurements and on the choice of appropriate model functions. The simplification of the unmixing problem is closely related to the number of parameters required to fully characterize a magnetic component, and the significance of these parameters in rock magnetic terms. A systematic analysis of synthetic and natural samples shows that a combination of four parameters, here called magnetic fingerprints, is sufficient for this purpose. The fingerprints of individual magnetic components isolated from a wide range of natural sediments and sedimentary rocks form well-defined groups with specific properties. These groups reflect common processes of formation, transport and dissolution of magnetic particles. A clear distinction can be made between two sorts of biogenic magnetite, atmospheric dust, urban pollution and ultrafine magnetite produced in soils and lacustrine/marine sediments. � 2004 Elsevier Ltd. All rights reserved.

The analysis of magnetization curves with model functions has been proposed independently in several works as a method to unmix and characterize magnetic minerals assemblages in sediments and sedimentary rocks. Unfortunately, a successful result of such analysis relies on time-consuming measurements and on the choice of appropriate model functions. However, once the magnetic properties of individual magnetic components have been determined on a small set of selected samples, a simpler and faster analysis of similar samples is possible. The fast analysis of a large number of samples allows investigation of the effect of natural processes on the properties of single magnetic components. The simplification of the unmixing problem proposed in this paper is based on an iterative linearization procedure, which considers the variability of magnetic components. Any simplification of the unmixing problem is limited by a minimum number of parameters, which are required to fully characterize a magnetic component. It has been shown that a combination of four parameters, so-called magnetic fingerprints, is sufficient for a complete characterization of the remanent magnetization of a component. The usefulness of magnetic fingerprints in tracking natural processes is demonstrated exemplarily for lake sediments. The response of Baldeggersee (Switzerland) to environmental changes has been investigated, with special regard to the role of bacterial magnetite in the iron cycle and its possible use as a sensitive paleoredox indicator. The relation between the magnetic properties of lake sediments on one hand, and climatic, tectonic- and human-driven environmental changes on the other, is strongly non-linear. Therefore, a classic correlation between so-called magnetic proxies and environmental signals should be considered with care.