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We have determined the local structure of photoexcited metastable WO$_3$ created 150 ps after 400 nm laser irradiation by the pulse pump--probe L$_3$-edge extended X-ray absorption fine structure spectroscopy and the constrained thorough search analysis. We have found a highly distorted octahedral local structure with one of the shortest W=O bonds being further shortened to 1.66 \AA while the other five bonds were elongated even though theoretical calculations predicted the reverse change. We discuss this contradiction and propose a possible structure for the metastable state., Comment: 9 pages, 3 figures with SI

Decoy state method quantum key distribution (QKD) is one of the promising practical solutions to BB84 QKD with coherent light pulses. In the real world, however, statistical fluctuations with the finite code length cannot be negligible, and the securities of theoretical and experimental researches of the decoy method state QKD so far are based on the asymptotic GLLP's formula which guarantees only that the limit of eavesdropper's information becomes zero as the code length approaches infinity. In this paper, we propose a substantially improved decoy state QKD in the framework of the finite code length and derive the upper bound of eavesdropper's information in the finite code length decoy state QKD with arbitrary number of decoy states of different intensities incorporating the finite statistics. We also show the performance of our decoy QKD and optimal values of parameters by numerical simulation., Comment: 13 pages, 4 figures

We propose the improved decoy state quantum key distribution incorporating finite statistics due to the finite code length and report on its demonstration. In our experiment, four different intensities including the vacuum state for optimal pulses are used and the key generation rate of 200 bps is achieved in the 20 km telecom optical fiber transmission keeping the eavesdropper's mutual information with the final key less than 2^{-9}., Comment: 5 pages, 1 figure

This paper deals with graph colouring games, an example of pseudo-telepathy, in which two provers can convince a verifier that a graph $G$ is $c$-colourable where $c$ is less than the chromatic number of the graph. They win the game if they convince the verifier. It is known that the players cannot win if they share only classical information, but they can win in some cases by sharing entanglement. The smallest known graph where the players win in the quantum setting, but not in the classical setting, was found by Galliard, Tapp and Wolf and has 32,768 vertices. It is a connected component of the Hadamard graph $G_N$ with $N=c=16$. Their protocol applies only to Hadamard graphs where $N$ is a power of 2. We propose a protocol that applies to all Hadamard graphs. Combined with a result of Frankl, this shows that the players can win on any induced subgraph of $G_{12}$ having 1609 vertices, with $c=12$. Combined with a result of Frankl and Rodl, our result shows that all sufficiently large Hadamard graphs yield pseudo-telepathy games., Comment: 5page

In this paper, we analyze the quantum counting under the decoherence, which can find the number of solutions satisfying a given oracle. We investigate probability distributions related to the first order term of the error rate on the quantum counting with the depolarizing channel. We also implement two circuits for the quantum counting -- the ascending-order circuit and the descending-order circuit -- by reversing ordering of application of controlled-Grover operations. By theoretical and numerical calculations for probability distributions, we reveal the difference of probability distributions on two circuits in the presence of decoherence and show that the ascending-order circuit is more robust against the decoherence than the descending-order circuit. This property of the robustness is applicable to the phase estimation such as the factoring., Comment: 22 pages, 21 figures, submitted to Journal of Physics A