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Double and triple ionization of allene are investigated using electron-electron, ion-ion, electron-electron-ion and electron-electron-ion-ion (ee, ii, eei, eeii) coincidence spectroscopies at selected photon energies. The results provide supporting evidence for a previously proposed roaming mechanism in H$_3^+$ formation by double ionisation. The lowest vertical double ionization energy is found to be 28.5 eV, while adiabatic double ionisation is not accessed by vertical ionisation at the neutral geometry. The triple ionization energy is found to be close to 50 eV in agreement with theoretical predictions. The doubly charged parent ion is stable up to about 2 eV above threshold, after which dissociations by charge separation and by double charge retention occur with comparable intensities. Fragmentation to H$^+$ + C$_3$H$_3^+$ starts immediately above threshold as a slow (metastable) decay with 130+/-10 ns mean lifetime.

To calculate the conductivity of a material having full knowledge of its composition is a reasonably simple task. To do the same in reverse, i.e., to find information about the composition of a device from its conductivity response alone, is very challenging and even more so in the presence of disorder. An inversion methodology capable of decoding the information contained in the conductivity response of disordered structures has been recently proposed but despite claims of generality and robustness, the method has only been used with 2D systems possessing relatively simple electronic structures. Here we put these claims to the test and generalise the inversion method to the case of monolayer MoS$_2$, a material whose electronic structure is far more complex and elaborate. Starting from the spectral function that describes the DC conductivity of a disordered sample of a single layered MoS$_2$ containing a small concentration of randomly dispersed vacancies, we are able to invert the signal and find the exact composition of defects with an impressive degree of accuracy. Remarkably, equally accurate results are obtained with the optical conductivity. This is indicative of a methodology that is indeed suitable to extract composition information from different 2D materials, regardless of their electronic structure complexity. Calculated conductivity results were used as a proxy for their experimental counterpart and were obtained with an efficient quantum transport code (KITE) based on a real-space multi-orbital tight-binding model with parameters generated by density functional theory., Comment: Main: 7 pages, 3 figures Suplemental Material: 2 pages, 4 figures Accepted and in process of being published in New Journal of Physics

In this letter, a C-RAN-type cluster-head-driven uplink model for multiple-antenna Unmanned Aerial Vehicles (UAV) relaying schemes, which enables joint Maximum Likelihood (ML) symbol detection in the UAV cluster-head and the selection of UAV sources to communicate with each other aided by UAV-based relays, {is presented. In this context,} a relay selection technique, named Cluster-Head-Driven Best-Link (CHD-Best-Link), that employs cluster-head buffers and physical-layer network coding, {is devised}. Then, a recursive maximum minimum distance relay selection strategy that exploits time-correlated channels and equips the CHD-Best-Link scheme is developed. Simulations illustrate that CHD-Best-Link has superior average delay and bit error rate performances to that of previous schemes., Comment: 8 pages, 4 figures

In this work, we present a cloud-aided uplink framework for multi-way multiple-antenna relay systems which facilitates joint linear Maximum Likelihood (ML) symbol detection in the cloud and where users are selected to simultaneously transmit to each other aided by relays. We also investigate relay selection techniques for the proposed cloud-aided uplink framework that uses cloud-based buffers and physical-layer network coding. In particular, we develop a novel multi-way relay selection protocol based on the selection of the best link, denoted as Multi-Way Cloud-Aided Best-User-Link (MWC-Best-User-Link). We then devise the maximum minimum distance relay selection criterion along with the algorithm that is incorporated into the proposed MWC-Best-User-Link protocol. Simulations show that MWC-Best-User-Link outperforms previous works in terms of average delay, sum-rate and bit error rate., Comment: 7 pages, 3 figures

In this work, we present a switched relaying framework for multiple-input multiple-output (MIMO) relay systems where a source node may transmit directly to a destination node or aided by relays. We also investigate relay selection techniques for the proposed switched relaying framework, whose relays are equipped with buffers. In particular, we develop a novel relay selection protocol based on switching and the selection of the best link, denoted as Switched Max-Link. We then propose the Maximum Minimum Distance (MMD) relay selection criterion for MIMO systems, which is based on the optimal Maximum Likelihood (ML) principle and can provide significant performance gains over other criteria, along with algorithms that are incorporated into the proposed Switched Max-Link protocol. An analysis of the proposed Switched Max-Link protocol and the MMD relay selection criterion in terms of computational cost, pairwise error probability, sum-rate and average delay is carried out. Simulations show that Switched Max-Link using the MMD criterion outperforms previous works in terms of sum-rate, pairwise error probability, average delay and bit error rate., Comment: 15 pages, 13 figures

Double and triple ionization spectra of isocyanic acid have been measured using multi-electron and ion coincidence techniques combined with synchrotron radiation and compared with high-level theoretical calculations. Vertical double ionization at an energy of 32.8+/-0.3 eV forms the 3A'' ground state in which the HNCO2+ ion is long-lived. The vertical triple ionization energy is determined as 65+/-1 eV. The core-valence double ionization spectra resemble the valence photoelectron spectrum in form, and their main features can be understood on the basis of a simple and rather widely applicable Coulomb model based on the characteristics of the molecular orbitals from which electrons are removed. Characteristics of the most important dissociation channels are examined and discussed., Comment: 15 pages, 6 figures

In this paper, we present a relay-selection strategy for multi-way cooperative multi-antenna systems that are aided by a central processor node, where a cluster formed by two users is selected to simultaneously transmit to each other with the help of relays. In particular, we present a novel multi-way relay selection strategy based on the selection of the best link, exploiting the use of buffers and physical-layer network coding, that is called Multi-Way Buffer-Aided Max-Link (MW-Max-Link). We compare the proposed MW-Max-Link to existing techniques in terms of bit error rate, pairwise error probability, sum rate and computational complexity. Simulations are then employed to evaluate the performance of the proposed and existing techniques., Comment: 5 pages, 3 figures

In this paper, we investigate relay selection for cooperative multiple-antenna systems that are equipped with buffers, which increase the reliability of wireless links. In particular, we present a novel relay selection technique based on switching and the selection of the best link, that is named Switched Max-Link. We also introduce a novel relay selection criterion based on the Maximum Likelihood (ML) principle and the Pairwise Error Probability (PEP) denoted Maximum Minimum Distance (MMD) that is incorporated into the proposed Switched Max-Link protocol. We compare the proposed MMD to the existing Quadratic Norm (QN), in terms of PEP and computational complexity. Simulations are then employed to evaluate the performance of the proposed and existing techniques., Comment: 8 pages, 6 figures. arXiv admin note: substantial text overlap with arXiv:1807.03642

In this paper, we investigate relay selection for cooperative multiple-antenna systems that are equipped with buffers, which increase the reliability of wireless links. In particular, we present a novel relay selection technique based on switching and the Max-Link protocol that is named Switched Max-Link. We also introduce a novel relay selection criterion based on the maximum likelihood (ML) principle denoted maximum minimum distance that is incorporated into. Simulations are then employed to evaluate the performance of the proposed and existing techniques., Comment: 8 pages, 3 figures. arXiv admin note: text overlap with arXiv:1707.00953