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Soil organic matter can be divided into different organic carbon (C) pools with different turnover rates. The organic pollutants in soils associated with these organic C pools may have different bioavailability and environmental risks during the decomposition of soil organic matter. We studied the distribution patterns of 15 USEPA priority polycyclic aromatic hydrocarbons (PAHs) in different particle-size separates (clay, fine silt, coarse silt, fine sand and coarse sand) and density fractions (light and heavy fractions) of nine agricultural topsoils (0–20 cm depth) from a contaminated area in the Yangtze River Delta region of east China. There was a decreasing trend in PAH concentration in particle-size separates with decreasing particle size. However, the different particle-size separates had similar PAH composition. The concentration of PAHs in the light fraction ranged from 13 037 to 107 299 μg kg−1, far higher than in the heavy fraction, which ranged from 222 to 298 μg kg−1. Although the light fraction accounted for only 0.4–2.3% of the soils, it was associated with 31.5–69.5% of soil PAHs. The organic matter in coarse silt had the strongest capacity for enrichment with PAHs. Combining the distributions of PAHs and the turnover rates of organic matter in different soil fractions, the environmental risks of PAH-polluted soils may be due mainly to the PAHs associated with sand and the light fraction. [ABSTRACT FROM AUTHOR]