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Sedimentary pyrite trace-element composition is an established proxy for determining paleo-ocean geochemistry and atmospheric oxygen concentrations through deep time. However, its applicability over shorter time-scales (i.e. <20 Ma) is not well known. To test this, we targeted fine-grained pyrite in the Hovea Member of the Kockatea Shale (Perth Basin, Western Australia), which encompasses the late Permian inertinitic interval and the end-Permian to Early Triassic sapropel, and spans approximately 10 million years. The end-Permian mass extinction (EPME) was the largest extinction event in Earth history, and its greatest effect is documented in the marine environment. Samples were collected from two oil exploration wells—Redback-2 and Hovea-3—spaced ∼20 km apart. In the two boreholes, a change in depositional facies (i.e. between the inertinite and sapropel) occurs below the Permian–Triassic boundary and records the transition from a marginal marine to a shelf environment. This transition is highlighted by several lithogeochemical indicators (e.g. negative shift δ13C values and Corg reduction; increases in Ca, Fe and P), which are themselves tied to fundamental changes in modal mineralogy between the two zones. Importantly, the sapropel also records a major increase in iron sulfide burial over that in the inertinite. LA-ICPMS analyses of pyrite demonstrate that trace-element abundance is highest in samples below the facies transition, and in places reaches a few percent, particularly of Ni (4 wt%), Co (1.5 wt%) and As (2.8 wt%). Moreover, these and other trace elements decrease by an order of magnitude in concert with the negative shift in δ13C values in the sapropel zone. Various whole-rock based paleosalinity indicator ratios (e.g. B/Ga) indicate that the areas of the Perth Basin intersected by Redback-2 and Hovea-3 were not fully connected to the open ocean at the time of the EPME, which leads us to conclude that the very high trace-element values in the sedimentary sulfides are reflective of regional environmental shifts rather than a global signal. Nonetheless, a geochemical contribution from a distant igneous province, such as the Siberian Traps Large Igneous Province, cannot be ruled out. Our work underscores the strength of sedimentary pyrite as a robust paleoenvironmental proxy in the marine environment and highlights the need for further investigation of pyrite trace-element profiles across the mass extinction interval in other sedimentary sequences around the globe. LA-ICPMS-based geochemistry of sedimentary pyrite from the Hovea Member of the Kockatea Shale is considered within a lithochemostratigraphic context. The overall interpretation of the results involves a change in depositional setting from the marginal in the late Permian brackish waters to shelfal marine and loss of oxygen in the Early Triassic Perth Basin. [ABSTRACT FROM AUTHOR]

The late early Permian coincided with a short-lived cold episode in Western Australia, which occurred long after the demise of late Paleozoic ice sheets, and is manifested by conspicuous dropstones in corresponding marine strata. In the northern Perth Basin, this time interval is represented by the Carynginia Formation, which has long been regarded as a record of low-energy marginal-marine sedimentation. The low-diversity body-fossil content and impoverished trace-fossil assemblages in the formation were recognised as evidence of low salinities, low dissolved-oxygen levels and high suspended-sediment concentrations presumably related to freshwater influxes into a restricted basin. However, sedimentary facies indicative of river processes have yet to be documented to explain the sedimentological and paleontological character of the formation. This study examines an overlooked sandstone-rich interval of the Carynginia Formation in the Irwin Sub-basin, a marginal half graben faulted against crystalline basement of the Yilgarn Craton and forming part of a series of late Paleozoic intracratonic rift basins in Western Australia. Facies analysis indicates that the lower part of the interval is dominated by storm-generated deposits containing extraformational pebbles and boulders. These deposits are interpreted as recording lower-shoreface sedimentation under the influence of seasonal sea ice, and constitute a shallower, sandstone-rich equivalent of mudstone-prone strata that otherwise characterise the Carynginia Formation. The upper part of the interval consists of river-borne deposits representing friction-dominated deposition of a river-mouth bar, the first direct record of deltaic sedimentation in the Carynginia Formation. The stratal organisation of mouth-bar bedsets is likely the result of successive sediment-laden pulses related to seasonal floods in a shallow marine basin, and the autogenic evolution of the mouth-bar complex in response to fluctuating river discharge and compensational stacking. Formative runoff events were arguably responsible for reductions in salinity and the introduction of turbid buoyant plumes into the shallow sea that were adverse to faunal development. A fluvial influence may explain the sedimentary character and fossil content of coeval mudstone-prone formations in Western Australian rift basins, especially in the vicinity of cratonic margins. The lower Permian (late Artinskian–Kungurian) mudstone-prone Carynginia Formation in the northern Perth Basin has long been regarded as the record of low-energy, marginal-marine conditions in a cold-water seaway. The low-diversity fossil content in the lower part of the formation indicates stressed physico-chemical conditions influenced by freshwater, sediment-laden influxes. The described mouth-bar deposits are the first direct evidence of deltaic sedimentation in the Carynginia Formation, demonstrating that river outflows likely controlled water chemistry and impacted faunal development. [ABSTRACT FROM AUTHOR]