1. Bisphenols and alternative developers in thermal paper receipts from the U.S. market assessed by Fourier transform infrared spectroscopy.
- Author
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Miller, Gillian Zaharias, Pitzzu, Daniela Tapia, Sargent, Melissa Cooper, and Gearhart, Jeff
- Subjects
FOURIER transform infrared spectroscopy ,BISPHENOLS ,REFLECTANCE spectroscopy ,INFRARED spectroscopy ,CHEMICAL testing ,ATTENUATED total reflectance - Abstract
Cash register receipts made of thermal paper expose workers and shoppers to endocrine-disrupting chemicals and contaminate paper recycling streams. In 2022, 571 receipts were collected from retail stores in the United States and tested for developer chemicals using attenuated total reflection infrared spectroscopy. The results were compared to a 2017 study of 167 receipts to determine changes in color developer use over time. Receipts were tested as-is and a subset were additionally subjected to a simple extraction that improved detection of receipt chemicals. Bisphenol S was the most frequently detected developer (85% of tested receipts), followed by Pergafast 201 (12%), bisphenol A (1%); and Appvion Alpha Free, D-8, and NKK-1304 (each below 1%). NKK-1304 is reported here for the first time in a scientific journal. The frequency of bisphenol A usage in receipts decreased and the frequency of bisphenol S and Pergafast 201 increased between 2017 and 2022, particularly among large companies. National retailers were more likely than regional or local retailers to have adopted non-bisphenol alternatives. Potential health and environmental hazards of the detected developer chemicals and strategies for reduction are discussed. [Display omitted] • Infrared spectroscopy was used to identify thermal paper receipt chemicals. • BPS is a major replacement chemical for BPA in U.S. thermal paper receipts. • Non-bisphenol receipt frequency was 5% in 2017 and 16% in 2022. • Between 2017 and 2022 large national businesses mostly replaced BPA with non-bisphenols. • Between 2017 and 2022 local/regional businesses mostly replaced BPA with BPS. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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