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Diagenetic iron (oxyhydr)oxide minerals are common precipitates expected in CO2 reservoirs, and these minerals record fluid flow for application to carbon capture and sequestration ( CSS). Multiple mineralogy and spectroscopy analyses on a pore to meter scale characterize a well-exposed, lithologically controlled, iron (oxyhydr)oxides reaction front in the Jurassic Navajo Sandstone. Dolomite is the most prevalent cement (up to 23 area%), followed by only several percent or less of iron (oxyhydr)oxides, kaolinite, illite, and gypsum cements. Bulk geochemistry based on diagenetic mineralogies in the reaction front is compared with the water chemistry from nearby modern spring effluent emanating from the Navajo Sandstone to conclude that similar fluids (i.e., CO2-charged, saline waters containing hydrocarbons) are responsible for the precipitation. A second comparison of bulk geochemistry and diagenetic mineralogies of the reaction front with data from other abundant Navajo Sandstone concretions in the Spencer Flat region (in south central Utah) shows that reservoir fluids likely vary spatially and temporally in the porous and permeable Navajo Sandstone. CO2 injection into porous and permeable, quartz arenite, saline aquifers will likely result in minor clay and abundant dolomite precipitation that will significantly decrease porosity. [ABSTRACT FROM AUTHOR]

• We developed and validated Carboxymethyl-dextran coated iron oxide nanoparticles (CION). • We disseminated a step-by-step protocol of our one-pot, cost-efficient synthesis protocol. • We performed several experiments in vivo , demonstrating the use of CION for functional and structural MRI applications. Superparamagnetic iron-oxide nanoparticles are robust contrast agents for magnetic resonance imaging (MRI) used for sensitive structural and functional mapping of the cerebral blood volume (CBV) when administered intravenously. To date, many CBV-MRI studies are conducted with Feraheme, manufactured for the clinical treatment of iron-deficiency. Unfortunately, Feraheme is currently not available outside the United States due to commercial and regulatory constraints, making CBV-MRI methods either inaccessible or very costly to achieve. To address this barrier, we developed a simple, one-pot recipe to synthesize Carboxymethyl-dextran coated Iron Oxide Nanoparticles, namely, "CION", suitable for preclinical CBV-MRI applications. Here we disseminate a step-by-step instruction of our one-pot synthesis protocol, which allows CION to be produced in laboratories with minimal cost. We also characterized different CION-conjugations by manipulating polymer to metal stoichiometric ratio in terms of their size, surface chemistry, and chemical composition, and shifts in MR relaxivity and pharmacokinetics. We performed several proof-of-concept experiments in vivo , demonstrating the utility of CION for functional and structural MRI applications, including hypercapnic CO 2 challenge, visual stimulation, targeted optogenetic stimulation, and microangiography. We also present evidence that CION can serve as a cross-modality research platform by showing concurrent in vivo optical and MRI measurement of CBV using fluorescent-labeled CION. The simplicity and cost-effectiveness of our one-pot synthesis method should allow researchers to reproduce CION and tailor the relaxivity and pharmacokinetics according to their imaging needs. It is our hope that this work makes CBV-MRI more openly available and affordable for a variety of research applications. [ABSTRACT FROM AUTHOR]

Abstract: Iron oxides and other associated minerals (ochre) were widely used in ancient times, however, the use and procurement of these materials is not well understood and there has been little research on the elemental characterization of the material compared to other artifact classes. To assess the possibility of identifying ochre differences between locations, the original potential geological sources should be thoroughly characterized. This paper describes the collection of potential geologic sources of ochre in the Tucson basin of Arizona, sampling of those sources, instrumental neutron activation analysis (INAA), and subsequent multivariate analysis of the data. This paper has several goals, including characterizing geochemical trends within and between ochre sources, identifying the important elements in geochemical characterization of ochre, and establishing a database for further investigations. This preliminary study indicates that the inter- and intra-source variations in geological sources of ochre in the Tucson basin region can be differentiated. Future analysis of iron oxide artifacts will be performed to examine correlations between artifacts and sources and provide a basis for further deductions concerning ancient ochre procurement. [Copyright &y& Elsevier]

Pb adsorption capacities of Fe oxide. Mn oxide and organic materials in natural surface coatings (biofilms and associated minerals ) collected in three lakes, two ponds and a river in Jilin Province, China and Cayuga Lake in US were studied. A novel extraction technique was employed to remove one or more component(s) from the surface coatings. Pb adsorption to surface coatings before and after extraction was performed to determine the adsorptive properties of the extracted component(s), The statistical analysis of observed Pb adsorption was carried out using nonlinear least squares fitting (NLSF) to estimate the Pb adsorption capacity of each component of surface coatings. For each body of water, the estimated Pb adsorption capacity of Mn oxide (mol Pb/mol Mn) was significantly higher than that of Fe oxide (mol Pb/ mol Fe). The value of estimated adsorption capacities of organic materials with the unit mol Pb per kg COD was similar to or Less than that of Fe oxides with the unit mol Pb per mol Fe. Comparison of components of surface coatings in different waters showed that the estimated Pb adsorption capacities of components in surface coatings developed in different natural waters were different, especially for Mn oxides. [ABSTRACT FROM AUTHOR]