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Desorption rates for sediment-associated contaminants during resuspension events are investigated for a site on the Palos Verdes shelf, California. This study focuses on p,p′-DDE, the most abundant DDT compound present in an effluent-affected near-surface sediment deposit on the Palos Verdes shelf. Frequency, magnitude, and duration of resuspension events are estimated from bottom boundary layer measurements and a 17-yr record of surface wave conditions. Desorption of p,p′-DDE from sediment in suspension is calculated using a radial diffusion model for porous aggregates. Suspended sediment concentrations and size distributions during resuspension events are found using a shelf sediment-transport model. Calculations are made for a 60-m site where measurements of near-bed flow and sediment properties, including p,p′-DDE concentration and percent organic carbon by size fraction, are available. The results indicate that the time scales of p,p′-DDE desorption from the finest sediment fractions (<20 μm) are typically much shorter than the duration of resuspension events, which average 1.6 days at the study site, whereas desorption time scales are almost always much longer than event duration for the coarser size fractions (>63 μm); the median bed grain size is about 45 μm. Our calculations suggest that 25–50% of the mass of p,p′-DDE in the surface active layer of the bed is lost during a resuspension event; mean active layer depth is 0.2 cm and mean p,p′-DDE concentration in the uppermost 2 cm of the bed at the study site is 11 μg−1. Total annual loss depends on the number of events per year. Wave data indicate an average of 10 resuspension events per year at a depth of 60-m on the Palos Verdes shelf from 1982 to 1999. This leads to an estimated average loss of p,p′-DDE by desorption during wave-driven resuspension of 3–7 μg cm−2 yr−1 for the 60-m site. The range in average loss rates is due to the large range in published values of the partition coefficient for DDE. [Copyright &y& Elsevier]

We combine direct observations, longer-term wave data, and model calculations to characterize resuspension and transport of fine-grained, effluent-affected sediment on the Palos Verdes shelf. Near-bed waves, currents, and suspended sediment concentrations were monitored during the winter of 1992–93 with a bottom tripod and current-meter mooring at a 63-m-deep site. Wave conditions that winter were moderate (∼2 year recurrence interval), and mean current was alongshelf to the northwest; currents were not significantly correlated with wave conditions. Seven wave events during the winter (December–March) produced near-bed wave orbital velocities at the study site in excess of 14 cm s−1, the observed threshold for significant resuspension. Three of these events occurred during the bottom tripod deployment and are characterized by the highest persistent suspended sediment concentrations in the tripod record. Suspended sediment flux was alongshelf to the northwest for 5 of the 6 wave events for which current data were available; one event occurred during low southeast currents. Measured suspended sediment concentration and grain size generally agree with values that were calculated using a shelf sediment transport model with no adjustment of parameters from values determined for two muddy sites on the northern California shelf. We extend our seasonal observations to a period of almost 2 decades by applying the observed thresholds for wave-driven resuspension to near-bed wave conditions calculated from NDBC Buoy 46025 surface wave data. An average of 10 resuspension events per year, with an average duration of 1.6 days, were identified at a water depth of 60 m; the number of events dropped to 3 per year at 90 m, beyond the shelf break. For the majority of these events, calculated net suspended sediment flux is toward the northwest (alongshelf) at an average rate of 140 kg m−1 h−1; about a third of the events have net southeastward flux at an average rate of 30 kg m−1 h−1. The calculated thickness of the resuspended surface layer of the bed was less than 1 cm for all events at 60 m. [Copyright &y& Elsevier]