1. Thermal Alteration History of the Fenghuoshan Group, Hoh Xil Basin, Northern Tibetan Plateau: Insights From Clumped Isotope Thermometry.
- Author
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Kong, Kai, Deng, Wenfeng, Guo, Yangrui, Jin, Chunsheng, Liu, Qingsong, and Wei, Gangjian
- Subjects
THERMOMETRY ,TEMPERATURE measurements ,PLATEAUS ,PALEOCLIMATOLOGY - Abstract
The carbonate clumped isotope (Δ47) thermometer has been widely used for paleoclimatic and paleo‐elevation reconstructions in sedimentary basins. Its reliable use requires that carbonates are free from later diagenetic alteration and retain their depositional Δ47 compositions, which is not always the case during the burial history of a basin. Therefore, identifying the alteration mechanisms that occurred during burial is essential for the correct interpretation of Δ47 signatures. In this study, we used the Δ47 thermometer to investigate possible carbonate alteration during burial of the Fenghuoshan Group (FHSG) in the Hoh Xil Basin, northern Tibetan Plateau, China. The Δ47 temperatures [T(Δ47)] of 30 carbonate samples through the ∼4.5 km thickness of the FHSG range from 51 to 132°C and exceed the surface temperature, implying the effects of thermal alteration on FHSG carbonates. The T(Δ47) values combined with the water‐rock exchange model, indicating that the alteration occurred under closed burial conditions at low water:rock ratios. The solid‐state reordering model fails to predict the Δ47 values, even with a modified time‐temperature history. In contrast, most measured Δ47 values are in agreement with predictions from recrystallization models. Therefore, the proposed alteration scenario is that FHSG carbonates underwent progressive microscale recrystallization during deep burial and subsequent exhumation, during which process recrystallized carbonate equilibrated with ambient burial temperature and therefore modified Δ47 values. This study highlights the potential of Δ47 thermometry and related models for evaluating the burial history and diagenesis of carbonates in sedimentary basins. Plain Language Summary: Carbonate clumped isotope composition (defined as Δ47) refers to the abundance of 13C–18O bonds in the carbonate, which is solely temperature dependent. This temperature dependence makes Δ47 a useful tool that can be used to obtain the carbonate formation temperature. However, the original Δ47 composition could be altered by either solid‐state reordering of C–O bonds or carbonate recrystallization during the burial history of sedimentary basin. Discriminating which alteration occurred during burial process is essential for the correct interpretation of Δ47 signature and the burial history. In this study, we measured Δ47 values of Fenghuoshan Group (FHSG) carbonates in the Hoh Xil Basin, northern Tibetan Plateau, China, and investigated their alteration during the burial history of FHSG by using the solid‐state reordering and recrystallization models. Our results indicate that FHSG carbonates underwent progressive microscale recrystallization during deep burial history, and the recrystallized carbonates recorded modified higher Δ47 temperatures. This study highlights the potential of Δ47 thermometry and related models for evaluating the burial history of sedimentary basins. Key Points: Clumped isotope temperatures of 51–132°C reflect thermal alteration during the burial history of the Fenghuoshan Group (FHSG)The alteration of FHSG carbonate Δ47 occurred in a late‐burial environment at a low water‐rock ratioFHSG carbonate underwent microscale recrystallization during burial and exhumation and eventually recorded high T(Δ47) [ABSTRACT FROM AUTHOR]
- Published
- 2021
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