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Combustion-derived black carbon (BC) is an important component of sedimentary carbon pool. Due to different physicochemical properties, determining the source of char and soot is crucial for BC cycling, especially for nonhomologous char and soot in the Tibetan Plateau (TP). This study analyzed the sequestration and source of BC, char, and soot in the Dagze Co (inner TP) sediment core via the content and δ 13 C, revealing the biomass and fossil fuel driving on nonsynchronous char and soot and their response to local anthropogenic activities and atmospheric transmission. The results showed that BC concentration increased from 1.19 ± 0.35 mg g -1 (pre-1956) to 2.03 ± 1.05 mg g -1 (after 1956). The variation of char was similar to BC, while nonhomologous growth was detected in char and soot ( r = 0.29 and p > 0.05). The source apportionment showed that biomass burning for 71.52 ± 10.23% of char and promoted char sequestration. The contribution of fossil fuel combustion to soot (46.67 ± 14.07%) is much higher than char (28.48 ± 10.23%). Redundancy analysis confirmed that local anthropogenic activities significantly influenced BC burial and atmospheric transport from outside TP-regulated BC burial. The contribution of biomass and fossil fuels to nonsynchronous char and soot is conducive to understanding the anthropogenic effect on BC burial in the TP.

Receptor models are a useful tool for identifying sources of polycyclic aromatic hydrocarbons (PAHs) in multiple environmental media. In this study, three different receptor models (including the principal component analysis-multiple linear regression (PCA-MLR), positive matrix factorization (PMF), and Unmix models) were used to apportion the sources of 16 priority PAHs in a sediment core of Lake Dagze Co. The ∑PAHs (sum of all 16 measured PAHs) concentrations ranged from 51.89 to 132.82 ng/g with an average of 80.39 ng/g. The ∑PAHs were dominated by 2-3 ring PAHs, accounting for 80.12% on average, thereby indicating that they mainly originated from biomass and coal combustion and/or from long-range atmospheric transportation. The three models produced consistent source apportionment results. The greatest contributor to ∑PAHs was biomass combustion, followed by coal combustion, vehicle emissions, and petrogenic sources. Moreover, the temporal variation of the common sources was well-correlated among models. The multi-method comparison and evaluation results showed that all three models were useful tools for source apportionment of PAHs, with the PMF model providing better results than the PCA-MLR and Unmix models. The temporal trends of factor contributions were verified by PAHs with different ring numbers. Significant correlations were found between the simulated concentrations of each source factor and the PAHs with different ring numbers (P<0.01), except for the petrogenic source identified by the Unmix model (P>0.05). This study can provide useful information for further investigation of source apportionment of PAHs in the sediment cores., (Copyright © 2022. Published by Elsevier B.V.)

Polycyclic aromatic hydrocarbons (PAHs) have received worldwide attention due to their potential teratogenic, persistent, and carcinogenic characteristics. In this study, the PAHs concentrations in two dated sediment cores taken from central Tibetan Plateau (TP) were analyzed to study the deposition history, potential sources, ecological risks, and influencing factors. Total concentration of PAHs (∑PAHs) ranged from 50.0 to 195 ng g -1 and 51.9-133 ng g -1 in sediments of Pung Co (PC) and Dagze Co (DZC), respectively. 2-3-ring PAHs were dominant in the two lake sediments, accounting for an average of 77.5% and 80.1%, respectively. The historical trends of ∑PAHs in the two lakes allowed to distinguish three periods, namely, relative stability before the 1950s, a gradual increase between the 1950s and the 1990s, and then a decline to the present-day. In addition, the trend in the concentration level of each PAH composition was consistent with ∑PAHs before the 1990s, while they exhibited different trends since the 1990s, which may be the result of a combination of anthropogenic activities and climate change in recent years, whereas before the 1990s the PAH profile was mainly influenced by atmospheric deposition. The results of source apportionment examined according to diagnostic ratios and positive matrix factorization were consistent and revealed that PAHs were primarily derived from biomass and coal combustion. Significant correlations between PAHs and organic carbon (OC) indicate that OC might be a key factor influencing the concentration of PAHs in sediments. The ecological risk assessment demonstrated that PAHs in TP sediments occurred at a low risk level. Results of this study could be helpful to develop a deeper insight into the deposition history of PAHs in remote lakes of the TP region and explore the response of these variations to climate change and human activities., (Copyright © 2022 Elsevier Ltd. All rights reserved.)