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Tricholorethylene (TCE) has been recognized as second common organic pollutant found in groundwater in Taiwan. Several advanced oxidation processes (AOPs) have been applied for TCE removal and photocatalytic is one of promising AOP techniques. In this study, LaFeO3 is successfully synthesized via sol-gel method and investigated for its photocatalytic oxidation rate toward TCE in water. Experimental results indicate that 95% removal efficiency of TCE can be achieved in aqueous solution with LaFeO3 (2 g/L) as photocatalyst within 1 h of Xenon lamp illumination. Additionally, the influences of initial TCE concentration, light intensity, photocatalyst loading, and pH value on the TCE removal efficiency are evaluated as well. The highest energy efficiency obtained in this study is 10.8 mg TCE/kWh and the value is higher than those reported in previous studies. Besides, removal mechanisms have been identified and the results indicate that the overall removal efficiency reaches 82%, with adsorption and photolysis accounting for 20% and 39%, respectively. [ABSTRACT FROM AUTHOR]

In this paper, a piezoelectric wave-energy converter (PWEC), consisting of a buoy, a frequency up-conversion mechanism, and a piezoelectric power-generator component, is developed. The frequency up-conversion mechanism consists of a gear train and geared-linkage mechanism, which converted lower frequencies of wave motion into higher frequencies of mechanical motion. The slider had a six-period displacement compared to the wave motion and was used to excite the piezoelectric power-generation component. Therefore, the operating frequency of the piezoelectric power-generation component was six times the frequency of the wave motion. The developed, flexible piezoelectric composite films of the generator component were used to generate electrical voltage. The piezoelectric film was composed of a copper/nickel foil as the substrate, lead–zirconium–titanium (PZT) material as the piezoelectric layer, and silver material as an upper-electrode layer. The sol-gel process was used to fabricate the PZT layer. The developed PWEC was tested in the wave flume at the Tainan Hydraulics Laboratory, Taiwan (THL). The maximum height and the minimum period were set to 100 mm and 1 s, respectively. The maximum voltage of the measured value was 2.8 V. The root-mean-square (RMS) voltage was 824 mV, which was measured through connection to an external 495 kΩ resistive load. The average electric power was 1.37 μW. [ABSTRACT FROM AUTHOR]